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Final master work plan: environmental investigations at former CCC/USDA facilities in Kansas, 2002 revision.

Description: The Commodity Credit Corporation (CCC) of the U.S. Department of Agriculture (USDA) has entered into an interagency agreement with the U.S. Department of Energy (DOE) under which Argonne National Laboratory provides technical assistance for hazardous waste site characterization and remediation for the CCC/USDA. Carbon tetrachloride is the contaminant of primary concern at sites in Kansas where former CCC/USDA grain storage facilities were located. Argonne applies its QuickSite(reg sign) Expedited Site Characterization (ESC) approach to these former facilities. The QuickSite environmental site characterization methodology is Argonne's proprietary implementation of the ESC process (ASTM 1998). Argonne has used this approach at several former CCC/USDA facilities in Kansas, including Agenda, Agra, Everest, and Frankfort. The Argonne ESC approach revolves around a multidisciplinary, team-oriented approach to problem solving. The basic features and steps of the QuickSite methodology are as follows: (1) A team of scientists with diverse expertise and strong field experience is required to make the process work. The Argonne team is composed of geologists, geochemists, geophysicists, hydrogeologists, chemists, biologists, engineers, computer scientists, health and safety personnel, and regulatory staff, as well as technical support staff. Most of the staff scientists are at the Ph.D. level; each has on average, more than 15 years of experience. The technical team works together throughout the process. In other words, the team that plans the program also implements the program in the field and writes the reports. More experienced scientists do not remain in the office while individuals with lesser degrees or experience carry out the field work. (2) The technical team reviews, evaluates, and interprets existing data for the site and the contaminants there to determine which data sets are technically valid and can be used in initially designing the field program. A basic mistake sometimes made in the site characterization process is failure to ...
Date: January 23, 2003
Creator: Burton, J. C.
Partner: UNT Libraries Government Documents Department

IMPROVED APPROACHES TO DESIGN OF POLYMER GEL TREATMENTS IN MATURE OIL FIELDS: FIELD DEMONSTRATION IN DICKMAN FIELD, NESS COUNTY, KANSAS

Description: This report describes the results of the one-year project entitled ''Improved Approaches to Design of Polymer Gel Treatments in Mature Oil Fields: Field Demonstration in Dickman Field, Ness County, Kansas''. The project was a 12-month collaboration of Grand Mesa Operating Company (a small independent), TIORCO Inc. (a company focused on improved recovery technology) and the University of Kansas. The study undertook tasks to determine an optimum polymer gel treatment design in Mississippian reservoirs, demonstrate application, and evaluate the success of the program. The project investigated geologic and engineering parameters and cost-effective technologies required for design and implementation of effective polymer gel treatment programs in the Mississippian reservoir in the Midcontinent. The majority of Mississippian production in Kansas occurs at or near the top of the Mississippian section just below the regional sub-Pennsylvanian unconformity and karst surface. Dickman Field with the extremely high water cuts and low recovery factors is typical of Mississippian reservoirs. Producibility problems in these reservoirs include inadequate reservoir characterization, drilling and completion design problems, and most significantly extremely high water cuts and low recovery factors that place continued operations at or near their economic limits. Geologic, geophysical and engineering data were integrated to provide a technical foundation for candidate selection and treatment design. Data includes core, engineering data, and 3D seismic data. Based on technical and economic considerations a well was selected for gel-polymer treatment (Grand Mesa Operating Company Tilley No.2). The treatment was not successful due to the small amount of polymer that could be injected. Data from the initial well and other candidates in the demonstration area was analyzed using geologic, geophysical and engineering data. Based on the results of the treatment and the integrated reservoir characterization it was determined that a second polymer-gel treatment could not be justified. The Mississippian reservoir at Dickman Field ...
Date: November 30, 2004
Creator: Fowler, Ronald
Partner: UNT Libraries Government Documents Department

April 2008 monitoring report for Morrill, Kansas.

