Overcoming Degradation in Organic Photovoltaics: Illuminating the Role of Fullerene Functionalization: Preprint
Description:
Photobleaching rates are investigated for thin films of poly(3-hexylthiophene) (P3HT) blends employing either an indene-C60 bisadduct (ICBA) or [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor. Relative to the bisindene, PCBM significantly enhances resistance to photobleaching of the P3HT donor polymer. We tentatively attribute a decrease in the charge transfer rate as the mechanism responsible for the more rapid photobleaching in the sample containing the bisindene ad…
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Date:
July 1, 2011
Creator:
Lloyd, M. T.; Garcia, A.; Berry, J. J.; Reese, M. O.; Ginley, D. S. & Olson, D. C.
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