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Measuring Atmospheric Ozone and Nitrogen Dioxide Concentration by Differential Optical Absorption Spectroscopy

Description: The main objective was to develop a procedure based on differential optical absorption spectroscopy (DOAS) to measure atmospheric total column of ozone, using the automated instrument developed at the University of North Texas (UNT) by Nebgen in 2006. This project also explored the ability of this instrument to provide measurements of atmospheric total column nitrogen dioxide. The instrument is located on top of UNT’s Environmental Education, Science and Technology Building. It employs a low cost spectrometer coupled with fiber optics, which are aimed at the sun to collect solar radiation. Measurements taken throughout the day with this instrument exhibited a large variability. The DOAS procedure derives total column ozone from the analysis of daily DOAS Langley plots. This plot relates the measured differential column to the airmass factor. The use of such plots is conditioned by the time the concentration of ozone remains constant. Observations of ozone are typically conducted throughout the day. Observations of total column ozone were conducted for 5 months. Values were derived from both DOAS and Nebgen’s procedure and compared to satellite data. Although differences observed from both procedures to satellite data were similar, the variability found in measurements was reduced from 70 Dobson units, with Nebgen’s procedure, to 4 Dobson units, with the DOAS procedure.A methodology to measure atmospheric nitrogen dioxide using DOAS was also investigated. Although a similar approach to ozone measurements could be applied, it was found that such measurements were limited by the amount of solar radiation collected by the instrument. Observations of nitrogen dioxide are typically conducted near sunrise or sunset, when solar radiation experiences most of the atmospheric absorption.
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Date: December 2011
Creator: Jerez, Carlos J.
Partner: UNT Libraries

Anthropogenic Ozone Depletion: Status and Human Health Implications, USGCRP Seminar, 13 November 1995.

Description: In this USGRP Seminar, speakers answer the following questions: what is the status of the Earth's ozone layer? Is the Montreal Protocol working? How much time will be necessary for nature to restore the ozone layer? What are the human health effects of increased ultraviolet radiation associated with depletion of the ozone layer? Who is at risk?
Date: November 13, 1995
Creator: Albritton, Daniel & Kripke, Margaret
Partner: UNT Libraries

IPCC Special Report Aviation and the Global Atmosphere: Summary for Policymakers

Description: The Intergovernmental Panel on Climate Change (IPCC) was jointly established by the World Meteorological Organization (WMO) and the United Nations Environment Programme (UNEP) in 1988 to: (i) assess available information on the science, the impacts, and the economics of, and the options for mitigating and/or adapting to, climate change and (ii) provide, on request, scientific/technical/socio-economic advice to the Conference of the Parties (COP) to the United Nations Framework Convention on Climate Change (UNFCCC). Since then the IPCC has produced a series of Assessment Reports, Special Reports, Technical Papers, methodologies, and other products that have become standard works of reference, widely used by policymakers, scientists, and other experts. This Special Report was prepared following a request from the International Civil Aviation Organization (ICAO) and the Parties to the Montreal Protocol on Substances that Deplete the Ozone Layer. The state of understanding of the relevant science of the atmosphere, aviation technology, and socio-economic issues associated with mitigation options is assessed and reported for both subsonic and supersonic fleets. The potential effects that aviation has had in the past and may have in the future on both stratospheric ozone depletion and global climate change are covered; environmental impacts of aviation at the local scale, however, are not addressed. The report synthesizes the findings to identify and characterize options for mitigating future impacts.
Date: 1999
Creator: Intergovernmental Panel on Climate Change (IPCC) Working Groups I and III
Partner: UNT Libraries

Trends in Emissions of Ozone-Depleting Substances, Ozone Layer Recovery, and Implications for Ultraviolet Radiation Exposure

Description: This Synthesis and Assessment Product (SAP 2.4) focuses on the Climate models. Depletion of the stratospheric ozone layer by human-produced ozone-depleting substances has been recognized as a global environmental issue for more than three decades, and the international effort to address the issue via the United Nations Montreal Protocol marked its 20-year anniversary in 2007. Scientific understanding underpinned the Protocol at its inception and ever since. As scientific knowledge advanced and evolved, the Protocol evolved through amendment and adjustment. Policy-relevant science has documented the rise, and now the beginning decline, of the atmospheric abundances of many ozone-depleting substances in response to actions taken by the nations of the world. Projections are for a return of ozone-depleting chemicals (compounds containing chlorine and bromine) to their "pre-ozone-depletion" (pre-1980) levels by the middle of this century for the midlatitudes; the polar regions are expected to follow suit within 20 years after that. Since the 1980s, global ozone sustained a depletion of about 5 percent in the midlatitudes of both the Northern Hemisphere and Southern Hemisphere, where most of the Earth's population resides; it is now showing signs of turning the corner towards increasing ozone. The large seasonal depletions in the polar regions are likely to continue over the next decade but are expected to subside over the next few decades.
Date: November 2008
Creator: US Climate Change Science Program and the Subcommittee on Global Change Research.
Partner: UNT Libraries

