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Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: April-July 2004

Description: Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library are being sampled to collect CO{sub 2} adsorption isotherms. Sidewall core samples have been acqu… more
Date: August 1, 2004
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
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Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: October-December 2002

Description: Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is est… more
Date: February 11, 2003
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: January-March 2005

Description: Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples wer… more
Date: April 26, 2005
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: October-December 2004

Description: Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples wer… more
Date: January 28, 2005
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: July-Septmeber 2002

Description: Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is est… more
Date: February 10, 2003
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
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Quenching and stabilization of MIS retorts: Bench-scale experiments

Description: This research was conducted to evaluate in situ retort stabilization methods. The objective of the bench-scale simulations was to evaluate possible post-retorting operations procedures for the optimum cleaning of spent retorts. After simulating conditions of modified in situ (MIS) retorts at the time retorting had ended, procedures to accelerate retort cleanup without using large volumes of water were investigated. Samples from various levels of the retort were used to determine the amount of w… more
Date: April 1, 1991
Creator: Barbour, F. A. & Boysen, J. E.
Partner: UNT Libraries Government Documents Department
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Natural gas accumulations in low-permeability Tertiary, and Cretaceous (Campanian and Maastrichtian) rock, Uinta Basin, Utah. Final report

Description: This report characterizes Upper Cretaceous Campanian and Maastrichtian, and lower Tertiary gas-bearing rocks in the Uinta Basin with special emphasis on those units that contain gas in reservoirs that have been described as being tight. The report was prepared for the USDOE whose Western Tight Gas Sandstone Program cofunded much of this research in conjunction with the US Geological Survey`s Evolution of Sedimentary Basins, and Onshore Oil and Gas Programs. (VC)
Date: February 1, 1992
Creator: Fouch, T. D.; Wandrey, C. J.; Pitman, J. K.; Nuccio, V. F.; Schmoker, J. W.; Rice, D. D. et al.
Partner: UNT Libraries Government Documents Department
open access

Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: January-March 2003

Description: Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, strategy is to inject CO{sub 2} into organic-rich shales of Devonian age. Devonian black shales underlie approximately two-thirds of Kentucky and are generally thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky. The Devonian black shales serve as both the source and trap for large quantities of natural gas; total gas in place for the shales in Kentucky is est… more
Date: April 28, 2003
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: April-June 2005

Description: Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples wer… more
Date: July 29, 2005
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: July-Septmeber 2004

Description: Devonian gas shales underlie approximately two-thirds of Kentucky. In the shale, natural gas is adsorbed on clay and kerogen surfaces. This is analogous to methane storage in coal beds, where CO{sub 2} is preferentially adsorbed, displacing methane. Black shales may similarly desorb methane in the presence of CO{sub 2}. Drill cuttings from the Kentucky Geological Survey Well Sample and Core Library were sampled to determine CO{sub 2} and CH{sub 4} adsorption isotherms. Sidewall core samples wer… more
Date: January 1, 2005
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

NATURAL GAS RESOURCES IN DEEP SEDIMENTARY BASINS

Description: From a geological perspective, deep natural gas resources are generally defined as resources occurring in reservoirs at or below 15,000 feet, whereas ultra-deep gas occurs below 25,000 feet. From an operational point of view, ''deep'' is often thought of in a relative sense based on the geologic and engineering knowledge of gas (and oil) resources in a particular area. Deep gas can be found in either conventionally-trapped or unconventional basin-center accumulations that are essentially large … more
Date: February 5, 2002
Creator: Dyman, Thaddeus S.; Cook, Troy; Crovelli, Robert A.; Henry, Allison A.; Hester, Timothy C.; Johnson, Ronald C. et al.
Partner: UNT Libraries Government Documents Department
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Solid-state NMR characterization of Mowry Formation shales

