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Review of analytical results from the proposed agent disposal facility site, Aberdeen Proving Ground

Description: Argonne National Laboratory reviewed the analytical results from 57 composite soil samples collected in the Bush River area of Aberdeen Proving Ground, Maryland. A suite of 16 analytical tests involving 11 different SW-846 methods was used to detect a wide range of organic and inorganic contaminants. One method (BTEX) was considered redundant, and two {open_quotes}single-number{close_quotes} methods (TPH and TOX) were found to lack the required specificity to yield unambiguous results, especially in a preliminary investigation. Volatile analytes detected at the site include 1, 1,2,2-tetrachloroethane, trichloroethylene, and tetrachloroethylene, all of which probably represent residual site contamination from past activities. Other volatile analytes detected include toluene, tridecane, methylene chloride, and trichlorofluoromethane. These compounds are probably not associated with site contamination but likely represent cross-contamination or, in the case of tridecane, a naturally occurring material. Semivolatile analytes detected include three different phthalates and low part-per-billion amounts of the pesticide DDT and its degradation product DDE. The pesticide could represent residual site contamination from past activities, and the phthalates are likely due, in part, to cross-contamination during sample handling. A number of high-molecular-weight hydrocarbons and hydrocarbon derivatives were detected and were probably naturally occurring compounds. 4 refs., 1 fig., 8 tabs.
Date: September 1, 1997
Creator: Brubaker, K.L.; Reed, L.L.; Myers, S.W.; Shepard, L.T. & Sydelko, T.G.
Partner: UNT Libraries Government Documents Department

Biotic and Abiotic Transformation of a Volatile Organics Plume in a Semi-Arid Vadose Zone

Description: An evaluation of biotic and abiotic attenuation processes potentially important to chlorinated and non-chlorinated volatile organic compound (VOC) fate and transport in the 148 meter thick vadose zone beneath the Chemical Waste Landfill (CWL) was conducted. A unique feature of this evaluation is the comparison of two estimates of VOC mass present in the soil gas, pore-water, and solid phases (but not including mass as non-aqueous phase liquid [NAPL]) of the vadose zone in 1993. One estimate, 1,800 kg, was obtained from vadose zone transport modeling that incorporated molecular diffusion and volatilization to the atmosphere, but not biotic or chemical processes. The other estimate, 2,120 kg, was obtained from the sum of VOC mass physically removed during soil vapor extraction and an estimate of VOC mass remaining in the vadose zone in 1998, both adjusted to exclude NAPL mass. This comparison indicates that biogeochemical processes were at best slightly important to historical VOC plume development. Some evidence of aerobic degradation of non-chlorinated VOCs and abiotic transformation of 1,1,1-Trichloroethane was identified. Despite potentially amenable site conditions, no evidence was found of cometabolic and anaerobic transformation pathways. Relying principally on soil-gas analytical results, an upper-bound estimate of 21% mass reduction due to natural biogeochemical processes was developed. Although available information for the CWL indicates that natural attenuation processes other than volatilization to the atmosphere did not effective y enhance groundwater protection, these processes could be important in significantly reducing groundwater contamination and exposure risks at other sites. More laboratory and field research is required to improve our collective ability to characterize and exploit natural VOC attenuation processes, especially with respect to the combination of relatively thick and dry vadose zones and chlorinated VOCs.
Date: April 8, 1999
Creator: Studer, J.E.; Singletary, M.A. & Miller, D.R.
Partner: UNT Libraries Government Documents Department

Pacific Northwest National Laboratory 300 area facility liquid effluent monitoring: 1994 and 1995 field tests

