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The Vapor Pressures of VCl2, VCl3, VBr2, and VBr3 by Knudsen Effusion

Description: Technical report. From Abstract : "The vapor pressures of crystalline VCl2, VBr2, VCl3 and VBr3 have been measured by the Knudsen effusion method using pyrex and Vycor effusion cells. ... During the measurements on VCl3 and VBr3 dissociation and disproportionation of the samples occurred simultaneously with the simple vaporization. However, because the product of each of these processes was collected separately during an experiment, the vapor pressure due to sublimation was obtained without difficulty."
Date: August 21, 1962
Creator: McCarley, R. E. & Roddy, J. W.
Partner: UNT Libraries Government Documents Department

Transport Reactions of Some Vanadium (III) Halides

Description: Technical report. From Abstract : "The reactions of VCl2. VCl3, and VCl3-VBr3 mixtures with bromine vapor at 350 to 450°C led to vaporization of the halides and deposition of mixed halides of vanadium (III) at lower temperatures."
Date: August 21, 1962
Creator: McCarley, Robert E.; Roddy, James W. & Berry, Keith O.
Partner: UNT Libraries Government Documents Department

The Thallium-Indium Phase Diagram as a Function of Composition, Temperature, and Pressure

Description: Technical report. From Abstract : "The thallium-rich region of the thallium-indium phase diagram was determined from atmospheric pressure to 5.5 kbars primary from electrical resistivity data obtained as a function of composition, temperature, and pressure."
Date: unknown
Creator: Meyerhoff, Robert Wagner & Smith, J. F.
Partner: UNT Libraries Government Documents Department

Phase Diagram and Thermodynamic Properties of the Yttrium-Zinc System

Description: Technical report. From Abstract : "Thermal, metallographic, and vapor pressure data were obtained to establish the phase boundaries and the standard free energy, enthalpy, and entropy of formation for the compounds in the yttrium-zinc system."
Date: July 27, 1962
Creator: Chiotti, P. & Mason, J. T.
Partner: UNT Libraries Government Documents Department

Propagation Characteristics of Capillary Ripples II. Instrumentation for Measurement of Ripple Velocity and Amplitude

Description: Technical report. From Abstract : "An instrument for measuring the propagation velocity of capillary ripples to within 0.3% and for measuring the amplitude of such ripples to within 1 to 10% (depending upon amplitude) was designed and constructed. The principle components of the instrument were a Teflon Langmuir trough (with provision for automatic recording of compression data); generating and receiving probes consisting of a thin rod and a razor blade respectively mounted so that the rod and razor edge were parallel and accurately placed in the surface to be studied."
Date: January 1963
Creator: Mann, J. Adin, Jr. & Hansen, R. S.
Partner: UNT Libraries Government Documents Department

I. Niobium(IV) Bromide and Pyridine Adducts of the Niobium(IV) Halides

Description: Technical report. From Abstract : "Reaction of NbBr5 and niobium metal in a sealed tube under a temperature gradient from 410° to 350° gave NbBr4 in good yields. However, an increase in the higher temperature from 410° to 450° was sufficient to eliminate NbBr4 as a product and cause deposition of a lower bromide."
Date: September 5, 1962
Creator: McCarley, Robert E. & Torp, Bruce A.
Partner: UNT Libraries Government Documents Department

The Preparation of TaBr4, TaI4 and Pyridine Adducts of the Tantalum(IV) Halides

Description: Technical report. From Abstract : "The necessary conditions for preparation of TaBr4 and TaI4 by reduction of the pentahalides with tantalum or aluminum metal in a sealed tube under a controlled temperature gradient have been demonstrated."
Date: September 5, 1962
Creator: McCarley, R. E. & Boatman, J. C.
Partner: UNT Libraries Government Documents Department

Magnetization and Electrical Resistivity Terbium Single Crystals

Description: Technical report. From Abstract : "Magnetic moment measurements have been made on single crystals of terbium (hcp) with fields of 50 to 18,000 oe applied along the <1120> (a-axis), <1010> (b-axis), and <0001> (c-axis) directions. The temperature range covered was 1.4 to 500°K."
Date: August 23, 1962
Creator: Hegland, D. E.; Legvold, S. & Spedding, F. H.
Partner: UNT Libraries Government Documents Department

Rare Earth Metal - Metal Halide Systems, Lanthanum, Cerium, and Praseodymium Bromides

Description: Technical report. From Abstract : "The MBr3 + M phase diagrams for lanthanum, cerium, and praseodymium are presented. Lanthanum and cerium exhibit simple solutions of metal, with 14 and 12 mole % dissolved at eutectic temperatures of 728 and 687°, respectively. The compound PrBr2.38 is found, melting incongruently to a solution of 16% Pr in PRBr3 and Pr(s) at 601°. For praseodymium the cryoscopic behavior of dilute solutions of metal is consistent with the primary formation of the Pr2+ solute. But with lanthanum and cerium the results are anomalous, as the cryoscopic analyses indicate 1.6-1.7 and 2.0 new particles (cation basis) per metal dissolved instead of ~3."
Date: September 4, 1962
Creator: Sallach, Robert A. & Corbett, John D.
Partner: UNT Libraries Government Documents Department

