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A Green Prison: The Santa Rita Jail Campus Microgrid

Description: A large microgrid project is nearing completion at Alameda County’s twenty-two-year-old 45 ha 4,000-inmate Santa Rita Jail, about 70 km east of San Francisco. Often described as a green prison, it has a considerable installed base of distributed energy resources (DER) including an eight-year old 1.2 MW PV array, a five-year old 1 MW fuel cell with heat recovery, and considerable efficiency investments. A current US$14 M expansion adds a 2 MW-4 MWh Li-ion battery, a static disconnect switch, and various controls upgrades. During grid blackouts, or when conditions favor it, the Jail can now disconnect from the grid and operate as an island, using the on-site resources described together with its back-up diesel generators. In other words, the Santa Rita Jail is a true microgrid, or μgrid, because it fills both requirements, i.e. it is a locally controlled system, and it can operate both grid connected and islanded. The battery’s electronics includes Consortium for Electric Reliability Technology (CERTS) Microgrid technology. This enables the battery to maintain energy balance using droops without need for a fast control system.
Date: January 22, 2012
Creator: Marnay, Chris; DeForest, Nicholas & Lai, Judy
Partner: UNT Libraries Government Documents Department

Healthcare Energy Efficiency Research and Development

Description: Hospitals are known to be among the most energy intensive commercial buildings in California. Estimates of energy end-uses (e.g. for heating, cooling, lighting, etc.) in hospitals are uncertain for lack of information about hospital-specific mechanical system operations and process loads. Lawrence Berkeley National Laboratory developed and demonstrated a benchmarking system designed specifically for hospitals. Version 1.0 featured metrics to assess energy performance for the broad variety of ventilation and thermal systems that are present in California hospitals. It required moderate to extensive sub-metering or supplemental monitoring. In this new project, we developed a companion handbook with detailed equations that can be used toconvert data from energy and other sensors that may be added to or already part of hospital heating, ventilation and cooling systems into metrics described in the benchmarking document.This report additionally includes a case study and guidance on including metering into designs for new hospitals, renovations and retrofits. Despite widespread concern that this end-use is large and growing, there is limited reliable information about energy use by distributed medical equipment and other miscellaneouselectrical loads in hospitals. This report proposes a framework for quantifying aggregate energy use of medical equipment and miscellaneous loads. Novel approaches are suggested and tried in an attempt to obtain data to support this framework.
Date: January 31, 2011
Creator: Black, Douglas R.; Lai, Judy; Lanzisera, Steven M; Parrish, Kristen D. & Singer, Brett C.
Partner: UNT Libraries Government Documents Department

Financial Innovation Among the Community Wind Sector in the United States

Description: In the relatively brief history of utility-scale wind generation, the 'community wind' sector - defined here as consisting of relatively small utility-scale wind power projects that are at least partly owned by one or more members of the local community - has played a vitally important role as a 'test bed' or 'proving ground' for wind turbine manufacturers. In the 1980s and 1990s, for example, Vestas and other now-established European wind turbine manufacturers relied heavily on community wind projects in Scandinavia and Germany to install - and essentially field-test - new turbine designs. The fact that orders from community wind projects seldom exceeded more than a few turbines at a time enabled the manufacturers to correct any design flaws or manufacturing defects fairly rapidly, and without the risk of extensive (and expensive) serial defects that can accompany larger orders. Community wind has been slower to take root in the United States - the first such projects were installed in the state of Minnesota around the year 2000. Just as in Europe, however, the community wind sector in the U.S. has similarly served as a proving ground - but in this case for up-and-coming wind turbine manufacturers that are trying to break into the broader U.S. wind power market. For example, community wind projects have deployed the first U.S. installations of wind turbines from Suzlon (in 2003), DeWind (2008), Americas Wind Energy (2008) and later Emergya Wind Technologies (2010),1 Goldwind (2009), AAER/Pioneer (2009), Nordic Windpower (2010), Unison (2010), and Alstom (2011). Just as it has provided a proving ground for new turbines, so too has the community wind sector in the United States served as a laboratory for experimentation with innovative new financing structures. For example, a variation of one of the most common financing arrangements in the U.S. wind market ...
Date: January 19, 2011
Creator: Bolinger, Mark
Partner: UNT Libraries Government Documents Department

