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Importance of the specific heat anomaly in the design of binary Rankine cycle power plants

Description: The transposed critical temperature (TPCT) is shown to be an extremely important thermodynamic property in the selection of working fluids and turbine states for geothermal power plants operating on a closed organic (binary) Rankine cycle. When the optimum working fluid composition and process states are determined for specified source and sink conditions, turbine inlet states consistently lie adjacent to the working fluids' TPCT line for all resource temperatures, constraints, and cost and eff… more
Date: May 1, 1980
Creator: Pope, W.L.; Doyle, P.A.; Fulton, R.L. & Silvester, L.F.
Partner: UNT Libraries Government Documents Department
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Vacuum ultraviolet electronic properties of liquids. Annual progress report, 1 November 1979-31 October 1980

Description: Areas covered are: optical and dielectric properties of hexamethyl-phosphoric triamide; photoemission from uv irradiated liquids; photon and photoelectron mean free paths in liquids; properties of Kapton films; and uv transmission of polycyclic organic molecules. (GHT)
Date: January 1, 1980
Creator: Painter, L.R.
Partner: UNT Libraries Government Documents Department
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Establishment of viscometer capability for geopressured fluids. Project 61024 final report, November 19, 1978-December 31, 1979

Description: The feasibility of modifying the IGT capillary viscometer for the measurement of methane-saturated brines at 10,000 psi and 200/sup 0/C was evaluated. The viscometer was cleaned, modified, reassembled and pressure treated. The density cells were calibrated to a precision of approximately 7%. The viscosity of pure value was measured and the best value obtained was 6% below values reported in the literature. The operation of the viscometer was time-consuming and required meticulous cleaning betwe… more
Date: October 1, 1980
Creator: Rockar, E. & Randolph, P.
Partner: UNT Libraries Government Documents Department
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Organic components of nuclear wastes and their potential for altering radionuclide distribution when released to soil

Description: Normal waste processing at the Hanford operations requires the use of many organic materials, chiefly in the form of complexing agents and diluents. These organic materials and their chemical and radiolytic degradation products, have potential for complexing fission products and transuranium elements, both in the waste streams and upon infiltration into soil, perhaps influencing future sorption or migration of the nuclides. Particular complexation characteristics of various nuclides which const… more
Date: August 1, 1980
Creator: McFadden, K.M.
Partner: UNT Libraries Government Documents Department
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Energy from biological processes

Description: This assessment responds to a request by the Senate Committee on Commerce, Science, and Transportation for an evaluation of the energy potential of various sources of plant and animal matter (biomass). This report complements an earlier OTA report on the Application of Solar Technology to Today's Energy Needs in evaluating the major solar energy resources available to the United States. The findings also will serve as part of the material to be used in an upcoming OTA assessment of synthetic fu… more
Date: July 1, 1980
Partner: UNT Libraries Government Documents Department
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Multiheteromacrocycles that complex metal ions. Sixth progress report, 1 May 1979-30 April 1980. [Hemispherands; spherands]

Description: Objective is to design synthesize, and evaluate cyclic and polycyclic host organic compounds for their abilities to complex and lipophilize guest metal ions, their complexes, and their clusters. Host organic compounds consist of strategically placed solvating, coordinating, and ion-pairing sites tied together by covalent bonds through hydrocarbon units around cavities shaped to be occupied by guest metal ions or by metal ions plus their ligands. Specificity in complexation is sought by matching… more
Date: January 15, 1980
Creator: Cram, D. J.
Partner: UNT Libraries Government Documents Department
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Measurement of energy deposited by charged-particle beams in composite targets

Description: We have measured the energy deposited in two types of composite targets by a number of charged-particle beams: targets made of /sup 238/U, Lucite, and polyethylene were exposed to 0.26-GeV protons and 0.33-GeV deuterons, and aluminum-Lucite composites were exposed to 0.5-GeV electrons. In addition, we measured neutrons and gamma rays emitted from solid targets of various materials (including /sup 238/U and iron) exposed to 0.26-GeV protons and 0.33-GeV deuterons. We used passive detectors (ther… more
Date: July 2, 1980
Creator: Farley, E.; Becker, J.; Crase, K.; Howe, R. & Selway, D.
Partner: UNT Libraries Government Documents Department
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Organic iodine removal from simulated dissolver off-gas streams using silver-exchanged mordenite

Description: The removal of methyl iodide by absorption onto silver mordenite was studied using a simulated off-gas from the fuel dissolution step of a nuclear fuel reprocessing plant. The methyl iodide absorption of silver mordenite was examined for the effects of NO/sub x/, humidity, iodine concentration, filter temperature, and filter pretreatment. The highest iodine loading achieved in these tests has been 34 mg CH/sub 3/I per g of substrate, approximately five times less than the elemental iodine loadi… more
Date: January 1, 1980
Creator: Jubin, R. T.
Partner: UNT Libraries Government Documents Department
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Protective coatings and sealants for solar applications

