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Some Properties of Stub Tuners Which Can Be Displayed On Smith Charts

Description: Use of the Smith chart in studying stub tuners is demonstrated. Several properties of the tuners are shown, and charts for various wave length spacings, tuning trajectories, and admittances are included.
Date: May 9, 1962
Creator: Walters, J. L.
Partner: UNT Libraries Government Documents Department
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Design of Reflectometers for Coaxial Lines Used at AGS LINAC

Description: This report describes the design procedure for a reflectometer or directional coupler to replace the probe part of the D07-1020 assembly used at the Brookhaven Alternating Gradient Synchrotron linac. Mathematical treatment and diagrams of various reflectometers are included.
Date: May 9, 1962
Creator: Walters, J. L.
Partner: UNT Libraries Government Documents Department
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The Ball Tuner Change Tables

Description: Technique used in deriving values of the linac ball tuner settings to produce various fields is discussed briefly, and tables showing ball tuner change numbers and values used in making up the ball tuner change numbers are given.
Date: May 3, 1962
Creator: Walters, J. L.
Partner: UNT Libraries Government Documents Department
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Synchrotron Oscillations

Description: Some numerical calculations have been done which permit the deduction of many properties of the synchrotron oscillation problem. For the presentation of the numerical results, it is useful to review the formulation framework to which the results are to be fitted. These are worked out for an arbitrary circular accelerator. The algebra woud have to be modified slightly to include straight sections but the numerical results are still useful.
Date: May 1, 1962
Creator: Hochman, E. H. & Barton, M. Q.
Partner: UNT Libraries Government Documents Department
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Safety Evaluation of PNPF Modifications

Description: "The purpose of this report is to examine the safety aspects of PNPF restart on continued operation, after completion of the core cleanup and system modifications."
Date: May 1, 1969
Creator: Huntsinger, M. & Hart, R. S.
Partner: UNT Libraries Government Documents Department
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Annual Technical Progress Report, AEC Unclassified Programs: Fiscal Year 1968

Description: Annual report with the objectives of evaluating, producing, and maintaining an up-to-date set of basic nuclear data; producing and evaluating multigroup constants; and improving of present day methods of neutronic calculations as related to microscopic and macroscopic nuclear data, for unclassified research sponsored by the U.S. Atomic Energy Commission during FY 1968.
Date: May 24, 1969
Partner: UNT Libraries Government Documents Department
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Quarterly Technical Progress Report, AEC Unclassified Programs: Fiscal Year 1968

Description: Quarterly report with the objectives of evaluating, producing, and maintaining of an up-to-dat set of basic nuclear data; producing and evaluating of multigroup constants; and the improvement of present day methods of neutronic calculations as relates to microscopic and macroscopic nuclear data, for unclassified research sponsored by the U.S. Atomic Energy Commission during FY 1968.
Date: May 24, 1969
Partner: UNT Libraries Government Documents Department
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Chlorotriammineplatinum(II) Ion : Acid Hydrolysis and Isotopic Exchange of Chloride Ligand

Description: Abstract: The acid hydrolysis of [Pt(NH3)3Cl] has been shown to occur to a measurable extent. for this reaction: [APt(NH3)cCl]+ + H2O [chemical equilibrium symbol with rate constant k-1 above and k1 below] [Pt(NH3)c(H2O)]++ + Cl-, the equilibrium quotient was measured at 25 degree C and 35 degree C. At 25 degree C this quotient was 8.4 x 10-5 at [Mu] (ionic strength) = 0 and 25 x 10-5 at [mu] = .318 M. This variation is consistent with the expected changes in activity coefficients. [Delta]H for the reaction was found to be approximately 0. The rate constant, k1 was 2.3 x 10-5 sec.-1 at 25 degree C and it was nearly independent of ionic strength. The acid hydrolysis provides a mechanism for the exchange of the chloride ligand and Cl-. Exchange experiments with Cl36 showed that in addition to the acid hydrolysis, a process, first order in both, [Pt(NH3)3Cl] and Cl- with a rate constant of 6. 10-5 sec.-1M.-1 contributes to the exchange. The behavior of the entire series of chloro-ammines of platinum(II) toward acid hydrolysis and chloride exchange has been summarized, and a likely mechanism for the process has been discussed.
Date: May 15, 1961
Creator: Aprile, Ferruccio. & Martin, Don S., Jr.
Partner: UNT Libraries Government Documents Department
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Cation Exchange in Acetone-Water-Hydrochloric Acid

