Substitution chemistry of Ruthenium clusters with the diphosphine ligands: 4,5-Bis(diphenylphosphino)-4-cyclo-penten-1,3-dione (bpcd), (Z)-Ph₂PCH=CHPP₂ and 3,4-Bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf)
Description: This study embarks on a program designed to study the reactivity of polynuclear clusters with redox-active phospines in an effort to prepare new ligand/cluster redox systems. This study aims to prove that such compounds will display superior electron reservoir capabilities, as a result of the cooperative mixing of ligand and cluster orbitals.
Date: May 1997
Creator: Shen, Huafeng
Partner: UNT Libraries