A nonplanar porphyrin-based receptor molecule for chiral amine ligands
Description:
A novel porphyrin-based receptor molecule for chiral amine ligands is described in which nonplanarity of the porphyrin macrocycle is used to orient the ligand and to enhance porphyrin-ligand interactions. The porphyrin macrocycle provides a versatile platform upon which to build elaborate superstructures, and this feature coupled with a rich and well-developed synthetic chemistry has led to the synthesis of many elegant models of heme protein active sites and numerous porphyrin-based receptor m…
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Date:
March 6, 2000
Creator:
Muzzi, Cinzia M.; Medforth, Craig J.; Smith, Kevin M.; Jia,Song-Ling & Shelnutt, John A.
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UNT Libraries Government Documents Department