Calcium

Description: Technical report outlining the element calcium as well as its occurrences, physical properties, chemical properties, methods of manufacture, economic aspects, and uses.
Date: September 1962
Creator: Carlson, O. N. & Haefling, J. A.
Partner: UNT Libraries Government Documents Department

Study of Metal-1.10-Phenanthroline Complex Equilibria by Potentiometric Measurement

Description: Technical report. From Abstract : "The silver-1,10-phenanthroline system has been studied and the stability constants determined for the 1:1 and 2:1 complexes using the silver electrode. This known system was then used to study the complexes of 1,10-phenanthroline with other metals. The log βn values found for the over-all stoichiometric stability constants are as follows: Ag, 5.02, 12.07; Mn, 3.88, 7.04, 10.11; Cd, 5.93, 10.52, 14.30; Zn, 6.83, 12.05, 16.92. The stoichiometric stability constants determined for copper are log k2 = 6.42 and log k2k3 = 11.05."
Date: October 25, 1962
Creator: Dale, John M. & Banks, Charles V.
Partner: UNT Libraries Government Documents Department

III. Crystalline Complexes of Bis(Di-2-Ethylbutylphosphinyl) Methahe With Uranium(VI) Nitrate and With Thorium Nitrate

Description: Technical report. From Abstract : "Bis(di-2-ethylbutylphosphinyl)methane, EBDPM, forms complexes with uranium (VI) nitrate and thorium (IV) nitrate in which EBDPM acts as a bidentate ligand and the nitrato groups appear to be coordinated. The complex with uranium (VI) is a monomer, UO2(NO3)29EBDPM), while the complex with thorium in a dimer, [Th(NO3)4]2(EBDPM)3. Both complexes are of high thermal stability."
Date: October 16, 1962
Creator: Parker, James R. & Banks, Charles V.
Partner: UNT Libraries Government Documents Department

Separation and Spectrophotometric Determination of Rare Earths

Description: Technical report. From Summary : "At the present time arsenazo appears to be widely used for the spectrophotometric determination of rare earths. Unfortunately, the method is not selective. The separation of rare earths and yttrium from interfering elements has been studied, and the following method has been proposed. Rare earths are precipitated as fluorides using fluorides using calcium fluoride as the carrier. Thorium and zirconium are removed by extraction with thenoyltrifluoroacetone (TTA) in xylene at pH 1.3. Small amounts of residual aluminum, iron, etc. are removed by extraction with 8-quinolinolchloroform at pH 4.5. Rare earths are separated from calcium by TTA extraction at the same pH, and they are then back-extracted into 1 M nitric acid. After evaporation of the solution, the rare earths are determined spectrophotometrically with arsenazo."
Date: October 18, 1962
Creator: Onishi, Hiroshi & Banks, Charles V.
Partner: UNT Libraries Government Documents Department

X-Ray Analytical Spectroscopy of the Rare Earths

Description: Technical report. From Abstract : "The term 'rare earths' is the classic name given to the group of elements with atomic numbers 57 to 71. The element yttrium is usually included in this group. The chemical properties of these elements are so strikingly similar that they always occur together in nature and their separation from each other is a singularly difficult task. With but few exceptions, mixtures of these elements have also defied analysis by classical methods of analytical chemistry. Consequently for the analysis of ores, minerals, and mixtures obtained from fractionation processes, and for the assessment of the purity of isolated elements, it has been necessary to resort to measurements on physical properties. Of these properties, emission and absorption spectra of these elements have found the widest application."
Date: September 1962
Creator: Heidel, Robert H. & Fassel, Velmer A.
Partner: UNT Libraries Government Documents Department

The Enhancement of Acidity of Very Weak Acids in Tertiary Butyl Alcohol

Description: Technical report. From Abstract : "The acidity of a solution of acid, HX, and salt, MX, is affected by both the concentration of X- and M+ owing to incomplete dissociation of the salt, MX. it was possible to increase the acidity of a solution of 2,6-di-tert-butylphenol - tetrabutylammonium 2,6-di-tert-butylphenolate relative to a dilute solution of tetrabutylammonium hydroxide by increasing the tetrabutylammonium bromide content. This indicates that the dissociation constant of the hydroxide base is sufficiently large that extensive dissociation occurs in dilute solutions. The addition of tetrabutylammonium bromide is therefore recommended as a general method for increasing the acidity and improving the titration characteristics of extremely weak acids."
Date: October 22, 1962
Creator: Marple, Leland & Fritz, J. S.
Partner: UNT Libraries Government Documents Department