Description: In September 2005, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) initiated periodic sampling of groundwater in the vicinity of a grain storage facility formerly operated by the CCC/USDA at Morrill, Kansas. The sampling at Morrill is being performed on behalf of the CCC/USDA by Argonne National Laboratory, in accord with a monitoring program approved by the Kansas Department of Health and Environment (KDHE), to monitor levels of carbon tetrachloride contamination identified in the groundwater at this site (Argonne 2004, 2005a). This report provides results for the most recent monitoring event, in April 2008. Under the KDHE-approved monitoring plan (Argonne 2005b), groundwater was initially sampled twice yearly for a recommended period of two years (in fall 2005, in spring and fall 2006, and in spring and fall 2007). The samples were analyzed for volatile organic compounds (VOCs), as well as for selected geochemical parameters to aid in the evaluation of possible natural contaminant degradation (reductive dechlorination) processes in the subsurface environment. During the recommended two-year period, the originally approved scope of the monitoring was expanded to include vegetation sampling (initiated in October 2006) and surface water and stream bed sediment sampling (initiated in March 2007, after a visual reconnaissance along Terrapin Creek [Argonne 2007a]). The analytical results for groundwater sampling events at Morrill in September 2005, March 2006, September 2006, March 2007, and October 2007 were documented previously (Argonne 2006a,b, 2007b, 2008). Those results consistently demonstrated the presence of carbon tetrachloride contamination, at levels exceeding the KDHE Tier 2 risk-based screening level (5.0 {micro}g/L) for this compound, in a groundwater plume extending generally south-southeastward from the former CCC/USDA facility, toward Terrapin Creek at the south edge of the town. The results of those five monitoring events gave little indication of consistent changes in the contaminant concentrations at ...
Date: November 4, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final phase I report and phase II work plan: QuickSite{reg_sign} investigation, Centralia, Kansas.

Description: The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), formerly operated a grain storage facility approximately 1,100 ft north of Centralia (Figure 1.2). The CCC/USDA operated this facility from 1949 until 1971. None of the CCC/USDA structures remain. Two additional grain storage facilities currently exist in and near Centralia: the Nemaha County Co-op, approximately 4,000 ft south of the former CCC/USDA facility, and a private grain storage facility near the Don Morris residence, 3,500 ft north of the former CCC/USDA facility. Prior to 1986, commercial grain fumigants containing carbon tetrachloride were commonly used by the CCC/USDA and the grain storage industry to preserve grain. In April 1998, the Kansas Department of Health and Environment (KDHE) sampled the domestic well at the Don Morris residence near Centralia (Figure 1.2) as part of the CCC/USDA Private Well Sampling Program, which was initiated to determine whether carbon tetrachloride was present in domestic wells located near former CCC/USDA grain storage facilities in Kansas. Carbon tetrachloride was detected in the Morris well at 19.3 mg/L and confirmed at 25.4 mg/L, both concentrations above the maximum contaminant level (MCL) of 5 mg/L for carbon tetrachloride in drinking water. On the basis of the detection of carbon tetrachloride in the Morris well, the KDHE in August-September 1998 conducted preliminary investigations at the former CCC/USDA facility. For the details of previous investigations in the area and a summary of their findings, see the QuickSite{reg_sign} Phase I Work Plan for Centralia (Argonne 2002a). Because the KDHE found carbon tetrachloride at the former CCC/USDA facility at Centralia that might, in part, be linked to historical use of carbon tetrachloride-based grain fumigants at the facility, the CCC/USDA is conducting an environmental site investigation at Centralia. However, the KDHE established in 1998 that the probable groundwater flow ...
Date: March 1, 2003
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final Phase II report : QuickSite(R) investigation, Everest, Kansas.

