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The Synthesis and Testing of Differential Herbicides

Description: This investigation was limited to the preparation of substituted phenoxyacetic acids and related compounds. The types of substances prepared for testing can, in general, be placed in three groups. These are: aryloxyacetic acids, arylmercaptoacetic acids, and those acids containing the thiophene nucleus.
Date: 1948
Creator: Ashmore, James
Partner: UNT Libraries

Pesticide Use and Water Quality: Are the Laws Complementary or in Conflict?

Description: This report provides background on the conflict over interpretation and implementation of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) and the Clean Water Act (CWA). A brief discussion of the two laws is followed by a review of the major litigation of interest.
Date: March 19, 2014
Creator: Copeland, Claudia
Item Type: Report
Partner: UNT Libraries Government Documents Department

Pesticide Law: A Summary of the Statutes

Description: This report defines key terms, provides a brief history of the federal pesticide laws, and describes key provisions of the laws, including the pesticide registration process and how it interfaces with food safety requirements. In addition, this report lists several references for more detailed information about the acts, and two tables cross reference sections of the U.S. Code with corresponding sections of the acts. The report is descriptive rather than analytic, highlights key provisions rather than providing a comprehensive inventory of the acts' numerous sections, and addresses authorities and limitations imposed by statute, rather than the status of the Environmental Protection Agency (EPA) implementation or other policy issues.
Date: November 17, 2008
Creator: Schierow, Linda-Jo
Item Type: Report
Partner: UNT Libraries Government Documents Department

Pesticide Registration and Tolerance Fees: An Overview

Description: This report gives an overview of the collection of fees to support U.S. Environmental Protection Agency (EPA) pesticide program activities. Authority to collect fees in addition to appropriated funds has been provided over the years in part to accelerate the agency's review efforts and to fund its increasing statutory responsibilities.
Date: August 18, 2008
Creator: Esworthy, Robert
Item Type: Report
Partner: UNT Libraries Government Documents Department

Bee Health: The Role of Pesticides

Description: This report briefly describes recent scientific research and analysis regarding the potential role of pesticides among the factors affecting the health and well-being of bees.
Date: February 17, 2015
Creator: Johnson, Renée & Corn, M. Lynne
Item Type: Report
Partner: UNT Libraries Government Documents Department

Evaluation of TVA`s model site and individual technology pollution prevention demonstration programs and their impact on the agrichemical industry

Description: The high volume of fertilizer and pesticides funneled through a relatively small number of distribution outlets has made these agribusiness sites potential sources of surface/groundwater contamination in watersheds surrounding the agrichemical facilities. The agrichemical industry came under increased pressures in the mid-1980s to implement environmentally sound management practices and to install containment structures around fertilizer and chemical storage/handling areas to prevent future contamination of existing sites or the movement of contaminants offsite. TVA`s long and successful history of technology transfer to the retail fertilizer industry, as well as the technical expertise of the Agency`s staff, made TVA ideally suited to handle the new environmental challenge. It was during this time period that TVA`s Model Site Demonstration Program (MSD) and Individual Technology Demonstration Program (ITD) were conceived. Since inception, the pollution prevention program and the technologies advanced by it have made a very positive impact on the US agrichemical industry, as well as on other TVA programs. This paper is an attempt to document these impacts, with primary focus being placed on the program`s impact on the agribusiness dealer who implements the pollution prevention technologies/practices recommended by TVA.
Date: June 1, 1995
Creator: Simpson, G.S.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Economic costs and benefits associated with investments in pollution prevention structures

Description: Both fertilizers and pesticides are primary sources of surface and groundwater contamination in the US. The agrichemical industry came under increased pressures in the mid-1980s to implement environmentally sound management practices and to install containment structures around fertilizer and chemical storage/handling areas to prevent future contamination of existing sites or the movement of contaminants offsite. TVA`s long and successful history of technology transfer to the retail fertilizer industry, as well as the technical expertise of the Agency`s staff, made TVA ideally suited to handle the new environmental challenge. It was during this time period that TVA`s Model Site Demonstration Program (MSD) and Individual Technology Demonstration Program (ITD) were conceived. The general objective of these programs is to provide research, development, and application of pollution prevention technologies and strategies for industries which market or use fertilizers, pesticides, and other agricultural chemicals. From an economic perspective, the installation of pollution prevention structures, as well as adherence to other regulatory requirements carries a real cost to the agrichemical retailer. However, there may also be benefits tied to the adoption of new technology that would offset some or all of the additional operating costs accrued as a result of investment in the environmental technology. This paper attempts to document the economic costs associated with investments in pollution prevention technologies and adherence to environmental regulations at TVA demonstrator sites; as well as the potential benefits an agribusiness dealer may accrue as a result of the environmental investment.
Date: September 1, 1995
Creator: Simpson, G.S.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Estimating the economic impact of environmental investments on retail costs and dealer strategies for offsetting these costs

