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1/6TH SCALE STRIP EFFLUENT FEED TANK-MIXING RESULTS USING MCU SOLVENT

Description: The purpose of this task was to determine if mixing was an issue for the entrainment and dispersion of the Modular Caustic Side Solvent Extraction (CSSX) Unit (MCU) solvent in the Defense Waste Processing Facility (DWPF) Strip Effluent Feed Tank (SEFT). The MCU strip effluent stream containing the Cs removed during salt processing will be transferred to the DWPF for immobilization in HLW glass. In lab-scale DWPF chemical process cell testing, mixing of the solvent in the dilute nitric acid solution proved problematic, and the Savannah River National Laboratory (SRNL) was requested to perform scaled SEFT mixing tests to evaluate whether the problem was symptomatic of the lab-scale set-up or of the solvent. The solvent levels tested were 228 and 235 ppm, which represented levels near the estimated DWPF solvent limit of 239 ppm in 0.001M HNO{sub 3} solution. The 239 ppm limit was calculated by Norato in X-CLC-S-00141. The general approach for the mixing investigation was to: (1) Investigate the use of fluorescent dyes to aid in observing the mixing behavior. Evaluate and compare the physical properties of the fluorescent dyed MCU solvents to the baseline Oak Ridge CSSX solvent. Based on the data, use the dyed MCU solvent that best approximates the physical properties. (2) Use approximately a 1/6th linear scale of the SEFT to replicate the internal configuration for DWPF mixing. (3) Determine agitator speed(s) for scaled testing based on the DWPF SEFT mixing speed. (4) Perform mixing tests using the 1/6th SEFT and determine any mixing issues (entrainment/dispersion, accumulation, adhesion) through visual observations and by pulling samples to assess uniformity. The mixing tests used MCU solvent fabricated at SRNL blended with Risk Reactor DFSB-K43 fluorescent dye. This dyed SRNL MCU solvent had equivalent physical properties important to mixing as compared to the Oak Ridge baseline solvent, ...
Date: February 1, 2006
Creator: Hansen, E.
Partner: UNT Libraries Government Documents Department

FLAME-SAMPLING PHOTOIONIZATION MASS SPECTROSCOPY - FINAL TECHNICAL REPORT

Description: Research focused on detailed studies of the complex combustion chemistry of oxygenated, bio-derived fuels. In particular, studies were done of the flame chemistry of simple methyl and ethyl esters chosen as surrogates for the long-chain esters that are primary constituents of biodiesel fuels. The principal goals of these studies were: (1) show how fuel-specific structural differences including degree of unsaturation, linear vs. branched chain structures, and methoxy vs. ethoxy functions affect fueldestruction pathways, (2) understand the chemistry leading to potential increases in the emissions of hazardous air pollutants including aldehydes and ketones inherent in the use of biodiesel fuels, and (3) define the key chemical reaction mechanisms responsible for observed reductions in polycyclic aromatic hydrocarbons and particulate matter when oxygenated fuels are used as replacements for conventional fuels.
Date: February 12, 2013
Creator: Hansen, Nils
Partner: UNT Libraries Government Documents Department

Combined plate motion and density driven flow in the asthenosphere beneath Saudi Arabia: Evidence from shear-wave splitting and seismic anisotropy

Description: A comprehensive study of mantle anisotropy along the Red Sea and across Saudi Arabia was performed by analyzing shear-wave splitting recorded by stations from three different seismic networks: the largest, most widely distributed array of stations examined across Saudi Arabia to date. Stations near the Gulf of Aqaba display fast orientations that are aligned parallel to the Dead Sea Transform Fault, most likely related to the strike-slip motion between Africa and Arabia. However, most of our observations across Saudi Arabia are statistically the same, showing a consistent pattern of north-south oriented fast directions with delay times averaging about 1.4 s. Fossilized anisotropy related to the Proterozoic assembly of the Arabian Shield may contribute to the pattern but is not sufficient to fully explain the observations. We feel that the uniform anisotropic signature across Saudi Arabia is best explained by a combination of plate and density driven flow in the asthenosphere. By combining the northeast oriented flow associated with absolute plate motion with the northwest oriented flow associated with the channelized Afar plume along the Red Sea, we obtain a north-south oriented resultant that matches our splitting observations and supports models of active rifting processes. This explains why the north-south orientation of the fast polarization direction is so pervasive across the vast Arabian Plate.
Date: February 8, 2006
Creator: Hansen, S & Schwartz, S
Partner: UNT Libraries Government Documents Department