Description: The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated grain storage facilities at two different locations at Everest, Kansas (Figure 1.1). One facility (referred to in this report as the Everest facility) was at the western edge of the city of Everest. The CCC/USDA operated this facility from 1950 until the early 1970s. The second facility (referred to in this report as Everest East) was about 0.5 mi northeast of the town. The CCC/USDA operated this facility from 1954 until the early 1970s. While these two former CCC/USDA grain storage facilities were in operation, commercial grain fumigants containing carbon tetrachloride were in common use by the CCC/USDA and the private grain storage industry to preserve grain. In 1997, the Kansas Department of Health and Environment (KDHE) sampled several domestic drinking water and nondrinking water wells in the Everest area. The KDHE sampling was part of the CCC/USDA Private Well Sampling Program, which was initiated to determine whether carbon tetrachloride was present in domestic wells near former CCC/USDA grain storage facilities in Kansas. All of the sampled domestic drinking water wells were located outside the Everest city boundaries. As a result of this sampling, carbon tetrachloride contamination was identified at a single domestic drinking water well (the Nigh well; DW06) approximately 3/8 mi northwest of the former Everest CCC/USDA grain storage facility. The CCC/USDA subsequently connected the Nigh residence to the Everest municipal water system. As a result of the detection of carbon tetrachloride in this well, the KDHE conducted preliminary investigations to further evaluate the existence of contamination and its potential effect on public health and the environment. The KDHE concluded that carbon tetrachloride in groundwater at Everest might, in part, be linked to historical use of carbon tetrachloride-based grain fumigants at the former ...
Date: November 1, 2003
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report : groundwater monitoring at Morrill, Kansas, in September 2005 and March 2006, with expansion of the monitoring network in January 2006.

Description: This document reports the results of groundwater monitoring in September 2005 and March 2006 at the grain storage facility formerly operated at Morrill, Kansas, by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). These activities were the first and second twice yearly sampling events of the two-year monitoring program approved by the CCC/USDA and Kansas Department of Health and Environment (KDHE) project managers. The monitoring network sampled in September 2005 consisted of 9 monitoring wells (MW1S-MW5S and MW1D [installed in the mid 1990s] and MW6S-MW8S [installed in 2004]), plus 3 private wells (Isch, Rillinger, and Stone). The groundwater samples collected in this first event were analyzed for volatile organic compounds (VOCs), dissolved hydrogen, and additional groundwater parameters to aid in evaluating the potential for reductive dechlorination processes. After the monitoring in September 2005, Argonne recommended expansion of the initial monitoring network. Previous sampling (August 2004) had already suggested that the initial network was inadequate to delineate the extent of the carbon tetrachloride plume. With the approval of the CCC/USDA and KDHE project managers, the monitoring network was expanded in January 2006 through the installation of 3 additional monitoring wells (MW9S-MW11S). Details of the monitoring well installations are reported in this document. The expanded monitoring network of 12 monitoring wells (MW1S-MW11S and MW1D) and 3 private wells (Isch, Rillinger, and Stone) was sampled in March 2006, the second monitoring event in the planned two-year program. Results of analyses for VOCs showed minor increases or decreases in contaminant levels at various locations but indicated that the leading edge of the contaminant plume is approaching the intermittent stream leading to Terrapin Creek. The groundwater samples collected in March 2006 were also analyzed for additional groundwater parameters to aid in the evaluation of the potential for reductive dechlorination processes. Preliminary screening ...
Date: June 30, 2007
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report : Phase III targeted investigation, Everest, Kansas.

Description: The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), formerly operated grain storage facilities at two different locations at Everest, Kansas (Figure 1.1). One facility (referred to in this report as the Everest facility) was at the western edge of the city. The second facility (referred to in this report as Everest East) was about 0.5 mi northeast of the town. The CCC/USDA operated these facilities from the early 1950s until the early 1970s, at a time when commercial fumigants containing carbon tetrachloride were in common use by the CCC/USDA and private industry for the preservation of grain in storage. In 1997 the Kansas Department of Health and Environment (KDHE) sampled several domestic drinking water and non-drinking water wells in the Everest area as part of the CCC/USDA Private Well Sampling Program. All of the sampled wells were outside the Everest city limits. Carbon tetrachloride contamination was identified at a single domestic drinking water well (the Nigh well, DW06; Figure 1.1) approximately 3/8 mi northwest of the former Everest CCC/USDA grain storage facility. Subsequent KDHE investigations suggested that the contamination in DW06 could be linked to the former use of grain fumigants at the CCC/USDA facility. For this reason, the CCC/USDA is conducting a phased environmental study to determine the source and extent of the carbon tetrachloride contamination at Everest and to identify potential remedial options. The studies are being performed by the Environmental Research Division of Argonne National Laboratory. Two phases of investigation were completed previously; this report presents the findings of the targeted Phase III investigation at Everest.
Date: January 31, 2006
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report : results of aquifer pumping and groundwater sampling at Everest, Kansas, in January-March 2006.

