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REDUCING ULTRA-CLEAN TRANSPORTATION FUEL COSTS WITH HYMELT{reg_sign} HYDROGEN

Description: This report describes activities for the eighth quarter of work performed under this agreement. We await approval from the Swedish pressure vessel board to allow us to proceed with the procurement of the vessel for super atmospheric testing.
Date: April 1, 2005
Creator: Malone, Donald P. & Renner, William R.
Partner: UNT Libraries Government Documents Department

Process for Generation of Hydrogen Gas from Various Feedstocks Using Thermophilic Bacteria

Description: A method for producing hydrogen gas is provided comprising selecting a bacteria from the Order Thermotogales, subjecting the bacteria to a feedstock and to a suitable growth environment having an oxygen concentration below the oxygen concentration of water in equilibrium with air; and maintaining the environment at a predetermined pH and at a temperature of at least approximately 45 degrees C. for a time sufficient to allow the bacteria to metabolize the feedstock.
Date: September 13, 2005
Creator: Ooteghem Van, Suellen
Partner: UNT Libraries Government Documents Department

Energetic Proton Generation in Ultra-Intense Laser-Solid Interactions

Description: An explanation for the energetic ions observed in the PetaWatt experiments is presented. In solid target experiments with focused intensities exceeding 10{sup 20} W/cm{sup 2}, high-energy electron generation, hard bremsstrahlung, and energetic protons have been observed on the backside of the target. In this report, we attempt to explain the physical process present that will explain the presence of these energetic protons, as well as explain the number, energy, and angular spread of the protons observed in experiment. In particular, we hypothesize that hot electrons produced on the front of the target are sent through to the back off the target, where they ionize the hydrogen layer there. These ions are then accelerated by the hot electron cloud, to tens of MeV energies in distances of order tens of microns, whereupon they end up being detected in the radiographic and spectrographic detectors.
Date: March 1, 2000
Creator: Wilks, S.C.; Langdon, A.B.; Cowan, T.E.; Roth, M.; Singh, M.; Hatchett, S. et al.
Partner: UNT Libraries Government Documents Department

Characterizations of Hydrogen Energy Technologies

Description: In 1996, Dr. Ed Skolnik of Energetics, Incorporated, began a series of visits to the locations of various projects that were part of the DOE Hydrogen Program. The site visits/evaluations were initiated to help the DOE Program Management, which had limited time and limited travel budgets, to get a detailed snapshot of each project. The evaluations were soon found to have other uses as well: they provided reviewers on the annual Hydrogen Program Peer Review Team with an in-depth look at a project--something that is lacking in a short presentation--and also provided a means for hydrogen stakeholders to learn about the R&D that the Hydrogen Program is sponsoring. The visits were conducted under several different contract mechanisms, at project locations specified by DOE Headquarters Program Management, Golden Field Office Contract Managers, or Energetics, Inc., or through discussion by some or all of the above. The methodology for these site-visit-evaluations changed slightly over the years, but was fundamentally as follows: Contact the Principal Investigator (PI) and arrange a time for the visit; Conduct a literature review. This would include a review of the last two or three years of Annual Operating Plan submittals, monthly reports, the paper submitted with the last two or three Annual Peer Review, published reviewers' consensus comments from the past few years, publications in journals, and journal publications on the same or similar topics by other researchers; Send the PI a list of questions/topics about a week ahead of time, which we would discuss during the visit. The types of questions vary depending on the project, but include some detailed technical questions that delve into some fundamental scientific and engineering issues, and also include some economic and goal-oriented topics; Conduct the site-visit itself including--Presentations by the PI and/or his staff. This would be formal in some cases, ...
Date: April 1, 2003
Creator: Inc, Energetics
Partner: UNT Libraries Government Documents Department

FLAMMABLE GAS DIFFUSION THROUGH SINGLE SHELL TANK (SST) DOMES

Description: This report quantified potential hydrogen diffusion through Hanford Site Single-Shell tank (SST) domes if the SSTs were hypothetically sealed airtight. Results showed that diffusion would keep headspace flammable gas concentrations below the lower flammability limit in the 241-AX and 241-SX SST. The purpose of this document is to quantify the amount of hydrogen that could diffuse through the domes of the SSTs if they were hypothetically sealed airtight. Diffusion is assumed to be the only mechanism available to reduce flammable gas concentrations. The scope of this report is limited to the 149 SSTs.
Date: November 10, 2003
Creator: MEACHAM, J.E.
Partner: UNT Libraries Government Documents Department