Modeling Low-Platinum-Loading Effects in Fuel-Cell Catalyst Layers

Description: The cathode catalyst layer within a proton-exchange-membrane fuel cell is the most complex and critical, yet least understood, layer within the cell. The exact method and equations for modeling this layer are still being revised and will be discussed in this paper, including a 0.8 reaction order, existence of Pt oxides, possible non-isopotential agglomerates, and the impact of a film resistance towards oxygen transport. While the former assumptions are relatively straightforward to understand and implement, the latter film resistance is shown to be critically important in explaining increased mass-transport limitations with low Pt-loading catalyst layers. Model results demonstrate agreement with experimental data that the increased oxygen flux and/or diffusion pathway through the film can substantially decrease performance. Also, some scale-up concepts from the agglomerate scale to the more macroscopic porous-electrode scale are discussed and the resulting optimization scenarios investigated.
Date: January 20, 2011
Creator: Yoon, Wonseok & Weber, Adam Z.
Partner: UNT Libraries Government Documents Department

NYSERDA's Green Jobs-Green New York Program: Extending Energy Efficiency Financing To Underserved Households

Description: The New York legislature passed the Green Jobs-Green New York (GJGNY) Act in 2009. Administered by the New York State Energy Research and Development Authority (NYSERDA), GJGNY programs provide New Yorkers with access to free or low-cost energy assessments,1 energy upgrade services,2 low-cost financing, and training for various 'green-collar' careers. Launched in November 2010, GJGNY's residential initiative is notable for its use of novel underwriting criteria to expand access to energy efficiency financing for households seeking to participate in New York's Home Performance with Energy Star (HPwES) program.3 The GJGNY financing program is a valuable test of whether alternatives to credit scores can be used to responsibly expand credit opportunities for households that do not qualify for traditional lending products and, in doing so, enable more households to make energy efficiency upgrades.
Date: January 24, 2011
Creator: Zimring, Mark & Fuller, Merrian
Partner: UNT Libraries Government Documents Department

Commissioning: A Highly Cost-Effective Building Energy Management Strategy

Description: Quality assurance and optimization are essential elements of any serious technological endeavor, including efforts to improve energy efficiency. Commissioning is an important tool in this respect. The aim of commissioning new buildings is to ensure that they deliver-if not exceed-the performance and energy savings promised by their design. When applied to existing buildings, one-time or repeated commissioning (often called retrocommissioning) identifies the almost inevitable drift in energy performance and puts the building back on course, often surpassing the original design intent. In both contexts, commissioning is a systematic, forensic approach to improving performance, rather than a discrete technology.
Date: January 6, 2011
Creator: Mills, Evan
Partner: UNT Libraries Government Documents Department

COMMUNITY DEVELOPMENT IN FRESHWATER MICROCOSMS

Description: Two cylindrical freshwater microcosms with a volume of 700 {ell} were maintained under controlled laboratory conditions for 190 days. The two microcosms were identical with regard to initial chemical composition and biological inocula, with the exceptions that in one microcosm (designated Tank 2) mosquitofish (Gambusia) and herbivorous catfish (Placostomas) were added. Three distinct communities developed in the tanks: (1) a phytoplankton-zooplankton assemblage and (2) two periphyton-zoobenthos communities associated with the sides and bottom of the tank, respectively. Community development and successional patterns were similar in both tanks. Major differences between the tanks involved timing of succession of the zooplankton and zoobenthos, attributable to predation by fish, principally Gambusia. A major drawback for these microcosms as use for experimental analogs such as lakes was a luxuriant periphyton growth which eventually overwhelmed the biomass of the system. The tanks displayed a degree of successional replicability, a large number of species, and a diversity of community development. Microcosms of this size could find use as experimental systems for higher level trophic manipulation and observation of life cycles not amenable to field studies.
Date: January 1, 1978
Creator: Rees, John T.
Partner: UNT Libraries Government Documents Department