U.S. Department of Energy photovoltaic energy program contract summary, fiscal year 1999

Description: This report summarizes the in-house and subcontracted research and development (R and D) activities under the National Center for Photovoltaics (NCPV) and US Department of Energy (DOE) National Photovoltaics Program from October 1, 1998, through September 30, 1999 (FY 1999). The mission of the DOE National Photovoltaics Program is to make PV a significant part of the domestic economy as an industry and an energy resource. The two primary goals of the national program are to (1) maintain the US industry's world leadership in research and technology development and (2) help the US industry remain a major, profitable force in the world market. The NCPV is part of the National PV Program and provides leadership and support to the national program toward achieving its mission and goals.
Date: February 17, 2000
Creator: Surek, T. & Hansen, A.
Partner: UNT Libraries Government Documents Department

Laboratory Directed Research and Development Program FY98

Description: The Ernest Orlando Lawrence Berkeley National Laboratory (LBNL or Berkeley Lab) Laboratory Directed Research and Development Program FY 1998 report is compiled from annual reports submitted by principal investigators following the close of the fiscal year. This report describes the supported projects and summarizes their accomplishments. It constitutes a part of the Laboratory Directed Research and Development (LDRD) program planning and documentation process that includes an annual planning cycle, projection selection, implementation, and review. The LBNL LDRD program is a critical tool for directing the Laboratory's forefront scientific research capabilities toward vital, excellent, and emerging scientific challenges. The program provides the resources for LBNL scientists to make rapid and significant contributions to critical national science and technology problems. The LDRD program also advances LBNL's core competencies, foundations, and scientific capability, and permits exploration of exciting new opportunities. All projects are work in forefront areas of science and technology. Areas eligible for support include the following: Advanced study of hypotheses, concepts, or innovative approaches to scientific or technical problems; Experiments and analyses directed toward ''proof of principle'' or early determination of the utility of new scientific ideas, technical concepts, or devices; and Conception and preliminary technical analyses of experimental facilities or devices.
Date: February 5, 1999
Creator: Hansen, T. & Chartock, M.
Partner: UNT Libraries Government Documents Department

AN ASSESSMENT OF FLYWHEEL HIGH POWER ENERGY STORAGE TECHNOLOGY FOR HYBRID VEHICLES

Description: An assessment has been conducted for the DOE Vehicle Technologies Program to determine the state of the art of advanced flywheel high power energy storage systems to meet hybrid vehicle needs for high power energy storage and energy/power management. Flywheel systems can be implemented with either an electrical or a mechanical powertrain. The assessment elaborates upon flywheel rotor design issues of stress, materials and aspect ratio. Twelve organizations that produce flywheel systems submitted specifications for flywheel energy storage systems to meet minimum energy and power requirements for both light-duty and heavy-duty hybrid applications of interest to DOE. The most extensive experience operating flywheel high power energy storage systems in heavy-duty and light-duty hybrid vehicles is in Europe. Recent advances in Europe in a number of vehicle racing venues and also in road car advanced evaluations are discussed. As a frame of reference, nominal weight and specific power for non-energy storage components of Toyota hybrid electric vehicles are summarized. The most effective utilization of flywheels is in providing high power while providing just enough energy storage to accomplish the power assist mission effectively. Flywheels are shown to meet or exceed the USABC power related goals (discharge power, regenerative power, specific power, power density, weight and volume) for HEV and EV batteries and ultracapacitors. The greatest technical challenge facing the developer of vehicular flywheel systems remains the issue of safety and containment. Flywheel safety issues must be addressed during the design and testing phases to ensure that production flywheel systems can be operated with adequately low risk.
Date: February 1, 2012
Creator: Hansen, James Gerald
Partner: UNT Libraries Government Documents Department

