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Crucible melts and bench-scale ISV (in situ vitrification) tests on simulated wastes in INEL (Idaho National Engineering Laboratory) soils

Description: This report summarizes the results of eight crucible melt tests and three bench-scale in situ vitrification (ISV) test that were performed on simulated metals/soils mixtures containing actual site soils from the Idaho National Engineering Laboratory (INEL). The crucible melt and bench-scale ISV tests are a part of efforts by the Pacific Northwest Laboratory (PNL) to assist the INEL in conducting a treatability study on ISV for application to the mixed waste buried at the INEL subsurface disposa… more
Date: May 1, 1990
Creator: Farnsworth, R. K.; Oma, K. H. & Reimus, M. A. H.
Partner: UNT Libraries Government Documents Department
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Examination of fast reactor fuels, FBR analytical quality assurance standards and methods, and analytical methods development: irradiation tests. Progress report, April 1--June 30, 1976, and FY 1976. [UO/sub 2/; PuO/sub 2/]

Description: Characterization of unirradiated and irradiated LMFBR fuels by analytical chemistry methods will continue, and additional methods will be modified and mechanized for hot cell application. Macro- and microexaminations will be made on fuel and cladding using the shielded electron microprobe, emission spectrograph, radiochemistry, gamma scanner, mass spectrometers, and other analytical facilities. New capabilities will be developed in gamma scanning, analyses to assess spatial distributions of fue… more
Date: August 1, 1976
Creator: Baker, R. D. (comp.)
Partner: UNT Libraries Government Documents Department
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Thorium utilization program. Quarterly progress report for the period ending November 30, 1975. [Fuel element crushing, solids handling, fluidized bed combustion, aqueous separations, solvent extraction, systems design and drafting, alternative head-end reprocessing, and fuel recycle systems analysis]

Description: The development program for HTGR fuel reprocessing continues to emphasize the design and construction of a prototype head-end line. Design work on the multistage crushing system, the primary and secondary fluidized bed burners, the pneumatic transfer systems, and the ancillary fixtures for semiremote assembly and disassembly is essentially complete. Fabrication and receipt of all major components is under way, and auxiliary instrumentation and support systems are being installed. Studies of flo… more
Date: December 31, 1975
Partner: UNT Libraries Government Documents Department
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''Glassy'' low temperature thermal properties in crystalline solids

Description: Amorphous dielectrics are known to exhibit anomalous low temperature properties. An extensive review of these properties is presented with an eye toward an understanding of low-lying excitation modes thought to exist in glasses. Work on these systems is described in which a Zr-20 percent Nb samplewhich would be expected to reduce and redistribute the proposed tunneling states. Indeed, the thermal conductivity becomes similar to that of a quenched Zr-8 percent Nb sample and the ''excess'' specif… more
Date: May 1, 1976
Creator: Nathan, B. D.
Partner: UNT Libraries Government Documents Department
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Examination of fast reactor fuels, FBR analytical quality assurance standards and methods, and analytical methods development: irradiation tests. Progress report, January 1--March 31, 1977. [UO/sub 2/; PuO/sub 2/]

Description: This project is directed toward the examination and comparison of the effects of neutron irradiation on LMFBR Program fuel materials. Characterization of unirradiated and irradiated fuels by analytical chemistry methods will continue, and additional methods will be modified and mechanized for hot cell application. Macro- and microexaminations will be made on fuel and cladding, using the shielded electron microprobe, emission spectrograph, radiochemistry, gamma scanner, mass spectrometers, and o… more
Date: May 1, 1977
Creator: Baker, R. D. (comp.)
Partner: UNT Libraries Government Documents Department
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Retention, isotope exchange, and thermal release of hydrogen in candidate materials for TFTR