Materials Performance in USC Steam

Description: Materials Performance in USC Steam: (1) pressure effects on steam oxidation - unique capability coming on-line; (2) hydrogen evolution - hydrogen permeability apparatus to determine where hydrogen goes during steam oxidation; and (3) NETL materials development - steam oxidation resource for NETL developed materials.
Date: September 7, 2011
Creator: Holcomb, G. R.; Tylczak, J.; Meier, G. H. & Yanar, N. M.
Partner: UNT Libraries Government Documents Department

2011 GASEOUS IONS GORDON RESEARCH CONFERENCE

Description: The Gaseous Ions: Structures, Energetics and Reactions Gordon Research Conference will focus on ions and their interactions with molecules, surfaces, electrons, and light. The conference will cover theory and experiments, and systems ranging from molecular to biological to clusters to materials. The meeting goal continues to be bringing together scientists interested in fundamentals, with those applying fundamental phenomena to a wide range of practical problems. Each of the ten conference sessions will focus on a topic within this spectrum, and there will also be poster sessions for contributed papers, with sufficient space and time to allow all participants to present their latest results. To encourage active participation by young investigators, about ten of the poster abstracts will be selected for 15 minute 'hot topic' talks during the conference sessions. Hot topic selection will be done about a month before the meeting. Funds should be available to offset the participation cost for young investigators.
Date: March 4, 2011
Creator: Anderson, Scott
Partner: UNT Libraries Government Documents Department

STUDY OF RESONANCES IN THE Σ-π SYSTEM

Description: In order to study resonances in the {Sigma}-{pi} system, we have analyzed reactions in which a {Sigma} hyperon and two or three pions are produced in K{sup -}-p interactions at 1.22 {+-} 0.040 and 1.51 {+-} 0.050 GeV/c incident K{sup -} momentum (i. e., 1895 and 2025 MeV center-of-mass energy), using the Lawrence Radiation Laboratory's 72-in. hydrogen bubble chamber.
Date: June 12, 1962
Creator: Alston, Margaret H.; Alvarez, Luis W.; Ferro-Luzzi, Massimiliano; Rosenfeld, Arthur H..; Ticho, Harold K. & Wojcicki, Stanley G.
Partner: UNT Libraries Government Documents Department

PRODUCTION OF S = 0, -1 RESONANT STATES IN K<sup>-</sup> p INTERACTIONS AT 2.45 GeV/c

Description: About 70,000 pictures of 2.45-GeV/c K{sup -}-p interactions have been obtained in the present 72-inch hydrogen bubble-chamber experiment. Approximately 24,000 events of all topologies except 1-, 2-, and 3-prong events have been measured, and 50% have been remeasured. They report here on a study of the production of known resonances in the reactions: (1) K{sup -} + p {yields} {Lambda} + {pi}{sup +} + {pi}{sup -}; (2) K{sup -} + p {yields} {Lambda} + {pi}{sup +} + {pi}{sup 0} + {pi}{sup -}. The cross section for production and number of events in reactions (1) and (2) are given in Table I.
Date: July 7, 1964
Creator: Ross, Ronald R.; Friedman, Jerome H.; Siegel, Daniel M.; Flatte,Stanley; Alvarez, Luis W.; Barbaro-Galtieri, Angela et al.
Partner: UNT Libraries Government Documents Department

Liquid Hydrogen Bubble Chambers

Description: After the first hydrocarbon bubble chambers were built by Donald Glaser in 1952, work was started at Chicago and Berkeley to find if liquid hydrogen could be used as the working fluid in a bubble chamber. In the fall of 1953, it was found by the Chicago group that superheated liquid hydrogen could be made to boil under the influence of ionizing radiation, but no tracks were observed. The observation of tracks at Berkeley a few months later completed the proof that hydrogen was a usable bubble chamber liquid. (Irradiated liquid nitrogen boils when superheated, but as of spring 1956 no one has seen tracks in liquid nitrogen.) In the past two years, the Chicago group has built several all-glass hydrogen chambers, the most recent of which is approximately 5.5 by 5.5 by 20 cm inside dimensions. Their chambers have been of the so-called clean variety (like Glaser's eariy ones), in which no boiling takes place unless ionizing particles aze present. They have used their latest chamber in an extensive study of the scattering of low-energy pions by protons.
Date: April 4, 1956
Creator: Alvarez, Luis W.
Partner: UNT Libraries Government Documents Department