Description: Retail agrichemical dealers have become increasingly familiar with the concept of containment over the past several years. Currently, containment regulations are in place in 13 states, and are being drafted in 7 others. Agrichemical dealers in these states will be required to assess the potential environmental impact of their operating practices on the land under and around the retail production site. A recent survey of TVA model site and individual technology demonstration dealers attempted to gain insight into the impact these investments in containment structures, changing operating practices, and state containment regulations were having on annual production costs. The purpose of this paper is to (1) provide the agrichemical dealer a methodology for quickly estimating the potential impact that environmental investments will have on annual production costs, and (2) to evaluate the effectiveness of alternative management strategies employed to offset some, or in some cases, all of these additional costs.
Date: September 1, 1995
Creator: Simpson, G.S.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Corrective Action Investigation Plan for Corrective Action Unit 232: Area 25 Sewage Lagoons, Nevada Test Site, Nevada, Revision 0

Description: The Corrective Action Investigation Plan for Corrective Action Unit 232, Area 25 Sewage Lagoons, has been developed in accordance with the Federal Facility Agreement and Consent Order that was agreed to by the U.S. Department of Energy, Nevada Operations Office; the State of Nevada Division of Environmental Protection; and the U. S. Department of Defense. Corrective Action Unit 232 consists of Corrective Action Site 25-03-01, Sewage Lagoon. Corrective Action Unit 232, Area 25 Sewage Lagoons, received sanitary effluent from four buildings within the Test Cell ''C'' Facility from the mid-1960s through approximately 1996. The Test Cell ''C'' Facility was used to develop nuclear propulsion technology by conducting nuclear test reactor studies. Based on the site history collected to support the Data Quality Objectives process, contaminants of potential concern include volatile organic compounds, semivolatile organic compounds, Resource Conservation and Recovery Act metals, petroleum hydrocarbons, polychlorinated biphenyls, pesticides, herbicides, gamma emitting radionuclides, isotopic plutonium, isotopic uranium, and strontium-90. A detailed conceptual site model is presented in Section 3.0 and Appendix A of this Corrective Action Investigation Plan. The conceptual model serves as the basis for the sampling strategy. Under the Federal Facility Agreement and Consent Order, the Corrective Action Investigation Plan will be submitted to the Nevada Division of Environmental Protection for approval. Field work will be conducted following approval of the plan. The results of the field investigation will support a defensible evaluation of corrective action alternatives in the Corrective Action Decision Document.
Date: May 1, 1999
Creator: /NV, USDOE
Item Type: Report
Partner: UNT Libraries Government Documents Department

The Federal Food Safety System: A Primer

Description: The combined efforts of the food industry and the regulatory agencies often are credited with making the U.S. food supply among the safest in the world. Nonetheless, many food-related health issues persist. At issue is whether the current U.S. regulatory system has the resources and structural organization to protect consumers from these dangers. Also at issue is whether the federal food safety laws themselves, first enacted in the early 1900s, have kept pace with the significant changes that have occurred in the food production, processing, and marketing sectors since then.
Date: December 15, 2010
Creator: Johnson, Renée
Item Type: Report
Partner: UNT Libraries Government Documents Department

The Federal Food Safety System: A Primer

Description: Report concerning food safety, the resources required to ensure food safety, and whether federal food safety laws themselves, first enacted in the early 1900s, have kept pace with the significant changes that have occurred in the food production, processing, and marketing sectors since then.
Date: January 11, 2011
Creator: Johnson, Renée
Item Type: Report
Partner: UNT Libraries Government Documents Department

The Federal Food Safety System: A Primer

Description: The combined efforts of the food industry and the regulatory agencies often are credited with making the U.S. food supply among the safest in the world. Nonetheless, many food-related health issues persist. At issue is whether the current U.S. regulatory system has the resources and structural organization to protect consumers from these dangers. Also at issue is whether the federal food safety laws themselves, first enacted in the early 1900s, have kept pace with the significant changes that have occurred in the food production, processing, and marketing sectors since then.
Date: September 22, 2010
Creator: Johnson, Renée
Item Type: Report
Partner: UNT Libraries Government Documents Department

Pesticide Law: A Summary of the Statutes

Description: This report summarizes the major statutory authorities governing pesticide regulation: the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA), and Section 408 of the Federal Food, Drug, and Cosmetic Act (FFDCA), as well as the major regulatory programs for pesticides.
Date: March 19, 2008
Creator: Schierow, Linda-Jo
Item Type: Report
Partner: UNT Libraries Government Documents Department

