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Flame Spectra of Vanadium, Niobium, Rhenium, Titanium and Molybdenum

Description: Abstract Line spectra of vanadium, niobium, titanium, molybdenum and rhenium of sufficient intensity to allow detection at the 1–10 p.p.m. level can be excited in fuel-rich, oxy-acetylene flames. For the strongest lines of tungsten, the sensitivity of detection is 90 p.p.m. Weak lines of zirconium, hafnium, osmium, tantalum and uranium are also observed in these flames. Recordings of the spectra are given along with wavelength tables of the strongest lines.
Date: July 23, 1962
Creator: Fassel, Velmer A.; Myers, Robert B. & Kniseley, Richard N.
Partner: UNT Libraries Government Documents Department
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Cation Exchange in Acetone-Water-Hydrochloric Acid

Description: Abstract: Distribution coefficients have been measured for the partition of metal ions between cation exchange resin and acetone-water-hydrochloric acid solutions. the differences in distribution coefficients of metal ions are greater in acetone-water media than in aqueous media of the same hydrochloric acid concentration. Using distribution coefficient data, conditions for column separations of mixtures can be selected. Column separations of metal ion mixtures can be effected by eluting wit… more
Date: May 10, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Rettig, Thomas A.
Partner: UNT Libraries Government Documents Department
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Acid-Base Reactions and Kinetics of the Halates in Fused Nitrates

Description: From Abstract : "The mechanism of the reactions of the halates, bromate, chlorate, and iodate, with dichromate in fused alkali nitrates has been shown to involve a fast equilibrium followed by a slow rate determining strip to give oxygen and halogen gases as final products." Experiments outlined serve as insight into the structure of fused salts or fused electrolytes.
Date: November 1962
Creator: Schlegel, James Max & Duke, P. R.
Partner: UNT Libraries Government Documents Department
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Propagation Characteristics of Capillary Ripples, III. Capillary Ripple Velocity and Attenuation Dispersion on Clean Water Surfaces and on Various Monolayers

Description: From Abstract: "The theory and instrumentation previously described by us were applied to the systems monolayer-free distilled water; stearic acid, mixed hexadecanol and octadecanol and several long chain fatty ester monolayers; stearic acid - polyvinyl acetate mixed films and egg albumen spread films; heptanoic acid adsorbed monolayers."
Date: January 1962
Creator: Mann, J. Adiin, Jr. & Hansen, R. S.
Partner: UNT Libraries Government Documents Department
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Transport Reactions of Some Vanadium (III) Halides

Description: Technical report. From Abstract : "The reactions of VCl2. VCl3, and VCl3-VBr3 mixtures with bromine vapor at 350 to 450°C led to vaporization of the halides and deposition of mixed halides of vanadium (III) at lower temperatures."
Date: August 21, 1962
Creator: McCarley, Robert E.; Roddy, James W. & Berry, Keith O.
Partner: UNT Libraries Government Documents Department
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The Thallium-Indium Phase Diagram as a Function of Composition, Temperature, and Pressure

Description: Technical report. From Abstract : "The thallium-rich region of the thallium-indium phase diagram was determined from atmospheric pressure to 5.5 kbars primary from electrical resistivity data obtained as a function of composition, temperature, and pressure."
Date: August 21, 1962
Creator: Meyerhoff, Robert Wagner & Smith, J. F.
Partner: UNT Libraries Government Documents Department
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Phase Diagram and Thermodynamic Properties of the Yttrium-Zinc System

Description: Technical report. From Abstract : "Thermal, metallographic, and vapor pressure data were obtained to establish the phase boundaries and the standard free energy, enthalpy, and entropy of formation for the compounds in the yttrium-zinc system."
Date: July 27, 1962
Creator: Chiotti, P. & Mason, J. T.
Partner: UNT Libraries Government Documents Department
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Magnetization and Electrical Resistivity Terbium Single Crystals

Description: Technical report. From Abstract : "Magnetic moment measurements have been made on single crystals of terbium (hcp) with fields of 50 to 18,000 oe applied along the <1120> (a-axis), <1010> (b-axis), and <0001> (c-axis) directions. The temperature range covered was 1.4 to 500°K."
Date: August 23, 1962
Creator: Hegland, D. E.; Legvold, S. & Spedding, F. H.
Partner: UNT Libraries Government Documents Department
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Rare Earth Metal - Metal Halide Systems, Lanthanum, Cerium, and Praseodymium Bromides