Description: On September 8-9, 2005, representatives of the Kansas Department of Health and Environment (KDHE), the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA), and Argonne National Laboratory met at the KDHE's offices in Topeka to review the status of the CCC/USDA's environmental activities in Kansas. As a result of this meeting, the KDHE recommended several additional activities to augment the CCC/USDA's investigations at Everest, Kansas, and assist in the selection of remedial approaches to be evaluated as part of a Corrective Action Study (CAS) for this site. The requested actions included the following: (1) Construction of several additional interpretive cross sections illustrating the hydrogeologic setting along the apparent main plume migration pathway to the north-northwest of the former CCC/USDA facility, as well as in the vicinity of the Nigh property. (2) Installation of additional permanent monitoring wells, to better constrain the apparent western, northern, and northwestern margins of the existing groundwater plume. (3) Development of technical recommendations for a phased pumping study of the Everest aquifer unit in the area near and to the north of the Nigh property.
Date: September 30, 2006
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report : results of the 2006-2007 investigation of potential contamination at the former CCC/USDA facility in Barnes, Kansas.

Description: The 2006-2007 investigation of carbon tetrachloride and chloroform contamination at Barnes, Kansas, was conducted at the request of the Kansas Department of Health and Environment (KDHE). The Environmental Science Division of Argonne National Laboratory implemented the investigation on behalf of the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). The overall goal of the investigation was to establish criteria for monitoring leading to potential site reclassification. The investigation objectives were to (1) determine the hydraulic gradient near the former CCC/USDA facility, (2) delineate the downgradient carbon tetrachloride plume, and (3) design and implement an expanded monitoring network at Barnes (Argonne 2006a).
Date: August 28, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report : results of the 2006 investigation of potential contamination at the former CCC/USDA facility in Ramona, Kansas.

Description: The investigation reported here was conducted by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) in 2006. The investigation addressed carbon tetrachloride contamination on the former CCC/USDA grain storage facility at Ramona, Kansas. The results clearly demonstrate that only minimal contamination is associated with the past use of carbon tetrachloride on the former CCC/USDA property. No soil contamination was detected at concentrations above Kansas Department of Health and Environment (KDHE) risk-based screening level (RBSL) Tier 2 standard of 200 {micro}g/kg for the soil-to-groundwater protection pathway. Carbon tetrachloride concentrations in groundwater above the RBSL and maximum contaminant level (MCL) value of 5.0 {micro}g/L were detected in only two samples, collected at adjacent locations on the southeast part of the property. The relatively low concentrations detected and the limited areal extent of the contamination demonstrate that no imminent threat exists on the former CCC/USDA property to warrant remediation. The soil and groundwater contamination detected on the former CCC/USDA property is clearly separate from contamination detected at off-site locations. The carbon tetrachloride and chloroform contamination in groundwater (at concentrations above the RBSL and MCL value) associated with past activities on the former CCC/USDA property is contained within the property boundaries. Data collected independently by the KDHE in 2006 validate these findings and, furthermore, provide additional evidence that the sources identified on the Co-op property (west of the former CCC/USDA property) are separate from the comparatively minor results of past activities on the former CCC/USDA property. The KDHE concluded in its 2006 report that the sources are separate and that the Co-op is the principally responsible party for the carbon tetrachloride contamination detected during its 2006 investigation.
Date: October 18, 2007
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report: results of the 2007 investigation of potential contamination at the former CCC/USDA facility in Powhattan, Kansas.

Description: The 2007 investigation of carbon tetrachloride and chloroform contamination at Powhattan, Kansas, was conducted at the request of the Kansas Department of Health and Environment (KDHE 2006a). The Environmental Science Division of Argonne National Laboratory implemented the investigation on behalf of the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). The primary purposes of the investigation were to evaluate potential contaminant source areas on the former CCC/USDA property, determine the horizontal and vertical extent of potential contamination, conduct groundwater monitoring, and provide recommendations for future action.
Date: August 15, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final report: results of the 2007 targeted investigation at Hilton, Kansas.