Laboratory Directed Research and Development FY 2000

Description: The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab or LBNL) is a multi-program national research facility operated by the University of California for the Department of Energy (DOE). As an integral element of DOE's National Laboratory System, Berkeley Lab supports DOE's missions in fundamental science, energy resources, and environmental quality. Berkeley Lab programs advance four distinct goals for DOE and the nation: (1) To perform leading multidisciplinary research in the computing sciences, physical sciences, energy sciences, biosciences, and general sciences in a manner that ensures employee and public safety and protection of the environment. (2) To develop and operate unique national experimental facilities for qualified investigators. (3) To educate and train future generations of scientists and engineers to promote national science and education goals. (4) To transfer knowledge and technological innovations and to foster productive relationships among Berkeley Lab's research programs, universities, and industry in order to promote national economic competitiveness. Annual report on Laboratory Directed Research and Development for FY2000.
Date: February 27, 2001
Creator: Hansen, Todd & Levy, Karin
Partner: UNT Libraries Government Documents Department

Laboratory Directed Research and Development Program FY 2008 Annual Report

Description: The Ernest Orlando Lawrence Berkeley National Laboratory (Berkeley Lab or LBNL) is a multi-program national research facility operated by the University of California for the Department of Energy (DOE). As an integral element of DOE's National Laboratory System, Berkeley Lab supports DOE's missions in fundamental science, energy resources, and environmental quality. Berkeley Lab programs advance four distinct goals for DOE and the nation: (1) To perform leading multidisciplinary research in the computing sciences, physical sciences, energy sciences, biosciences, and general sciences in a manner that ensures employee and public safety and protection of the environment. (2) To develop and operate unique national experimental facilities for qualified investigators. (3) To educate and train future generations of scientists and engineers to promote national science and education goals. (4) To transfer knowledge and technological innovations and to foster productive relationships among Berkeley Lab's research programs, universities, and industry in order to promote national economic competitiveness. Berkeley Lab's research and the Laboratory Directed Research and Development (LDRD) program support DOE's Strategic Themes that are codified in DOE's 2006 Strategic Plan (DOE/CF-0010), with a primary focus on Scientific Discovery and Innovation. For that strategic theme, the Fiscal Year (FY) 2008 LDRD projects support each one of the three goals through multiple strategies described in the plan. In addition, LDRD efforts support the four goals of Energy Security, the two goals of Environmental Responsibility, and Nuclear Security (unclassified fundamental research that supports stockpile safety and nonproliferation programs). The LDRD program supports Office of Science strategic plans, including the 20-year Scientific Facilities Plan and the Office of Science Strategic Plan. The research also supports the strategic directions periodically under consideration and review by the Office of Science Program Offices, such as LDRD projects germane to new research facility concepts and new fundamental science directions. Berkeley Lab LDRD ...
Date: February 23, 2009
Creator: editor, Todd C Hansen
Partner: UNT Libraries Government Documents Department

Friction model of the 2.5mts SDSS telescope

Description: The 2.5mts telescope designed for the Sloan Digital Sky Survey (SDSS) is a mechanical structure that presents five degree-of-freedom. Azimuth, altitude and the instrument rotator axis are fitted with servo controls. The low frequency dynamic are dominated by the bearing friction. Several mathematical models have been presented in the literature to include its effect into the dynamic model of mechanical structures. The model employed in this paper includes consideration of the Striebeck effect, dynamic behavior at very low velocities and the pre-sliding at near zero-velocity. Results of the parameter estimation of the friction model of the three principal axes are presented as well as the behavior of the structure when different torque stimuli are applied. The mathematical model used to include the friction phenomena into the telescope dynamic model is simple. It does a good job of describing the friction over a wide range of velocities but particularly at or below siderial rate. It is a straight forward process to determine the parameters and, in simulations, does not require large amounts of computer time. 10 refs. , 8 figs.
Date: February 1, 1998
Creator: Rivetta, Claudio H. & Hansen, Sten
Partner: UNT Libraries Government Documents Department

An evaluation of new high resolution image collection and processing techniques for estimating shrub cover and detecting landscape changes associated with military training in arid lands

