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Geothermal waste treatment biotechnology: Progress and advantages to the utilities

Description: Development of biotechnology for treatment of geothermal residual waste is aimed at the application of low-cost biochemical processes for the surface treatment and disposal of residual geothermal sludges. These processes, in addition to the lowering of disposal cost, are designed to be environmentally acceptable. Recent studies at Brookhaven National Laboratory (BNL) have shown that optimization of several process variables results in fast rates (<24h) of metal removal from residual sludges at … more
Date: March 1, 1992
Creator: Premuzic, E.T.; Lin, M.S. & Jin, J.
Partner: UNT Libraries Government Documents Department
open access

Investigation of Celotex trademark charring depths in the DT-18 shipping container

Description: Celotex {trademark}, the insulating material used between the outer and inner containers of the DT-18 shipping package, undergoes decomposition, combustion, or both when heated to temperatures exceeding 150{degrees}C. Several DT-18 packages that had previously undergone hypothetical thermal accident testing were opened and Celotex {trademark} charring depths ranging from {1/2} to 1 {1/2} in. were recorded. The majority of char depth data taken was between 3/4 and 1 {1/4} in. One-dimensional HEA… more
Date: March 1, 1992
Creator: Anderson, J.C.
Partner: UNT Libraries Government Documents Department
open access

Molecular biological enhancement of coal biodesulfurization. [Rhodococcus]

Description: The objective of this project is to produce one or more microorganisms capable of removing the organic and inorganic sulfur in coal. The original specific technical objectives of the project were to: Clone and characterize the genes encoding the enzymes of the 4S'' pathway (sulfoxide/sulfone/sulfonate/sulfate) for release of organic sulfur from coal; Return multiple copies of genes to the original host to enhance the biodesulfurization activity of that organism; Transfer this pathway into a fas… more
Date: March 15, 1990
Creator: Litchfield, J. H.; Fry, I.; Wyza, R. E.; Palmer, D. T.; Zupancic, T. J. & Conkle, H. N.
Partner: UNT Libraries Government Documents Department
open access

Chemical Processing Technology Quarterly Progress Report, October-December 1961

Description: The ICPP processed Al fuel, prtncipally of the MTR-ETR type, durtng this quarter. Newly designed and installed processing equipment exhibited excellent operating performance. This included direct-air-pulsed extraction, stripping and scrub columns, and a cascade-controlled continuous evaporator in first cycle product concentration service. Aqueous zirconium fuel processing studies continued with the objective of adapting the hydrofluoric acid process to continuous dissolution-complexing to incre… more
Date: March 28, 1962
Creator: Bower, J. R.
Partner: UNT Libraries Government Documents Department
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Chemical Technology Division, Unit Operations Section Monthly Progress Report, August 1961

Description: Engineering studies of a 6-in.-ID countercurrent foam column were started. The capacity of Mark II Stacked Clone Contactor was found to be limited by gradually increasing entrainment. Thoria sols were prepared from trough denitrator products in a conical bottom tank agitated by circulation through an external centrifugal pump. Experimental results agreed favorably with predicted results for the reaction of CO with CuO and fur the simultaneous reactions of H/ sub 2/ and CO with CuO. In a 2-in. d… more
Date: March 1, 1962
Creator: Whatley, M. E.; Haas, P. A.; Horton, R. W.; Ryon, A. D.; Suddath, J. C. & Watson, C. D.
Partner: UNT Libraries Government Documents Department
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Hydrogen-Transfer and Charge Transfer in Photochemical and High Energy Radiation Induced Reactions: Effects of Thiols. Final Report, February 1, 1960-January 31, 1979

Description: Absorption of ultraviolet or visible light, or high energy radiation, may lead to highly reactive free radicals. Thiols affect the reactions of these radicals in the following ways: (1) transfer of hydrogen from sulfur of the thiol to a substrate radical, converting the radical to a stable molecule, and the thiol to a reactive thiyl radical; and (2) transfer of hydrogen from a substrate radical or molecule to thiyl, regenerating thiol. The thiol is thus used repeatedly and a single molecule may… more
Date: March 1, 1980
Creator: Cohen, S. G.
Partner: UNT Libraries Government Documents Department
open access

Physical and chemical characterization of synthetic calcined sludge

Description: Calcined synthetic sludge was chemically characterized in support of engineering studies to design a processing plant to solidify highly radioactive waste at the Savannah River Plant. An analytical technique is described which provides quantitative data by mass spectrometric analysis of gases evolved during thermogravimetric analysis without measurements of gas flow rates or mass spectrometer sensitivities. Scanning electron microprobe analysis, Mossbauer spectroscopy, and several other common … more
Date: March 1, 1982
Creator: Slates, R.V.; Mosley, W.C. Jr.; Tiffany, B. & Stone, J.A.
Partner: UNT Libraries Government Documents Department
open access

