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Gas atomized precursor alloy powder for oxide dispersion strengthened ferritic stainless steel

Description: Gas atomization reaction synthesis (GARS) was employed as a simplified method for producing precursor powders for oxide dispersion strengthened (ODS) ferritic stainless steels (e.g., Fe-Cr-Y-(Ti,Hf)-O), departing from the conventional mechanical alloying (MA) process. During GARS processing a reactive atomization gas (i.e., Ar-O{sub 2}) was used to oxidize the powder surfaces during primary break-up and rapid solidification of the molten alloy. This resulted in envelopment of the powders by an ultra-thin (t < 150 nm) metastable Cr-enriched oxide layer that was used as a vehicle for solid-state transport of O into the consolidated microstructure. In an attempt to better understand the kinetics of this GARS reaction, theoretical cooling curves for the atomized droplets were calculated and used to establish an oxidation model for this process. Subsequent elevated temperature heat treatments, which were derived from Rhines pack measurements using an internal oxidation model, were used to promote thermodynamically driven O exchange reactions between trapped films of the initial Cr-enriched surface oxide and internal Y-enriched intermetallic precipitates. This novel microstructural evolution process resulted in the successful formation of nano-metric Y-enriched dispersoids, as confirmed using high energy X-ray diffraction and transmission electron microscopy (TEM), equivalent to conventional ODS alloys from MA powders. The thermal stability of these Y-enriched dispersoids was evaluated using high temperature (1200°C) annealing treatments ranging from 2.5 to 1,000 hrs of exposure. In a further departure from current ODS practice, replacing Ti with additions of Hf appeared to improve the Y-enriched dispersoid thermal stability by means of crystal structure modification. Additionally, the spatial distribution of the dispersoids was found to depend strongly on the original rapidly solidified microstructure. To exploit this, ODS microstructures were engineered from different powder particle size ranges, illustrating microstructural control as a function of particle solidification rate. The consolidation of ultra-fine powders (dia. ≤ 5μm) resulted in ...
Date: December 13, 2011
Creator: Rieken, Joel
Partner: UNT Libraries Government Documents Department

Imaging gene expression in real-time using aptamers

Description: Signal transduction pathways are usually activated by external stimuli and are transient. The downstream changes such as transcription of the activated genes are also transient. Real-time detection of promoter activity is useful for understanding changes in gene expression, especially during cell differentiation and in development. A simple and reliable method for viewing gene expression in real time is not yet available. Reporter proteins such as fluorescent proteins and luciferase allow for non-invasive detection of the products of gene expression in living cells. However, current reporter systems do not provide for real-time imaging of promoter activity in living cells. This is because of the long time period after transcription required for fluorescent protein synthesis and maturation. We have developed an RNA reporter system for imaging in real-time to detect changes in promoter activity as they occur. The RNA reporter uses strings of RNA aptamers that constitute IMAGEtags (Intracellular MultiAptamer GEnetic tags), which can be expressed from a promoter of choice. The tobramycin, neomycin and PDC RNA aptamers have been utilized for this system and expressed in yeast from the GAL1 promoter. The IMAGEtag RNA kinetics were quantified by RT-qPCR. In yeast precultured in raffinose containing media the GAL1 promoter responded faster than in yeast precultured in glucose containing media. IMAGEtag RNA has relatively short half-life (5.5 min) in yeast. For imaging, the yeast cells are incubated with their ligands that are labeled with fluorescent dyes. To increase signal to noise, ligands have been separately conjugated with the FRET (Förster resonance energy transfer) pairs, Cy3 and Cy5. With these constructs, the transcribed aptamers can be imaged after activation of the promoter by galactose. FRET was confirmed with three different approaches, which were sensitized emission, acceptor photobleaching and donor lifetime by FLIM (fluorescence lifetime imaging microscopy). Real-time transcription was measured by FLIM-FRET, which ...
Date: December 13, 2011
Creator: Shin, Il Chung
Partner: UNT Libraries Government Documents Department

Observation of the submillimeter cosmic background spectrum

Description: An experimental measurement of the spectrum of the submillimeter cosmic background radiation is described. The experiment consists of measuring the night sky emission at an altitude of 39 km, correcting for the atmospheric molecular line emission, and placing limits on the contamination from sources of continuum radiation such as the apparatus itself and the earth. The observations were made on 24 July 1974 using a fully calibrated liquid-helium-cooled balloon- borne spectrophotometer. Important features of the apparatus include a cooled antenna, a polarizing interferometer, and a germanium bolometric detector. The characterization of the spectrophotometer includes the large angle response and emission of the antenna. The calibration of the instrument and corrections to the observed sky spectrum are based on measurements made during the flight. A simple model of the molecular line emission is used to determine the atmospheric contribution. The resulting spectrum covers the frequency range from 4 to 17 cm$sup -1$ and establishes that the cosmic background radiation follows the high frequency quantum cutoff for a 3K blackbody. A blackbody temperature of 2.99/sub -.$sub 14$/$sup +$.$sup 07$/K is deduced from our data. The present status of the cosmic background observations, which span more than three decades in frequency, is analyzed and it is concluded that they are all consistent with a blackbody temperature of 2.90 +- .04K (+- 1 SIGMA). This firmly supports the Big Bang cosmological model of the universe. (auth)
Date: November 13, 1975
Creator: Woody, D.P.
Partner: UNT Libraries Government Documents Department