Description: The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility in Hilton, Kansas, in 1954-1965. In 1992, carbon tetrachloride was first identified, at a concentration of 910 {micro}g/L, in groundwater from well GW01 at Hilton. This discovery occurred in association with the sale of the private grain storage facility on which well GW01 is located to the current owner, the Mid-Kansas Cooperative Association. The Kansas Department of Health and Environment conducted investigations at Hilton in 1992-1994. In 1996-1997, Argonne National Laboratory conducted Phase I and Phase II investigations on behalf of the CCC/USDA to characterize the distribution of the carbon tetrachloride contamination identified in well GW01, the stratigraphic units potentially hosting contaminant migration, and local hydrogeology in the Hilton area. The 2007 targeted investigation reported here focused specifically on the former CCC/USDA property at Hilton, west of the railroad tracks. (Until a property record search in 2005, the location of the CCC/USDA's former facility at Hilton was not known with certainty.) The objectives of the investigation, as implemented, were to (1) investigate for carbon tetrachloride contamination in the shallower soil and shallow aquifer units below the former CCC/USDA property and (2) investigate groundwater flow patterns. The key results of the 2007 targeted investigation are as follows: (1) No carbon tetrachloride or chloroform contamination was found in soil or groundwater below the former CCC/USDA facility. (2) The 2007 groundwater level data support a southwesterly direction for groundwater flow in the main Hilton aquifer (Equus Beds), consistent with findings of previous investigations. Contaminated well GW01 was confirmed to be upgradient from the former CCC/USDA facility. (3) The contaminants carbon tetrachloride, chloroform, and 1,2-dibromoethane (ethylene dibromide) were found in groundwater only at well GW01. No evidence of contamination was found in other monitoring wells ...
Date: April 29, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan for targeted investigation at Hilton, Kansas.

Description: This Work Plan outlines the scope of a targeted investigation to update the status of carbon tetrachloride contamination in groundwater associated with grain storage operations at Hilton, Kansas. The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility in Hilton during the 1950s and 1960s. At the time of the CCC/USDA operation in Hilton, grain storage facilities (CCC/USDA and private) were located along the both sides of the former Union Pacific railroad tracks (Figure 1.1). The main grain storage structures were on or near the railroad right-of-way. The proposed targeted investigation, to be conducted by Argonne National Laboratory on the behalf of CCC/USDA, will supplement Argonne's Phase I and Phase II investigations in 1996-1997. The earlier investigations erroneously focused on an area east of the railroad property where the CCC/USDA did not operate, specifically on a private grain storage facility. In addition, the investigation was limited in scope, because access to railroad property was denied (Argonne 1997a,b). The hydrogeologic system at Hilton is potentially complex.
Date: August 28, 2007
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan for targeted investigation at Inman, Kansas.

Description: In 1997, low levels of carbon tetrachloride (below the maximum contaminant level [MCL] of 5 {micro}g/L) were detected in groundwater at Inman, Kansas, by the Kansas Department of Health and Environment (KDHE). The 1997 KDHE sampling was conducted under the U.S. Department of Agriculture (USDA) private well sampling program. The Commodity Credit Corporation (CCC), a USDA agency, operated a grain storage facility in Inman from 1954 to 1965. Carbon tetrachloride is the contaminant of primary concern at sites associated with former CCC/USDA grain storage operations. Inman is located in southwest McPherson County, approximately 10 mi southwest of the city of McPherson (Figure 1.1). To determine whether the former CCC/USDA facility at Inman is a potential contaminant source and its possible relationship to the contamination in groundwater, the CCC/USDA has agreed to conduct an investigation at Inman, in accordance with the Intergovernmental Agreement between the KDHE and the Farm Service Agency of the USDA. For this work plan, Argonne compiled historical data related to the previous investigations and grain storage operations at Inman. Through a review of documents acquired from all available sources, other potential contaminant source areas (in addition to the former CCC/USDA facility) have been identified as (1) the commercial grain storage structures northwest of Inman, along the railroad right-of-way, and (2) small former private grain storage facilities west of Main Street and near the former CCC/USDA facility at the southern edge of Inman (Figure 1.2). Previous investigations and the potential source areas are discussed in Section 2.
Date: November 5, 2007
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan for targeted sampling at Webber, Kansas.