Alternative fuels for vehicles fleet demonstration program. Final report, volume 2: Appendices

Description: The Alternative Fuels for Vehicles Fleet Demonstration Program (AFV-FDP) was a multiyear effort to collect technical data for use in determining the costs and benefits of alternative-fuel vehicles (AFVs) in typical applications in New York State. This report, Volume 2, includes 13 appendices to Volume 1 that expand upon issues raised therein. Volume 1 provides: (1) Information about the purpose and scope of the AFV-FDP; (2) A summary of AFV-FDP findings organized on the basis of vehicle type and fuel type; (3) A short review of the status of AFV technology development, including examples of companies in the State that are active in developing AFVs and AFV components; and (4) A brief overview of the status of AFV deployment in the State. Volume 3 provides expanded reporting of AFV-FDP technical details, including the complete texts of the brochure Garage Guidelines for Alternative Fuels and the technical report Fleet Experience Survey Report, plus an extensive glossary of AFV terminology. The appendices cover a wide range of issues including: emissions regulations in New York State; production and health effects of ozone; vehicle emissions and control systems; emissions from heavy-duty engines; reformulated gasoline; greenhouse gases; production and characteristics of alternative fuels; the Energy Policy Act of 1992; the Clean Fuel Fleet Program; garage design guidelines for alternative fuels; surveys of fleet managers using alternative fuels; taxes on conventional and alternative fuels; and zero-emission vehicle technology.
Date: June 1, 1997
Partner: UNT Libraries Government Documents Department

Documenting the Effectiveness of Cosorption of Airborne Contaminants by a Field-Installed Active Desiccant System: Final Report - Phase 2D

Description: The final report for Phase 1 of this research effort (ORNL/SUB/94-SV004/1) concluded that a significant market opportunity would exist for active desiccant systems if it could be demonstrated that they can remove a significant proportion of common airborne contaminants while simultaneously performing the primary function of dehumidifying a stream of outdoor air or recirculated building air. If the engineering community begins to follow the intent of ASHRAE Standard 62, now part of all major building codes, the outdoor air in many major cities may need to be pre-cleaned before it is introduced into occupied spaces. Common air contaminant cosorption capability would provide a solution to three important aspects of the ASHRAE 62-89 standard that have yet to be effectively addressed by heating, ventilation, and air-conditioning (HVAC) equipment manufacturers: (1) The ASHRAE standard defines acceptable outdoor air quality. If the outdoor air contains unacceptable levels of certain common outdoor air contaminants (e.g., sulfur dioxide, ozone), then the standard requires that these contaminants be removed from the outdoor air stream to reach compliance with the acceptable outdoor air quality guidelines. (2) Some engineers prefer to apply a filtration or prescriptive approach rather than a ventilation approach to solving indoor air quality problems. The ASHRAE standard recognizes this approach provided that the filtration technology exists to remove the gaseous contaminants encountered. The performance of current gaseous filtration technologies is not well documented, and they can be costly to maintain because the life of the filter is limited and the cost is high. Moreover, it is not easy to determine when the filters need changing. In such applications, an additional advantage provided by the active desiccant system would be that the same piece of equipment could control space humidity and provide filtration, even during unoccupied periods, if the active desiccant system were operated in ...
Date: January 23, 2003
Creator: Fischer, J.
Partner: UNT Libraries Government Documents Department

Scale-Up and Demonstration of Fly Ash Ozonation Technology

Description: The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.
Date: March 1, 2006
Creator: Afonso, Rui; Hurt, R. & Kulaots, I.
Partner: UNT Libraries Government Documents Department

