Conversion of the rocket propellant UDMH to a reagent useful in vicarious nucleophilic substitution reactions
Description:
The objective of our program is to develop novel, innovative solutions for the disposal of surplus energetic materials resulting from the demilitarization of conventional and nuclear munitions. In this report we describe the use of surplus propellant (UDMH) and explosives (TNT, Explosive D) as chemical precursors for higher value products. The conversion of UDMH to 1,1,1-trimethylhydrazinium iodide (TMHI) provides a new aminating reagent for use in Vicarious Nucleophilic Substitution (VNS) reac…
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Date:
November 10, 1995
Creator:
Mitchell, A. R.; Pagoria, P. F. & Schmidt, R. D.
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UNT Libraries Government Documents Department