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The Effect of Acidity and Reducing Agents on Ruthenium Solvent Extraction by Tributyl Phosphate in the 25 Process

Description: Results of tracer studies suggest that, in tributyl phosphate extraction processes designed to recover and purify fissionable material, minimum ruthenium extraction should be obtained from feeds at least 2 M in nitric acid or at least 1 M acid-deficient. Ruthenium decontamination was decreased by preheating the feed and increased by pretreatment with reducing agents. A pretreatment using 0.06 M ferrous ion and 0.5 M urea with 1 hr simmering at 85°C should increase ruthenium decontamination abou… more
Date: December 15, 1954
Creator: Flanary, J. R. & Frashier, L. D.
Partner: UNT Libraries Government Documents Department
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