Description: An aging study has been completed which evaluated a number of polymeric materials for potential use as (1) protective coatings for back surfaces of mirrors and (2) solar heliostat edge seals. These investigations were conducted in an artificial weathering chamber that accelerated thermal cycling. The primary mirror failure mode was observed to be silver corrosion resulting from moisture exposure. To increase mirror longevity in current heliostat designs, intimate bonding at all the composite in… more
Date: September 1, 1980
Creator: Wischmann, K. B. & Gonzales, M. H.
Partner: UNT Libraries Government Documents Department
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Size selective synergism by crown ethers in the extraction of alkali metals by di(2-ethylhexyl) phosphoric acid

Description: Although the macrocyclic polyethers, known as crown ethers, complex metal ions and do so preferentially according to the size correspondance between the ion and the crown ether cavity, their usefulness as liquid-liquid extraction reagents has been limited by the necessity of solubilizing the anion in the organic phase. The common mineral acid anions are difficult to transfer to the organic phase and organophilic anions are expensive or impractical. A method is described that avoids this problem… more
Date: January 1, 1980
Creator: McDowell, W.J.; Kinard, W.F. & Shoun, R.R.
Partner: UNT Libraries Government Documents Department
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Tar sand extraction by steam stimulation and steam drive: measurement of physical properties

Description: The measurement of the following thermophysical properties of Utah tar sands is in progress: thermal conductivity, specific heat relative permeability, and viscosity (of the recovered bitumen). During the report period (October 1, 1978 to November 1, 1979), experimental procedures have been developed and a basic data set has been measured. Additionally, standard core analysis has been performed for four drill sites in the Asphalt Ridge, Utah area.
Date: September 10, 1980
Creator: Linberg, W.R.
Partner: UNT Libraries Government Documents Department
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Emission computed tomography of /sup 18/F-fluorodeoxyglucose and /sup 13/N-ammonia in stroke and epilepsy

Description: The ECAT Positron Tomograph was used to scan normal control subjects, stroke patients at various times during recovery, and patients with partial epilepsy during EEG monitoring. /sup 18/F-fluorodeoxyglucose (/sup 18/FDG) and /sup 13/N-Ammonia (/sup 13/NH/sub 3/) were used as indicators of abnormalities in local cerebral glucose utilization (LCMR/sub glc/) and relative perfusion, respectively. Hypometabolism, due to deactivation or minimal damage, was demonstrated with the /sup 18/FDG scan in de… more
Date: January 1, 1980
Creator: Kuhl, D. E.; Phelps, M. E. & Engel Jr., J.
Partner: UNT Libraries Government Documents Department
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Optimization of steam explosion pretreatment. Final report

Description: Different operating conditions are required to optimize the yield from each of the various fractions in the substrate. Xylose recovery is maximized at short cooking times whereas maximum lignin recovery requires much longer cooking times. Peak glucose yield and rumen digestibility occur at intermediate times. If process conditions are set for maximum glucose yield we have achieved a yield of 68% of the theoretical, based on an average of a dozen substrates tested. Individual results ranged from… more
Date: April 1, 1980
Creator: Foody, P.
Partner: UNT Libraries Government Documents Department
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Application of pressurized ion exchange to separations of transplutonium elements

Description: High-pressure ion exchange chromatography, used first for nucleic acid separations, was applied to the production of the heavier actinides, particularly the transcurium elements. Its use at the TRU plant is described. Future developments are considered briefly. (DLC)
Date: January 1, 1980
Creator: Campbell, D.O.
Partner: UNT Libraries Government Documents Department
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Methane entrained in geopressured aquifers, Texas Gulf Coast

Description: Six tests of geopressured aquifers have yielded between 3.6 to 4.5 m/sup 3//m/sup 3/ (20 to 25 scf/bbl) of gas. These low gas concentrations are attributed to high salinities, that in all tests exceeded 100,000 mg/l, but undersaturated conditions cannot be ruled out completely. Research efforts are designed to delineate the geographic and stratigraphic variations in salinity and to recognize regional and local trends so that zones of lower salinity and higher gas concentration can be identified… more
Date: July 1, 1980
Creator: Morton, R. A.
Partner: UNT Libraries Government Documents Department
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Multi-transducer dummy unit evaluation of polystyrene bead foam as an encapsulant for electronic packages