Description: Research funded by the US Department of Defense, US Department of Energy, and the US Environmental Protection Agency as part of Project CS-1131 of the Strategic Environmental Research and Development Program evaluated novel techniques for collecting high-resolution images in the Mojave Desert using helicopters, helium-filled blimps, kites, and hand-held telescoping poles at heights from 1 to 150 meters. Several camera types, lens, films, and digital techniques were evaluated on the basis of their ability to correctly estimate canopy cover of shrubs. A high degree of accuracy was obtained with photo scales of 1:4,000 or larger and flatbed scanning rates from films or prints of 300 lines per inch or larger. Smaller scale images were of value in detecting retrospective changes in cover of large shrubs, but failed to detect smaller shrubs. Excellent results were obtained using inexpensive 35-millimeter cameras and new super-fine grain film such as Kodak's Royal Gold{trademark} (ASA 100) film or megapixel digital cameras. New image-processing software, such as SigmaScan Pro{trademark}, makes it possible to accurately measure areas up to 1 hectare in size for total cover and density in 10 minutes compared to several hours or days of field work. In photographs with scales of 1:1,000 and 1:2,000, it was possible to detect cover and density of up to four dominant shrub species. Canopy cover and other parameters such as width, length, feet diameter, and shape factors can be nearly instantaneously measured for each individual shrub yielding size distribution histograms and other statistical data on plant community structure. Use of the technique is being evaluated in a four-year study of military training impacts at Fort Irwin, California, and results compared with image processing using conventional aerial photography and satellite imagery, including the new 1-meter pixel IKONOS images. The technique is a valuable new emerging tool to accurately ...
Date: February 1, 2000
Creator: Hansen, D.J. & Ostler, W.K.
Partner: UNT Libraries Government Documents Department

Long term decontamination at the Hanford Site: A case study

Description: This paper describes an engineering study that evaluates decontamination requirements at Hanford and the potential reutilization of the first plutonium processing production facility as a decontamination facility. The logic used to develop the study, the options available for a long-term decontamination mission, and the resultant strategy recommended in the study are presented. The paper provides a starting point for other similar study efforts. The process flowsheets, regulatory restrictions, and preconceptual designs developed in this study are common throughout the nuclear waste industry.
Date: February 1, 1995
Creator: Geuther, W.J. & Hansen, G.E.
Partner: UNT Libraries Government Documents Department

An Automatic Lithium Drifting Apparatus for Silicon and Germanium Detectors

Description: Drifting a thick lithium-drifted counter (silicon and germanium) is a time-consuming operation that frequently results in a poor device, owing to inadequate knowledge of progress of the drifting operation. The drifting apparatus described here automatically controls the temperature of the detector that is being drifted to maintain the leakage current at a preselected value. While drifting proceeds, a continuous measurement is made of the distance of the lithium-drifted region from the opposite face of the wafer. When the drifted region reaches 30 mil or less from the back of the wafer a meter indicates the thickness of the undrifted region and, when this thickness falls below a preselected value, the temperature of the detector is automatically reduced to room temperature. The need for constant supervision of the drifting operation is thereby eliminated, and reliance on theoretical drift-rate calculations to predict the drift-through time is avoided. The technique has been applied to the manufacture of lithium-drifted silicon detectors with excellent results. The application of the technique to lithium-drifted germanium {gamma} detectors is also discussed briefly.
Date: February 8, 1964
Creator: Goulding, Fred S. & Hansen, W. L.
Partner: UNT Libraries Government Documents Department

Monazite Placers on Rabon Creek, Laurens County, and Big Generostee Creek, Anderson County, South Carolina

Description: Introduction: Rabon Creek in Laurens County, South Carolina and Big Generostee Creek in Anderson County, have large established flood plains. Preliminary investigations by the U.S. Geological Survey showed the presence of monazite in these streams, and the areas were recommended for detailed investigation.
Date: February 1955
Creator: Hansen, Leland A. & Caldwell, Dabney W.
Partner: UNT Libraries Government Documents Department

Rigel: An interactive structured grid generation system

Description: An interactive structured grid generation application that facilitates the construction of complex, discretized, simulation models directly from the original CAD geometry specifications is presented. The application, named Rigel, reads physical model descriptions generated by modern CAD packages. Rigel includes a suite of interactive geometry editing functions to assist the user in the construction of a topologically correct geometry from the original CAD specification. Once a topologically correct geometry is created, an interactively steered grid generation capability is provided to facilitate the construction of an appropriate discretization for the simulation. Grid quality enhancement is supported with the application of user-directed elliptic smoothing, refinement, and coarsening operators. After a grid is completed, various output filters are supplied to write an input file for the target simulation code. This paper is intended to provide an overview of the mechanics of this process and to highlight some of the novel algorithms and techniques employed.
Date: February 1, 1998
Creator: Hachfeld, W.D.; Khamayseh, A.K. & Hansen, G.A.
Partner: UNT Libraries Government Documents Department