NOx Control for Utility Boiler OTR Compliance

Description: Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), the Babcock and Wilcox Company (B and W), and Fuel Tech teamed together to investigate an integrated solution for NO{sub x} control. The system is comprised of B and W's DRB-4Z{trademark} ultra low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NOxOUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. Development of the low-NO{sub x} burner technology has been a focus in B and W's combustion program. The DRB-4Z{trademark} burner is B and W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by controlled mixing of the fuel and air. Based on data from several 500 to 600 MWe boilers firing PRB coal, NOx emissions levels of 0.15 to 0.20 lb/ 106 Btu have been achieved from the DRB-4Z{trademark} burners in combination with overfire air ports. Although NOx emissions from the DRB-4Z{trademark} burner are nearing the Ozone Transport Rule (OTR) level of 0.15 lb NO{sub x}/106 Btu, the utility boiler owners can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them. Large-scale testing is planned in B and W's 100-million Btu/hr Clean Environment Development Facility (CEDF) that simulates the conditions of large coal-fired utility boilers. The objective of the project is to achieve a NO{sub x} level below 0.15 lb/106 Btu (with ammonia slip of less than 5 ppm) in the CEDF using PRB coal and B and W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner in combination with dual zone overfire air ports and Fuel Tech's NO{sub x}OUT{reg_sign}. During this period B and W prepared and submitted the project management plan and hazardous substance plan to DOE. The negotiation of a ...
Date: December 31, 2003
Creator: Farzan, Hamid
Partner: UNT Libraries Government Documents Department

TOXICOLOGICAL EVALUATION OF REALISTIC EMISSIONS OF SOURCE AEROSOLS (TERESA): APPLICATION TO POWER PLANT-DERIVED PM2.5

Description: This report documents progress made on the subject project during the period of September 1, 2005 through February 28, 2006. The TERESA Study is designed to investigate the role played by specific emissions sources and components in the induction of adverse health effects by examining the relative toxicity of coal combustion and mobile source (gasoline and/or diesel engine) emissions and their oxidative products. The study involves on-site sampling, dilution, and aging of coal combustion emissions at three coal-fired power plants, as well as mobile source emissions, followed by animal exposures incorporating a number of toxicological endpoints. The DOE-EPRI Cooperative Agreement (henceforth referred to as ''the Agreement'') for which this technical progress report has been prepared covers the performance and analysis of field experiments at the first TERESA plant, located in the Upper Midwest and henceforth referred to as Plant 0, and at two additional coal-fired power plants (Plants 1 and 2) utilizing different coal types and with different plant configurations. During this reporting period, data processing and analyses were completed for exposure and toxicological data collected during the field campaign at Plant 1, located in the Southeast. To recap from the previous progress report, Stage I toxicological assessments were carried out in normal Sprague-Dawley rats, and Stage II assessments were carried out in a compromised model (myocardial infarction-MI-model). Normal rats were exposed to the following atmospheric scenarios: (1) primary particles; (2) oxidized emissions; (3) oxidized emissions + SOA--this scenario was repeated; and (4) oxidized emissions + ammonia + SOA. Compromised animals were exposed to oxidized emissions + SOA (this scenario was also conducted in replicate). Mass concentrations in exposure atmospheres ranged from 13.9 {micro}g/m{sup 3} for the primary particle scenario (P) to 385 {micro}g/m{sup 3} for one of the oxidized emissions + SOA scenarios (POS). There was a fair amount ...
Date: March 31, 2006
Creator: Rohr, Annette
Partner: UNT Libraries Government Documents Department

The dynamics of unsteady detonation in ozone

Description: An ultra-fine, sub-micron discrete grid is used to capture the unsteady dynamics of a one-dimensional detonation in an inviscid O - O{sub 2} - O{sub 3} mixture. The ultra-fine grid is necessary to capture the length scales revealed by a complementary analysis of the steady detonation wave structure. For the unsteady calculations, shock-fitting coupled with a high order spatio-temporal discretization scheme combine to render numerical corruption negligible. As a result, mathematically verified solutions for a mixture initially of all O{sub 3} at one atmosphere and 298.15 K have been obtained; the solutions are converging at a rate much faster than the sub-first order convergence rate of all shock-capturing schemes. Additionally, the model has been validated against limited experimental data. Transient calculations show that strongly overdriven waves are stable and moderately overdriven waves unstable. New limit cycle behavior is revealed, and the first high resolution bifurcation diagram for etonation with detailed kinetics is found.
Date: January 1, 2008
Creator: Aslam, Tariq D & Powers, Joseph M
Partner: UNT Libraries Government Documents Department

THE EFFECT OF THE PRESENCE OF OZONE ON THE LOWER FLAMMABILITY LIMIT OF HYDROGEN IN VESSELS CONTAINING SAVANNAH RIVER SITE HIGH LEVEL WASTE