Description: Solid-state {sup 13}C and {sup 29}Si NMR measurements were carried out on a series of petroleum source rocks from the Mowry Formation of the Powder River Basin in Wyoming. The objectives of this study wereto use CP/MAS {sup 13}C NMR measurements to monitor changes in the carbon structure of the kerogen that result from depth of burial, and to examine the feasibility of {sup 29}Si NMR for studying the thermal alteration of clay minerals during diagenesis. Carbon and silicon NMR measurements were… more
Date: April 1, 1992
Creator: Miknis, F. P.
Partner: UNT Libraries Government Documents Department
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Pressurized fluidized-bed hydroretorting of eastern oil shales. Volume 3, Task 4, Beneficiation research: Final report, September 1987--May 1991

Description: The Mineral Resources Institute at the University of Alabama, along with investigators from the University of Pittsburgh and the University of Nevada Reno, have conducted a research program on the beneficiation of Eastern oil shales. The objective of the research program was to evaluate and adapt those new and emerging technologies that have the potential to improve the economics of recovering oil from Eastern oil shales. The technologies evaluated in this program can be grouped into three area… more
Date: March 1, 1992
Partner: UNT Libraries Government Documents Department
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Kinetic models of hydrocarbon generation

Description: We are carrying out an integrated program of laboratory experiments, kinetics modeling, and basin thermal history modeling in order to better understand the natural breakdown of organic matter into oil and gas. Our kinetic models of organic maturation are being used to better understand the coupling of generation, cracking, expulsion, and overpressuring in both the laboratory and geologic setting. Currently we are carrying out chemical experiments and developing more efficient chemical kinetic … more
Date: October 25, 1990
Creator: Burnham, A. K. & Sweeney, J. J.
Partner: UNT Libraries Government Documents Department
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Transition metal catalysis in the generation of petroleum and natural gas. Progress report, [1992--1993]

Description: A new hypothesis is introduced for the generation of petroleum and natural gas. The transition metals, activated under the reducing conditions of diagenesis, are proposed as catalysts in the generation of light hydrocarbons. The objective of this proposal is to test that hypothesis. Transition metals (Ni, V, Ti, Co, Fe), in kerogen, porphyrins, and as pure compounds, will be tested under catagenic conditions for catalytic activity in the conversion of normal paraffins and hydrogen into light hy… more
Date: August 1, 1993
Creator: Mango, F.
Partner: UNT Libraries Government Documents Department
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Characterization of coals, other kerogens, and their extracts by thermal mass spectrometry

Description: The objective of this study is to elucidate the nature of the medium size molecules derived from coals by a succession of stronger extraction conditions. The Argonne Premium Coals have been extracted with pyridine, binary solvents and with KOH/ethylene glycol at 250{degrees}C. Thermal desorption and pyrolysis mass spectrometry were the major approaches chosen to provide detailed information on structure and heteroatom composition. Soft ionization techniques including desorption chemical ionizat… more
Date: April 1, 1992
Creator: Winans, R. E.; Melnikov, P. E. & McBeth, R. L.
Partner: UNT Libraries Government Documents Department
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Organic/Inorganic interactions of nitrogen in oil fields Geochemistry. Part 1, Geochemistry: Final report, September 15, 1991--March 15, 1994

Description: This research examines the nitrogen isotopic composition of fixed-NH{sub 4} in order to test the hypothesis that NH{sub 4}{sup +} is released from organic matter during hydrocarbon generation and can be incorporated in diagenetic clay minerals along migration conduits. Anomalously high levels of NH{sub 4}-substitution recognized in hydrocarbon bearing sandstones may indicate paths of hydrocarbon migration long after the hydrocarbons have moved on toward a trap. This is important because most of… more
Date: March 1994
Creator: Willimas, L. B.
Partner: UNT Libraries Government Documents Department
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Analysis of high pressure oil shale Hugoniots

Description: A collection of low and high stress level Hugoniot data for a low kerogen content, porous Anvil Points oil shale are analyzed with the P-..cap alpha.. model to give a Hugoniot for kerogen free shale. The P-..cap alpha.. model suggests an ''elastic'' yield stress, P/sub e/, of 0.5 GPa and a solid density complete compaction pressure, P/sub s/, of 10.0 GPa. Knowledge of this behavior permits the calculations of the in situ, ''effective,'' Hugoniot of kerogen from extensive Hugoniot data for vario… more
Date: February 1, 1977
Creator: Munson, D. E.
Partner: UNT Libraries Government Documents Department
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Analysis of low stress oil shale Hugoniots