Pesticide Registration and Tolerance Fees: An Overview

Description: This report gives an overview of the collection of fees to support U.S. Environmental Protection Agency (EPA) pesticide program activities. Authority to collect fees in addition to appropriated funds has been provided over the years in part to accelerate the agency's review efforts and to fund its increasing statutory responsibilities.
Date: August 18, 2008
Creator: Esworthy, Robert
Item Type: Report
Partner: UNT Libraries Government Documents Department

Pesticide Use and Water Quality: Are the Laws Complementary or in Conflict?

Description: This report provides background on the conflict over interpretation and implementation of the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA) and the Clean Water Act. A brief discussion of the two laws is followed by a review of the major litigation of interest. EPA's efforts to clarify its policy in this area and the November 2006 rule and the 2009 federal court ruling are discussed, as well as possible options for EPA and Congress to further address the FIFRA-CWA issues. In June, EPA proposed a draft general CWA permit that it intends to finalize by April 2011 in response to the court ruling.
Date: October 13, 2010
Creator: Copeland, Claudia
Item Type: Report
Partner: UNT Libraries Government Documents Department

Closure Report for Corrective Action Unit 404: Roller Coaster Sewage Lagoons and North Disposal Trench, Tonopah Test Range, Nevada with ROTC 1, Revision 0

Description: This Closure Report provides the documentation for closure of the Roller Coaster Sewage Lagoons and North Disposal Trench Comective Action Unit (CAU) 404. CAU 404 consists of the Roller Coaster Sewage Lagoons (Corrective Action Site [CAS] TA-03-O01-TA-RC) and the North Disposal Trench (CAS TA-21-001-TA-RC). The site is located on the Tonopah Test Range, approximately 225 kilometers (km) (140 miles [mi]) northwest ofLas Vegas, Nevada. . The sewage lagoons received ~quid sanitary waste horn the Operation Roller Coaster Man Camp in 1963 and debris from subsequent range and construction cleanup activities. The debris and ordnance was subsequently removed and properly dispos~, however, pesticides were detected in soil samples born the bottom of the lagoons above the U,S. Environmental Protection Agency Region IX Prelimimuy Remediation Goals (EPA 1996). . The North Disposal Trench was excavated in 1963. Debris from the man camp and subsequent range and construction cleanup activities was placed in the trench. Investigation results indicated that no constituents of concern were detected in soil samples collected from the trench. Remedial alternative proposed in the Comctive Action Decision Document (CADD) fm the site was “Covering” (DOE, 1997a). The Nevada Division of”Enviromnental Protection (NDEP)-approved Correction Action Plan (CAP) proposed the “Covering” niethodology (1997b). The closure activities were completed in accorhce with the approwil CAP and consisted of baclctllling the sewage lagoons and disposal trench, constructing/planting an engineered/vegetative cover in the area of the sewage lagoons and dikposal trencQ installing a perimeter fence and signs, implementing restrictions on fi~e use, and preparing a Post-Closure Monitoring Plan. “ Since closure activities. for CAU 404 have been completed in accordance with the Nevada Division of Environmental Protection-approved CAP (DOE, 1997b) as documented in this Closure Report, the U.S. Department of Energy, NevadaOperations Office (DOE/NV) requests: CAU 404 be moved from Appendix III to Appendix IV ...
Date: September 1, 1998
Creator: Kidman, Lynn
Item Type: Report
Partner: UNT Libraries Government Documents Department

Methyl-parathion decreases sperm function and fertilization capacity after targeting spermatocytes and maturing spermatozoa