Description: Pacific Northwest National Laboratory Effluent Management Services manages liquid waste streams from some of the 300 Area buildings on the Hanford Site near Richland, Washington, to ensure liquid discharges to the Columbia River are in compliance with permit requirements. The buildings are owned by the U.S. Department of Energy and operated by Pacific Northwest National Laboratory. In fiscal year (FY) 1994 and FY 1995, three field tests were conducted to gather information that could be used to (1) increase the understanding of 300 Area building liquid waste streams based on the characterization and monitoring data collected during calendar year (CY) 1994 and CY 1995 and (2) establish improved methods for evaluating facility releases. The three field tests were (1) an evaluation of a continuous monitoring/event-triggered sampling system, (2) a volatile organic compound hold-time study, and (3) an investigation of the dilution and retention properties of the 300 Area process sewer. The results from the first field test showed that future characterization and monitoring of 300 Area facility liquid waste streams could benefit significantly from augmenting continuous monitoring with event-triggered sampling. Current continuous-monitoring practices (i.e., monitoring of pH, conductivity, and flow) cannot detect discharges of organic pollutants. Effluent control effectiveness would be enhanced by incorporating a continuous total organic carbon analyzer in the system to detect events involving releases of organic compounds. In the second field test, sample hold times were shown to have a significant effect on volatile organic compound data. Samples analyzed in the field within 1 hour of collection generally had 1.5 to 3 times higher volatile organic compound concentrations than those analyzed 1.5 to 4 weeks later at on-site and off-site laboratories, respectively. The number of volatile organic compounds detected also decreased with increasing hold times.
Date: July 1, 1997
Creator: Riley, R.G.; Thompson, C.J.; Damberg, E.G. & Ballinger, M.Y.
Partner: UNT Libraries Government Documents Department

Resolution of Hanford tanks organic complexant safety issue

Description: The Hanford Site tanks have been assessed for organic complexant reaction hazards. The results have shown that most tanks contain insufficient concentrations of TOC to support a propagating reaction. It has also been shown that those tanks where the TOC concentration approaches levels of concern, degradation of the organic complexants to less energetic compounds has occurred. The results of the investigations have been documented. The residual organic complexants in the Hanford Site waste tanks do not present a safety concern for long-term storage.
Date: May 14, 1998
Creator: Kirch, N.W.
Partner: UNT Libraries Government Documents Department

Capillary electrophoresis separation of neutral organic compounds, pharmaceutical drugs, proteins and peptides, enantiomers, and anions

Description: Addition of a novel anionic surfactant, namely lauryl polyoxyethylene sulfate, to an aqueous-acetonitrile electrolyte makes it possible to separate nonionic organic compounds by capillary electrophoresis. Separation is based on differences in the association between analytes and the surfactant. Highly hydrophobic compounds such as polyaromatic hydrocarbons are well separated by this new surfactant. Migration times of analytes can be readily changed over an unusually large range by varying the additive concentration and the proportion of acetonitrile in the electrolyte. Several examples are given, including the separation of four methylbenz[a]anthracene isomers and the separation of normal and deuterated acetophenone. The effect of adding this new surfactant to the acidic electrolyte was also investigated. Incorporation of cetyltrimethylammonium bromide in the electrolyte is shown to dynamically coat the capillary and reverse electroosmotic flow. Chiral recognition mechanism is studied using novel synthetic surfactants as chiral selectors, which are made from amino acids reacting with alkyl chloroformates. A satisfactory separation of both inorganic and organic anions is obtained using electrolyte solutions as high as 5 M sodium chloride using direct photometric detection. The effect of various salts on electrophoretic and electroosmotic mobility is further discussed. Several examples are given under high-salt conditions.
Date: February 12, 1999
Creator: Ding, W.L.
Partner: UNT Libraries Government Documents Department

Organic waste processing using molten salt oxidation

Description: Molten Salt Oxidation (MSO) is a thermal means of oxidizing (destroying) the organic constituents of mixed wastes, hazardous wastes, and energetic materials while retaining inorganic and radioactive constituents in the salt. For this reason, MSO is considered a promising alternative to incineration for the treatment of a variety of organic wastes. The U. S. Department of Energy`s Office of Environmental Management (DOE/EM) is currently funding research that will identify alternatives to incineration for the treatment of organic-based mixed wastes. (Mixed wastes are defined as waste streams which have both hazardous and radioactive properties.) One such project is Lawrence Livermore National Laboratory`s Expedited Technology Demonstration of Molten Salt Oxidation (MSO). The goal of this project is to conduct an integrated demonstration of MSO, including off-gas and spent salt treatment, and the preparation of robust solid final forms. Livermore National Laboratory (LLNL) has constructed an integrated pilot-scale MSO treatment system in which tests and demonstrations are presently being performed under carefully controlled (experimental) conditions. The system consists of a MSO process vessel with dedicated off-gas treatment, a salt recycle system, feed preparation equipment, and equipment for preparing ceramic final waste forms. In this paper we describe the integrated system and discuss its capabilities as well as preliminary process demonstration data. A primary purpose of these demonstrations is to identify the most suitable waste streams and waste types for MSO treatment.
Date: March 1, 1998
Creator: Adamson, M. G., LLNL
Partner: UNT Libraries Government Documents Department