A Liquid-Hydrogen Cerenkov Counter

Description: Two models of a liquid-hydrogen (?-illegible) Cherenkov counter (illegible) been constructed (illegible). The first served as a prototype (?-illegible) and was (illegible) to demonstrate the feasibility (?-illegible) of the (illegible) concept (?-illegible) (illegible) liquid hydrogen does not give scintillation (?-illegible) (illegible) that of Cherenkov light. The second, final version (?-illegible), (illegible) in an experiment (?-illegible) in which particles brought to rest (?-illegible) (illegible) (illegible) electrons. In this second counter, the efficiency (?-illegible) (illegible) relativistic (?-illegible) particles (?-illegible) by their Cherenkov radiation in liquid hydrogen (?-illegible) was measured by stopping (illegible) mesons in the hydrogen and detecting their decay electrons outside (?-illegible) of the flask (?-illegible) after a suitable time delay. An average detection (?-illegible) efficiency (?-illegible) of 75% (?-illegible) was (illegible) taken over the volume of the hydrogen (?-illegible).
Date: May 9, 1963
Creator: Zipi, T.F.; Chamberlain, Owen; Kadyk, John A. & York, Carl M.
Partner: UNT Libraries Government Documents Department

EXPERIMENTS ON N-P SCATTERING WITH 260 MEV NEUTRONS

Description: Neutrons produced by 350 Mev protons impinging on beryllium are scattered by hydrogen. We measure the differential scattering cross section as a function of the scattering angle. Results are summarized in Fig. 3 of the paper.
Date: March 6, 1950
Creator: Kelly, E.; Leith, C.; Segre, E. & Wiegand, C.
Partner: UNT Libraries Government Documents Department

MODIFIED BOROHYDRIDES FOR REVERSIBLE HYDROGEN STORAGE

Description: This paper reports the results in the effort to destabilize lithium borohydride for reversible hydrogen storage. A number of metals, metal hydrides, metal chlorides and complex hydrides were selected and evaluated as the destabilization agents for reducing dehydriding temperature and generating dehydriding-rehydriding reversibility. It is found that some additives are effective. The Raman spectroscopic analysis shows the change of B-H binding nature.
Date: May 10, 2006
Creator: Au, Ming
Partner: UNT Libraries Government Documents Department

HYDROGEN EFFECTS ON LASER ENGINEERED NET SHAPE (LENS) REPAIRED WELDMENTS

Description: New methods of repairing mis-machined components are always of interest. In this study, an innovative method using Laser Engineered Net Shape{trademark} (LENS{reg_sign}) forming was used to repair intentionally mis-machined test articles. The components were repaired and subsequently hydrogen charged and burst tested. The LENS repair did not have an adverse effect on the solid state weld process that was used to repair the components. Hydrogen charged samples failed in a similar manner to the uncharged samples. Overall, the prospects for LENS repairing similar products are favorable and further work is encouraged.
Date: October 6, 2006
Creator: Korinko, P & Thad Adams, T
Partner: UNT Libraries Government Documents Department

SLUDGE BATCH 4 FOLLOW-UP QUALIFICATION STUDIES TO EVALUATE HYDROGEN GENERATION

Description: Follow-up testing was conducted to better understand the excessive hydrogen generation seen in the initial Sludge Batch 4 (SB4) qualification Sludge Receipt and Adjustment Tank/Slurry Mix Evaporator (SRAT/SME) simulation in the Savannah River National Laboratory (SRNL) Shielded Cells. This effort included both radioactive and simulant work. The initial SB4 qualification test produced 0.59 lbs/hr hydrogen in the SRAT, which was just below the DWPF SRAT limit of 0.65 lbs/hr, and the test produced over 0.5 lbs/hr hydrogen in the SME cycle on two separate occasions, which were over the DWPF SME limit of 0.223 lbs/hr.
Date: August 23, 2007
Creator: Pareizs, J; David Koopman, D; Dan Lambert, D & Cj Bannochie, C
Partner: UNT Libraries Government Documents Department