Community Wind: Once Again Pushing the Envelope of Project Finance

Description: In the United States, the 'community wind' sector - loosely defined here as consisting of relatively small utility-scale wind power projects that sell power on the wholesale market and that are developed and owned primarily by local investors - has historically served as a 'test bed' or 'proving grounds' for up-and-coming wind turbine manufacturers that are trying to break into the U.S. wind power market. For example, community wind projects - and primarily those located in the state of Minnesota - have deployed the first U.S. installations of wind turbines from Suzlon (in 2003), DeWind (2008), Americas Wind Energy (2008) and later Emergya Wind Technologies (2010), Goldwind (2009), AAER/Pioneer (2009), Nordic Windpower (2010), Unison (2010), and Alstom (2011). Thus far, one of these turbine manufacturers - Suzlon - has subsequently achieved some success in the broader U.S. wind market as well. Just as it has provided a proving grounds for new turbines, so too has the community wind sector served as a laboratory for experimentation with innovative new financing structures. For example, a variation of one of the most common financing arrangements in the U.S. wind market today - the special allocation partnership flip structure (see Figure 1 in Section 2.1) - was first developed by community wind projects in Minnesota more than a decade ago (and is therefore sometimes referred to as the 'Minnesota flip' model) before being adopted by the broader wind market. More recently, a handful of community wind projects built over the past year have been financed via new and creative structures that push the envelope of wind project finance in the U.S. - in many cases, moving beyond the now-standard partnership flip structures involving strategic tax equity investors. These include: (1) a 4.5 MW project in Maine that combines low-cost government debt with local tax ...
Date: January 18, 2011
Creator: bolinger, Mark A.
Partner: UNT Libraries Government Documents Department

Embodied Energy and Off-Grid Lighting

Description: The greenhouse gas (GHG) emissions from fuel-based lighting are substantial given the paltry levels of lighting service provided to users, leading to a great opportunity for GHG mitigation byencouraging the switch from fuel-based to rechargeable LED lighting. However, as with most new energy technology, switching to efficient lighting requires an up-front investment of energy(and GHGs) embedded in the manufacture of replacement components. We studied a population of off-grid lighting users in 2008-2009 in Kenya who were given the opportunity to adopt LEDlighting. Based on their use patterns with the LED lights and the levels of kerosene offset we observed, we found that the embodied energy of the LED lamp was"paid for" in only one month for grid charged products and two months for solar charged products. Furthermore, the energyreturn-on investment-ratio (energy produced or offset over the product's service life divided by energy embedded) for off-grid LED lighting ranges from 12 to 24, which is on par with on-gridsolar and large-scale wind energy. We also found that the energy embodied in the manufacture of a typical hurricane lantern is about one-half to one-sixth of that embodied in the particular LEDlights that we evaluated, indicating that the energy payback time would be moderately faster if LEDs ultimately displace the production of kerosene lanterns. As LED products improve, weanticipate longer service lives and more successful displacement of kerosene lighting, both of which will speed the already rapid recovery of embodied energy in these products. Our studyprovides a detailed appendix with embodied energy values for a variety of components used to construct off-grid LED lighting, which can be used to analyze other products.
Date: January 25, 2011
Creator: Alstone, Peter; Mills, Evan & Jacobson, Arne
Partner: UNT Libraries Government Documents Department

Energy and air quality implications of passive stack ventilation in residential buildings