Magnetic Properties of Some Intra-Rare Earth Alloys

Description: Technical report. From Abstract : "Paramagnetic susceptibilities of samarium structure alloys in the systems La-Gd, Nd-Y, Nd-Tm, and Ce-Y were measured from 4.2 - 300°K to determine what effect the formation of this structure has on the magnetic properties of the alloys. Susceptibility maxima were observed in the Nd-Y and Nd-Tm alloys, at 34.5 and 28.5°K, respectively. Slope changes were observed in the curve of 1/x versus T for the La-Gd alloy at 155 and 130°K, and the susceptibility of this alloy remained temperature-independent from 130-7°K. A rather poorly defined region of constant susceptibility was also observed or the Ce-Y alloy, from 26-37°K. Above these transition temperatures, the alloys obeyed the Curie-Weiss law, the susceptibilities of the La-Gd and Ce-Y samples indicating the possibility of electron transfer occurring in these cases."
Date: September 10, 1962
Creator: Roughan, P. E. & Deane, A. H.
Partner: UNT Libraries Government Documents Department

The Weighting of Intensities

Description: Technical report. From report : "The method of least squares refinement is based on the prediction of the theory of errors that, if the errors of the observed structure factors follow the Gaussian distribution, the most nearly correct atomic parameters will be those which result in the minimization of the residual R = Σi [√wi(|Fo| - |Fc|)i]2."
Date: December 13, 1962
Creator: Hershaft, Alex & Corbett, John D.
Partner: UNT Libraries Government Documents Department

Process Simulation on a Digital Computer Using Analog Methods

Description: Technical report. From Abstract : "A system has been developed to program a digital computer in much the same manner as an analog computer is programmed. Properties of a general purpose analog computer and a digital differential analyzer are combined to yield a program which employs, as input, standard data cards prepared from a diagram analogous to an analog computer diagram. The capacity of the system is much greater than that of most analog computers, making it applicable to large simulation problems. No scaling is required. The system is compatible with the Fortran symbolic language and may be used as part of a larger digital computer program. It may be applied to the more general types of boundary value problems arising in process simulation in addition to the initial value problems ordinarily solved on analog computers. It is particularly well adapted to non-linear problems and to control problems involving large transport delays. The program operates in basic machine language and, when used by itself, requires no compilation time."
Date: July 10, 1963
Creator: Farris, George J. & Burkhart, Lawrence E.
Partner: UNT Libraries Government Documents Department

An Experimental Approach to a Simplified Band Structure of the Rare Earth Metals

Description: Technical report. From Abstract : "A number of the physical properties from which we can obtain both direct and indirect information concerning the band structures of metals, have been measured for most of the rare earth metals. It was thought that it would be desirable to review ans examine these data and try to tie them together. For this purpose the very low and room temperature heat capacities, Hall coefficients, magnetic susceptibilities, spectral data and electrical resistivities were examined."
Date: unknown
Creator: Gschneider, Karl A., Jr.
Partner: UNT Libraries Government Documents Department

The Y-Nd and Sc-Nd Phase Systems

Description: Technical report. From Introduction : "In a recent study by Spedding, et al. on some rare earth alloy systems, an intermediate phase was found to form when a light rare earth (ABAC stacking) was alloyed with a heavy rare earth (ABAC stacking). This intermediate phase was found to have the structure of samarium metal with the stacking ABABCBCAC and was designated "delta". Since the cause of this rather unusual structure occurring in either samarium metal or these alloys is not known the study of these phases as some of their properties is continuing in the Ames Laboratory. It was the purpose of the present study to extend our knowledge of the composition and more of formation of these phases."
Date: February 1964
Creator: Beaudry, B. J.; Michel, M.; Daane, A. H. & Spedding, F. H.
Partner: UNT Libraries Government Documents Department

The Isotope Shift of the Uranium Ka1 X Ray

Description: Technical report. From Introduction : "The nuclear volume dependent isotope shift of optical spectral lines has long been a very useful means for studying the changes in the nuclear size or shape for different isotopes of heavy elements."
Date: June 25, 1964
Creator: Brockmeier, R.; Boehm, F. & Hatch, E. N.
Partner: UNT Libraries Government Documents Department

Boiling Points and Surface Tensions of Mixtures of Benzyl Acetate With Dioxan, Aniline and Meta-Cresol

Description: Technical report. From Abstract : "Accurate measurements on boiling points and surface tensions of mixtures of benzyl acetate with dioxan, aniline and meta-cresol over the entire range of concentration are reported. The results have been analysed in terms of quasi-crystalline model which is partially successful in representing the composition dependence of heats of mixing, boiling points and surface tension except for composition dependence of boiling points of benzyl acetate and meta-cresol."
Date: September 13, 1962
Creator: Katti, P. K. & Chaudhri, M. M.
Partner: UNT Libraries Government Documents Department