Description: Analysis of low stress Hugoniot data on Anvil Points oil shale was accomplished through careful categorization of data depending upon density. Density is directly related to kerogen content and kerogen content is a strong variable in determining the Hugoniot. For a given density (kerogen content), the shock velocity-particle velocity data show a minimum in shock velocity believed related to yielding in the rock constituent of the oil shale. Low stress Hugoniot data blend smoothly with high pres… more
Date: October 1, 1977
Creator: Munson, D. E.
Partner: UNT Libraries Government Documents Department
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Regional assessments of the hydrocarbon generation potential of selected North American proterozoic rock sequences. Progress report, September 1989--April 1990

Description: Our primary research objectives for the first year of this grant are nearing completion. This includes comprehensive sedimentologic/organic geochemical studies of two depositionally distinct, unmetamorphosed units, the Nonesuch Formation ({approximately}1.1 Ga lacustrine rift deposit) and the Dripping Spring Quartzite ({approximately}1.3 Ga marine shelf deposit). As discussed in this progress report, an attempt has been made to (1) identify source rocks by quantification and characterization of… more
Date: April 1, 1990
Creator: Engel, M. H. & Elmore, R. D.
Partner: UNT Libraries Government Documents Department
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Analysis of Devonian Black Shales in Kentucky for Potential Carbon Dioxide Sequestration and Enhanced Natural Gas Production Quarterly Report: October-December 2003

Description: CO{sub 2} emissions from the combustion of fossil fuels have been linked to global climate change. Proposed carbon management technologies include geologic sequestration of CO{sub 2}. A possible, but untested, sequestration strategy is to inject CO{sub 2} into organic-rich shales. Devonian black shales underlie approximately two-thirds of Kentucky and are thicker and deeper in the Illinois and Appalachian Basin portions of Kentucky than in central Kentucky. The Devonian black shales serve as bo… more
Date: January 1, 2004
Creator: Nuttall, Brandon C.
Partner: UNT Libraries Government Documents Department
open access

Hugoniots of Colorado oil shale

Description: Standard experimental shock wave techniques were used to obtain Hugoniots of Anvil Points oil shale as functions of richness and orientation in the pressure regime encountered in the near-field region of an explosion. The shock response was found to be sensitive to kerogen content but independent of bedding orientation relative to the direction of shock propagation. A two-component model combining the inferred dynamic parameters for the end members (kerogen and mineral matrix) is adequate to pr… more
Date: January 1, 1977
Creator: Carter, W. J.
Partner: UNT Libraries Government Documents Department
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Providing solutions to energy and environmental problems. Quarterly report, January 1--March 31, 1997

Description: Summaries are presented for the following tasks: Development and demonstration of a practical electric downhole steam generator for thermal recovery of heavy oil and tar; Wetting behavior of selected crude oil/brine/rock systems; Coal gasification, power generation and product market study; Impact of leachate from Clean Coal Technology waste on the stability of clay liners; Investigation of coprocessing heavy oil, automobile shredder residue, and coal; Injection into coal seams for simultaneous… more
Date: September 1, 1997
Partner: UNT Libraries Government Documents Department
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Optical constants of kerogen from 0. 15 to 40. mu. m: Comparison with meteoritic organics

Description: Kerogens are dark, complex organic materials produced on the earth primarily by geologic processing of biologic materials, but kerogens have chemical and spectral similarities to some classes of highly processed extraterrestrial organic materials. Kerogen-like solids have been proposed as constituents of the very dark reddish surfaces of some asteroids and are also spectrally similar to some carbonaceous organic residues and the Iapetus dark material. Kerogen can thus serve as a useful laborato… more
Date: January 1, 1989
Creator: Khare, B.N.; Thompson, W.R.; Sagan, C. (Cornell Univ., Ithaca, NY (USA). Lab. for Planetary Studies); Arakawa, E.T.; Meisse, C. (Oak Ridge National Lab., TN (USA)) & Gilmour, I. (Chicago Univ., IL (USA))
Partner: UNT Libraries Government Documents Department
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