Cygnus Diverter Switch Analysis

Description: The Cygnus Dual Beam Radiographic Facility consists of two 2.25-MV, 60-kA, 50-ns x-ray sources fielded in an underground laboratory at the Nevada Test Site. The tests performed in this laboratory involve study of the dynamic properties of plutonium and are called subcritical experiments. From end-to-end, the Cygnus machines utilize the following components: Marx generator, water-filled pulse-forming line (PFL), waterfilled coaxial transmission line (WTL), 3-cell inductive voltage adder (IVA), and rod-pinch diode. The upstream WTL interface to the PFL is via a radial insulator with coaxial geometry. The downstream WTL terminates in a manifold where the center conductor splits into three lines which individually connect to each of the IVA cell inputs. There is an impedance mismatch at this juncture. It is a concern that a reflected pulse due to anomalous behavior in the IVA or diode might initiate breakdown upon arrival at the upstream PFL/WTL insulator. Therefore near the beginning of the WTL a radial diverter switch is installed to protect the insulator from over voltage and breakdown. The diverter has adjustable gap spacing, and an in-line aqueous-solution (sodium thiosulfate) resistor array for energy dissipation. There are capacitive voltage probes at both ends of the WTL and on the diverter switch. These voltage signals will be analyzed to determine diverter performance. Using this analysis the usefulness of the diverter switch will be evaluated.
Date: February 1, 2008
Creator: G. Corrow, M. Hansen, D. Henderson, C. Mitton et al.
Partner: UNT Libraries Government Documents Department

Cygnus Trigger System

Description: The Cygnus Dual Beam Radiographic Facility consists of two radiographic sources (Cygnus 1, Cygnus 2) each with a dose rating of 4 rads at 1 m, and a 1-mm diameter spot size. The electrical specifications are: 2.25 MV, 60 kA, 60 ns. This facility is located in an underground environment at the Nevada Test Site (NTS). These sources were developed as a primary diagnostic for subcritical tests, which are single-shot, high-value events. In such an application there is an emphasis on reliability and reproducibility. A robust, low-jitter trigger system is a key element for meeting these goals. The trigger system was developed with both commercial and project-specific equipment. In addition to the traditional functions of a trigger system there are novel features added to protect the investment of a high-value shot. Details of the trigger system, including elements designed specifically for a subcritical test application, will be presented. The individual electronic components have their nominal throughput, and when assembled have a system throughput with a measured range of jitter. The shot-to-shot jitter will be assessed both individually and in combination. Trigger reliability and reproducibility results will be presented for a substantial number of shots executed at the NTS.
Date: February 1, 2008
Creator: G. Corrow, M. Hansen, D. Henderson, C. Mitton
Partner: UNT Libraries Government Documents Department

GOING UNDERGROUND IN FINLAND: DESIGN OF ONKALO IN PROGRESS

Description: The long-term program aimed at selection of a site for a deep repository was initiated in Finland in 1983. This program has come to end in 2001 and a new phase aimed at implementation of the geological disposal of spent fuel has been started. In this new phase the first milestone is the application for a construction license for the disposal facility around 2010. To fulfill the needs for detailed design of the disposal system, an underground rock characterization facility (URCF) will be constructed at the representative depth at Olkiluoto. The excavation of this facility will start the work for underground characterization, testing and demonstration, which is planned to be a continuous activity throughout the whole life cycle of the deep repository. The overall objectives for the underground site characterization are (1) verification of the present conclusions on site suitability, (2) definition and identification of suitable rock volumes for repository space and (3) characterization of planned host rock for detailed design, safety assessment and construction planning. The objective for verification aims at assessing that the Olkiluoto site meets the basic criteria for long-term safety and as well the basic requirements for construction and thus justifies the site selection. The two other main objectives are closely related to design of the repository and assessing the long-term safety of the site-specific disposal system. The most important objective of ONKALO should allow an in-depth investigation of the geological environment and to provide the opportunity to allow validation of models at more appropriate scales and conditions than can be achieved from the surface. In some areas, such as in demonstrating operational safety, in acquiring geological information at a repository scale and in constructional and operational feasibility, the ONKALO will provide the only reliable source of in situ data. The depth range envisaged for URCF ...
Date: February 27, 2003
Creator: Dikds, T.; Ikonen, A.; Niiranen, S. & Hansen, J.
Partner: UNT Libraries Government Documents Department