Description: Ventilation requires energy to transport and condition the incoming air. The energy consumption for ventilation in residential buildings depends on the ventilation rate required to maintain an acceptable indoor air quality. Historically, U.S. residential buildings relied on natural infiltration to provide sufficient ventilation, but as homes get tighter, designed ventilation systems are more frequently required particularly for new energy efficient homes and retrofitted homes. ASHRAE Standard 62.2 is used to specify the minimum ventilation rate required in residential buildings and compliance is normally achieved with fully mechanical whole-house systems; however, alternative methods may be used to provide the required ventilation when their air quality equivalency has been proven. One appealing method is the use of passive stack ventilation systems. They have been used for centuries to ventilate buildings and are often used in ventilation regulations in other countries. Passive stacks are appealing because they require no fans or electrical supply (which could lead to lower cost) and do not require maintenance (thus being more robust and reliable). The downside to passive stacks is that there is little control of ventilation air flow rates because they rely on stack and wind effects that depend on local time-varying weather. In this study we looked at how passive stacks might be used in different California climates and investigated control methods that can be used to optimize indoor air quality and energy use. The results showed that passive stacks can be used to provide acceptable indoor air quality per ASHRAE 62.2 with the potential to save energy provided that they are sized appropriately and flow controllers are used to limit over-ventilation.
Date: January 1, 2011
Creator: Mortensen, Dorthe Kragsig; Walker, Iain S. & Sherman, Max
Partner: UNT Libraries Government Documents Department

ENERGY CONSERVATION AND ENERGY DECENTRALIZATION: ISSUES AND PROSPECTS

Description: We have presented views of the seemingly paradoxical nature and irrationality of the energy system and the decisions that determine its evolution. An economic approach to energy decisions, while widely espoused and generally believed to be the underpinning of our system. appears not to be functioning in very important areas. The result is enormous waste of economic and intangible resources to produce energy that could be effectively replaced by energy conservation at low costs. This inefficiency in the economic system is, in our judgment. far greater than is recognized either by the public or by 'experts.' It has led to an over-investment in centralized energy systems and has discouraged the use of decentralized systems that could contribute significantly in the near term to a lessening of our energy problems. There are some signs that the situation is changing. albeit rather slowly. High prices and the widespread recognition of the seriousness of our energy problems have contributed to an increasing involvement of individuals in energy decisions profoundly affecting their future. To achieve an evolution of the energy system in which decentralized technologies (and, in the near term, particularly technologies that improve the efficiency of energy use) play an important role, the government must act forcefully. This action needs to recognize and be responsive to the powerful discriminatory effect of the economic system, as it is presently constituted, against investments in energy conservation.
Date: January 1, 1980
Creator: Levine, Mark D. & Craig, Paul P.
Partner: UNT Libraries Government Documents Department

Energy Savings Assessment for Digital-to-Analog Converter Boxes

Description: The Digital Television (DTV) Converter Box Coupon Program was administered by the U.S. government to subsidize purchases of digital-to-analog converter boxes, with up to two $40 coupons for each eligible household. In order to qualify as Coupon Eligible Converter Boxes (CECBs), these devices had to meet a number of minimum performance specifications, including energy efficiency standards. The Energy Star Program also established voluntary energy efficiency specifications that are more stringent than the CECB requirements. In this study, we measured the power and energy consumptions for a sample of 12 CECBs (including 6 Energy Star labeled models) in-use in homes and estimated aggregate energy savings produced by the energy efficiency policies. Based on the 35 million coupons redeemed through the end of the program, our analysis indicates that between 2500 and 3700 GWh per year are saved as a result of the energy efficiency policies implemented on digital-to-analog converter boxes. The energy savings generated are equivalent to the annual electricity use of 280,000 average US homes.
Date: January 18, 2011
Creator: Cheung, Hoi Ying Iris; Meier, Alan & Brown, Richard
Partner: UNT Libraries Government Documents Department

An Examination of Temporal Trends in Electricity Reliability Based on Reports from U.S. Electric Utilities

