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Solid State Division Semiannual Progress Report For Period Ending February 28, 1955

Description: This semiannual progress report and future reports will be published as two documents to permit a wider distribution of the unclassified material. The report numbers are assigned in sequence so that the two reports will fall together when filed by report number.
Date: July 12, 1960
Creator: Billington, D. S. & Crawford, J. H., Jr.
Partner: UNT Libraries Government Documents Department
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The Oak Ridge National Laboratory Research Reactor Safeguard Report

Description: The proposed ORNL Research Reactor is designed to serve as a general purpose research tool delivering a maximum thermal flux of 8x10^13 n/cm2-sec at the initial power level of five megawatts. Operation at power levels up to ten megawatts is proposed for such items as sufficient cooling capacity is available to handle the increased heat load. The reactor will use MTR-type fuel elements and beryllium reflector pieces in a 7 x 9 grid with moderation and cooling provided by forced circulation of de… more
Date: October 7, 1954
Creator: Binford, F. T.; Cole, T. E. & Gill, J. P.
Partner: UNT Libraries Government Documents Department
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The Oak Ridge National Laboratory Research Reactor Safeguard Report

Description: This memorandum sets forth a recommended uniform basis for designing the ORN shield.This includes design values for power level and emergent radiation, standards values for various material properties, and basic radiation intensities.
Date: October 7, 1954
Creator: Binford, F. T.; Cole, T. E. & Gill, J.P.
Partner: UNT Libraries Government Documents Department
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The Extraction and Recovery of Uranium (and Vanadium) from Acidic Liquors with DI (2-Ethylhexyl) Phosphoric Acid and Some Other Organophosphorus Acids

Description: Bench scale studies have been made of the recovery of uranium from acid leach liquors (and slurries) by solvent extracting with di (2-ethylhexyl) phosphoric acid in an organic diluent. Uranium may be stripped from the organic solvent by either alkaline or acidic reagents, the former having been studied in greater detail. On the basis of these tests, a recovery process may be considered which shows promise both from the standpoint of operation and chemical costs. Under proper conditions, vanadiu… more
Date: May 13, 1955
Creator: Blake, C. A.; Brown, K. B.; Coleman, C. F.; Horner, D. E. & Schmitt, J. M.
Partner: UNT Libraries Government Documents Department
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Hexone Extraction-Coulometric Titration of Uranium

Description: Samples containing 5 to 10 mg of uranium were extracted with hexone (methyl isobutyl ketone) and titrated coulometrically in sulphate media. Relative standard deviations of 0.45% for samples containing 5 mg and 0.56% for 10 mg were determined by precision studies.
Date: June 22, 1959
Creator: Blevins, E. L.
Partner: UNT Libraries Government Documents Department
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Aqueous Uranium Slurry Studies

Description: A summary of the laboratory development program on aqueous uranium slurry fuels for the Homogenous Reactor Project during the period April 1951 through March 1953 is presented. These investigations were devoted primarily to a study of the uranium oxides in aqueous suspensions. It was concluded that U(VI) was most likely to be the stable valence state in such slurry fuels and it was shown that β-UO3·H2O platelet crystals were the stable modification at 250°C. Very pure slurries of β-UO3·H2O pla… more
Date: October 20, 1955
Creator: Blomeke, J. O.; Bamberg, J. L.; Blomeke, J. O.; Bruce, F. R.; Fulmer, J. M.; McBride, J. P. et al.
Partner: UNT Libraries Government Documents Department
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Stress-Corrosion Cracking Problems in the Homogeneous Reactor Test

Description: Chloride-induced stress-corrosion cracking has been encountered in the Homogeneous Reactor Test during the preliminary testing. The rector is constructed of austenitic stainless steels. It is unique in that it will operate at 250 to 300 C with an aqueous uranyl sulfate solution fuel containing 200 to 500 ppm of dissolved oxygen. The cracking has occurred in a secondary system used for detecting leaks in the flanged joints of the primary systems and in the grooves of flanges in the primary syste… more
Date: January 31, 1957
Creator: Bohlmann, E. G. & Adamson, G. M.
Partner: UNT Libraries Government Documents Department
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A Preliminary Survey of Radioactive Constituents in Rainwater at ORNL

Description: Technical report surveying radio-chemical analyses by ORNL's Analytical Chemistry Division and Health-Physics Division of large volumes of rainwater for plutonium, uranium, and fission products. Overall, carrying efficiencies for Al(OH)3 scavenging of rainwater were determined for these elements, as well as for Pu and U. [From Abstract, Introduction]
Date: December 4, 1950
Creator: Booksbank, W. A., Jr.; Emmons, A. H.; Gost, J. W. & Reynolds, S. A.
Partner: UNT Libraries Government Documents Department
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The Rate of Uranium Sorption by a Strong-Base Anion-Exchange Resin