Effect of acidity on microbial processes in a forest soil

Description: The objective of this study is to obtain comprehensive baseline information on the microbial activity in a forest soil in order to begin an evaluation of the impact of pollutants resulting from energy related activities. Since most of the soils on Long Island, New York, are poorly buffered and may respond to acid precipitation more quickly, it was decided to study the effect of acidity on various microbial processes. A Riverhead sandy loam soil collected from an oak-pine forest with a pH of 4.6… more
Date: March 1, 1980
Creator: Francis, A J; Olson, D & Bernatsky, R
Partner: UNT Libraries Government Documents Department
open access

Operator Manual: High Temperature Heat Pump

Description: Experimental data is being obtained from operating a high temperature heat pump system. The use of methanol as a working fluid will necessitate careful monitoring of refrigerant temperatures and pressures with chemical analysis performed on the working fluid during scheduled down time. Materials sent to vendors by Auburn University and quotes received by Auburn concerning equipment (compressor, evaporator, condensor, air heater, dryer, two accumulator tanks, and three expansion valves) are disc… more
Date: March 4, 1980
Creator: Dyer, D. F.; Maples, G.; Burch, T. E. & Chancellor, P. D.
Partner: UNT Libraries Government Documents Department
open access

Immobilization of high-level defense wastes in SYNROC-D: recent research and development results on process scale-up

Description: SYNROC is a titanate-based ceramic waste form being developed to immobilize high-level nuclear reactor wastes. SYNROC-D is a unique variation of SYNROC designed to contain high-level defense wastes, particularly those in storage at the Savannah River Plant (SRP). We review recent research and development on SYNROC-D processing options and report on work in progress on various unit operations. The overall immobilization process can be divided into three general parts: (1) slurry preparation (for… more
Date: March 15, 1982
Creator: Campbell, J. H.; Rozsa, R. B. & Hoenig, C. L.
Partner: UNT Libraries Government Documents Department
open access

Improved radioimmunotherapy of hematologic malignancies

Description: This research project proposes to develop novel new approaches of improving the radioimmunodetection and radioimmunotherapy of malignancies by augmenting retention of radioimmunoconjugates by tumor cells. The approaches shown to be effective in these laboratory experiments will subsequently be incorporated into out ongoing clinical trials in patients. Specific project objectives include: to study the rates of endocytosis, intracellular routing, and metabolic degradation of radiolabeled monoclon… more
Date: March 24, 1992
Creator: Press, O.W.
Partner: UNT Libraries Government Documents Department
open access

Thermal cycling tests on surface-mount assemblies

Description: The capability of surface-mount (SM) solder joints to withstand various thermal cycle stresses was evaluated through electrical circuit resistance changes of a test pattern and by visual examination for cracks in the solder after exposure to thermal cycling. The joints connected different electrical components, primarily leadless-chip carriers (LCCs), and printed wiring-board (PWB) pads on different laminate substrates. Laminate compositions were epoxy-glass and polyimide-glass with and without… more
Date: March 1, 1988
Creator: Jennings, C.W.
Partner: UNT Libraries Government Documents Department
open access

Defense waste processing facility precipitate hydrolysis process

Description: Sodium tetraphenylborate and sodium titanate are used to assist in the concentration of soluble radionuclide in the Savannah River Plant&#x27;s high-level waste. In the Defense Waste Processing Facility, concentrated tetraphenylborate/sodium titanate slurry containing cesium-137, strontium-90 and traces of plutonium from the waste tank farm is hydrolyzed in the Salt Processing Cell forming organic and aqueous phases. The two phases are then separated and the organic phase is decontaminated for … more
Date: March 1, 1986
Creator: Doherty, J P; Eibling, R E & Marek, J C
Partner: UNT Libraries Government Documents Department
open access

Office of Technology Development's integrated program for development of in situ remediation technologies

Description: The In-Situ Remediation Integrated Program (ISR IP) was initiated in FY 1991 and is progressing through the planning stages. The ISR IP currently plans to invest in the development of in situ bioremediation for the cleanup of volatile organics in the vadose zone and in groundwater, and in R D activities to support the development of electrokinetics. Additional investment decisions will be made as a result of convening technical support groups to evaluate and recommend R D activities for other i… more
Date: March 1, 1992
Creator: Peterson, M.E. (Pacific Northwest Lab., Richland, WA (United States)); Shupe, M.; Walker, J. (USDOE, Washington, DC (United States)) & Ellis, B. (BDM International, Inc., McLean, VA (United States))
Partner: UNT Libraries Government Documents Department
open access

Spin-mapping of coal structures with ESE and ENDOR

Description: Advanced EPR methods have demonstrated cability for study of molecular components (including organic sulfur) in coal. We have constructed a unique Very High Frequency Electron Paramagnetic Resonance (VHF EPR) instrument operating at the W-band (96 GHz), one of only two such instruments in the world, and the only one studying coal. We are employing this instrument, as well as collaborating with scientists at Cornell University who have constructed a 250 GHz EPR spectrometer, to develop a clearer… more
Date: March 1, 1991
Creator: Belford, R. L. & Clarkson, R. B.
Partner: UNT Libraries Government Documents Department
open access