Description: Since the 1960s, the U.S. electric power system has experienced a major blackout about once every 10 years. Each has been a vivid reminder of the importance society places on the continuous availability of electricity and has led to calls for changes to enhance reliability. At the root of these calls are judgments about what reliability is worth and how much should be paid to ensure it. In principle, comprehensive information on the actual reliability of the electric power system and on how proposed changes would affect reliability ought to help inform these judgments. Yet, comprehensive, national-scale information on the reliability of the U.S. electric power system is lacking. This report helps to address this information gap by assessing trends in U.S. electricity reliability based on information reported by electric utilities on power interruptions experienced by their customers. Our research augments prior investigations, which focused only on power interruptions originating in the bulk power system, by considering interruptions originating both from the bulk power system and from within local distribution systems. Our research also accounts for differences among utility reliability reporting practices by employing statistical techniques that remove the influence of these differences on the trends that we identify. The research analyzes up to 10 years of electricity reliability information collected from 155 U.S. electric utilities, which together account for roughly 50% of total U.S. electricity sales. The questions analyzed include: 1. Are there trends in reported electricity reliability over time? 2. How are trends in reported electricity reliability affected by the installation or upgrade of an automated outage management system? 3. How are trends in reported electricity reliability affected by the use of IEEE Standard 1366-2003?
Date: January 6, 2012
Creator: Eto, Joseph H.; LaCommare, Kristina Hamachi; Larsen, Peter; Todd, Annika & Fisher, Emily
Partner: UNT Libraries Government Documents Department

DSM Electricity Savings Potential in the Buildings Sector in APP Countries

Description: The global economy has grown rapidly over the past decade with a commensurate growth in the demand for electricity services that has increased a country's vulnerability to energy supply disruptions. Increasing need of reliable and affordable electricity supply is a challenge which is before every Asia Pacific Partnership (APP) country. Collaboration between APP members has been extremely fruitful in identifying potential efficiency upgrades and implementing clean technology in the supply side of the power sector as well established the beginnings of collaboration. However, significantly more effort needs to be focused on demand side potential in each country. Demand side management or DSM in this case is a policy measure that promotes energy efficiency as an alternative to increasing electricity supply. It uses financial or other incentives to slow demand growth on condition that the incremental cost needed is less than the cost of increasing supply. Such DSM measures provide an alternative to building power supply capacity The type of financial incentives comprise of rebates (subsidies), tax exemptions, reduced interest loans, etc. Other approaches include the utilization of a cap and trade scheme to foster energy efficiency projects by creating a market where savings are valued. Under this scheme, greenhouse gas (GHG) emissions associated with the production of electricity are capped and electricity retailers are required to meet the target partially or entirely through energy efficiency activities. Implementation of DSM projects is very much in the early stages in several of the APP countries or localized to a regional part of the country. The purpose of this project is to review the different types of DSM programs experienced by APP countries and to estimate the overall future potential for cost-effective demand-side efficiency improvements in buildings sectors in the 7 APP countries through the year 2030. Overall, the savings potential is estimated ...
Date: January 12, 2011
Creator: McNeil, MIchael; Letschert, Virginie; Shen, Bo; Sathaye, Jayant & de la Ru du Can, Stephane
Partner: UNT Libraries Government Documents Department

Impact of Large Scale Energy Efficiency Programs On Consumer Tariffs and Utility Finances in India