Description: The rate of uranium sorption by a strong-base anion-exchange resin (Dovex 21K) from a uranyl sulfate solution (U 0.005 M, H2SO4 0.02M, SO4 0.2 M) was studied using a stirred vessel technique and measuring the U235 gamma radiation on each bead. Resin initially in the chloride form and the sulfate for was studied.
Date: July 8, 1959
Creator: Bresee, J. C.
Partner: UNT Libraries Government Documents Department
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Unit Operations Section Monthly Progress Report May 1959

Description: The measured diffusivity of uranyl nitrate in water at 25ºC was 0.7*10^e cm^2/sec with about 40% average deviation. A program was started to develop nonnuclear uses for depleted uranium. Two continuous DRUHM reaction tuns were terminate due to erratic operation of the sodium metering system. In the second Fluorox run with crude UF, which lasted for 29 hr, a total material balance of 94.8% was obtained and 17.9& of the theoretical amount of UF was collected in cold traps and chemical traps.
Date: August 25, 1959
Creator: Bresee, J. C.; Haas, P. A.; Horton, R. W.; Watson, C. D. & Whatley, M. E.
Partner: UNT Libraries Government Documents Department
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Unit Operations Section Monthly Progress Report June 1959

Description: The addition of a surface active agent to an aqeous-organic interface produced a resistance to mass transfer equivalent to slightly more than 1 cm of water. Five semicontinuous Druhm runs were made with 1/2in. thick MgO liners and terminated due to either failures of the UFe nozzle or a top gasket leak. In preliminary scale-up tests of the flame calcination equipment, a maximum feed rate equivalent to 720 g oxides/hr was achieved using a 3-in. i.d. magnesia reflector with an outside wall temper… more
Date: September 4, 1959
Creator: Bresee, J. C.; Haas, P. A.; Watson, C. D.; Whatley, M. E. & Horton, R. W.
Partner: UNT Libraries Government Documents Department
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Unit Operations Section Monthly Progress Report July 1959

Description: A Lucite model of a multi-stage countercurrent hydroclone solvent extraction apparatus has been constructed and tested with Amsco-water. The diffusivity of Cs 134 tracer in aqueous chloride solution was measured to check the performance of the capillary diffusivity measuring system. The experimental data from four Druhm runs showed that 1/8in. thick graphite liners are usable for reactor temperatures above the boiling point of sodium.
Date: October 9, 1959
Creator: Bresee, J. C.; Haas, P.A.; Horton, R. W.; Watson, C. D. & Whatley, M. E.
Partner: UNT Libraries Government Documents Department
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The Development of a Fluidized Bed Reactor for the Fluorox Process: Unit operations Monthly Status Reports for the Period November, 1958, Through May, 1959

Description: Results of four experiemental runs in the Fluorox fluidized bed reactor system are reported. The engineering feasibility of UF6 production from UF4 by use of dry air of O2, 2UF4 + O2 = UF6 + UO2F2, in an Inconel fluidized bed reactor at 800-850°C was demonstrated in two experimental tests in which greater than 90% of the theoretical amount of UF6 was collected or measured. Two runs made with crude UF4 (produced from unpurified mill concentrate) as the feed material, showed that UF6 could be pro… more
Date: May 26, 1959
Creator: Bresee, J. C.; Scott, C. D. & Horton, R. W.
Partner: UNT Libraries Government Documents Department
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ORNL Mortal Recovery Plant: Processing of ORNL Graphite Reactor Fuel Elements During the Period July and August, 1955

Description: From July 7 to August 31, 1955, 20 tons of uranium and 1,200 g of plutonium were recovered in 47 days of plant operation at an average rate of 833 lb/day of uranium and at a cost of $2.60/lb of uranium. Uranium and plutonium recoveries were, respectively, 99.9 and 95.5 per cent.
Date: November 11, 1955
Creator: Brooksbank, R. E.; Chandler, J. M. & Hylton, C. D.
Partner: UNT Libraries Government Documents Department
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Chemical Development Section C Progress Report for October-November 1960

Description: Studies are being made on the recovery of thorium (and uranium) from granitic rock, since this source represents a very large potential thorium reserve for the nuclear power industry. In preliminary leaching studies on 16 granite samples (containing 8-95 ppm thorium and 1.5-16 ppm uranium), maximum recoveries of thorium and uranium ranged 30-85% and 15-65% respectively, and sulfuric acid consumption was high (30-120 lbs H2SO4 per ton of granite). A relatively high acidity was needed to obtain r… more
Date: March 3, 1961
Creator: Brown, K. B.
Partner: UNT Libraries Government Documents Department
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Progress Report for August-September 1960

