SALT PHASE CHLORINATION OF REACTOR FUELS. IV. NIOBIUM BEHAVIOR IN THE LEAD CHLORIDE AND CHLORINE-LEAD CHLORIDE SYSTEMS
Description:
Investigation of the behavior of Nb in PbCl/sub 2/ showed that the Nb dissolution rate is quite low. Since stirring increases the rate appreciably, it is likely that the initial reaction is diffusion controlled. A subsequent reaction is linear in rate with an activation energy of 23.4 kcal per mole. Incomplete volatilization of dissolved Nb from PbCl/sub 2/ is due to the presence of lower oxidation states of Nb. The addition of Cl to PbCl/sub 2/ increases the rate of dissolution of Nb. The rate…
more
Date:
March 15, 1962
Creator:
Teague, J. L.; Hahn, H. T. & Vander Wall, E. M.
Item Type:
Refine your search to only
Report
Partner:
UNT Libraries Government Documents Department