Description: The Enhanced Chemical Cleaning (ECC) process uses ozone to effect the oxidation of metal oxalates produced during the dissolution of sludge in the Savannah River Site (SRS) waste tanks. The ozone reacts with the metal oxalates to form metal oxide and hydroxide precipitants, and the CO{sub 2}, O{sub 2}, H{sub 2}O and any unreacted O{sub 3} gases are discharged into the vapor space. In addition to the non-radioactive metals in the waste, however, the SRS radioactive waste also contains a variety of radionuclides, hence, hydrogen gas is also present in the vapor space of the ECC system. Because hydrogen is flammable, the impact of this resultant gas stream on the Lower Flammability Limit (LFL) of hydrogen must be understood for all possible operating scenarios of both normal and off-normal situations, with particular emphasis at the elevated temperatures and pressures of the typical ECC operating conditions. Oxygen is a known accelerant in combustion reactions, but while there are data associated with the behavior of hydrogen/oxygen environments, recent, relevant studies addressing the effect of ozone on the flammability limit of hydrogen proved scarce. Further, discussions with industry experts verified the absence of data in this area and indicated that laboratory testing, specific to defined operating parameters, was needed to comprehensively address the issue. Testing was thus designed and commissioned to provide the data necessary to support safety related considerations for the ECC process. A test matrix was developed to envelope the bounding conditions considered credible during ECC processing. Each test consists of combining a gas stream of high purity hydrogen with a gas stream comprised of a specified mixture of ozone and oxygen in a temperature and pressure regulated chamber such that the relative compositions of the two streams are controlled. The gases are then stirred to obtain a homogeneous mixture and ...
Date: January 12, 2012
Creator: Sherburne, C.
Partner: UNT Libraries Government Documents Department

Indoor Secondary Pollutants from Household Product Emissions inthe Presence of Ozone: A Bench-Scale Chamber Study

Description: Ozone-driven chemistry is a major source of indoor secondary pollutants of health concern. This study investigates secondary air pollutants formed from reactions between constituents of household products and ozone. Gas-phase product emissions were introduced along with ozone at constant rates into a 198-L Teflon-lined reaction chamber. Gas-phase concentrations of reactive terpenoids and oxidation products were measured. Formaldehyde was a predominant oxidation byproduct for the three studied products, with yields under most conditions of 20-30% with respect to ozone consumed. Acetaldehyde, acetone, glycolaldehyde, formic acid and acetic acid were each also detected for two or three of the products. Immediately upon mixing of reactants, a scanning mobility particle sizer detected particle nucleation events that were followed by a significant degree of ultrafine particle growth. The production of secondary gaseous pollutants and particles depended primarily on the ozone level and was influenced by other parameters such as the air-exchange rate. Hydroxyl radical concentrations in the range 0.04-200 x 10{sup 5} molecules cm{sup -3} were measured. OH concentrations were observed to vary strongly with residual ozone level in the chamber, which was in the range 1-25 ppb, as is consistent with expectations from a simplified kinetic model. In a separate test, we exposed the dry residue of two products to ozone in the chamber and observed the formation of gas-phase and particle-phase secondary oxidation products.
Date: October 1, 2005
Creator: Destaillats, Hugo; Lunden, Melissa M.; Singer, Brett C.; Coleman,Beverly K.; Hodgson, Alfred T.; Weschler, Charles J. et al.
Partner: UNT Libraries Government Documents Department

Indoor pollutants emitted by office equipment: A review ofreported data and information needs

Description: There is concern that potentially harmful pollutants may be emitted from office equipment. Although office equipment has been a focal point for governmental efforts to promote energy efficiency through programs such as the US EPA's Energy Star, little is known about the relationship between office equipment use and indoor air quality, and information on pollutant emissions is sparse. In this review, we summarize available information on emission rates and/or ambient concentrations of various pollutants that are related to office equipment use. Experimental methods used in the characterization of emissions are briefly described. The office equipment evaluated in this review includes computers (desktops and notebooks), printers (laser, ink-jet and all-in-one machines) and photocopy machines. Reported emission rates of the following pollutant groups are summarized: volatile organic chemicals (VOCs), ozone, particulate matter and several semivolatile organic chemicals (SVOCs). The latter include phthalate esters, brominated flame retardants, organophosphate flame retardants and polycyclic aromatic hydrocarbons (PAHs). We also review studies reporting airborne concentrations in indoor environments where office equipment was present and thought to be a significant contributor to the total pollutant burden (offices, residences, schools, electronics recycling plants). For certain pollutants, such as organophosphate flame retardants, the link between emission by office equipment and indoor air concentrations is relatively well established. However, indoor VOCs, ozone, PAHs and phthalate esters can originate from a variety of sources, and their source apportionment is less straightforward. This literature review identifies substances of toxicological significance, with the purpose of serving as a guide to evaluate their potential importance with respect to human exposures.
Date: February 1, 2007
Creator: Destaillats, Hugo; Maddalena, Randy L.; Singer, Brett C.; Hodgson, Alfred T. & McKone, Thomas E.
Partner: UNT Libraries Government Documents Department