Description: A dummy electronic assembly without electronic components was used to measure loadings and deflections caused by 0.2, 0.3, 0.4, 0.5 and 0.6 g/cm/sup 3/ densities of polystyrene bead foam during fusion and thermal cycling. Previously developed and proven transducers showed that the lower three densities caused low and safe loads and deflections, but that the highest two densities must be used with care for fragile electronic components.
Date: September 1, 1980
Creator: Swanson, G. D.
Partner: UNT Libraries Government Documents Department
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Photoproduction of hydrogen by membranes of green photosynthetic bacteria

Description: Photoproduction of H/sub 2/ from ascorbate by unit-membrane vesicles from Chlorobium limicola f. thiosulfatophilum was achieved with a system containing gramicidin D, tetramethyl-p-phenylenediamine, methyl viologen, dithioerythritol, Clostridium hydrogenase, and an oxygen-scavenging mixture of glucose, glucose oxidase, ethanol, and catalase. Maximum quantum yield was less than one percent. Half maximum rate of H/sub 2/ production occurred at a white-light intensity of approximately 0.15 cm/sup … more
Date: January 1, 1980
Creator: Bernstein, J D & Olson, J M
Partner: UNT Libraries Government Documents Department
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Excited-state proton-transfer kinetics in 1-naphthol, 1-naphthol-sulfonates, and organometallic complexes

Description: The dissociation of 1-naphthol in aqueous solution occurs so rapidly that the fluorescence from the neutral form, ROH, has been previously described as completely extinguished or hardly noticeable. Apparently nearly all of the fluorescence originates from the naphtholate ion. This paper reports on the proton-transfer characteristics of a series of 1-naphthol compounds, and also reports preliminary data on excited-state proton transfer in an organometallic complex of ruthenium.
Date: July 1, 1980
Creator: Shapiro, S. L.; Winn, K. R. & Clark, J. H.
Partner: UNT Libraries Government Documents Department
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Preparation of curium-americium oxide microspheres by resin-bead loading

Description: Resin-bead loading and calcination techniques have been used to produce all curium and americium oxide feed material (about 2.2 kg) for HFIR targets since 1971. The process based on Dowex 50W resin has progressed from a series of test runs, through special production runs, into routine production in permanent equipment beginning in 1975. Key attributes of this process are its reliability, high yields, and ease of operation. The process is suited for remote operation in hot cells. Yields approac… more
Date: January 1, 1980
Creator: Chattin, F. R.; Benker, D. E.; Lloyd, M. H.; Orr, P. B.; Ross, R. G. & Wiggins, J. T.
Partner: UNT Libraries Government Documents Department
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Investigation and evaluation of geopressured-geothermal wells

Description: Over the life of the project, 1143 wildcat wells were screened for possible use. Although many did not meet the program's requirement for sand development, a surprisingly large number were abandoned because of downhole mechanical problems. Only 94 of these wells were completed as commercial hydrocarbon producers. Five wells of opportunity were funded for testing. Of these, two were evaluated for their hydraulic energy, thermal energy, and recoverable methane, and three were abandoned because of… more
Date: September 1, 1980
Creator: Hartsock, J.H. & Rodgers, J.A.
Partner: UNT Libraries Government Documents Department
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Assessment of the potential of colloidal fuels in future energy usage. Final report. [97 references]

Description: Pulverized coal has been an increasing important source of energy over the past century. Most large utility boilers, all modern coking plants, and many industrial boilers and blast furnaces employ pulverized coal as a major feed stream. In periods of oil shortages, such as during World Wars I and II, the concept of adding powdered coal to oil for use in combustion equipment originally designed for oil has been actively pursued but rarely used. Over this same period of time, there have been atte… more
Date: February 25, 1980
Partner: UNT Libraries Government Documents Department
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HC quench layer formation in combustion processes. Technical progress report, September-December 1979

Description: The project is aimed at understanding wall quenching and other processes responsible for surface generated hydrocarbons in combustion under engine-like conditions. The study concerns the effects of turbulence on the evolution of hydrocarbons. At the conclusion of the program, significant new experimental information will have been generated and an analytical model of the fluid mechanics and some aspects of the chemistry of quenching will be formulated. The work is divided into three tasks: (1) … more
Date: February 1, 1980
Creator: Lavoie, G. A.
Partner: UNT Libraries Government Documents Department
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Sampling and analysis of trace-organic constituents in ambient and workplace air at coal-conversion facilities

Description: A review of the recent literature reveals that current sampling procedures involve the use of glass fiber filters for particulate-sorbed organics and sorbent resins such as Tenax GC and XAD-2 for vapor-phase organics. Ultra trace-organic analysis of air pollutants or particulates may require the collection of a large (1000 to 3000 m/sup 3/) sample by a high volume air sampler. Personal air sampling requires a smaller (approx. = 0.5 m/sup 3/) and a portable collection apparatus. Trapped organic … more
Date: July 1, 1980
Creator: Flotard, R D
Partner: UNT Libraries Government Documents Department
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