Description: This Work Plan outlines the scope of work for targeted sampling at Webber, Kansas (Figure 1.1). This activity is being conducted at the request of the Kansas Department of Health and Environment (KDHE), in accordance with Section V of the Intergovernmental Agreement between the KDHE and the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). Data obtained in this sampling event will be used to (1) evaluate the current status of previously detected contamination at Webber and (2) determine whether the site requires further action. This work is being performed on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by the University of Chicago for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an interagency agreement with DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. Argonne has issued a Master Work Plan (Argonne 2002) that describes the general scope of and guidance for all investigations at former CCC/USDA facilities in Kansas. The Master Work Plan, approved by the KDHE, contains the materials common to investigations at all locations in Kansas. This document should be consulted for complete details of the technical activities proposed at the former CCC/USDA facility in Webber.
Date: May 1, 2006
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan: groundwater monitoring at Centralia, Kansas.

Description: This Work Plan outlines the scope of work for a program of twice yearly groundwater monitoring at the site of a former grain storage facility at Centralia, Kansas (Figure 1.1). The purposes of this monitoring program are to follow changes in plume dynamics and to collect data necessary to evaluate the suitability of monitored natural attenuation as a remedial option, under the requirements of Kansas Department of Health and Environment (KDHE) Policy No.BER-RS-042. This monitoring program is planned for a minimum of 2 yr. The planned monitoring activity is part of an investigation at Centralia being performed on behalf of the Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), by the Environmental Research Division of Argonne National Laboratory. Argonne is a nonprofit, multidisciplinary research center operated by the University of Chicago for the U.S. Department of Energy (DOE). The CCC/USDA has entered into an interagency agreement with DOE, under which Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at its former grain storage facilities. Details and background for this Work Plan were presented previously (Argonne 2004, 2005). Argonne has also issued a Master Work Plan (Argonne 2002) that describes the general scope of and guidance for all investigations at former CCC/USDA facilities in Kansas. The Master Work Plan (approved by the KDHE) contains the materials common to investigations at all locations in Kansas. These documents must be consulted for the complete details of plans for this work associated with the former CCC/USDA facility at Centralia.
Date: August 31, 2005
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan: investigation of potential contamination at the former CCC/USDA grain storage facility in Hanover, Kansas.

Description: The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility at the northeastern edge of the city of Hanover, Kansas, from 1950 until the early 1970s. During this time, commercial grain fumigants containing carbon tetrachloride were in common use by the grain storage industry to preserve grain in their facilities. In February 1998, trace to low levels of carbon tetrachloride (below the maximum contaminant level [MCL] of 5.0 {micro}g/L) were detected in two private wells near the former grain storage facility at Hanover, as part of a statewide USDA private well sampling program that was implemented by the Kansas Department of Health and Environment (KDHE) near former CCC/USDA facilities. In April 2007, the CCC/USDA collected near-surface soil samples at 1.8-2 ft BGL (below ground level) at 61 locations across the former CCC/USDA facility. All soil samples were analyzed by the rigorous gas chromatograph-mass spectrometer analytical method (purge-and-trap method). No contamination was found in soil samples above the reporting limit of 10 {micro}g/kg. In July 2007, the CCC/USDA sampled indoor air at nine residences on or adjacent to its former facility to address the residents concerns regarding vapor intrusion. Low levels of carbon tetrachloride were detected at four of the nine homes. Because carbon tetrachloride found in private wells and indoor air at the site might be linked to historical use of fumigants containing carbon tetrachloride at its former grain storage facility, the CCC/USDA is proposing to conduct an investigation to determine the source and extent of the carbon tetrachloride contamination associated with the former facility. This investigation will be conducted in accordance with the intergovernmental agreement between the KDHE and the Farm Service Agency (FSA) of the USDA. The investigation at Hanover will be performed, on behalf of the CCC/USDA, by ...
Date: November 19, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan: investigation of potential contamination at the former USDA facility in Powhattan, Kansas.