Task 1.8 -- Wet air oxidation. Semi-annual report, January 1--June 30, 1995

Description: A novel aqueous-phase thermal (APT) oxidation apparatus has been designed for the cost-effective treatment of organically contaminated aqueous streams. During the operational period of this task, the specific components will be integrated and tested to evaluate their operability. A determination will also be made as to the ability of the integrated system to adequately remediate an organically contaminated aqueous stream. The overall objective of this task is to perform a sequentially integrated test of the critical components of the novel APT oxidation apparatus to evaluate the ability of this system to remediate an organically contaminated aqueous stream.
Date: August 1, 1997
Creator: Rindt, J.R.
Partner: UNT Libraries Government Documents Department

Accelerated cleanup risk reduction

Description: There is no proven technology for remediating contaminant plume source regions in a heterogeneous subsurface. This project is an interdisciplinary effort to develop the requisite new technologies so that will be rapidly accepted by the remediation community. Our technology focus is hydrous pyrolysis/oxidation (HPO) which is a novel in situ thermal technique. We have expanded this core technology to leverage the action of steam injection and place an in situ microbial filter downstream to intercept and destroy the accelerated movement of contaminated groundwater. Most contaminant plume source regions, including the chlorinated solvent plume at LLNL, are in subsurface media characterized by a wide range in hydraulic conductivity. At LLNL, the main conduits for contaminant transport are buried stream channels composed of gravels and sands; these have a hydraulic conductivity in the range of 10{sup -1} to 10{sup -2} cm/s. Clay and silt units with a hydraulic conductivity of 10{sup -1} to 10{sup -6} cm/s bound these buried channels; these are barriers to groundwater movement and contain the highest contaminant concentrations in the source region. New remediation technologies are required because the current ones preferentially access the high conductivity units. HPO is an innovative process for the in situ destruction of contaminants in the entire subsurface. It operates by the injection of steam. We have demonstrated in laboratory experiments that many contaminants rapidly oxidize to harmless compounds at temperatures easily achieved by injecting steam, provided sufficient dissolved oxygen is present. One important challenge in a heterogeneous source region is getting heat, contaminants, and an oxidizing agent in the same place at the same time. We have used the NUFT computer program to simulate the cyclic injection of steam into a contaminated aquifer for design of a field demonstration. We used an 8 hour, steam/oxygen injection cycle followed by a 56 hour ...
Date: February 1, 1998
Creator: Knapp, R.B.; Aines, R.M.; Blake, R.G.; Copeland, A.B.; Newmark, R.L. & Tompson, A.F.B.
Partner: UNT Libraries Government Documents Department

Safety criteria for organic watch list tanks at the Hanford Site

Description: This document reviews the hazards associated with the storage of organic complexant salts in Hanford Site high-level waste single- shell tanks. The results of this analysis were used to categorize tank wastes as safe, unconditionally safe, or unsafe. Sufficient data were available to categorize 67 tanks; 63 tanks were categorized as safe, and four tanks were categorized as conditionally safe. No tanks were categorized as unsafe. The remaining 82 SSTs lack sufficient data to be categorized.Historic tank data and an analysis of variance model were used to prioritize the remaining tanks for characterization.
Date: August 1, 1996
Creator: Meacham, J. E.
Partner: UNT Libraries Government Documents Department

Structure-Based Predictive model for Coal Char Combustion.