Description: Technical report. From Abstract : "The MBr3 + M phase diagrams for lanthanum, cerium, and praseodymium are presented. Lanthanum and cerium exhibit simple solutions of metal, with 14 and 12 mole % dissolved at eutectic temperatures of 728 and 687°, respectively. The compound PrBr2.38 is found, melting incongruently to a solution of 16% Pr in PRBr3 and Pr(s) at 601°. For praseodymium the cryoscopic behavior of dilute solutions of metal is consistent with the primary formation of the Pr2+ solute. … more
Date: September 4, 1962
Creator: Sallach, Robert A. & Corbett, John D.
Partner: UNT Libraries Government Documents Department
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I. Niobium(IV) Bromide and Pyridine Adducts of the Niobium(IV) Halides

Description: Technical report. From Abstract : "Reaction of NbBr5 and niobium metal in a sealed tube under a temperature gradient from 410° to 350° gave NbBr4 in good yields. However, an increase in the higher temperature from 410° to 450° was sufficient to eliminate NbBr4 as a product and cause deposition of a lower bromide."
Date: September 5, 1962
Creator: McCarley, Robert E. & Torp, Bruce A.
Partner: UNT Libraries Government Documents Department
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The Preparation of TaBr4, TaI4 and Pyridine Adducts of the Tantalum(IV) Halides

Description: Technical report. From Abstract : "The necessary conditions for preparation of TaBr4 and TaI4 by reduction of the pentahalides with tantalum or aluminum metal in a sealed tube under a controlled temperature gradient have been demonstrated."
Date: September 5, 1962
Creator: McCarley, R. E. & Boatman, J. C.
Partner: UNT Libraries Government Documents Department
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Calcium

Description: Technical report outlining the element calcium as well as its occurrences, physical properties, chemical properties, methods of manufacture, economic aspects, and uses.
Date: September 1962
Creator: Carlson, O. N. & Haefling, J. A.
Partner: UNT Libraries Government Documents Department
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Boiling Points and Surface Tensions of Mixtures of Benzyl Acetate With Dioxan, Aniline and Meta-Cresol

Description: Technical report. From Abstract : "Accurate measurements on boiling points and surface tensions of mixtures of benzyl acetate with dioxan, aniline and meta-cresol over the entire range of concentration are reported. The results have been analysed in terms of quasi-crystalline model which is partially successful in representing the composition dependence of heats of mixing, boiling points and surface tension except for composition dependence of boiling points of benzyl acetate and meta-cresol."
Date: September 13, 1962
Creator: Katti, P. K. & Chaudhri, M. M.
Partner: UNT Libraries Government Documents Department
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X-Ray Analytical Spectroscopy of the Rare Earths

Description: Technical report. From Abstract : "The term 'rare earths' is the classic name given to the group of elements with atomic numbers 57 to 71. The element yttrium is usually included in this group. The chemical properties of these elements are so strikingly similar that they always occur together in nature and their separation from each other is a singularly difficult task. With but few exceptions, mixtures of these elements have also defied analysis by classical methods of analytical chemistry. Co… more
Date: September 1962
Creator: Heidel, Robert H. & Fassel, Velmer A.
Partner: UNT Libraries Government Documents Department
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Magnetic Properties of Some Intra-Rare Earth Alloys

Description: Technical report. From Abstract : "Paramagnetic susceptibilities of samarium structure alloys in the systems La-Gd, Nd-Y, Nd-Tm, and Ce-Y were measured from 4.2 - 300°K to determine what effect the formation of this structure has on the magnetic properties of the alloys. Susceptibility maxima were observed in the Nd-Y and Nd-Tm alloys, at 34.5 and 28.5°K, respectively. Slope changes were observed in the curve of 1/x versus T for the La-Gd alloy at 155 and 130°K, and the susceptibility of this a… more
Date: September 10, 1962
Creator: Roughan, P. E. & Deane, A. H.
Partner: UNT Libraries Government Documents Department
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III. Crystalline Complexes of Bis(Di-2-Ethylbutylphosphinyl) Methahe With Uranium(VI) Nitrate and With Thorium Nitrate

Description: Technical report. From Abstract : "Bis(di-2-ethylbutylphosphinyl)methane, EBDPM, forms complexes with uranium (VI) nitrate and thorium (IV) nitrate in which EBDPM acts as a bidentate ligand and the nitrato groups appear to be coordinated. The complex with uranium (VI) is a monomer, UO2(NO3)29EBDPM), while the complex with thorium in a dimer, [Th(NO3)4]2(EBDPM)3. Both complexes are of high thermal stability."
Date: October 16, 1962
Creator: Parker, James R. & Banks, Charles V.
Partner: UNT Libraries Government Documents Department
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Separation and Spectrophotometric Determination of Rare Earths

