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Savannah River Site offsite hazardous waste shipment data validation report. Revision 1

Description: The objective of this data validation is to verify that waste shipments reported in response to the US Department of Energy Headquarters data request are properly categorized according to DOE-HQ definitions. This report documents all findings and actions resulting from the independent review of the Savannah River Site data submittal, and provides a summary of the SRS data submittal and data validation strategy. The overall hazardous waste management and offsite release process from 1987--1991 i… more
Date: May 1, 1995
Creator: Casey, C.; Kudera, D. E.; Page, L. A. & Rohe, M. J.
Partner: UNT Libraries Government Documents Department
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Argonne National Laboratory, east hazardous waste shipment data validation

Description: At the request of EM-331, the Radioactive Waste Technical Support Program (TSP) is conducting an evaluation of data regarding past hazardous waste shipments from DOE sites to commercial TSDFs. The intent of the evaluation is to find out if, from 1984 to 1991, DOE sites could have shipped hazardous waste contaminated with DOE-added radioactivity to commercial TSDFs not licensed to receive radioactive material. A team visited Argonne National Laboratory, East (ANL-E) to find out if any data exist… more
Date: September 1, 1995
Creator: Casey, C.; Graden, C. & Coveleskie, A.
Partner: UNT Libraries Government Documents Department
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Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Progress report, April 1, 1979-March 31, 1980

Description: The stoichiometric reactions of metal complexes which parallel probable steps in the metal catalyzed reduction of CO are being investigated. It is hoped that the study of these model reactions will lead to an understanding of the structural factors influencing these individual reaction steps. The information obtained should be useful in the design and discovery of homogeneous catalysts for the reduction of CO to hydrocarbons. We have studied metal formyl complexes which may be involved in the i… more
Date: April 1, 1980
Creator: Casey, C. P.
Partner: UNT Libraries Government Documents Department
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Product assurance planning in an environment of increased need for accountability

Description: Projects producing data are too often providing a product that is neither defensible nor usable. Instead of planning for data of known and required quality, managers are too often asking for (and getting) the wrong thing. The problem is a lack of correct planning strategy. A planning strategy to produce usable, defensible data requires communication from the customer to top-level management and from top-level management to the project leader, who must then communicate with the technical experts… more
Date: October 1, 1991
Creator: Esparza, V. & Casey, C.
Partner: UNT Libraries Government Documents Department
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Organometallic chemistry of bimetallic compounds

Description: This report consists of six sections: heterobimetallic dihydrides, early-late transition metal heterobimetallic compounds, amphiphilic carbene complexes and hydroxycarbene complexes, diiron compounds with bridging hydrocarbon ligands, diphosphine chelates with natural bite angles near 120 degrees, and synthesis and reactions of M=M compounds. (WET)
Date: July 1, 1991
Creator: Casey, C. P.
Partner: UNT Libraries Government Documents Department
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Non-equilibrium fission processes in intermediate energy nuclear collisions

Description: We have measured the target fragment yields, angular and energy distributions for the interaction of 12-16 MeV/A/sup 32/S with /sup 165/Ho and /sup 197/Au and for the interaction of 32 and 44 MeV/A /sup 40/Ar with /sup 197/Au. The Au fission fragments associated with the peripheral collision peak in the folding angle distribution originate in a normal, ''slow'' fission process in which statistical equilibrium has been established. At the two lowest projectile energies, the Au fission fragments … more
Date: April 1, 1989
Creator: Loveland, W.; Casey, C.; Xu, Z.; Seaborg, G. T.; Aleklett, K. & Sihver, L.
Partner: UNT Libraries Government Documents Department
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Organometallic chemistry of bimetallic compounds

Description: Hydrogenation of alkynes by the heterobimetallic compound C{sub 5}H{sub 5}(CO){sub 2}Re({mu}-H)Pt(H)(PPh{sub 3}){sub 2} is being studied. The compound C{sub 5}Me{sub 5}(CO){sub 2}Re{double bond}Re(CO){sub 2}C{sub 5}Me{sub 5} was synthesized; its chemistry is being studied. Compounds discovered in a reinvestigation of a spurious report of (C{sub 5}Me{sub 5})Co{double bond}Co(C{sub 5}Me{sub 5}), are being studied. The deuterioformylation of alkenes using wide bite angle phosphines will be studied. more
Date: July 1, 1992
Creator: Casey, C.P.
Partner: UNT Libraries Government Documents Department
open access