Description: The materials studied included TiC, TiB/sub 2/, VB/sub 2/, B/sub 4/C, B, Si, graphite, and the metals Ti, V, and 304L stainless steel. The TiC and TiB/sub 2/ were formed by chemical vapor deposition on a graphite substrate. The C/Ti ratio of the TiC was measured to be 1.0 +- .05 by ion backscattering analysis. The Ti and V were explosively bonded to copper substrates, and the VB/sub 2/ was made by borodizing vanadium. Carbon (compression annealed pyrolytic graphite from Union Carbide and Papyex… more
Date: August 1, 1980
Creator: Wampler, W. R.; Doyle, B. L.; Brice, D. K. & Picraux, S. T.
Partner: UNT Libraries Government Documents Department
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INEL BNCT Research Program, September--October 1992

Description: This report presents summaries for two months of current research of the Idaho National Engineering Laboratory (INEL) Boron Neutron Capture Therapy (BNCT) Program. Information is presented on development and murine screening experiments of low-density lipoprotain. carboranyl alanine, and liposome boron containing compounds. Pituitary tumor call culture studies are described. Drug stability, pharmacology and toxicity evaluation of borocaptate sodium (BSH) and boronophonylalanine (BPA) are descri… more
Date: December 1, 1992
Creator: Venhuizen, J.R.
Partner: UNT Libraries Government Documents Department
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Effect of Internal Alpha Radiation on Borosilicate Glass Containing Savannah River Plant Waste

Description: Effects of internal alpha radiation on borosilicate glass, a perspective matrix for long-term storage of Savannah River Plant (SRP) radioactive waste, were evaluated in samples containing 45 wt % simulated waste (Fe(OH)/sub 3/--MnO/sub 2/) and either 0.5 wt % /sup 244/Cm or 1 wt % /sup 238/Pu. A glass containing /sup 238/Pu without waste was also studied for comparison. The glasses were examined for changes in physical stability, leachability, and dilatation. Alpha dose rates in the test glasse… more
Date: May 1, 1978
Creator: Bibler, N. E. & Kelley, J. A.
Partner: UNT Libraries Government Documents Department
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Metallographic preparation of titanium diboride coatings

Description: A method is described for preparing metallographic cross sections of thin, hard, chemically vapor deposited titanium diboride coatings on various softer substrates. Standard metallographic preparation techniques were found to result in fracturing and edge rounding of the coatings. It is shown that these problems can be avoided by unidirectional grinding on worn 600 grit silicon carbide abrasive paper. Typical photomicrographs of chemically vapor deposited titanium diboride coatings are shown al… more
Date: March 1, 1980
Creator: McAllaster, Mark E.
Partner: UNT Libraries Government Documents Department
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Leach rates of high activity waste from borosilicate glass

Description: Radioactive Savannah River Plant wastes (tank sludges) were mixed with two types of borosilicate glass frit. Leaching rates in static distilled water were measured. Leach rates of /sup 137/Cs, /sup 90/Sr, and plutonium were approximately equal: 10/sup -5/ to 10/sup -6/ g/cm/sup 2/-day initially, 10/sup -7/ to 10/sup -8/ g/cm/sup 2/-day after two weeks, and 10/sup -8/ to 10/sup -9/ g/cm/sup 2/-day after 100 days. The glasses showing the highest leachability were also devitrified easily. The leac… more
Date: January 1, 1978
Creator: Wiley, J. R.
Partner: UNT Libraries Government Documents Department
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Electron reflection from one-dimensional potential barriers

Description: This report summarizes the relevant experimental evidence for electron reflectivity effects in TEC and describes the analytical effort to better understand electron reflectivity as a function of the potential configuration of the surface layer. The analyses consider rectangular and triangular barrier models with, and without, image potentials. The calculated results are presented and discussed. Details of the solutions are given in Appendices A, B, and C. The computer programs to obtain these r… more
Date: September 1, 1978
Creator: Balestra, C. L.; Huffman, F. N. & Wang, C. C.
Partner: UNT Libraries Government Documents Department
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Boron arsenide thin film solar cell development. Final report

Description: Pyrolytic decomposition of diborane and arsine has been used in attempts to grow polycrystalline BAs films. This method, however, produced only amorphous films for deposition temperatures below 920/sup 0/C and polycrystalline boron subarsenide (B/sub 12/As/sub 2/) flms for deposition temperatures above this value. The amorphous films have been determined to have a significant arsenic content but the actual stoichiometry was not obtained. The films were adherent on single crystal sapphire (0001)… more
Date: September 1, 1980
Creator: Boone, J.L. & Van Doren, T.P.
Partner: UNT Libraries Government Documents Department
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Development of low level liquid waste treatment systems: April-September 1981