Description: During the third quarter of this project, progress was made on both major technical tasks. Progress was made in the chemistry department at OSU on the calculation of thermodynamic properties for a number of model organic compounds. Modelling work was carried out at Brown to adapt a thermodynamic model of carbonaceous mesophase formation, originally applied to pitch carbonization, to the prediction of coke texture in coal combustion. This latter work makes use of the FG-DVC model of coal pyrolysis developed by Advanced Fuel Research to specify the pool of aromatic clusters that participate in the order/disorder transition. This modelling approach shows promise for the mechanistic prediction of the rank dependence of char structure and will therefore be pursued further. Crystalline ordering phenomena were also observed in a model char prepared from phenol-formaldehyde carbonized at 900{degrees}C and 1300{degrees}C using high-resolution TEM fringe imaging. Dramatic changes occur in the structure between 900 and 1300{degrees}C, making this char a suitable candidate for upcoming in situ work on the hot stage TEM. Work also proceeded on molecular dynamics simulations at Boston University and on equipment modification and testing for the combustion experiments with widely varying flame types at Ohio State.
Date: September 24, 1997
Creator: Hurt, R.; Colo, J; Essenhigh, R.; Hadad, C & Stanley, E.
Partner: UNT Libraries Government Documents Department

Surface moisture measurement system operation and maintenance manual

Description: The purpose of this manual is to provide detailed operating instructions for the Surface Moisture Measurement System (SMMS).In addition, operating instructions for the Liquid Observation Well Moisture Measurement System (LOWMMS) are included. These systems were developed primarily in support of Tank Waste Remediation System (TWRS) Safety Programs for moisture measurement in organic and ferrocyanide watch list tanks.
Date: June 11, 1996
Creator: Vargo, G.F., Westinghouse Hanford
Partner: UNT Libraries Government Documents Department

Electromagnetic induction moisture measurement system acceptance test plan

Description: The purpose of this acceptance test plan (ATP) is to verify that the mechanical, electrical and software features of the ElectroMagnetic Induction (EMI) probe are operating as designed,and that the unit is ready for field service. The accepted EMI and Surface Moisture Measurement Systems (SMMS) will be used primarily in support of Tank Waste Remediation System (TWRS) Safety Programs for moisture measurement of organic and ferrocyanide watch list tanks.
Date: August 1, 1996
Creator: Vargo, G.F., Westinghouse Hanford
Partner: UNT Libraries Government Documents Department

Lasagna{trademark} soil remediation

Description: Lasagna{trademark} is an integrated, in situ remediation technology being developed by an industrial consortium consisting of Monsanto, E. I. DuPont de Nemours & Co., Inc. (DuPont), and General Electric, with participation from the Department of Energy (DOE) Office of Environmental Management, Office of Science and Technology (EM-50), and the Environmental Protection Agency (EPA) Office of Research and Development (Figure 1). Lasagna{trademark} remediates soils and soil pore water contaminated with soluble organic compounds. Lasagna{trademark} is especially suited to sites with low permeability soils where electroosmosis can move water faster and more uniformly than hydraulic methods, with very low power consumption. The process uses electrokinetics to move contaminants in soil pore water into treatment zones where the contaminants can be captured or decomposed. Initial focus is on trichloroethylene (TCE), a major contaminant at many DOE and industrial sites. Both vertical and horizontal configurations have been conceptualized, but fieldwork to date is more advanced for the vertical configuration.
Date: April 1, 1996
Partner: UNT Libraries Government Documents Department

Chemical and chemically-telated considerations associated with sluicing tank C-106 waste to tank AY-102

Description: New data on tank 241-C-106 were obtained from grab sampling and from compatibility testing of tank C-106 and tank AY-102 wastes.All chemistry-associated and other compatibility information compiled in this report strongly suggests that the sluicing of the contents of tank C-106; in accord with appropriate controls;will pose no unacceptable risk to workers; public safety; or the environment. In addition; it is expected that the sluicing operation will successfully resolve the High-Heat Safety issue for tank C-106.
Date: July 3, 1996
Creator: Babad, H.
Partner: UNT Libraries Government Documents Department