Commercial Decommissioning at DOE's Rocky Flats

Description: Due in large part to the number of nuclear facilities that make up the DOE complex, DOE-EM work has historically been paperwork intensive and driven by extensive regulations. Requirements for non-nuclear facilities are often grouped with those of nuclear facilities, driving up costs. Kaiser-Hill was interested in applying a commercial model to demolition of these facilities and wanted to apply necessary and sufficient standards to the work activities, but avoid applying unnecessary requirements. Faced with demolishing hundreds of uncontaminated or non-radiologically contaminated facilities, Kaiser-Hill has developed a subcontracting strategy to drastically reduce the cost of demolishing these facilities at Rocky Flats. Aiming to tailor the demolition approach of such facilities to more closely follow commercial practices, Kaiser-Hill recently released a Request for Proposals (RFP) for the demolition of the site's former central administration facility. The RFP significantly reduced requirements for compliance with specific DOE directives. Instead, the RFP required subcontractors to comply with health and safety requirements commonly found in the demolition of similar facilities in a commercial setting. This resulted in a number of bids from companies who have normally not bid on DOE work previously and at a reduced cost over previous approaches. This paper will discuss the details of this subcontracting strategy.
Date: February 25, 2002
Creator: Freiboth, C.; Sandlin, N.; Schubert, A. & Hansen, S.
Partner: UNT Libraries Government Documents Department

Constitutive behavior of reconsolidating crushed salt

Description: The constitutive model used to describe deformation of crushed salt is presented in this paper. Two mechanisms--dislocation creep and grain boundary diffusional pressure solutioning--are combined to form the basis for the constitutive model governing deformation of crushed salt. The constitutive model is generalized to represent three-dimensional states of stress. Recently completed creep consolidation tests are combined with an existing database that includes hydrostatic consolidation and shear consolidation tests conducted on Waste Isolation Pilot Plant (WIPP) and southeastern New Mexico salt to determine material parameters for the constitutive model. Nonlinear least-squares model fitting to data from shear consolidation tests and a combination of shear and hydrostatic tests produces two sets of material parameter values for the model. Changes in material parameter values from test group to test group indicate the empirical nature of the model but show significant improvement over earlier work. To demonstrate the predictive capability of the model, each parameter value set was used to predict each of the tests in the database. Based on fitting statistics and ability of the model to predict test data, the model appears to capture the creep consolidation behavior of crushed salt quite well.
Date: February 1998
Creator: Callahan, G. D.; Mellegard, K. D. & Hansen, F. D.
Partner: UNT Libraries Government Documents Department

DEVELOPMENT OF A FABRICATION PROCESS FOR SOL-GEL/METAL HYDRIDE COMPOSITE GRANULES

Description: An external gelation process was developed to produce spherical granules that contain metal hydride particles in a sol-gel matrix. Dimensionally stable granules containing metal hydrides are needed for applications such as hydrogen separation and hydrogen purification that require columns containing metal hydrides. Gases must readily flow through the metal hydride beds in the columns. Metal hydrides reversibly absorb and desorb hydrogen and hydrogen isotopes. This is accompanied by significant volume changes that cause the metal hydride to break apart or decrepitate. Repeated cycling results in very fine metal hydride particles that are difficult to handle and contain. Fine particles tend to settle and pack making it more difficult to flow gases through a metal hydride bed. Furthermore, the metal hydrides can exert a significant force on the containment vessel as they expand. These problems associated with metal hydrides can be eliminated with the granulation process described in this report. Small agglomerates of metal hydride particles and abietic acid (a pore former) were produced and dispersed in a colloidal silica/water suspension to form the feed slurry. Fumed silica was added to increase the viscosity of the feed slurry which helped to keep the agglomerates in suspension. Drops of the feed slurry were injected into a 27-foot tall column of hot ({approx}70 C), medium viscosity ({approx}3000 centistokes) silicone oil. Water was slowly evaporated from the drops as they settled. The drops gelled and eventually solidified to form spherical granules. This process is referred to as external gelation. Testing was completed to optimize the design of the column, the feed system, the feed slurry composition, and the operating parameters of the column. The critical process parameters can be controlled resulting in a reproducible fabrication technique. The residual silicone oil on the surface of the granules was removed by washing in mineral spirits. The ...
Date: February 23, 2004
Creator: Hansen, E; Eric Frickey, E & Leung Heung, L
Partner: UNT Libraries Government Documents Department