Organometallic chemistry of bimetallic compounds. Final progress report

Description: This report consists of six sections: heterobimetallic dihydrides, early-late transition metal heterobimetallic compounds, amphiphilic carbene complexes and hydroxycarbene complexes, diiron compounds with bridging hydrocarbon ligands, diphosphine chelates with natural bite angles near 120 degrees, and synthesis and reactions of M=M compounds. (WET)
Date: July 1, 1991
Creator: Casey, C. P.
Partner: UNT Libraries Government Documents Department
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Organometallic chemistry of bimetallic compounds. Progress report, January 1992--July 1995

Description: Four main projects at the interface between organometallic chemistry and homogeneous catalysis were pursued. All were designed to give increased understanding of the mechanisms of organometallic reactions related to homogeneous and heterogeneous catalysis. In addition, a minor study involving {eta}{sup 5}-to {eta}{sup 1}-cyclopentadienyl ring slippage in catalysis was completed.
Date: July 1, 1994
Creator: Casey, C. P.
Partner: UNT Libraries Government Documents Department
open access

Product Assurance Planning in an Environment of Increased Need for Accountability

Description: Projects producing data are too often providing a product that is neither defensible nor usable. Instead of planning for data of known and required quality, managers are too often asking for (and getting) the wrong thing. The problem is a lack of correct planning strategy. A planning strategy to produce usable, defensible data requires communication from the customer to top-level management and from top-level management to the project leader, who must then communicate with the technical experts… more
Date: October 1, 1991
Creator: Esparza, V. & Casey, C.
Partner: UNT Libraries Government Documents Department
open access

Material Not Categorized As Waste (MNCAW) data report. Radioactive Waste Technical Support Program

Description: The Department of Energy (DOE), Headquarters, requested all DOE sites storing valuable materials to complete a questionnaire about each material that, if discarded, could be liable to regulation. The Radioactive Waste Technical Support Program entered completed questionnaires into a database and analyzed them for quantities and type of materials stored. This report discusses the data that TSP gathered. The report also discusses problems revealed by the questionnaires and future uses of the data… more
Date: November 1, 1992
Creator: Casey, C. & Heath, B. A.
Partner: UNT Libraries Government Documents Department
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Organometallic chemistry of bimetallic compounds. [Annual report]

Description: Hydrogenation of alkynes by the heterobimetallic compound C{sub 5}H{sub 5}(CO){sub 2}Re({mu}-H)Pt(H)(PPh{sub 3}){sub 2} is being studied. The compound C{sub 5}Me{sub 5}(CO){sub 2}Re{double_bond}Re(CO){sub 2}C{sub 5}Me{sub 5} was synthesized; its chemistry is being studied. Compounds discovered in a reinvestigation of a spurious report of (C{sub 5}Me{sub 5})Co{double_bond}Co(C{sub 5}Me{sub 5}), are being studied. The deuterioformylation of alkenes using wide bite angle phosphines will be studied. more
Date: July 1, 1992
Creator: Casey, C. P.
Partner: UNT Libraries Government Documents Department
open access

Organometallic chemistry of bimetallic compounds. Annual progress report

Description: Research is reported under 5 headings: reactions of heterobimetallic dihydrides (hydrogenation of alkynes by Re, Pt complex), metal-metal double bonds (Re=Re), C{sub 5}Me{sub 5}Co=CoC{sub 5}Me{sub 5} is actually (C{sub 5}Me{sub 5}){sub 3}Co{sub 3}({mu}{sub 2}-H){sub 3}({mu}{sub 3}-H), reactions of (C{sub 5}Me{sub 5}){sub 3}Co{sub 3}({mu}{sub 2}-H){sub 3}({mu}{sub 3}-H), and wide bite angle phosphines in hydroformylation.
Date: July 1, 1993
Creator: Casey, C. P.
Partner: UNT Libraries Government Documents Department
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