Analysis of consequences of postulated solvent fires in Hanford site waste tanks

Description: This document contains the calculations that support the accident analyses for accidents involving organic solvents. This work was performed to support the Basis for Interim Operation (BIO) and the Final Safety Analysis Report (FSAR) for Tank Waste Remediation Systems (TWRS).
Date: August 12, 1996
Creator: Cowley, W. L.
Partner: UNT Libraries Government Documents Department

Origins of volatile organic compounds emerging from tank 241-C-106 during sluicing

Description: Unexpectedly high concentrations of inorganic gases and volatile organic compounds (VOC) were released from the ventilation stack of tank 241-C-106 during sluicing operations on November 18, 1998. Workers experienced serious discomfort. They reported an obnoxious acrid odor and the 450 ppm VOC in ventilation stack 296-C-006 exceeded the level approved in the air discharge permit. Consequently, the operation was terminated. Subsequent analyses of samples collected opportunistically from the stack indicated many organic compounds including heptenes, heptanones, and normal paraffin hydrocarbons (NPH) and their remnants were present. Subsequently, a process test designed to avoid unnecessary worker exposure and enable collection of analytical samples from the stack, the breathing area, and the receiver tank was conducted on December 16, 1998. The samples obtained during that operation, in which the maximum VOC content of the stack was approximately 35 ppm, have been analyzed by teams at Pacific Northwest National Laboratory and Special Analytic Services (SAS). This report examines the results of these investigations. Future revisions of the report will examine the analytical results obtained for samples collected during sluicing operations in March. This report contains the available evidence about the source term for these emissions. Chapter 2 covers characterization work, including historical information about the layers of waste in the tank, the location of organic compounds in these layers, the total organic carbon (TOC) content and the speciation of organic compounds. Chapter 3 covers the data for the samples from the ventilation stack, which has the highest concentrations of organic compounds. Chapter 4 contains an interpretation of the information connecting the composition of the organic emissions with the composition of the original source term. Chapter 5 summarizes the characterization work, the sample data, and the interpretation of the results.
Date: June 2, 1999
Creator: STAUFFER, L.A.
Partner: UNT Libraries Government Documents Department

Effects of the Cerro Grande Fire (Smoke and Fallout Ash) on Soil Chemical Properties Within and Around Los Alamos National Laboratory

Description: Soil surface (0- to 2-in. depth) samples were collected from areas within and around Los Alamos National Laboratory (LANL) just after the Cerro Grande fire, analyzed for radionuclides, radioactivity, and trace elements (heavy metals), and compared to soil samples collected in 1999 from the same sites. In addition, many types of organic substances (volatile and semivolatile organic compounds, organochlorine pesticides, polychlorinated biphenyls, high explosives, and dioxin and dioxin-like compounds) were assessed in soils from LANL, perimeter, and regional sites after the fire. Results show that impacts to regional, perimeter, and on-site (mesa top) areas from smoke and fallout ash as a result of the Cerro Grande fire were minimal.
Date: November 1, 2000
Creator: Fresquez, P.R.; Velasquez, W.R. & Naranjo, L. Jr.
Partner: UNT Libraries Government Documents Department

Tank 241-BX-103 tank characterization plan

Description: This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, and WHC 222-S Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples for tank 241-BX-103.
Date: April 21, 1995
Creator: Bell, K.E.
Partner: UNT Libraries Government Documents Department

Corrective Action Decision Document/Closure Report for Corrective Action Unit 263: Area 25 Building 4839 Leachfield, Nevada Test Site, Nevada