IMPACT OF ALUMINATE IONS ON THE PROPERTIES OF SALTSTONE GROUT MIXES

Description: It is important to identify and control the operational and compositional variables that impact the important processing and performance properties of Saltstone grout mixes. The grout that is produced at the Saltstone Production Facility (SPF) is referred to as Saltstone and is a waste form that immobilizes low concentrations of radionuclides as well as certain toxic metals. The Saltstone will be disposed of in vaults at Savannah River Site (SRS). An effort referred to as the Saltstone Variability Study has been initiated to achieve this goal. The protocols developed in this variability study are also ideally suited as a tool to assess the impact of proposed changes to the processing flow sheet for Liquid Waste Operations at SRS. One such proposal that is currently under consideration is to introduce a leaching step in the treatment of the High Level Waste (HLW) sludge to remove aluminum prior to vitrification at the Defense Waste Processing Facility (DWPF). This leachate would significantly increase the soluble aluminate concentration in the salt feed that will be processed at the SPF. Consequently, an initial study of the impact of increased aluminate concentration on the Saltstone grout properties was performed. Prior work by Lukens (1) showed that aluminate in the salt solutions increases the amount of heat generation.
Date: February 21, 2008
Creator: Harbour, J; Tommy Edwards, T; Erich Hansen, E & Vickie Williams, V
Partner: UNT Libraries Government Documents Department

Laboratory Characterization of Mechanical and Permeability Properties of Dynamically Compacted Crushed Salt

Description: The U. S. Department of Energy plans to dispose of transuranic wastes at the Waste Isolation Pilot Plant (WIPP), a geologic repository located at a depth of about 655 meters. The WIPP underground facility is located in the bedded salt of the Salado Formation. Access to the facility is provided through vertical shafts, which will be sealed after decommissioning to limit the release of hazardous waste from the repository and to limit flow into the facility. Because limited data are available to characterize the properties of dynamically compacted crushed salt, Sandia National Laboratories authorized RE/SPEC to perform additional tests on specimens of dynamically compacted crushed salt. These included shear consolidation creep, permeability, and constant strain-rate triaxial compression tests. A limited number of samples obtained from the large compacted mass were available for use in the testing program. Thus, additional tests were performed on samples that were prepared on a smaller scale device in the RE/SPEC laboratory using a dynamic-compaction procedure based on the full-scale construction technique. The laboratory results were expected to (1) illuminate the phenomenology of crushed-salt deformation behavior and (2) add test results to a small preexisting database for purposes of estimating parameters in a crushed-salt constitutive model. The candidate constitutive model for dynamically compacted crushed salt was refined in parallel with this laboratory testing.
Date: February 1, 1999
Creator: Hansen, F.D.; Mellegard, K.D. & Pfeifle, T.W.
Partner: UNT Libraries Government Documents Department

General safety basis development guidance for environmental restoration decontamination and decommissioning

Description: Safety analyses have the objective of contributing to two essential ingredients of a successful operation. The first is promoting the safety of the operation through worker involvement in information development (safety basis). The second is obtaining approval to conduct the operation (authorization). Typically these ingredients are assembled under separate programs covered by separate DOE requirements. DOE authorization relies on successful development of a document containing up to 21 topics written in terms and language suited to reviewers and approvers. Safety relies on successful training and procedures that convert the technical documented information into terms and language understandable to the worker. This separation can lead to successful incorporation of one ingredient independent of the other. At best, this separation may result in a safe but unauthorized operation; at worst, the separation may result in an unsafe operation authorized to proceed. This guide is based on experiences gained by contractors who have integrated rather than separated the safety and authorization. The short duration of ER/D&D activities, the uncertainties of hazards, and the publicly expressed desire for demonstrable progress in cleanup activities add emphasis to the need to integrate rather than separate and develop new programs. Experience-based information has been useful to workers, safety analysis practitioners, and reviewers in the following ways: (1) Acquiring or developing the needed information in a useful form; (2) Managing the uncertainties during activity development and operation; (3) Identifying the subset of applicable requirements for an activity; (4) Developing the appropriate level of documentation detail for a specific activity; and (5) Increasing the usefulness and use of safety analysis (ownership).
Date: February 1, 1994
Creator: Ellingson, D.R.; Kerr, N.; Bohlander, K.; Hansen, J. & Crowley, W.
Partner: UNT Libraries Government Documents Department