Probabilistic aspects of meteorological and ozone regional ensemble forecasts

Description: This study investigates whether probabilistic ozone forecasts from an ensemble can be made with skill; i.e., high verification resolution and reliability. Twenty-eight ozone forecasts were generated over the Lower Fraser Valley, British Columbia, Canada, for the 5-day period 11-15 August 2004, and compared with 1-hour averaged measurements of ozone concentrations at five stations. The forecasts were obtained by driving the CMAQ model with four meteorological forecasts and seven emission scenarios: a control run, {+-} 50% NO{sub x}, {+-} 50% VOC, and {+-} 50% NO{sub x} combined with VOC. Probabilistic forecast quality is verified using relative operating characteristic curves, Talagrand diagrams, and a new reliability index. Results show that both meteorology and emission perturbations are needed to have a skillful probabilistic forecast system--the meteorology perturbation is important to capture the ozone temporal and spatial distribution, and the emission perturbation is needed to span the range of ozone-concentration magnitudes. Emission perturbations are more important than meteorology perturbations for capturing the likelihood of high ozone concentrations. Perturbations involving NO{sub x} resulted in a more skillful probabilistic forecast for the episode analyzed, and therefore the 50% perturbation values appears to span much of the emission uncertainty for this case. All of the ensembles analyzed show a high ozone concentration bias in the Talagrand diagrams, even when the biases from the unperturbed emissions forecasts are removed from all ensemble members. This result indicates nonlinearity in the ensemble, which arises from both ozone chemistry and its interaction with input from particular meteorological models.
Date: March 20, 2006
Creator: Monache, L D; Hacker, J; Zhou, Y; Deng, X & Stull, R
Partner: UNT Libraries Government Documents Department

COST-EFFECTIVE CONTROL OF NOx WITH INTEGRATED ULTRA LOW-NOx BURNERS AND SNCR

Description: Under sponsorship of the Department of Energy's National Energy Technology Laboratory (NETL), McDermott Technology, Inc. (MTI), the Babcock & Wilcox Company (B&W), and Fuel Tech teamed together to investigate an integrated solution for NOx control. The system was comprised of B&W's DRB-4Z{trademark} low-NO{sub x} pulverized coal (PC) burner technology and Fuel Tech's NO{sub x}OUT{reg_sign}, a urea-based selective non-catalytic reduction (SNCR) technology. The technology's emission target is achieving 0.15 lb NO{sub x}/10{sup 6} Btu for full-scale boilers. Development of the low-NOx burner technology has been a focus in B&W's combustion program. The DRB-4Z{trademark} burner (see Figure 1.1) is B&W's newest low-NO{sub x} burner capable of achieving very low NO{sub x}. The burner is designed to reduce NO{sub x} by diverting air away from the core of the flame, which reduces local stoichiometry during coal devolatilization and, thereby, reduces initial NO{sub x} formation. Figure 1.2 shows the historical NO{sub x} emission levels from different B&W burners. Figure 1.2 shows that based on three large-scale commercial installations of the DRB-4Z{trademark} burners in combination with OFA ports, using Western subbituminous coal, the NO{sub x} emissions ranged from 0.16 to 0.18 lb/10{sup 6} Btu. It appears that with continuing research and development the Ozone Transport Rule (OTR) emission level of 0.15 lb NO{sub x}/10{sup 6} Btu is within the reach of combustion modification techniques for boilers using western U.S. subbituminous coals. Although NO{sub x} emissions from the DRB-4Z{trademark} burner are nearing OTR emission level with subbituminous coals, the utility boiler owners that use bituminous coals can still benefit from the addition of an SNCR and/or SCR system in order to comply with the stringent NO{sub x} emission levels facing them.
Date: July 1, 2003
Creator: Farzan, Hamid; Sivy, Jennifer; Sayre, Alan & Boyle, John
Partner: UNT Libraries Government Documents Department