Description: This Corrective Action Decision Document/Closure Report (CADD/CR) has been prepared for Corrective Action Unit (CAU) 263, Area 25 Building 4839 Leachfield, in accordance with the Federal Facility Agreement and Consent Order. Corrective Action Unit 263 is located in the southwestern part of the Nevada Test Site in Nevada and includes one Corrective Action Site (CAS), CAS 25-05-04 Leachfield. This CADD/CR identifies and rationalizes the U.S. Department of Energy, Nevada Operations Office's (DOE/NV's) recommendation that no corrective action for CAU 263 is necessary. The Corrective Action Decision Document and Closure Report have been combined into one report because sample data collected during the April 1999 corrective action investigation (CAI) disclosed no evidence of contamination at the site. The purpose of the CAI was to identify the presence and the vertical and lateral extent of contaminants of potential concern (COPCs), specifically volatile organic compounds (VOCs) and semivola tile organic compounds (SVOCs) such as 1,4-dichlorobenzene and p-isopropyl toluene. The subsequent investigation included direct-push environmental soil samples from within the leachfield using a Geoprobe{reg_sign} unit; field screening of soil samples for radiological constituents and VOCs; submittal of environmental and quality control samples for testing for total VOCs, total SVOCs, and gamma spectrometry; and collection of soil samples from both the liquid phase and the underlying sludge of the septic tank contents. The CAI activities determined that: (1) all total VOC and total SVOC results were below the preliminary action levels outlined in the Corrective Action Investigation Plan (CAIP), and (2) radiological results were not distinguishable from background concentrations identified in the CAIP. Therefore, the DOE/NV recommended that no corrective action was required at CAU 263. No use restrictions were required to be placed on the CAU because the investigation showed no evidence of co ntamination at the site.
Date: October 1, 1999
Partner: UNT Libraries Government Documents Department

[Energies of organic compounds]

Description: The first part of our study of the enthalpy of reduction of carbonyl compounds has been completed and includes four aldehydes, acetone, a series of cyclic ketones and ethyl acetate. Results suggest that some of the literature data for these compounds are significantly in error. Equilibrium constants have been measured for the reaction of carbonyl compounds with water to give hydrates as well as with methanol to give either hemiacetals or acetals. They cover a wide range, and studies are underway to determine the reasons for the differences. Studies of the enthalpies of hydration of some alkenes which yield tertiary alcohols have been completed, as well as a study of the hydrolysis of lactones. The ``gauche effect`` has been studied, and has been shown to result from the formation of bent bonds when atoms of much different electronegativity are joined.
Date: July 1, 1995
Partner: UNT Libraries Government Documents Department

Comparative Toxicity of Gasoline and Diesel Engine Emissions

Description: Better information on the comparative toxicity of airborne emissions from different types of engines is needed to guide the development of heavy vehicle engine, fuel, lubricant, and exhaust after-treatment technologies, and to place the health hazards of current heavy vehicle emissions in their proper perspective. To help fill this information gap, samples of vehicle exhaust particles and semi-volatile organic compounds (SVOC) were collected and analyzed. The biological activity of the combined particle-SVOC samples is being tested using standardized toxicity assays. This report provides an update on the design of experiments to test the relative toxicity of engine emissions from various sources.
Date: June 19, 2000
Creator: Seagrave, JeanClare; Mauderly, Joe L.; Zielinska, Barbara; Sagebiel, John; Whitney, Kevin; Lawson, Doughlas R. et al.
Partner: UNT Libraries Government Documents Department

OZONE PRODUCTION IN URBAN PLUMES.

Description: Ozone levels observed during a field campaign in Houston were significantly higher than that observed in Phoenix or Philadelphia. An examination of the slope of O{sub x} versus NO{sub z} in the urban plumes shows that NO{sub x} is used 2 to 3 times more efficiently in Houston as compared with Phoenix and Philadelphia. Representative values of OPEx are 7-12, 3, and 4, in Houston, Phoenix, and Philadelphia. Aircraft observations have been used to calculate P(O{sub 3})/P(NO{sub z}). Values in Houston are significantly higher than in Phoenix and Philadelphia. We show that P(O{sub 3})/P(NO{sub z}) is proportional to a VOC/NO{sub 2}-OH reactivity ratio. High values of P(O{sub 3})/P(NO{sub z}) in Houston are due to emissions of reactive olefins from the ship channel region. It is significant that high values of P(O{sub 3})/P(NO{sub z}) occur at NO{sub x} levels up to several 10's of ppb. Not only is the chemistry efficient but it will be long lasting. The occurrence of high NO{sub x} and high OPEx is fostered by the co-location of VOC and NO{sub x} sources in the Houston industrial areas.
Date: September 17, 2001
Creator: KLEINMAN,L.
Partner: UNT Libraries Government Documents Department