Description: Large-scale EE programs would modestly increase tariffs but reduce consumers' electricity bills significantly. However, the primary benefit of EE programs is a significant reduction in power shortages, which might make these programs politically acceptable even if tariffs increase. To increase political support, utilities could pursue programs that would result in minimal tariff increases. This can be achieved in four ways: (a) focus only on low-cost programs (such as replacing electric water heaters with gas water heaters); (b) sell power conserved through the EE program to the market at a price higher than the cost of peak power purchase; (c) focus on programs where a partial utility subsidy of incremental capital cost might work and (d) increase the number of participant consumers by offering a basket of EE programs to fit all consumer subcategories and tariff tiers. Large scale EE programs can result in consistently negative cash flows and significantly erode the utility's overall profitability. In case the utility is facing shortages, the cash flow is very sensitive to the marginal tariff of the unmet demand. This will have an important bearing on the choice of EE programs in Indian states where low-paying rural and agricultural consumers form the majority of the unmet demand. These findings clearly call for a flexible, sustainable solution to the cash-flow management issue. One option is to include a mechanism like FAC in the utility incentive mechanism. Another sustainable solution might be to have the net program cost and revenue loss built into utility's revenue requirement and thus into consumer tariffs up front. However, the latter approach requires institutionalization of EE as a resource. The utility incentive mechanisms would be able to address the utility disincentive of forgone long-run return but have a minor impact on consumer benefits. Fundamentally, providing incentives for EE programs to make ...
Date: January 20, 2011
Creator: Abhyankar, Nikit & Phadke, Amol
Partner: UNT Libraries Government Documents Department

Dark Shadows

Description: The U.S. Department of Energy's National Renewable Energy Laboratory, Sandia National Laboratories, the Solar Electric Power Association, the Utility Wind Integration Group, and the U.S. Department of Energy hosted a day-long public workshop on the variability of photovoltaic (PV) plants. The workshop brought together utilities, PV system developers, power system operators, and several experts to discuss the potential impacts of PV variability and uncertainty on power system operations.
Date: January 10, 2011
Creator: Mills, Andrew; Ahlstrom, Mark; Brower, Michael; Ellis, Abraham; George, Ray; Hoff, Tom et al.
Partner: UNT Libraries Government Documents Department

Assessing the Control Systems Capacity for Demand Response in California Industries

Description: California's electricity markets are moving toward dynamic pricing models, such as real-time pricing, within the next few years, which could have a significant impact on an industrial facility's cost of energy use during the times of peak use. Adequate controls and automated systems that provide industrial facility managers real-time energy use and cost information are necessary for successful implementation of a comprehensive electricity strategy; however, little is known about the current control capacity of California industries. To address this gap, Lawrence Berkeley National Laboratory, in close collaboration with California industrial trade associations, conducted a survey to determine the current state of controls technologies in California industries. This,study identifies sectors that have the technical capability to implement Demand Response (DR) and Automated Demand Response (Auto-DR). In an effort to assist policy makers and industry in meeting the challenges of real-time pricing, facility operational and organizational factors were taken into consideration to generate recommendations on which sectors Demand Response efforts should be focused. Analysis of the survey responses showed that while the vast majority of industrial facilities have semi- or fully automated control systems, participation in Demand Response programs is still low due to perceived barriers. The results also showed that the facilities that use continuous processes are good Demand Response candidates. When comparing facilities participating in Demand Response to those not participating, several similarities and differences emerged. Demand Response-participating facilities and non-participating facilities had similar timings of peak energy use, production processes, and participation in energy audits. Though the survey sample was smaller than anticipated, the results seemed to support our preliminary assumptions. Demonstrations of Auto-Demand Response in industrial facilities with good control capabilities are needed to dispel perceived barriers to participation and to investigate industrial subsectors suggested of having inherent Demand Response potential.
Date: January 18, 2012
Creator: Ghatikar, Girish; McKane, Aimee; Goli, Sasank; Therkelsen, Peter & Olsen, Daniel
Partner: UNT Libraries Government Documents Department

