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ADVANCED SULFUR CONTROL CONCEPTS FOR HOT GAS DESULFURIZATION TECHNOLOGY

Description: The objective of this project is to develop a hot-gas desulfurization process scheme for control of H{sub 2}S in HTHP coal gas that can be more simply and economically integrated with known regenerable sorbents in DOE/METC-sponsored work than current leading hot-gas desulfurization technologies. In addition to being more economical, the process scheme to be developed must yield an elemental sulfur byproduct.
Date: December 31, 1998
Partner: UNT Libraries Government Documents Department
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Demonstration of Selective Catalytic Reduction Technology to Control Nitrogen Oxide Emissions From High-Sulfur, Coal-Fired Boilers: A DOE Assessment

Description: The goal of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment of a project selected i… more
Date: December 1999
Creator: Federal Energy Technology Center (U.S.)
Partner: UNT Libraries Government Documents Department
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Char Crystalline Transformations During Coal Combustion and Their Implication for Carbon Burnout

Description: Recent work at Sandia National Laboratories, Imperial College, and the U.K. utility PowerGen, has identified an important mechanism believed to have a large influence on unburned carbon levels from pulverized coal fired boilers. That mechanism is char carbon crystalline rearrangements on subsecond times scales at temperatures of 1800 - 2500 K, which lead to char deactivation in the flame zones of furnaces. The so-called thermal annealing of carbons is a well known phenomenon, but its key role i… more
Date: December 30, 1997
Creator: Hurt, Robert H.
Partner: UNT Libraries Government Documents Department
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Commercial-Scale Demonstration of the Liquid Phase Methanol (LOMEOH(TM)) Process

Description: The Liquid Phase Methanol (LPMEOH) Demonstration Project at Kingsport, Tennessee, is a $213.7 million effort being conducted under a cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. A demonstration unit producing 80,000 gallons per day (260 tons-per-day (TPD))… more
Date: December 31, 1997
Partner: UNT Libraries Government Documents Department
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Advanced Emissions Control Development Program

Description: McDermott Technology, Inc. (MTI) is conducting a five-year project aimed at the development of practical, cost-effective strategies for reducing the emissions of hazardous air pollutants (commonly called air toxics) from coal-fired electric utility plants. The need for air toxic emissions controls may arise as the U. S. Environmental Protection Agency proceeds with implementation of Title III of the Clean Air Act Amendment (CAAA) of 1990. Data generated during the program will provide utilities… more
Date: December 3, 1998
Creator: Holmes, M. J.
Partner: UNT Libraries Government Documents Department
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Advanced Reservoir Characterization and Evaluation of CO2 Gravity Drainage in the Naturally Fractured Spraberry Reservoir

Description: Natural fractures exert a strong influence over oil production in Spraberry Trend Area reservoirs in the Permian Basin of west Texas. The importance of the fracture network has been known since the 1950s, but until recently, there has been very little detailed study of the fractures themselves. In 1996, a horizontal Spraberry well was cored as part of a DOE Class III Field Demonstration Project. Fractures from the horizontal core as well as other fractures encountered in vertical Spraberry core… more
Date: December 17, 1997
Creator: Schechter, David S.
Partner: UNT Libraries Government Documents Department
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Hindered Diffusion of Asphaltenes at Evaluated Temperature and Pressure

Description: During this time period, uptake experiments were performed at elevated temperatures up to 280 o C for the adsorptive diffusion of a coal asphaltene in 1- methylnaphthalene onto alumina catalyst pellets. Model simulation results showed that a mathematical model incorporating diffusion and adsorption mechanisms satisfactorily fitted the adsorptive diffusion of coal asphaltenes onto the alumina catalyst in a fairly wide temperature range of 55 o C to 280 o C. The logarithm of the adsorption consta… more
Date: December 4, 1998
Creator: Guin, James A.; Vadlamani, Surya & Yang, Xiafeng
Partner: UNT Libraries Government Documents Department
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Bench-Scale Demonstration of Hot-Gas Desulfurization Technology