Description: The pilot plant reverse osmosis system was demonstrated to be effective in removing large percentages of cobalt-60, iodine-125, and a mixture of cesium-137, cobalt-60, and iodine-125 from two types of aqueous streams. The effectiveness of three membrane porosities, 0, 50, and 97% salt rejection, were explored with each isotope. The 97% salt rejection membrane was the most effective in each experiment. Removals as high as 97.5% of the cobalt, 92.9% of the iodine and 95.1% of the combined isotope… more
Date: March 5, 1982
Creator: Williams, M.K.; Colvin, C.M. & Bond, W.H.
Partner: UNT Libraries Government Documents Department
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Vacuum deposited polycrystalline silicon films for solar cell applications. Second quarterly technical progress report. January 1-March 31, 1980

Description: A careful study of a specially formed thin silicon layer on TiB/sub 2/-coated sapphire reveals that the interaction layer of TiSi/sub 2/ is composed of larger grains. Processing steps were developed which lead closer to the goal of fabricating polycrystalline silicon photovoltaic devices completely by vacuum deposition. Both n-type and p-type silicon are now being deposited. New deposition masks were made for depositing the n-regions upon the p-layers. New electrode deposition masks were also m… more
Date: May 1, 1980
Creator: Feldman, C.; Arlington, III, C. H.; Blum, N. A. & Satkiewicz, F. G.
Partner: UNT Libraries Government Documents Department
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Vacuum deposited polycrystalline silicon films for solar cell applications. Quarterly report, 1 April-30 June 1980

Description: Polycrystalline p-type films were vacuum deposited onto TiB/sub 2/ coated alumina and sapphire substrates. Epitaxial layers were also formed on single crystal silicon substrates. Junctions in the layers were created by both gaseous diffusion in a tube furnace and by vacuum deposition. The TiB/sub 2/ vacuum deposited bottom electrodes have resistivities between 30 and 40 ..mu.. ..cap omega..-cm. All-vacuum-deposited solar cells were fabricated for the first time. Efficiencies approaching those i… more
Date: August 1, 1980
Creator: Feldman, C.; Arrington, III, C. H.; Blum, N. A. & Satkiewicz, F. G.
Partner: UNT Libraries Government Documents Department
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Defense waste processing facility precipitate hydrolysis process

Description: Sodium tetraphenylborate and sodium titanate are used to assist in the concentration of soluble radionuclide in the Savannah River Plant's high-level waste. In the Defense Waste Processing Facility, concentrated tetraphenylborate/sodium titanate slurry containing cesium-137, strontium-90 and traces of plutonium from the waste tank farm is hydrolyzed in the Salt Processing Cell forming organic and aqueous phases. The two phases are then separated and the organic phase is decontaminated for … more
Date: March 1, 1986
Creator: Doherty, J P; Eibling, R E & Marek, J C
Partner: UNT Libraries Government Documents Department
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Low-frequency nuclear quadrupole resonance with a dc SQUID

Description: Conventional pure nuclear quadrupole resonance (NQR) is a technique well suited for the study of very large quadrupolar interactions. Numerous nuclear magnetic resonance (NMR) techniques have been developed for the study of smaller quadrupolar interactions. However, there are many nuclei which have quadrupolar interactions of intermediate strength. Quadrupolar interactions in this region have traditionally been difficult or unfeasible to detect. This work describes the development and applicati… more
Date: July 1, 1991
Creator: Chang, J.W.
Partner: UNT Libraries Government Documents Department
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Moessbauer studies of ternary superconductors