China Energy and Emissions Paths to 2030

Description: After over two decades of staggering economic growth and soaring energy demand, China has started taking serious actions to reduce its economic energy and carbon intensity by setting short and medium-term intensity reduction targets, renewable generation targets and various supporting policies and programs. In better understanding how further policies and actions can be taken to shape China's future energy and emissions trajectory, it is important to first identify where the largest opportunities for efficiency gains and emission reduction lie from sectoral and end-use perspectives. Besides contextualizing China's progress towards reaching the highest possible efficiency levels through the adoption of the most advanced technologies from a bottom-up perspective, the actual economic costs and benefits of adopting efficiency measures are also assessed in this study. This study presents two modeling methodologies that evaluate both the technical and economic potential of raising China's efficiency levels to the technical maximum across sectors and the subsequent carbon and energy emission implications through 2030. The technical savings potential by efficiency measure and remaining gap for improvements are identified by comparing a reference scenario in which China continues the current pace of with a Max Tech scenario in which the highest technically feasible efficiencies and advanced technologies are adopted irrespective of costs. In addition, from an economic perspective, a cost analysis of selected measures in the key industries of cement and iron and steel help quantify the actual costs and benefits of achieving the highest efficiency levels through the development of cost of conserved energy curves for the sectors. The results of this study show that total annual energy savings potential of over one billion tonne of coal equivalent exists beyond the expected reference pathway under Max Tech pathway in 2030. CO2 emissions will also peak earlier under Max Tech, though the 2020s is a likely turning ...
Date: January 14, 2011
Creator: Fridley, David; Zheng, Nina; Zhou, Nan; Ke, Jing; Hasanbeigi, Ali; Morrow, Bill et al.
Partner: UNT Libraries Government Documents Department

Visual Comfort Analysis of Innovative Interior and Exterior Shading Systems for Commercial Buildings using High Resolution Luminance Images

Description: The objective of this study was to explore how calibrated high dynamic range (HDR) images (luminance maps) acquired in real world daylit environments can be used to characterize, evaluate, and compare visual comfort conditions of innovative facade shading and light-redirecting systems. Detailed (1536 x 1536 pixel) luminance maps were time-lapse acquired from two view positions in an unoccupied full scale testbed facility. These maps were analyzed using existing visual comfort metrics to quantify how innovative interior and exterior shading systems compare to conventional systems under real sun and sky conditions over a solstice-to-solstice test interval. The results provide a case study in the challenges and potential of methods of visualizing, evaluating and summarizing daily and seasonal variation of visual comfort conditions computed from large sets of image data.
Date: January 11, 2011
Creator: Konis, Kyle; Lee, Eleanor & Clear, Robert
Partner: UNT Libraries Government Documents Department

Simulating the Daylight Performance of Complex Fenestration Systems Using Bidirectional Scattering Distribution Functions within Radiance

Description: We describe two methods which rely on bidirectional scattering distribution functions (BSDFs) to model the daylighting performance of complex fenestration systems (CFS), enabling greater flexibility and accuracy in evaluating arbitrary assemblies of glazing, shading, and other optically-complex coplanar window systems. Two tools within Radiance enable a) efficient annual performance evaluations of CFS, and b) accurate renderings of CFS despite the loss of spatial resolution associated with low-resolution BSDF datasets for inhomogeneous systems. Validation, accuracy, and limitations of the methods are discussed.
Date: January 21, 2011
Creator: Ward, Gregory; Mistrick, Ph.D., Richard; Lee, Eleanor; McNeil, Andrew & Jonsson, Ph.D., Jacob
Partner: UNT Libraries Government Documents Department