Description: Paternal germline exposure to organophosphorous pesticides (OP) has been associated with reproductive failures and adverse effects in the offspring. Methyl parathion (Me-Pa), a worldwide-used OP, has reproductive adverse effects and is genotoxic to sperm. Oxidative damage has been involved in the genotoxic and reproductive effects of OP. The purpose of this study was to determine the effects of Me-Pa on spermatozoa function and ability to fertilize. Male mice were exposed to Me-Pa (20 mg/kg bw, i.p.) and spermatozoa from epididymis-vas deferens were collected at 7 or 28 days post-treatment (dpt) to assess the effects on maturing spermatozoa and spermatocytes, respectively. DNA damage was evaluated by nick translation (NT-positive cells) and SCSA (percentDFI); lipoperoxidation (LPO) by malondialdehyde production; sperm function by spontaneous- and induced-acrosome reactions (AR); mitochondrial membrane potential (MMP) by using the JC-1 flurochrome; and, fertilization ability by an in vitro assay and in vivo mating. Results showed alterations in DNA integrity (percentDFI and NT-positive cells) at 7 and 28 dpt, in addition to decreased sperm quality and a decrease in induced-AR; reduced MMP and LPO was observed only at 7 dpt. We found negative correlations between LPO and all sperm alterations. Altered sperm functional parameters were associated with reduced fertilization rates at both times, evaluated either in vitro or in vivo. These results show that Me-Pa exposure of maturing spermatozoa and spermatocytes affects many sperm functional parameters that result in a decreased fertilizing capacity. Oxidative stress seems to be a likely mechanism ofthe detrimental effects of Me-Pa in male germ cells.
Date: May 3, 2009
Creator: Pina-Guzman, Belem; Sanchez-Gutierrez, M.; Marchetti, Francesco; Hernandez-Ochoa, I.; Solis-Heredia, M.J . & Quintanilla-Vega, B.
Item Type: Article
Partner: UNT Libraries Government Documents Department

POST-REMEDIATION BIOMONITORING OF PESTICIDES AND OTHER CONTAMINANTS IN MARINE WATERS AND SEDIMENT NEAR THE UNITED HECKATHORN SUPERFUND SITE, RICHMOND, CALIFORNIA

Description: Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in February 1999 from four stations near Lauritzen Canal in Richmond, California, for Year 2 of post-remediation monitoring of marine areas near the United Heckathorn Site. Dieldrin and dichlorodiphenyl trichloroethane (DDT) were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Mussel tissues were also analyzed for polychlorinated biphenyls (PCB), which were detected in sediment samples. Chlorinated pesticide concentrations in water samples were similar to preremediation levels and did not meet remediation goals. Biomonitoring results indicated that the bioavailability of chlorinated pesticides has been reduced from preremediation levels both in the dredged area and throughout Richmond Harbor. Total DDT and dieldrin concentrations in mussel tissues were lower than measured levels from preremediation surveys and also lower than Year 1 levels from post-remediation biomonitoring. Sediment analyses showed the presence of elevated DDT, dieldrin, PCB aroclor 1254, and very high levels of polynuclear aromatic hydrocarbons (PAH) in Lauritzen Channel.
Date: September 6, 2000
Creator: Antrim, Liam D. & Kohn, Nancy P.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Post-Remediation Biomonitoring of Pesticides in Marine Waters Near the United Heckathorn Site, Richmond, California

Description: Marine sediment remediation at the United Heckathorn Superfund Site was completed in April 1997. Water and mussel tissues were sampled in January 1998 from four stations near Lauritzen Canal in Richmond, California, for the first post-remediation monitoring of marine areas near the United Heckathorn Site. Dieldrin and DDT were analyzed in water samples, tissue samples from resident mussels, and tissue samples from transplanted mussels deployed for 4 months. Concentrations of dieldrin and total DDT in water and total DDT in tissue were compared to pre-remediation data available from the California State Mussel Watch program (tissues) and the Ecological Risk Assessment for the United Heckathorn Superfund Site (tissues and water). Biomonitoring results indicated that pesticides were still bioavailable in the water column, and have not been reduced from pre-remediation levels. Annual biomonitoring will continue to assess the effectiveness of remedial actions at the United Heckathorn Site.
Date: September 5, 2000
Creator: Antrim, Liam D. & Kohn, Nancy P.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Remaining Sites Verification Package for the 1607-F5 Sanitary Sewer System (124-F-5), Waste Site Reclassification Form 2006-043

Description: The 1607-F5 waste site is a former septic tank, tile field, and associated pipeline located within the 100-FR-1 Operable Unit that received sewage from the former 181-F Pumphouse. Lead, gamma-chlordane, and heptachlor epoxide were identified within or around the septic system at concentrations exceeding the direct exposure cleanup criteria. Multiple metal and pesticide constituents were also identified as exceeding the groundwater and river protection cleanup criteria. The results of verification sampling demonstrated that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also showed that residual contaminant concentrations are protective of groundwater and the Columbia River.
Date: September 14, 2006
Creator: Dittmer, L. M.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Microwave Treatment as a Pesticide Alternative for Stored-Products