PHOTOCATALYTIC OXIDATION FOR NOx ABATEMENT: DEVELOPMENT OF A KINETIC EXPRESSION AND DESIGN TOOLS

Description: The ''Nitrogen Oxides Emission Reduction Program'' and ''Ozone Non-Attainment Program'' in the 1990 Clean Air Act provide guidelines for controlling NOx (NO and NO{sub 2}) emissions in new and existing stationary sources. NOx emissions have local (air quality), regional (acid rain), and global (ozone production) consequences. This study aids in developing the photocatalyst technology that has potential for use in abatement of NOx. The objective of the proposed project is to apply the principles of chemical engineering fundamentals--reaction kinetics, transport phenomena and thermodynamics--in the process design for a system that will utilize a photocatalytic reactor to oxidize NOx to nitric acid (HNO{sub 3}). HNO{sub 3} can be more easily trapped than NOx on adsorbent surfaces or in water. The project dealt with the engineering aspect of the gas-solid heterogeneous oxidation of NOx. The experiments were conducted in a photocatalyst wash-coated glass flow tube reactor. A mathematical model was developed based on a rigorous description of the physical and chemical processes occurring in the reactor. The mathematical model took into account (1) intrinsic reaction kinetics (i.e., true reaction rates), (2) transport phenomena that deal with the mass transfer effects in the reactor, and (3) the geometry of the reactor. The experimental results were used for validation of the mathematical model that provides the basis for a versatile and reliable method for the purpose of design, scale-up and process control. The NOx abatement was successfully carried out in a flow tube reactor surrounded by black lights under the exploratory grant. Due to lack of funds, a comprehensive kinetic analysis for the photocatalytic reaction scheme could not be carried out. The initial experiments look very promising for use of photocatalysis for NOx abatement.
Date: September 15, 2000
Creator: Srivastava, Rajiv & Ebadian, M. A.
Partner: UNT Libraries Government Documents Department

Evolution of cool-roof standards in the United States

Description: Roofs that have high solar reflectance and high thermal emittance stay cool in the sun. A roof with lower thermal emittance but exceptionally high solar reflectance can also stay cool in the sun. Substituting a cool roof for a noncool roof decreases cooling-electricity use, cooling-power demand, and cooling-equipment capacity requirements, while slightly increasing heating-energy consumption. Cool roofs can also lower citywide ambient air temperature in summer, slowing ozone formation and increasing human comfort. Provisions for cool roofs in energy-efficiency standards can promote the building- and climate-appropriate use of cool roofing technologies. Cool-roof requirements are designed to reduce building energy use, while energy-neutral cool-roof credits permit the use of less energy-efficient components (e.g., larger windows) in a building that has energy-saving cool roofs. Both types of measures can reduce the life-cycle cost of a building (initial cost plus lifetime energy cost). Since 1999, several widely used building energy-efficiency standards, including ASHRAE 90.1, ASHRAE 90.2, the International Energy Conservation Code, and California's Title 24 have adopted cool-roof credits or requirements. This paper reviews the technical development of cool-roof provisions in the ASHRAE 90.1, ASHRAE 90.2, and California Title 24 standards, and discusses the treatment of cool roofs in other standards and energy-efficiency programs. The techniques used to develop the ASHRAE and Title 24 cool-roof provisions can be used as models to address cool roofs in building energy-efficiency standards worldwide.
Date: July 11, 2008
Creator: Akbari, Hashem; Akbari, Hashem & Levinson, Ronnen
Partner: UNT Libraries Government Documents Department

Exposure information in environmental health research: Current opportunities and future directions for particulate matter, ozone, and toxic air pollutants

Description: Understanding and quantifying outdoor and indoor sources of human exposure are essential but often not adequately addressed in health-effects studies for air pollution. Air pollution epidemiology, risk assessment, health tracking and accountability assessments are examples of health-effects studies that require but often lack adequate exposure information. Recent advances in exposure modeling along with better information on time-activity and exposure factors data provide us with unique opportunities to improve the assignment of exposures for both future and ongoing studies linking air pollution to health impacts. In September 2006, scientists from the US Environmental Protection Agency (EPA) and the Centers for Disease Control and Prevention (CDC) along with scientists from the academic community and state health departments convened a symposium on air pollution exposure and health in order to identify, evaluate, and improve current approaches for linking air pollution exposures to disease. This manuscript presents the key issues, challenges and recommendations identified by the exposure working group, who used cases studies of particulate matter, ozone, and toxic air pollutant exposure to evaluate health-effects for air pollution. One of the over-arching lessons of this workshop is that obtaining better exposure information for these different health-effects studies requires both goal-setting for what is needed and mapping out the transition pathway from current capabilities to meeting these goals. Meeting our long-term goals requires definition of incremental steps that provide useful information for the interim and move us toward our long-term goals. Another over-arching theme among the three different pollutants and the different health study approaches is the need for integration among alternate exposure assessment approaches. For example, different groups may advocate exposure indicators, biomonitoring, mapping methods (GIS), modeling, environmental media monitoring, and/or personal exposure modeling. However, emerging research reveals that the greatest progress comes from integration among two or more of these efforts.
Date: February 1, 2007
Creator: McKone, Thomas E.; Ryan, P. Barry & Ozkaynak, Haluk
Partner: UNT Libraries Government Documents Department