SPECIES DETERMINATION OF ORGANOMETALLIC COMPOUNDS USING ZEEMAN ATOMIC ABSORPTION SPECTROSCOPY WITH LIQUID CHROMATOGRAPHY

Description: Over the past several years we have devised and expanded the capabilities of Zeeman atomic absorption spectroscopy (ZAA). Using this technique, trace elements in a complex matrix can be directly analyzed with high accuracy even when there is only one atom of interest contained in several million atoms of the host material. Quantities in the nanogram, or in some cases picogram, range can be determined within IS seconds for more than 30 elements. Because of its high selectivity and high sensitivity, ZAA can be used as a new technique for organometallic species determination by interfacing with a high pressure liquid chromatograph (HPLC). The HPLC separates various molecular species. Different kinds of mobil solvents can be directly introduced in the ZAA detection system; even organic solvents or high concentration salt solutions. Then, organometallic species in the ppb range are separately detected according to their retention times. This technique has a much larger field of application than HPLC coupled with conventional AA. The advantages of the ZAA technique are described in a recent publication. In this case, a steady magnetic field at 11 kgauss is applied to the sample vapor perpendicular to the incident light beam. The difference in absorption of the polarized constituents P{perpendicular} and P{parallel} is proportional to the atomic density, but is not affected by the various kind of spectral interferences caused by thermal decomposition of the eluants. The recently developed HPLC technique has many advantages over gas chromatography. Nonvolatile, polar, thermally unstable molecules or high molecular weight compounds can be separated. In the present system, the main requirement is that the solute be soluble in the mobile solvent. A demonstration of the operation of this system is provided by the analysis of a mixture of vitamin B12 and Co(No{sub 3}){sub 2}. As shown in Figure 1, vitamin B12 ...
Date: January 1, 1978
Creator: Koizumi, H.; Hadeishi, T. & McLaughlin, R.
Partner: UNT Libraries Government Documents Department

Terrestrial biogeochemical feedbacks in the climate system: from past to future

Description: The terrestrial biosphere plays a major role in the regulation of atmospheric composition, and hence climate, through multiple interlinked biogeochemical cycles (BGC). Ice-core and other palaeoenvironmental records show a fast response of vegetation cover and exchanges with the atmosphere to past climate change, although the phasing of these responses reflects spatial patterning and complex interactions between individual biospheric feedbacks. Modern observations show a similar responsiveness of terrestrial biogeochemical cycles to anthropogenically-forced climate changes and air pollution, with equally complex feedbacks. For future conditions, although carbon cycle-climate interactions have been a major focus, other BGC feedbacks could be as important in modulating climate changes. The additional radiative forcing from terrestrial BGC feedbacks other than those conventionally attributed to the carbon cycle is in the range of 0.6 to 1.6 Wm{sup -2}; all taken together we estimate a possible maximum of around 3 Wm{sup -2} towards the end of the 21st century. There are large uncertainties associated with these estimates but, given that the majority of BGC feedbacks result in a positive forcing because of the fundamental link between metabolic stimulation and increasing temperature, improved quantification of these feedbacks and their incorporation in earth system models is necessary in order to develop coherent plans to manage ecosystems for climate mitigation.
Date: January 5, 2010
Creator: Arneth, A.; Harrison, S. P.; Zaehle, S.; Tsigaridis, K; Menon, S; Bartlein, P.J. et al.
Partner: UNT Libraries Government Documents Department

Electronic Structure of CeFeAsO1-xFx (x=0, 0.11/x=0.12) compounds

Description: We report an extensive study on the intrinsic bulk electronic structure of the high-temperature superconductor CeFeAsO{sub 0.89}F{sub 0.11} and its parent compound CeFeAsO by soft and hard x-ray photoemission, x-ray absorption and soft-x-ray emission spectroscopies. The complementary surface/bulk probing depth, and the elemental and chemical sensitivity of these techniques allows resolving the intrinsic electronic structure of each element and correlating it with the local structure, which has been probed by extended-x-ray absorption fine structure spectroscopy. The measurements indicate a predominant 4f{sup 1} (i.e. Ce{sup 3+}) initial state configuration for Cerium and an effective valence-band-to-4f charge-transfer screening of the core hole. The spectra also reveal the presence of a small Ce f{sup 0} initial state configuration, which we assign to the occurrence of an intermediate valence state. The data reveal a reasonably good agreement with the partial density of states as obtained in standard density functional calculations over a large energy range. Implications for the electronic structure of these materials are discussed.
Date: January 25, 2011
Creator: Bondino, F.; Magnano, E.; Booth, C. H.; Offi, F.; Panaccione, G.; Malvestuto, M. et al.
Partner: UNT Libraries Government Documents Department