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Synthesis and Characterization of a New Perhalogenated Porphyrin

Description: The first synthesis of an octahalotetraalkylporphyrin [2,3,7,8,12,13,17,18 -octabromo-5,10,15,20- tetrakis(trifluoromethyl)porphinato nickel(II)] is reported; this perhalogenated porphyrin has several novel properties including a very nonplanar ruffled structure with an unusually short Ni- N distance, an extremely red-shifted optical spectrum, and hindered rotation of the trifluoromethyl groups ({Delta}G<sub>278K</sub> =47 kJ mol<sup>-1</sup>).
Date: May 19, 1999
Creator: Jia, Songling; Medforth, Craig J.; Nelson, Nora Y.; Nurco, Daniel J.; Shelnutt, John & Smith, Kevin M.
Partner: UNT Libraries Government Documents Department

Very long single- and few-walled boron nitride nanotubes via the pressurized vapor/condenser method

Description: Boron nitride nanotubes (BNNTs) are desired for their exceptional mechanical, electronic, thermal, structural, textural, optical, and quantum properties. A new method for producing long, small-diameter, single- and few-walled, boron nitride nanotubes (BNNTs) in macroscopic quantities is reported. The pressurized vapor/condenser (PVC) method produces, without catalysts, highly crystalline, very long, small-diameter, BNNTs. Palm-sized, cotton-like masses of BNNT raw material were grown by this technique and spun directly into centimeters-long yarn. Nanotube lengths were observed to be 100 times that of those grown by the most closely related method. Self-assembly and growth models for these long BNNTs are discussed.
Date: November 1, 2009
Creator: Michael W. Smith, Kevin Jordan, Cheol Park, Jae-Woo Kim, Peter Lillehei, Roy Crooks, Joycelyn Harrison
Partner: UNT Libraries Government Documents Department

A nonplanar porphyrin-based receptor molecule for chiral amine ligands

Description: A novel porphyrin-based receptor molecule for chiral amine ligands is described in which nonplanarity of the porphyrin macrocycle is used to orient the ligand and to enhance porphyrin-ligand interactions. The porphyrin macrocycle provides a versatile platform upon which to build elaborate superstructures, and this feature coupled with a rich and well-developed synthetic chemistry has led to the synthesis of many elegant models of heme protein active sites and numerous porphyrin-based receptor molecules. One design feature which is not usually considered in the design of porphyrin-based receptor molecules is nonplanarity of the porphyrin ring, although there are a few systems such as the pyridine sensitive Venus Flytrap and the chirality-memory molecule which illustrate that nonplanar porphyrin-based receptors can display unique and interesting behavior. Given the novel properties of these receptors and the continuing interest in the effects of nonplanarity on the properties of porphyrins the authors decided to investigate in more detail the potential applications of nonplanarity in the design of porphyrin-based receptors. Herein, they describe the design, synthesis, and characterization of a new kind of nonplanar porphyrin-based receptor molecule for chiral amines.
Date: March 6, 2000
Creator: MUZZI,CINZIA M.; MEDFORTH,CRAIG J.; SMITH,KEVIN M.; JIA,SONG-LING & SHELNUTT,JOHN A.
Partner: UNT Libraries Government Documents Department

Synthesis and unusual properties of the first 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraalkylporphyrin

Description: The new perhalogenated porphyrin 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetrakis(trifluoromethyl)porphinato-nickel(II) exhibits several striking features, including an extremely ruffled macrocycle with a very short Ni-N distance, an unusually red-shifted optical spectrum, and, surprisingly, hindered rotation of the meso-trifluoromethyl substituents ({Delta}G{sub 278}{sup +} = 47 kJ/mol).
Date: March 6, 2000
Creator: NELSON,NORA Y.; MEDFORTH,CRAIG J.; NURCO,DANIEL J.; JIA,SONG-LING; SHELNUTT,JOHN A. & SMITH,KEVIN M.
Partner: UNT Libraries Government Documents Department

Novel Dodecaarylporphyrins: Synthesis and Variable Temperature NMR Studies

Description: An investigation of the synthesis of novel dodecaarylporphyrins using the Suzuki coupling reaction of arylboronic acids with octabromotetraarylporphyrins is reported. Studies of the dynamic properties of these new porphyrins using variable temperature (VT) <SUP>1</SUP>H NMR spectroscopy and molecular mechanics provide interesting insights into their dynamic properties, including the first determination of {beta} aryl rotation in a porphyrin system.
Date: May 5, 1999
Creator: Cancilla, Mark; Lebrilla, Carlito; Ma, Jian-Guo; Medforth, Craig J.; Muzzi, Cinzia M.; Shelnutt, John A. et al.
Partner: UNT Libraries Government Documents Department