Description: Abstract: Distribution coefficients have been measured for the partition of metal ions between cation exchange resin and acetone-water-hydrochloric acid solutions. the differences in distribution coefficients of metal ions are greater in acetone-water media than in aqueous media of the same hydrochloric acid concentration. Using distribution coefficient data, conditions for column separations of mixtures can be selected. Column separations of metal ion mixtures can be effected by eluting with acetone-water-hydrochloric acid solutions of different compositions. Successful separations of a number of mixtures are reported.
Date: May 10, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Rettig, Thomas A.
Partner: UNT Libraries Government Documents Department
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Chemical Binding in the Water Molecule

Description: From Introduction : "This analysis partitions the electron density and the electronic pair density of the molecule into components corresponding promoted atomic states, to quasiclassical coulombic interactions of these promoted states, and to interactions resulting from the sharing of electrons between atoms."
Date: May 3, 1963
Creator: Edmiston, Clyde & Ruedenberg, Klaus, 1920-
Partner: UNT Libraries Government Documents Department
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Mass Spectrometric Evidence for the Pyridoxal-Leucine Reaction Mechanism

Description: From Abstract : "The mass spectrum of leucine-dn, prepared by the reaction of pyridoxal with excess leucine in D2O medium, has been established using the crucible source techniques. ... The reaction can be used for the selective α, β-deuteration of amino acids other than leucine.
Date: May 3, 1963
Creator: Junk, G. A. & Svec, H. J.
Partner: UNT Libraries Government Documents Department
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Normal Elliptic Integrals of the First and Second Kinds

Description: From Introduction : "In this paper we describe a choice of normal elliptic integrals which appears to be very well suited for use in integral tables as well as for numerical work."
Date: May 3, 1963
Creator: Carlson, B. C.
Partner: UNT Libraries Government Documents Department
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Reinvestigation of the CC Stretching and CH3 Rocking Assignments In Isopropyl and tert-Butyl Halides

Description: From report: "In a series of paper (1-3) Sheppard has analyzed the vibrational spectra of simple alkyl halides. During the course of an investigation of the spectra of similar alkyl thiocyanates certain anomalies appeared in the assignments of the CC stretching and methyl rocking vibrations in isopropyl and tert.-butyl halides."
Date: May 3, 1963
Creator: Hirschmann, R. P. & Kniseley, R. N.
Partner: UNT Libraries Government Documents Department
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Trimethyllactamide

Description: Technical report. From "3. Methods of Preparation" : "Pivadehyde cyanohydrin can be prepared by the reaction of pivadehyde with anhydrous HCN2 or by the sodium bisulfite process. Trimethyllactamide can be prepared by hydrolysis of pivaldehyde cyanohydrin with cold concentrated sulfuric acid. The procedure described here differs in the scale of preparation an in the use of cold fusing hydrochloric acid for hydrolizing the cyanohydrin."
Date: May 9, 1963
Creator: Powell, Jack E.
Partner: UNT Libraries Government Documents Department
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Spectrophotometric Determination of Perchlorate

Description: Technical report. Form Abstract : "Perchlorate is extracted from aqueous solution by n-butyronitrile as ferrous 1,10-phenanthroline perchlorate. The amount of perchlorate is calculated from spectrophotometric measurement of the absorbance of the extract. Moderate to large amounts of chloride, sulfate, or nitrate cause little or no interference. Chlorate is slightly extracted but the interference can be corrected."
Date: May 10, 1963
Creator: Fritz, James S. & Campbell, Patricia A.
Partner: UNT Libraries Government Documents Department
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Pressure-Volume-Temperature Measurements on Solids