Exposure-Relevant Ozone Chemistry in Occupied Spaces

Description: Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure in the cabin and compare to other environments. Byproduct levels are predicted to be similar to ozone levels in the cabin, which have been found to be tens to low hundreds of ppb in the absence of an ozone converter. In Chapter 4, a model is presented that predicts ozone uptake by and byproduct emission from residual chemicals on surfaces. The effects of input parameters (residue surface concentration, ozone concentration, reactivity of the residue and the surface, near-surface airflow conditions, and byproduct yield) were explored. In Chapter 5, the reaction of ozone with permethrin, a residual insecticide used in aircraft ...
Date: April 1, 2009
Creator: Coleman, Beverly Kaye
Partner: UNT Libraries Government Documents Department

Couplings between changes in the climate system and biogeochemistry

Description: The Earth's climate is determined by a number of complex connected physical, chemical and biological processes occurring in the atmosphere, land and ocean. The radiative properties of the atmosphere, a major controlling factor of the Earth's climate, are strongly affected by the biophysical state of the Earth's surface and by the atmospheric abundance of a variety of trace constituents. These constituents include long-lived greenhouse gases (LLGHGs) such as carbon dioxide (CO{sub 2}), methane (CH{sub 4}) and nitrous oxide (N{sub 2}O), as well as other radiatively active constituents such as ozone and different types of aerosol particles. The composition of the atmosphere is determined by processes such as natural and anthropogenic emissions of gases and aerosols, transport at a variety of scales, chemical and microphysical transformations, wet scavenging and surface uptake by the land and terrestrial ecosystems, and by the ocean and its ecosystems. These processes and, more generally the rates of biogeochemical cycling, are affected by climate change, and involve interactions between and within the different components of the Earth system. These interactions are generally nonlinear and may produce negative or positive feedbacks to the climate system. An important aspect of climate research is to identify potential feedbacks and assess if such feedbacks could produce large and undesired responses to perturbations resulting from human activities. Studies of past climate evolution on different time scales can elucidate mechanisms that could trigger nonlinear responses to external forcing. The purpose of this chapter is to identify the major biogeochemical feedbacks of significance to the climate system, and to assess current knowledge of their magnitudes and trends. Specifically, this chapter will examine the relationships between the physical climate system and the land surface, the carbon cycle, chemically reactive atmospheric gases and aerosol particles. It also presents the current state of knowledge on budgets of ...
Date: October 1, 2007
Creator: Menon, Surabi; Denman, Kenneth L.; Brasseur , Guy; Chidthaisong, Amnat; Ciais, Philippe; Cox, Peter M. et al.
Partner: UNT Libraries Government Documents Department

Efficiency of clay-TiO2 nanocomposites on the photocatalytic eliminationof a model hydrophobic air pollutant