Description: Moessbauer studies of the ternary Chevrel phase and rare earth rhodium boride superconductors have been made. Anomalous phonon properties at the Sn site in SnMo/sub 6/S/sub 8/, SnMo/sub 6/Se/sub 8/, and La/sub 0/ /sub 98/Sn/sub 0/ /sub 02/Mo/sub 6/Se/sub 8/ have been investigated. Studies of polarization of conduction electrons at the site of the magnetic ion have been made by means of the /sup 151/Eu Moessbauer effect in Eu/sub x/Sn/sub 1-x/Mo/sub 6/S/sub 8/ and the effects of such polarizatio… more
Date: January 1, 1978
Creator: Kimball, C. W.; Van Landuyt, G. L.; Barnet, C. D.; Shenoy, G. K.; Dunlap, B. D. & Fradin, F. Y.
Partner: UNT Libraries Government Documents Department
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DOE/JPL Advanced Thermionic Technology Program. Progress report No. 40, July-August-September 1979

Description: The primary long-term goal of the DOE effort at Thermo Electron Corporation is to improve TEC performance to the level that thermionic topping of fossil fuel steam powerplants becomes technically possible and economically attractive. The focus of the JPL program is to develop thermionic conversion technology appropriate for nuclear electric propulsion (NEP) missions. This report covers progress made during the three-month period from July through September 1979. During this period, significant … more
Date: January 1, 1979
Partner: UNT Libraries Government Documents Department
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DOE/JPL Advanced Thermionic Technology Program. Progress report No. 37, December 1978-January 1979

Description: Continuing research on thermionic converters is described. Topics include thermionic converter plasma studies, low-temperature converter development, component hardware development, and combustion-heated thermionic device. JPL tasks include basic surface experiments, triode converter experiments, design of cylindrical converter, and high-efficiency conversion experiments. Experimental results are reported. (WHK)
Date: January 1, 1979
Partner: UNT Libraries Government Documents Department
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DOE/JPL advanced thermionic technology program. Progress report No. 38, February-March 1979

Description: Progress on DOE tasks is reported including (1) surface and plasma investigations (surface characterization chamber experiments, spectroscopic plasma measurements, and converter theory), (2) low temperature converter development (tungsten emitter, lanthanum hexaboride collector and tungsten emitter, tungsten oxide collector), and (3) component hardware development. JPL tasks reported include high-temperature converter evaluation, advanced converter studies, and correlation of design interfaces.… more
Date: January 1, 1979
Partner: UNT Libraries Government Documents Department
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Investigation of materials for inert electrodes in aluminum electrodeposition cells

Description: Work was divided into major efforts. The first was the growth and characterization of specimens; the second was Hall cell performance testing. Cathode and anode materials were the subject of investigation. Preparation of specimens included growth of single crystals and synthesis of ultra high purity powders. Special attention was paid to ferrites as they were considered to be the most promising anode materials. Ferrite anode corrosion rates were studied and the electrical conductivities of a se… more
Date: September 14, 1987
Creator: Haggerty, J. S. & Sadoway, D. R.
Partner: UNT Libraries Government Documents Department
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ERDA/NASA Advanced Thermionic Technology Program. Progress report No. 25. Report No. TE4220/4233-14-78

Description: Progress is reported in the areas of (1) surface studies (surface theory, surface characterization chamber, activation chamber), (2) plasma studies (converter theory, enhanced mode conversion), (3) converter development (low-temperature conversion experiments, high-efficiency converter experiments), and (4) hot shell development. (WHK)
Date: July 1, 1977
Creator: Toy, A.
Partner: UNT Libraries Government Documents Department
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Relationship between borosilicate glass composition, structure, and durability test response (SRS)

Description: The chemical durability of 30 glasses from the Na[sub 2]O [center dot] B[sub 2]O[sub 3] [center dot] SiO[sub 2] [center dot] Al[sub 2]O[sub 3] [center dot] Fe[sub 2]O[sub 3][center dot]CaO system was examined. Two standard leach tests, MCC-1P and PCT, were performed in unbuffered, deionized water. PCT tests were performed for durations up to twenty-four weeks to obtain glass dissolution rate data. Short-term MCC-1P test leachate solutions are determined by the glass composition. Long-term glass… more
Date: January 1, 1992
Creator: Ramsey, W. G.; Jantzen, Carol M. & Taylor, T. D.
Partner: UNT Libraries Government Documents Department
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