TEMPERATURE-PROGRAMMED DESORPTION: PRINCIPLES, INSTRUMENT DESIGN, AND DEMONSTRATION WITH NAALH4

Description: This article is a brief introduction to temperature-programmed desorption (TPD), an analytical technique devised to analyze, in this case, materials for their potential as hydrogen storage materials. The principles and requirements of TPD are explained and the different components of a generic TPD apparatus are described. The construction of a modified TPD instrument from commercially available components is reported together with the control and acquisition technique used to create a TPD spectrum. The chemical and instrumental parameters to be considered in a typical TPD experiment and the analytical utility of the technique are demonstrated by the dehydrogenation of titanium-doped NaAlH{sub 4} by means of thermally programmed desorption.
Date: November 7, 2006
Creator: Stowe, A & Ragaiy Zidan, R
Partner: UNT Libraries Government Documents Department

Final Report - Novel Approach to Non-Precious Metal Catalysts

Description: This project was directed at reducing the dependence of PEM fuel cells catalysts on precious metals. The primary motivation was to reduce the cost of the fuel cell stack as well as the overall system cost without loss of performance or durability. Platinum is currently the catalyst of choice for both the anode & the cathode. However, the oxygen reduction reaction (ORR) which takes place on the cathode is an inherently slower reaction compared to the hydrogen oxidation reaction (HOR) which takes place on the anode. Therefore, more platinum is needed on the cathode than on the anode to achieve suitable fuel cell performance. As a result, developing a replacement for platinum on the cathode side will have a larger impact on overall stack cost. Thus, the specific objectives of the project, as stated in the solicitation, were to produce non-precious metal (NPM) cathode catalysts which reduce dependence on precious metals (especially Pt), perform as well as conventional precious metal catalysts currently in use in MEAs, cost 50% less compared to a target of 0.2 g Pt/peak kW, & demonstrate durability of greater than 2000 hours with less than 10% power degradation. During the term of the project, DOE refined its targets for NPM catalyst activity to encompass volumetric current density. The DOE Multi-Year RD&D Plan (2005) volumetric current density targets for 2010 & 2015 are greater than 130 A/cm3 & 300 A/cm3 at 800 mV (IR-free) respectively. The initial approach to achieve these targets was to use vacuum deposition techniques to deposit transition metal, carbon and nitrogen moieties onto 3M’s nanostructured thin film (NSTF) catalyst support. While this approach yielded compounds with similar physicochemical characteristics as catalysts reported by others as active for ORR, the activity of these vacuum deposited catalysts was not satisfactory. In order to enhance catalytic ...
Date: November 17, 2007
Creator: Atanasoski, Radoslav
Partner: UNT Libraries Government Documents Department

United States Energy Association Final Report International Partnership for the Hydrogen Economy Ministerial Conference

Description: This report summarizes the activities of the United States Energy Association as it conducted the initial Ministerial Meeting of the International Partnership for the Hydrogen Economy in Washington, DC on November 18-21, 2003. The report summarizes the results of the meeting and subsequent support to the Office of Energy Efficiency and Renewable Energy in its role as IPHE Secretariat.
Date: April 5, 2006
Creator: Polen, William L.
Partner: UNT Libraries Government Documents Department

METHODOLOGY FOR THE NUMBER OF FILTERS NEEDED IN A WASTE BOX

Description: Waste in large waste boxes can generate volatile organic compounds (VOCs) and hydrogen. These waste boxes may or may not have flow paths out of them (although it is believed that most do). These boxes will be retrieved, sampled, and then coated with polyurea. After coating, filters will be installed in the box to keep the concentration of VOCs and hydrogen acceptably low. The MDSA requires that a vent path must be protected during application of the polyurea coating. If the box has been sampled then it is vented and the vent path must be protected. This report provides a model in which the user inputs the free volume of the waste box, sample concentration (ppm of total VOC or volume fraction hydrogen) along with the number of filters to be placed into the waste box lid. Using this information, the model provides an estimate of concentration vs. time or the number of filters needed to reduce the concentration by a specified fraction. If the equations from this report are placed into spreadsheets which are then used to demonstrate TSR compliance, the spreadsheets must come under the Software QA Plan for such documents. Chapters 2 and 3 present the theory. Chapter 4 presents the method with examples of its use found in Chapter 5. Chapter 6 provides the basis far the use of 1,000 ppm as the concentration below which the method is valid under any condition.
Date: May 17, 2007
Creator: MARUSICH, R.M.
Partner: UNT Libraries Government Documents Department