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Photoacoustically Measured Speeds of Sound and the Equation of State of HBO2: On Understanding Detonation with Boron Fuel

Description: Elucidation of geodynamic, geochemical, and shock induced processes is limited by challenges to accurately determine molecular fluid equations of state (EOS). High pressure liquid state reactions of carbon species underlie physiochemical mechanisms such as differentiation of planetary interiors, deep carbon sequestration, propellant deflagration, and shock chemistry. In this proceedings paper we introduce a versatile photoacoustic technique developed to measure accurate and precise speeds of so… more
Date: March 9, 2010
Creator: Zaug, J M; Bastea, S; Crowhurst, J; Armstrong, M; Fried, L & Teslich, N
Partner: UNT Libraries Government Documents Department
open access

Major Effects in the Thermodynamics of Detonation Products: Phase Segregation versus Ionic Dissociation

Description: Water (H{sub 2}O) and nitrogen (N{sub 2}) are major detonation products of high explosives and it has long been conjectured that they may phase segregate at high enough temperatures and pressures to influence detonation properties of common explosives. We analyze the phase diagram of H{sub 2}O-N{sub 2} mixtures using a thermodynamic theory for polar-nonpolar mixtures and find that phase segregation is unlikely to occur above approximately 1600K. Therefore, H{sub 2}O-N{sub 2} immiscibility is no… more
Date: March 9, 2010
Creator: Bastea, S & Fried, L E
Partner: UNT Libraries Government Documents Department
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