Structure and Dynamics of Phosphate Glasses: From Ultra- to Orthophosphate Composition
Description:
The short- and intermediate-range order as well as atomic dynamics in various phosphate glasses were investigated using neutron diffraction and inelastic scattering. The 3-D network of corner-sharing PO{sub 4} tetrahedra in g-P{sub 2}O{sub 5} is highly unstable and hygroscopic. Depolymerization of the network to chain-like structure and eventually to unconnected PO{sub 4} units by incorporating alkali, alkali-earth or transition-metal modifiers is clearly evident in the structure factor S(Q) in…
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Date:
July 14, 1997
Creator:
Loong, C. K.; Price, D. L.; Sales, B. C. & Boatner, L. A.
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