Description: A chemical flowsheet is proposed for recovery of strontium and rare earths from Purex wastes. The iron in the waste is first complexed with tartrate and the pH is adjusted with caustic. Strontium and rare earths are extracted by a solvent comprised of di(2-ethylhexyl)phosphoric--sodium di (2-ethylhexyl) phosphate--tributyl phosphate -- Amsco 125-82. and are stripped with nitric acid. Processing the strip product through additional solvent extraction cycles yields isolated, concentrated strontiu… more
Date: December 29, 1960
Creator: Brown, K. B.
Partner: UNT Libraries Government Documents Department
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Chemical Development Section C Monthly Progress Report July 1959

Description: Nitrate contained in raffinates from Canadian Blind River mills interferes seriously with thorium extraction by secondary amines. With primary amines, however, the effect is negligible and these compounds are the preferred process extractants.
Date: August 5, 1959
Creator: Brown, K. B.; Allen, K. A.; Blake, C. A.; Coleman, C. F.; Crouse, D. J.; Ryon, A. D. et al.
Partner: UNT Libraries Government Documents Department
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Chemical Development Section C Monthly Progress Report August 1959

Description: Uranium extractions from carbonate solutions were effective and phase separation rates were rapid using a new commercial quaternary extractant, Alamine 336. Extraction coefficients were approximately proportional to the quaternary concentration. Addition of -0.5 mole tridecanol/mole quaternary to the solvent gave optimum extraction efficiency and phase separation rates.
Date: September 8, 1959
Creator: Brown, K. B.; Allen, K. A.; Coleman, C. F.; Crouse, D. J. & Ryon, A. D.
Partner: UNT Libraries Government Documents Department
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Removal of Fission Product Gases from reactor Off-Gas Streams by Adsorption (Presented at American Nuclear Society Meeting, Detroit, Michigan, December 10, 1958)

Description: In the operation of nuclear reactors, nuclear fuel reprocessing plants and in-pile experiments, special provision must be made for disposal of gaseous fission products to prevents contamination of the atmosphere to an unacceptable degree. A disposal process is described in which the noble gas fission products, krypton and xenon, are delayed relative to the sweep gas by physical adsorption as they pass through an adsorbent such as activated charcoal. A theoretical plate analysis, and has been ve… more
Date: June 11, 1959
Creator: Browning, W. E.; Adams, R. E. & Ackley, R. D.
Partner: UNT Libraries Government Documents Department
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Status and Future Program of Homogeneous Reactor Fuel Processing Studies

Description: The behavior of insoluble corrosion products in the HRT is generally understood and studies of the removal of these solids by hydroclones can logically be terminated after the effect of higher processing rates by the multiple hydroclone has been determined. Chemical descaling may be required to supplement solids removal by hydroclones. Laboratory studies to find suitable reagents will be continued in conjunction with decontamination work presently in progress.
Date: June 17, 1959
Creator: Burch, W. D.; Haas, P. A. & McNees, R. A.
Partner: UNT Libraries Government Documents Department
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The Isolation and Purification of Americium

Description: Gram amounts of americium were separated quantitatively from kilogram quantities of lanthanum to yield an americium product approaching 90% purity. The remaining impurity was chiefly yttrium. Elution of americium from 25% loaded Dowex 50 resin column with 0.15 M citric acid— 0.10 M diammonium citrate — 0.3 M ammonium nitrate, pH 3.3 gave a product containing 99% of the americium with a La/Am ratio of 1/100 or less in one fourth of a column volume, in this case about 1 100-fold volume reduction.… more
Date: April 17, 1956
Creator: Campbell, D. O.
Partner: UNT Libraries Government Documents Department
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The Effects of Reactor Irradiation of Thorium-Uranium Alloy Fuel Plates

Description: Several plates of 98.7% Th - 1.2% U 235 (clad in aluminum) were irradiated in the MTR for an integrated flux of 2.6 x 10 21 neutrons/cm2. Although these samples represent an early development in bonding of aluminum to thorium and there are better methods at present, the bond proved to be quite strong and both clad and core were dimensionally stable under irradiation. The production of uranium 233 was as much as theory would indicate and the total amount of fissionable material material after ir… more
Date: September 7, 1955
Creator: Carrell, R. M.
Partner: UNT Libraries Government Documents Department
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Uranium Recovery for Spent Fuel by Dissolution in Fused Salt and Fluorination

Description: A promising nonaqueous process for the recovery of uranium from spent fuel elements is under development at Oak Ridge National Laboratory. This process consists of dissolution of the fuel element in a fluoride melt by hydrofluorination at 600 to 700°C, direct fluorination with fluorine for the production and volatilization of UF6, with further decontamination of the product UF6 from fission product activity being secured in a NaF absorption-desorption step. Good decontamination is obtained in t… more
Date: January 29, 1957
Creator: Cathers, G. I.
Partner: UNT Libraries Government Documents Department
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