Description: This CRADA was a continuation of earlier work with Micro-Grain, Inc. to develop power, high frequency microwave treatment process to treat insect infested grain. ORNLs role was as a subcontractor to Micro-Grain's Phase II SBIR project funded by the US Department of Agriculture. The primary objective was to develop a commercial scale prototype unit capable of treating infested grain at flow rates approaching 1 kg/sec, which is required to be viable in the grain handling industry. A flow rate of {approx} 0.12 Kg/second was demonstrated at 20 kW microwave power level with 100% kill rate. The system is capable of 200 kW however waveguide arcing due to grain dust in the waveguide limited the power to 20 kW during the tests. Development tasks performed during the project included modification of an existing high-power microwave exposure facility to uniformly process large grain samples at high flow rates and improved instrumentation to detect grain flow and uniformity. Microwave processing tasks include a series of controlled exposure tests using infested grain samples provided and analyzed by the University of Oklahoma. Grain samples were infested with red flour beetles which proved the most difficult to kill in earlier tests. Most of the samples processed resulted in quite successful kill rates and a maximum grain temperature of 46 C. The facilities utilized at ORNL are located in the Fusion Energy building (9201-2 at Y-12) and include the 28 GHz 200 kW CW high power microwave facility and microwave test equipment associated with the FED Microwave Development Laboratory in 9201-2. An improved microwave exposure chamber and grain flow control and handling equipment were designed and build as a joint effort between Micro-Grain and ORNL. A number of insect infested grain tests were successfully performed although the higher power, higher flow rates were limited by arcing in ...
Date: May 21, 2003
Creator: Bigelow, T.S.; Forrester, S.C.; Halverson, S.; Halverson, B. & Phillips, T.
Item Type: Report
Partner: UNT Libraries Government Documents Department

A Critical Medical Anthropology Approach to Advocating for Social Justice and Policy Change in Pesticide Use and Practice to Reduce Health Risks Among Hispanic/latinos in Central California

Description: This mixed methods research was conducted in the fall of 2014 to understand the perceptions and experiences of health risks and health outcomes due to pesticide exposure among community members (n=13) - concerned community members, agriculture workers and teachers- that live in the Central California agriculture counties of Monterey, Santa Cruz, Tulare, Fresno and Madera. This research explored: 1) The crops growing in participants’ communities, and how exposure to pesticides used in these crops pose potential health risks to participants and their communities 2) How pesticide exposure is impacting Hispanic/Latino communities in Central California, particularly those that are most vulnerable including school children, agriculture workers, and community members 3) The major public health concerns of impacted communities 4) Feelings of empowered to advocate for community health and environment and 5) What impacted communities wish to see on behalf of government and agribusiness to protect public health from pesticide exposure and toxins.
Date: August 2015
Creator: Romero, Mariel Sintora
Partner: UNT Libraries

SPRAYTRAN 1.0 User’s Guide: A GIS-Based Atmospheric Spray Droplet Dispersion Modeling System

Description: SPRAY TRANsport (SPRAYTRAN) is a comprehensive dispersion modeling system that is used to simulate the offsite drift of pesticides from spray applications. SPRAYTRAN functions as a console application within Environmental System Research Institute’s ArcMap Geographic Information System (Version 9.x) and integrates the widely-used, U.S. Environmental Protection Agency (EPA)-approved CALifornia PUFF (CALPUFF) dispersion model and model components to simulate longer-range transport and diffusion in variable terrain and spatially/temporally varying meteorological (e.g., wind) fields. Area sources, which are used to define spray blocks in SPRAYTRAN, are initialized using output files generated from a separate aerial-spray-application model called AGDISP (AGricultural DISPersal). The AGDISP model is used for estimating the amount of pesticide deposited to the spray block based on spraying characteristics (e.g., pesticide type, spray nozzles, and aircraft type) and then simulating the near-field (less than 300-m) drift from a single pesticide application. The fraction of pesticide remaining airborne from the AGDISP near-field simulation is then used by SPRAYTRAN for simulating longer-range (greater than 300 m) drift and deposition of the pesticide.
Date: September 20, 2006
Creator: Allwine, K Jerry; Rutz, Frederick C.; Droppo, James G.; Rishel, Jeremy P.; Chapman, Elaine G.; Bird, S. L. et al.
Item Type: Report
Partner: UNT Libraries Government Documents Department

Remaining Sites Verification Package for the 120-F-1 Glass Dump Waste Site, Waste Site Reclassification Form 2008-028

Description: The 120-F-1 waste site consisted of two dumping areas located 660 m southeast of the 105-F Reactor containing laboratory equipment and bottles, demolition debris, light bulbs and tubes, small batteries, small drums, and pesticide contaminated soil. It is probable that 108-F was the source of the debris but the material may have come from other locations within the 100-F Area. In accordance with this evaluation, the verification sampling results support a reclassification of this site to Interim Closed Out. The results of verification sampling show that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.
Date: June 27, 2008
Creator: Capron, J. M.
Item Type: Report
Partner: UNT Libraries Government Documents Department