Description: The U.S. Department of Energy (DOE), Federal Energy Technology Center (FETC), is sponsoring research in advanced methods for controlling contaminants in hot coal gasifier gas (coal-derived fuel-gas) streams of integrated gasification combined-cycle (IGCC) power systems. The hot gas cleanup work seeks to eliminate the need for expensive heat recovery equipment, reduce efficiency losses due to quenching, and minimize wastewater treatment costs.
Date: December 1, 1998
Creator: Portzer, Jeffrey W. & Gangwal, Santosh K.
Partner: UNT Libraries Government Documents Department
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Detailed Gravity and Magnetic Survey of the Taylorsville Triassic Basin

Description: Our research to date has involved the Interpretation of the Bouguer Gravity Anomaly Associated with the Richmond and Taylorsville Triassic Basins and its Vicinity. Continental rift basins around the world contain about 5% of the earth's sedimentary layers and produce about 20% of the total hydrocarbon production of the world (Ziegler (1983). Nearly 30 large basins of this type are reported by Manspeizer and Cousminer (1988) in eastern North America and northwestern Africa. There are eleven expo… more
Date: December 31, 1997
Creator: Nowroozi, Ali A. & Leftwich, John
Partner: UNT Libraries Government Documents Department
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Design and Fabrication of the First Commercial-Scale Liquid Phase Methanol (LPMEOH) Reactor

Description: The Liquid Phase Methanol (LPMEOHT) process uses a slurry bubble column reactor to convert synthesis gas (syngas), primarily a mixture of carbon monoxide and hydrogen, to methanol. Because of its superior heat management the process can utilize directly the carbon monoxide (CO)-rich syngas characteristic of the gasification of coal, petroleum coke, residual oil, wastes, or other hydrocarbon feedstocks. The LPMEOHM Demonstration Project at Kingsport, Tennessee, is a $213.7 million cooperative ag… more
Date: December 21, 1998
Partner: UNT Libraries Government Documents Department
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Engineering Development of Coal-Fired High-Performance Power Systems

Description: The concept uses a pyrolyzation process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). It is a pulverized fuel- fired boiler/ air heater where steam and gas turbine air are indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research… more
Date: December 15, 1997
Creator: Shenker, J.
Partner: UNT Libraries Government Documents Department
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Commercial-Scale Demonstration of the Liquid Phase Methanol (LPMEOH) Process

Description: he Liquid Phase Methanol (LPMEOW) Demonstration Project at Kingsport Tennessee, is a $213.7 million cooperative agreement between the U.S. Department of Energy (DOE) and Air Products Liquid Phase Conversion Company, L.P. (the Partnership) to produce methanol from coal-derived synthesis gas (syngas). Air Products and Chemicals, Inc. (Air Products) and Eastman Chemical Company (Eastman) formed the Partnership to execute the Demonstration Project. The LPMEOEP Process Demonstration Unit was built a… more
Date: December 21, 1998
Partner: UNT Libraries Government Documents Department
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Improved recovery demonstration for Williston Basin carbonates

Description: The purpose of this project is to demonstrate targeted infill and extension drilling opportunities, better determination of oil-in-place, methods for improved completion efficiency and the suitability of waterflooding in certain shallow-shelf carbonate reservoirs in the Williston Basin, Montana, North Dakota and South Dakota. Improved reservoir characterization utilizing 3-dimensional (3D) is being investigated for identification of structural and stratigraphic reservoir compartments. These sei… more
Date: December 1997
Creator: Carrell, L. A., Luff Exploration Co., Denver, CO
Partner: UNT Libraries Government Documents Department
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New catalysts for coal processing: Metal carbides and nitrides

Description: The subject of this research project was to investigate the catalytic properties of a new class of materials, transition metal carbides and nitrides, for treatment of coal liquid and petroleum feedstocks. The main objectives were: (1) preparation of catalysts in unsupported and supported form; (2) characterization of the materials; (3) evaluation of their catalytic properties in HDS and HDN; (4) measurement of the surface properties; and (5) observation of adsorbed species. All of the objective… more
Date: December 3, 1999
Creator: Oyama, S. Ted & Cox, David F.
Partner: UNT Libraries Government Documents Department
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Mechanisms and optimization of coal combustion. Semiannual report, November 1, 1998--April 30, 1999

