Zintl cluster chemistry in the alkali-metal-gallium systems
Description:
Previous research into the alkali-metal-gallium systems has revealed a large variety of networked gallium deltahedra. The clusters are analogues to borane clusters and follow the same electronic requirements of 2n+2 skeletal electrons for closo-deltahedra. This work has focused on compounds that do not follow the typical electron counting rules. The first isolated gallium cluster was found in Cs{sub 8}Ga{sub 11}. The geometry of the Ga{sub 11}{sup 7{minus}} unit is not deltahedral but can be de…
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Date:
March 27, 1998
Creator:
Henning, R.
Partner:
UNT Libraries Government Documents Department