Sum-Frequency Generation from Chiral Media and Interfaces

Description: Sum frequency generation (SFG), a second-order nonlinear optical process, is electric-dipole forbidden in systems with inversion symmetry. As a result, it has been used to study chiral media and interfaces, systems intrinsically lacking inversion symmetry. This thesis describes recent progresses in the applications of and new insights into SFG from chiral media and interfaces. SFG from solutions of chiral amino acids is investigated, and a theoretical model explaining the origin and the strength of the chiral signal in electronic-resonance SFG spectroscopy is discussed. An interference scheme that allows us to distinguish enantiomers by measuring both the magnitude and the phase of the chiral SFG response is described, as well as a chiral SFG microscope producing chirality-sensitive images with sub-micron resolution. Exploiting atomic and molecular parity nonconservation, the SFG process is also used to solve the Ozma problems. Sum frequency vibrational spectroscopy is used to obtain the adsorption behavior of leucine molecules at air-water interfaces. With poly(tetrafluoroethylene) as a model system, we extend the application of this surface-sensitive vibrational spectroscopy to fluorine-containing polymers.
Date: February 13, 2006
Creator: Ji, Na
Partner: UNT Libraries Government Documents Department


Description: Thesis submitted to University of Tennessee, Knoxville. Activities in a program to determine the wetting behavior of pure metals such as Au, Ag, Ge, Al, and Cu on solid Be are reported. Results of similar investigations of binary alloys such as Be--Ti, Be-Zr, and Be--Pd are also included. The contact angles of the molten metals on Be as a function of temperature, exposure time, and atmosphere were measured. The solid-liquid interfacial reactions occurring as a function of test temperature and atmosphere were investigated, and the liquid- vapor and internal surface tensions for those systems in which interfacial reactions did not appear to occur were calculated. (J.R.D.)
Date: June 13, 1963
Creator: Gilliland, R.G.
Partner: UNT Libraries Government Documents Department

Quantum groups: Geometry and applications

Description: The main theme of this thesis is a study of the geometry of quantum groups and quantum spaces, with the hope that they will be useful for the construction of quantum field theory with quantum group symmetry. The main tool used is the Faddeev-Reshetikhin-Takhtajan description of quantum groups. A few content-rich examples of quantum complex spaces with quantum group symmetry are treated in details. In chapter 1, the author reviews some of the basic concepts and notions for Hopf algebras and other background materials. In chapter 2, he studies the vector fields of quantum groups. A compact realization of these vector fields as pseudodifferential operators acting on the linear quantum spaces is given. In chapter 3, he describes the quantum sphere as a complex quantum manifold by means of a quantum stereographic projection. A covariant calculus is introduced. An interesting property of this calculus is the existence of a one-form realization of the exterior differential operator. The concept of a braided comodule is introduced and a braided algebra of quantum spheres is constructed. In chapter 4, the author considers the more general higher dimensional quantum complex projective spaces and the quantum Grassman manifolds. Differential calculus, integration and braiding can be introduced as in the one dimensional case. Finally, in chapter 5, he studies the framework of quantum principal bundle and construct the q-deformed Dirac monopole as a quantum principal bundle with a quantum sphere as the base and a U(1) with non-commutative calculus as the fiber. The first Chern class can be introduced and integrated to give the monopole charge.
Date: May 13, 1996
Creator: Chu, C. S.
Partner: UNT Libraries Government Documents Department

Measurement of time dependent B{sub d}{sup 0} {bar B}{sub d}{sup 0} mixing parameter using opposite side lepton and D* meson in p{bar p} collisions at {radical}s = 1.8 TeV

Description: This thesis presents the results from the investigation of time dependent B{sub d}{sup 0} {bar B}{sub d}{sup 0} mixing in B {yields} lepton X, B{sub d}{sup 0} {yields} D*{sup -} {yields} {bar D}{sup 0} {pi}{sup -}, {bar D}{sup 0} {yields} K{sup +} {pi}{sup -} channel in p{bar p} collisions at {radical}s = 1.8 TeV using 110 pb{sup -1} data collected with the CDF detector at the Fermilab Tevatron Collider. The {bar D}{sup 0} vertex is reconstructed. The B{sub d}{sup 0} decay length is estimated using the distance from the primary vertex to the measured position of the D{sup 0} vertex. The B{sup 0} momentum is estimated using the D{sup 0} momentum and a kinematic correction factor from Monte Carlo. With the dilution floating, {Delta}M{sub d} = 0.55 {+-}{sub 0.16}{sup 0.15} (stat) {+-} 0.06 (syst)ps{sup -1} is measured.
Date: January 13, 1998
Creator: Vandenbrink, S.C.
Partner: UNT Libraries Government Documents Department

Matrix Isolation Studies of High-Temperature Species Group II Chlorides

Description: A matrix isolation technique for the investigation of infrared absorption spectra of molecules of hightemperature species trapped in a pseudo- gas phase'' is described. The spectra of the dichlorides of zinc, cadmium, and mercury in argon, krypton, and xenon matrices are reported. Presence in the gas phase of dimers of zinc chloride and mercuric chloride is noted. An absorption band, previously reported as due to the degenerate bending motion of zinc chloride, is attributed to zinc dimer. (auth)
Date: September 13, 1962
Creator: McNamee, R. W., Jr.
Partner: UNT Libraries Government Documents Department