Description: The effects of process conditions on the reactivity of Illinois No.6 coal in the kinetic and diffusion control regime were studied using new sequential combustion procedures. Reactivity patterns in the kinetic controlled regime were not influenced by the pyrolysis heating rates. Results presented in the previous DOE report have shown, however, that combustion rates were significantly affected by the pyrolysis heating rates at reaction temperatures higher than 550 C. These results establish the … more
Date: December 1, 1999
Creator: Zygourakis, K.
Partner: UNT Libraries Government Documents Department
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Alternative fuels and chemicals from synthesis gas

Description: A DOE/PETC funded study was conducted to examine the use of a liquid phase mixed alcohol synthesis (LPMAS) plant to produce gasoline blending ethers. The LPMAS plant was integrated into three utilization scenarios: a coal fed IGCC power plant, a petroleum refinery using coke as a gasification feedstock, and a standalone natural gas fed partial oxidation plant. The objective of the study was to establish targets for the development of catalysts for the LPMAS reaction. In the IGCC scenario, synga… more
Date: December 1, 1998
Partner: UNT Libraries Government Documents Department
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Calderon cokemaking process/demonstration project

Description: This project deals with the demonstration of a coking process using proprietary technology of Calderon, with the following objectives geared to facilitate commercialization: (1) making coke of such quality as to be suitable for use in hard-driving, large blast furnaces; (2) providing proof that such a process is continuous and environmentally closed to prevent emissions; (3) demonstrating that high-coking-pressure (non-traditional) coal blends which cannot be safely charged into conventional by… more
Date: December 21, 1999
Creator: Calderon, Albert
Partner: UNT Libraries Government Documents Department
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Toxic Substances From Coal Combustion

Description: The Clean Air Act Amendments of 1990 identify a number of hazardous air pollutants (HAPs) as candidates for regulation. Should regulations be imposed on HAP emissions from coal-fired power plants, a sound understanding of the fundamental principles controlling the formation and partitioning of toxic species during coal combustion will be needed. With support from the Federal Energy Technology Center (FETC), the Electric Power Research Institute, the Lignite Research Council, and VTT (Finland), … more
Date: December 8, 1998
Creator: Kolker, A.; Sarofim, A. F.; Senior, C. L.; Huggins, F. E.; Huffman, G. P.; Olmez, I. et al.
Partner: UNT Libraries Government Documents Department
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Cross flow flotation column for coal and minerals beneficiation

Description: An apparatus and process are disclosed for the separation of coal from pyritic impurities using a modified froth flotation system. The froth flotation column incorporates a helical track about the inner wall of the column in a region intermediate between the top and base of the column. A standard impeller located about the central axis of the column is used to generate a centrifugal force thereby increasing the separation efficiency of coal from the pyritic particles and hydrophilic tailings.
Date: December 1997
Creator: Lai, Ralph W. & Patton, Robert A.
Partner: UNT Libraries Government Documents Department
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Mechanisms and optimization of coal combustion. Semiannual report, May 1, 1998--October 31, 1998

Description: The effects of process conditions on the reactivity of Illinois No. 6 coal were studied using a new sequential combustion procedure. This procedure was developed to accurately simulate the reacting zones of industrial coal combustors. Reactivity patterns in the diffusion controlled regime were significantly affected by the pyrolysis heating rates, as well as by the oxygen concentration and combustion temperature. These results clearly show the importance of the macropore structure of chars in d… more
Date: December 1, 1999
Creator: Zygourakis, K.
Partner: UNT Libraries Government Documents Department
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Feasibility study for lowering the minimum gas pressure in solution-mined caverns based on geomechanical analyses of creep-induced damage and healing

Description: Geomechanical analyses were made to determine the minimum gas pressure allowable based on an existing stress-based criterion (Damage Potential) and an advanced constitutive model (MDCF model) capable of quantifying the level of damage and healing in rock salt. The MDCF model is a constitutive model developed for the WIPP to provide a continuum description of the dislocation and damage deformation of salt. The purpose of this study was to determine if the MDCF model is applicable for evaluating … more
Date: December 31, 1998
Creator: Ratigan, J.L.; Nieland, J.D. & Devries, K.L.
Partner: UNT Libraries Government Documents Department
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