Description: From abstract: "The results of recent measurements on the equations of state of sodium and xenon are discussed. The experimental data for each of these are analyzed to show that the isothermal compressibility is solely a function of volume within experimental accuracy. The basic differences between the low temperature PV relationships for sodium and xenon are shown to be easily understandable in terms of the elementary theories of these substances. The range of experimental pressures (to 20 kbars) and temperatures (20°K to the triple point) is sufficiently great so as to produce significant changes in the lattice thermal properties in each case. These changes are indicated through the use of zero pressure heat capacity data in combination with the equation of state data to calculate the volume and temperature dependence of the Debye Θ. The result is quite spectacular for xenon, where a pressure of 20 kbars roughly doubles ΘD."
Date: May 14, 1963
Creator: Swenson, C. A.
Partner: UNT Libraries Government Documents Department
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Molecular Spectra and Structure of the Compound, AlH3-2N(CH3)3

Description: This technical report discusses an infrared study of AlH3-2N(CH3)3 while the compound was in its gas phase. This investigation was then extended to include the Raman spectrum observed in liquid trimethylamine.
Date: May 25, 1962
Creator: Heitsch, C. W. & Kniseley, R. N.
Partner: UNT Libraries Government Documents Department
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Electron Requirements of Bonds in Metal Borides

Description: From abstract: "Electrical measurements have been made on CaB6, SrB6, BaB6, YB2, YB4, YB6, and YB12 for the purpose of testing models of the electronic structure of the boron atoms in the four boride types represented. The compounds CaB6, SrB6, and BaB6 were found to be semiconductors. The Hall coefficients of YB4 was also measured, but could not be interpreted because the free electron theory does not provide a theoretical value for comparison with experiment. The results are in agreement with the models proposed."
Date: May 28, 1962
Creator: Johnson, Robert W. & Daane, A. H. (Adrian Hill), 1919-
Partner: UNT Libraries Government Documents Department
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Discussion of Quadrupole Precession

Description: From abstract: "In this paper the motion of a nucleus with an intrinsic quadrupole moment in an external electrostatic field gradient is discussed from a classical point of view. It is shown that in the classical approximation the angular momentum may precess about the direction of strongest field gradient or about the direction of intermediate field gradient, but not about the direction of weakest field gradient. The classical precession frequencies are found to be related to the quantum mechanical dipole transition frequencies."
Date: May 31, 1962
Creator: Raich, J. C. & Good, R. H. (Roland Hamilton), 1923-
Partner: UNT Libraries Government Documents Department
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Effect of Oxygen on Mechanical Properties of Niobium

Description: From abstract: "The effects of oxygen on some mechanical properties of niobium were studied over the composition range of 20 ppm to 2400 ppm oxygen. The tensile properties of samples of these compositions were studied over the temperature range from room temperature to 500°C. Hardness values were obtained at room temperature only. The following observations and conclusions were made during these studies: 1. Oxygen additions to high purity niobium increase both the yield and tensile strengths of niobium at all temperatures investigated. As the temperature is increased above 250°C the effect of the first 200 ppm of oxygen has more influence than further additions on these strengths of niobium. 2. Strain aging behavior is observed. The peaks in the tensile strength versus temperature curves can be predicted with reliability by the relationship proposed by Cottrell, 3. A mechanism is proposed which, along with Cottrell's segregated atmosphere mechanism, can account for the serrated stress-strain curves obtained. This mechanism offers an explanation of the occurrence of serrations at room temperature, and the mechanism is composition dependent."
Date: May 1962
Creator: Neubauer, Edwin Paul & Wilhelm, H. A.
Partner: UNT Libraries Government Documents Department
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Gas-Phase Radiolysis of Propane

Description: Abstract. the direct and inert-gas radiolysis, as well as the vacuum ultra-violet photolysis of CD3CH2CD3, CH3CD2CH3 and C3H2+C3D3 mixtures have been investigated in the presence of radical scavengers. The major conclusions are : (a) at atmospheric pressures, neutral propane decomposition contributes to the observed products although to a lesser extent than parent ion decompositions ; (b) a variation in pressure has a pronounced effect on the fragmentation of the parent ion ; (c) the hydrogen atoms in the ethyl ion are randomized in the direct as well as in the inert-gas sensitized radiolysis ; (d) rearrangement in the parent ion is of minor importance in the radiolysis ; (e) although the formation of propylene is related to the propyl ion, it is not necessarily produced by the neutralization of this ion.
Date: May 31, 1963
Creator: Ausloos, Pierre J.; Lias, Sharon G., 1935- & Sandoval, L. B., (Mrs.)
Partner: UNT Libraries Government Documents Department
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