Description: This Work Plan outlines the scope of work to be conducted to investigate the subsurface contaminant conditions at the property formerly leased by the Commodity Credit Corporation (CCC) in Powhattan, Kansas (Figure 1.1). Data obtained during this event will be used to (1) evaluate potential contaminant source areas on the property; (2) determine the vertical and horizontal extent of potential contamination; and (3) provide recommendations for future action, with the ultimate goal of assigning this site No Further Action status. The planned investigation includes groundwater monitoring requested by the Kansas Department of Health and Environment (KDHE), in accordance with Section V of the Intergovernmental Agreement between the KDHE and the Farm Service Agency of the U.S. Department of Agriculture (USDA). The work is being performed on behalf of the CCC/USDA by the Environmental Science Division of Argonne National Laboratory. A nonprofit, multidisciplinary research center operated by the University of Chicago for the U.S. Department of Energy, Argonne provides technical assistance to the CCC/USDA with environmental site characterization and remediation at former CCC/USDA grain storage facilities. Argonne issued a Master Work Plan (Argonne 2002) that has been approved by the KDHE. The Master Work Plan describes the general scope of all investigations at former CCC/USDA facilities in Kansas and provides guidance for these investigations. It should be consulted for the complete details of plans for work associated with the former CCC/USDA facility at Powhattan.
Date: February 2, 2007
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Final work plan: supplemental upward vapor intrusion investigation at the former CCC/USDA grain storage facility in Hanover, Kansas.

Description: The Commodity Credit Corporation (CCC), an agency of the U.S. Department of Agriculture (USDA), operated a grain storage facility at the northeastern edge of the city of Hanover, Kansas, from 1950 until the early 1970s. During this time, commercial grain fumigants containing carbon tetrachloride were in common use by the grain storage industry to preserve grain in their facilities. In February 1998, trace to low levels of carbon tetrachloride (below the maximum contaminant level [MCL] of 5.0 {micro}g/L) were detected in two private wells near the former grain storage facility at Hanover, as part of a statewide USDA private well sampling program that was implemented by the Kansas Department of Health and Environment (KDHE) near former CCC/USDA facilities. In 2007, the CCC/USDA conducted near-surface soil sampling at 61 locations and also sampled indoor air at nine residences on or adjacent to its former Hanover facility to address the residents concerns regarding vapor intrusion. Low levels of carbon tetrachloride were detected at four of the nine homes. The results were submitted to the KDHE in October 2007 (Argonne 2007). On the basis of the results, the KDHE requested sub-slab sampling and/or indoor air sampling (KDHE 2007). This Work Plan describes, in detail, the proposed additional scope of work requested by the KDHE and has been developed as a supplement to the comprehensive site investigation work plan that is pending (Argonne 2008). Indoor air samples collected previously from four homes at Hanover were shown to contain the carbon tetrachloride at low concentrations (Table 2.1). It cannot be concluded from these previous data that the source of the detected carbon tetrachloride is vapor intrusion attributable to former grain storage operations of the CCC/USDA at Hanover. The technical objective of the vapor intrusion investigation described here is to assess the risk to human health ...
Date: December 15, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Interim measure conceptual design for remediation at the former CCC/USDA grain storage facility at Centralia, Kansas: pilot test and remedy implementation.

Description: This document presents an Interim Measure Work Plan/Design for the short-term, field-scale pilot testing and subsequent implementation of a non-emergency Interim Measure (IM) at the site of the former grain storage facility operated by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) in Centralia, Kansas. The IM is recommended to mitigate both (1) localized carbon tetrachloride contamination in the vadose zone soils beneath the former facility and (2) present (and potentially future) carbon tetrachloride contamination identified in the shallow groundwater beneath and in the immediate vicinity of the former CCC/USDA facility. Investigations conducted on behalf of the CCC/USDA by Argonne National Laboratory have demonstrated that groundwater at the Centralia site is contaminated with carbon tetrachloride at levels that exceed the Kansas Tier 2 Risk-Based Screening Level (RBSL) and the U.S. Environmental Protection Agency's maximum contaminant level of 5.0 {micro}g/L for this compound. Groundwater sampling and analyses conducted by Argonne under a monitoring program approved by the Kansas Department of Health and Environment (KDHE) indicated that the carbon tetrachloride levels at several locations in the groundwater plume have increased since twice yearly monitoring of the site began in September 2005. The identified groundwater contamination currently poses no unacceptable health risks, in view of the absence of potential human receptors in the vicinity of the former CCC/USDA facility. Carbon tetrachloride contamination has also been identified at Centralia in subsurface soils at concentrations on the order of the Kansas Tier 2 RBSL of 200 {micro}g/kg in soil for the soil-to-groundwater protection pathway. Soils contaminated at this level might pose some risk as a potential source of carbon tetrachloride contamination to groundwater. To mitigate the existing contaminant levels and decrease the potential future concentrations of carbon tetrachloride in groundwater and soil, the CCC/USDA recommends initial short-term, field-scale pilot testing of a ...
Date: November 9, 2007
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