Description: Technical report. From Summary : "At the present time arsenazo appears to be widely used for the spectrophotometric determination of rare earths. Unfortunately, the method is not selective. The separation of rare earths and yttrium from interfering elements has been studied, and the following method has been proposed. Rare earths are precipitated as fluorides using fluorides using calcium fluoride as the carrier. Thorium and zirconium are removed by extraction with thenoyltrifluoroacetone (TTA)… more
Date: October 18, 1962
Creator: Onishi, Hiroshi & Banks, Charles V.
Partner: UNT Libraries Government Documents Department
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The Enhancement of Acidity of Very Weak Acids in Tertiary Butyl Alcohol

Description: Technical report. From Abstract : "The acidity of a solution of acid, HX, and salt, MX, is affected by both the concentration of X- and M+ owing to incomplete dissociation of the salt, MX. it was possible to increase the acidity of a solution of 2,6-di-tert-butylphenol - tetrabutylammonium 2,6-di-tert-butylphenolate relative to a dilute solution of tetrabutylammonium hydroxide by increasing the tetrabutylammonium bromide content. This indicates that the dissociation constant of the hydroxide ba… more
Date: October 22, 1962
Creator: Marple, Leland & Fritz, J. S.
Partner: UNT Libraries Government Documents Department
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Study of Metal-1.10-Phenanthroline Complex Equilibria by Potentiometric Measurement

Description: Technical report. From Abstract : "The silver-1,10-phenanthroline system has been studied and the stability constants determined for the 1:1 and 2:1 complexes using the silver electrode. This known system was then used to study the complexes of 1,10-phenanthroline with other metals. The log βn values found for the over-all stoichiometric stability constants are as follows: Ag, 5.02, 12.07; Mn, 3.88, 7.04, 10.11; Cd, 5.93, 10.52, 14.30; Zn, 6.83, 12.05, 16.92. The stoichiometric stability consta… more
Date: October 25, 1962
Creator: Dale, John M. & Banks, Charles V.
Partner: UNT Libraries Government Documents Department
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The Scandium-Yttrium and Scandium-Zirconium System

Description: Technical report. From Abstract : "The scandium-yttrium and scandium-zirconium were studied by thermal and x-ray methods. Both systems are characterized by complete solid solubility in the low temperature hexagonal form and in the high temperature bcc form. In the Sc-Y system, there is a minimum in the solidus at 50 at. pct and 1365°C, while the solidus in the Sc-Zr system follows a nearly straight line relationship between the melting point of scandium and zirconium. There is a minimum in the … more
Date: October 26, 1962
Creator: Beaudry, B. J. & Daane, A. H.
Partner: UNT Libraries Government Documents Department
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The Weighting of Intensities

Description: Technical report. From report : "The method of least squares refinement is based on the prediction of the theory of errors that, if the errors of the observed structure factors follow the Gaussian distribution, the most nearly correct atomic parameters will be those which result in the minimization of the residual R = Σi [√wi(|Fo| - |Fc|)i]2."
Date: December 13, 1962
Creator: Hershaft, Alex & Corbett, John D.
Partner: UNT Libraries Government Documents Department
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The Crystal Structure of Bis(Meta-Chlorobenzoyl) Methane

Description: Technical report. From Abstract : "The crystal structure of bis(meta-chlorobenzoyl) methane has been determined by three dimensional anisotropic least squares refinement of scintillation counter data. The molecule was found to be nearly planar with a maximum deviation from the least squares molecular plane of 0.068Å and an average deviation of 0.023Å. Fourier transform techniques to locate phenyl rings provided the key to the structure determination. The intramolecular bond distances and therma… more
Date: December 13, 1962
Creator: Engebretson, Gordon R. & Rundle, R. E.
Partner: UNT Libraries Government Documents Department
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Crystal Structure of Bis (Meta-Chlorobenzoyl) Methane

Description: Technical report. From Abstract : "The determination of the crystal structure of bis(meta-chlorobenzoyl)-methane was undertaken by x-ray methods in an effort to clarify the ambiguous position of the hydrogen atom on the enolic form of β - diketones and hence in intramolecular hydrogen bonds."
Date: November 1962
Creator: Engebretson, Gordon Roy & Rundle, R. E.
Partner: UNT Libraries Government Documents Department
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Angular Distribution of Relativistic Atomic K-Shell Photoelectrons

Description: From abstract: "Using the high energy limit of the exact Coulomb wave function for the outgoing electron, the differential cross section, correct to three orders in aZ, is calculated for the K-shell photoeffect. An analytic expression, exact in aZ, is obtained for the differential cross section for the special case in which the electron emerges in the forward direction."
Date: 1962
Creator: Weber, T. A. & Mullin, C. J.
Partner: UNT Libraries Government Documents Department
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