Description: Clay-supported TiO2 photocatalysts can potentially improve the performance of air treatment technologies via enhanced adsorption and reactivity of target volatile organic compounds (VOCs). In this study, a bench-top photocatalytic flow reactor was used to evaluate the efficiency of hectorite-TiO2 and kaolinite-TiO2, two novel composite materials synthesized in our laboratory. Toluene, a model hydrophobic VOC and a common indoor air pollutant, was introduced in the air stream at realistic concentrations, and reacted under UVA (gamma max = 365 nm) or UVC (gamma max = 254 nm) irradiation. The UVC lamp generated secondary emission at 185 nm, leading to the formation of ozone and other short-lived reactive species. Performance of clay-TiO2 composites was compared with that of pure TiO2 (Degussa P25), and with UV irradiation in the absence of photocatalyst under identical conditions. Films of clay-TiO2 composites and of P25 were prepared by a dip-coating method on the surface of Raschig rings, which were placed inside the flow reactor. An upstream toluene concentration of ~;;170 ppbv was generated by diluting a constant flow of toluene vapor from a diffusion source with dry air, or with humid air at 10, 33 and 66percent relative humidity (RH). Toluene concentrations were determined by collecting Tenax-TA (R) sorbent tubes downstream of the reactor, with subsequent thermal desorption -- GC/MS analysis. The fraction of toluene removed, percentR, and the reaction rate, Tr, were calculated for each experimental condition from the concentration changes measured with and without UV irradiation. Use of UVC light (UV/TiO2/O3) led to overall higher reactivity, which can be partially attributed to the contribution of gas phase reactions by short-lived radical species. When the reaction rate was normalized to the light irradiance, Tr/I gamma, the UV/TiO2 reaction under UVA irradiation was more efficient for samples with a higher content of TiO2 (P25 and Hecto-TiO2), but ...
Date: January 1, 2009
Creator: Kibanova, Daria; Cervini-Silva, Javiera & Destaillats, Hugo
Partner: UNT Libraries Government Documents Department

Climate response to projected changes in short-lived species under an A1B scenario from 2000-2050 in the GISS climate model

Description: We investigate the climate forcing from and response to projected changes in short-lived species and methane under the A1B scenario from 2000-2050 in the GISS climate model. We present a meta-analysis of new simulations of the full evolution of gas and aerosol species and other existing experiments with variations of the same model. The comparison highlights the importance of several physical processes in determining radiative forcing, especially the effect of climate change on stratosphere-troposphere exchange, heterogeneous sulfate-nitrate-dust chemistry, and changes in methane oxidation and natural emissions. However, the impact of these fairly uncertain physical effects is substantially less than the difference between alternative emission scenarios for all short-lived species. The net global mean annual average direct radiative forcing from the short-lived species is .02 W/m{sup 2} or less in our projections, as substantial positive ozone forcing is largely offset by negative aerosol direct forcing. Since aerosol reductions also lead to a reduced indirect effect, the global mean surface temperature warms by {approx}0.07 C by 2030 and {approx}0.13 C by 2050, adding 19% and 17%, respectively, to the warming induced by long-lived greenhouse gases. Regional direct forcings are large, up to 3.8 W/m{sup 2}. The ensemble-mean climate response shows little regional correlation with the spatial pattern of the forcing, however, suggesting that oceanic and atmospheric mixing generally overwhelms the effect of even large localized forcings. Exceptions are the polar regions, where ozone and aerosols may induce substantial seasonal climate changes.
Date: March 26, 2007
Creator: Menon, Surabi; Shindell, Drew T.; Faluvegi, Greg; Bauer, Susanne E.; Koch, Dorothy M.; Unger, Nadine et al.
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Indoor Pollutants Emitted by Electronic Office Equipment

Description: The last few decades have seen major changes in how people collect and process information at work and in their homes. More people are spending significant amounts of time in close proximity to computers, video display units, printers, fax machines and photocopiers. At the same time, efforts to improve energy efficiency in buildings by reducing leaks in building envelopes are resulting in tighter (i.e., less ventilated) indoor environments. Therefore, it is critical to understand pollutant emission rates for office equipment because even low emissions in areas that are under-ventilated or where individuals are in close proximity to the pollutant source can result in important indoor exposures. We reviewed existing literature reports on pollutant emission by office equipment, and measured emission factors of equipment with significant market share in California. We determined emission factors for a range of chemical classes including volatile and semivolatile organic compounds (VOCs and SVOCs), ozone and particulates. The measured SVOCs include phthalate esters, brominated and organophosphate flame retardants and polycyclic aromatic hydrocarbons. Measurements were carried out in large and small exposure chambers for several different categories of office equipment. Screening experiments using specific duty cycles in a large test chamber ({approx}20 m{sup 3}) allowed for the assessment of emissions for a range of pollutants. Results from the screening experiments identified pollutants and conditions that were relevant for each category of office equipment. In the second phase of the study, we used a smaller test chamber ({approx}1 m{sup 3}) to measure pollutant specific emission factors for individual devices and explored the influence of a range of environmental and operational factors on emission rates. The measured emission factors provide a data set for estimating indoor pollutant concentrations and for exploring the importance of user proximity when estimating exposure concentrations.
Date: July 1, 2008
Creator: Maddalena, Randy L.; Destaillats, Hugo; Russell, Marion L.; Hodgson, Alfred T. & McKone, Thomas E.
Partner: UNT Libraries Government Documents Department