Pulse Radiolysis of Aqueous Thiocyanate Solution
Description:
The pulse radiolysis of N2O saturated aqueous solutions of KSCN was studied under neutral pH conditions. The observed optical absorption spectrum of the SCN• radical in solution is more complex than previously reported, but it is in good agreement with that measured in the gas phase. Kinetic traces at 330 nm and 472 nm corresponding to SCN• and (SCN)2•¯, respectively, were fit using a Monte Carlo simulation kinetic model. The rate coefficient for the oxidation of SCN¯ ions by OH radicals, an im…
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Date:
January 13, 2005
Creator:
Milosavljevic, Bratoljub H. & LaVerne, Jay A.
Partner:
UNT Libraries Government Documents Department