Biomass gasification: yesterday, today, and tomorrow

Description: The solid fuels, biomass and coal, can be converted by gasification into clean gaseous fuels that are easier to distribute and required for many technical processes. The simplest method of conversion is air gasification, producing a low-energy gas well suited for direct-heat or engine applications but unsuitable for pipeline use. Oxygen gasification produces a medium-energy gas composed primarily of CO and H/sub 2/, which can be used industrial pipelines for operation of turbines for power and … more
Date: March 1, 1980
Creator: Reed, T. B.
Partner: UNT Libraries Government Documents Department
open access

Molecular biological enhancement of coal biodesulfurization

Description: The objective of this project is to produce one or more microorganisms capable of the organic and inorganic sulfur in coal. The original specific technical objectives of the project were to: (1) clone and characterize the genes encoding the enzymes of the 4S'' pathway (sulfoxide/sulfone/sulfonate/sulfate) for release of organic sulfur from coal; (2) return multiple copies of genes to the original host to enhance the biodesulfurization activity of that organism; (3) transfer this pathway into a … more
Date: March 13, 1992
Creator: Litchfield, J. H.; Zupancic, T. J.; Kittle Jr., J. D.; Baker, B.; Palmer, D. T.; Traunero, C. G. et al.
Partner: UNT Libraries Government Documents Department
open access

Waste package environment studies. FY 1984 annual report.

Description: Tests were conducted by Pacific Northwest Laboratory in FY 1984 to examine the influence of heat and radiation on the chemical environment of a high-level nuclear waste package in a repository in salt and to determine the solubility of key radionuclides in site-specific brines. These tests are part of an ongoing effort by the Waste Package Program, whose objective is to help develop a data base on package components and system interactions necessary to qualify a nuclear waste package for geolog… more
Date: March 1, 1986
Creator: Pederson, L. R.; Gray, W. J.; Hodges, F. N.; McVay, G. L.; Moore, D. A.; Rai, D. et al.
Partner: UNT Libraries Government Documents Department
open access

System for utilizing shale oil fines. [Patent application]

Description: A system is provided for utilizing fines of carbonaceous materials such as particles or pieces of oil shale of about one-half inch or less diameter which are rejected for use in some conventional or prior surface retorting process, which obtains maximum utilization of the energy content of the fines and which produces a waste which is relatively inert and of a size to facilitate disposal. The system includes a cyclone retort which pyrolyzes the fines in the presence of heated gaseous combustion… more
Date: March 13, 1981
Creator: Harak, A. E.
Partner: UNT Libraries Government Documents Department
open access

Coal liquefaction: A research and development needs assessment: Final report, Volume 2

Description: Volume II of this report on an assessment of research needs for coal liquefaction contains reviews of the five liquefaction technologies---direct, indirect, pyrolysis, coprocessing, and bioconversion. These reviews are not meant to be encyclopedic; several outstanding reviews of liquefaction have appeared in recent years and the reader is referred to these whenever applicable. Instead, these chapters contain reviews of selected topics that serve to support the panel's recommendations or to illu… more
Date: March 1, 1989
Creator: Schindler, H. D.; Burke, F. P.; Chao, K. C.; Davis, B. H.; Gorbaty, M. L.; Klier, K. et al.
Partner: UNT Libraries Government Documents Department
open access

Electron Transfer Reactions of Excited Dyes With Metal Complexes. Progress Report, March 1, 1978-February 28, 1979. [Iron-Methylene Blue]

Description: An intense absorption band of /sup 3/MBH/sup 2 +/ at 700nm was characterized in several media and its pK/sub A/ was measured to be 7.17 +- .1 in water. Flash photolysis show that semiethylene blue, MBH/sup +/, formed by quenching /sup 3/MBH/sup 2 +/ with Fe/sub II/(H/sub 2/O)/sub 6//sup 2 +/, decays by disproportionation at a diffusion-controlled rate. Rates of decay of the photostationary state of solutions of MB/sup +/ and Fe/sup II/(H/sub 2/O)/sub 6//sup 2 +/ in acidic media were measured us… more
Date: March 15, 1979
Creator: Lichtin, N. N.
Partner: UNT Libraries Government Documents Department
open access

Enzymatic desulfurization of coal

Description: Our experimental approach focuses on the use of enzymes which catalyze the addition of oxygen to organic compounds. In tailoring the application of these enzymes to coal processing, we are particularly interested in ensuring that oxidation occurs at sulfur and not at carbon-carbon bonds. Previous studies with DBT have shown that the reaction most frequently observed in microbial oxidative pathways is one in which DBT is oxidized at ring carbons. These reactions, as we have said, are accompanied… more
Date: March 23, 1990
Creator: Boyer, Y.N.; Crooker, S.C.; Kitchell, J.P. & Nochur, S.V.
Partner: UNT Libraries Government Documents Department
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