Interim measure work plan/design for Agra, Kansas.

Description: This Interim Measure Work Plan/Design (IMWP/D) is supplemental to the Argonne document Interim Measure Conceptual Design for Remediation of Source Area Contamination at Agra, Kansas. The IMWP/D includes information required by Kansas Department of Health and Environment (KDHE) Policy BER-RS-029, Policy and Scope of Work for Interim Measures. Specific to Policy BER-RS-029 is the requirement for several documents that will ensure that an adequate amount and type of data are collected for implementation of the IMWP/D and that data quality and safe conditions are prevailed. Such information is included in the IMWP/D as follows: Appendix A: Data Acquisition Plan--Design Testing Requirements; Appendix B: Basis of Design; Appendix C: Permits; Appendix D: Quality Assurance Project Plan; Appendix E: Health and Safety Plan; and Appendix F: Operations, Maintenance, and Monitoring Schedule. The proposed remedial technology for this project is the installation of five large-diameter boreholes (LDBs) in a source area that has been identified on the property formerly used for grain storage by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA). The goal of the LDB technology is the remediation of the source area by removal of mass quantities of contaminated soil from the vadose zone and treatment of any remaining contaminated soils that are adjacent to the source area to achieve a carbon tetrachloride concentration below 200 {micro}g/kg. Secondary to the soil remediation is the remediation of groundwater at and adjacent to the source areas. The LDB technology serves the following purposes: (1) The physical removal of contaminated soil from the identified source area. (2) Replacement of less permeable native materials (silty clay, clayey silt, and silty sand) with more permeable materials to facilitate the capture of volatilized contaminants in the vertical borehole. (3) Removal of contaminants volatilized by air sparging (AS) and extracted from the vadose zone ...
Date: November 18, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department

July 2008 monitoring results for Barnes, Kansas.

Description: The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at Barnes, Kansas, during most of the interval 1949-1974. Carbon tetrachloride contamination was initially detected in 1986 in the town's public water supply wells. In 2006-2007, the CCC/USDA conducted a comprehensive targeted investigation at and near its former property in Barnes to characterize this contamination. Those results were reported previously (Argonne 2008a). In November 2007, the CCC/USDA began quarterly groundwater monitoring at Barnes. The monitoring is being conducted on behalf of the CCC/USDA by Argonne National Laboratory, in accord with the recommendations made in the report for the 2006-2007 targeted investigation (Argonne 2008a). The objective is to monitor the carbon tetrachloride contamination identified in the groundwater at Barnes. The sampling is presently conducted in a network of 28 individual monitoring wells (at 19 distinct locations), 2 public water supply wells, and 1 private well (Figure 1.1). The results of the 2006-2007 targeted investigation and the subsequent monitoring events in November 2007 (Argonne 2008b) and March 2008 (Argonne 2008c) demonstrated the presence of carbon tetrachloride contamination in groundwater at levels slightly exceeding the Kansas Department of Health and Environment (KDHE) Tier 2 risk-based screening level (RBSL) of 5.0 {micro}g/L for this compound. The contaminant plume appears to extend from the former CCC/USDA property northwestward, toward the Barnes public water supply wells. Information obtained during the 2006-2007 investigations indicates that at least one other potential source might have contributed to the groundwater contaminant plume (Argonne 2008a). This current report presents the results of the third monitoring event, conducted in July 2008. During this third monitoring event, low-flow sampling methods were used to purge and sample all wells. This was the second event at Barnes during which low-flow sampling methods were used.
Date: November 20, 2008
Creator: LaFreniere, L. M.
Partner: UNT Libraries Government Documents Department