Search Results

The DOE/NREL Environmental Science Program

Description: This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.
Date: May 14, 2001
Creator: Lawson, Douglas R. & Gurevich, Michael
Item Type: Article
Partner: UNT Libraries Government Documents Department

The Environmental Science and Health Effects Program

Description: The goal of the Environmental Science and Health Effect Program is to conduct policy-relevant research that will help us understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources.
Date: April 10, 2000
Creator: Gurevich, Michael; Lawson, Doug & Mauderly, Joe
Item Type: Article
Partner: UNT Libraries Government Documents Department

Potential nanotechnology applications for reducing freshwater consumption at coal fired power plants : an early view.

Description: This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements the overall research effort of the Existing Plants Research Program by evaluating water issues that could impact power plants. A growing challenge to the economic production of electricity from coal-fired power plants is the demand for freshwater, particularly in light of the projected trends for increasing demands and decreasing supplies of freshwater. Nanotechnology uses the unique chemical, physical, and biological properties that are associated with materials at the nanoscale to create and use materials, devices, and systems with new functions and properties. It is possible that nanotechnology may open the door to a variety of potentially interesting ways to reduce freshwater consumption at power plants. This report provides an overview of how applications of nanotechnology could potentially help reduce freshwater use at coal-fired power plants. It was developed by (1) identifying areas within a coal-fired power plant's operations where freshwater use occurs and could possibly be reduced, (2) conducting a literature review to identify potential applications of nanotechnology for facilitating such reductions, and (3) collecting additional information on potential applications from researchers and companies to clarify or expand on information obtained from the literature. Opportunities, areas, and processes for reducing freshwater use in coal-fired power plants considered in this report include the use of nontraditional waters in process and cooling water systems, carbon capture alternatives, more efficient processes for removing sulfur dioxide and nitrogen oxides, coolants that have higher thermal conductivities than water alone, energy storage options, and a variety of plant inefficiencies, which, if improved, would reduce energy use and concomitant water consumption. These inefficiencies include air heater inefficiencies, boiler corrosion, low ...
Date: September 17, 2010
Creator: Elcock, D. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Institutional impediments to using alternative water sources in thermoelectric power plants.

Description: This report was funded by the U.S. Department of Energy's (DOE's) National Energy Technology Laboratory (NETL) Existing Plants Research Program, which has an energy-water research effort that focuses on water use at power plants. This study complements the Existing Plants Research Program's overall research effort by evaluating water issues that could impact power plants. Obtaining adequate water supplies for cooling and other operations at a reasonable cost is a key factor in siting new and maintaining existing thermoelectric power plant operations. One way to reduce freshwater consumption is to use alternative water sources such as reclaimed (or recycled) water, mine pool water, and other nontraditional sources. The use of these alternative sources can pose institutional challenges that can cause schedule delays, increase costs, or even require plants to abandon their plans to use alternative sources. This report identifies and describes a variety of institutional challenges experienced by power plant owners and operators across the country, and for many of these challenges it identifies potential mitigating approaches. The information comes from publically available sources and from conversations with power plant owners/operators familiar with using alternative sources. Institutional challenges identified in this investigation include, but are not limited to, the following: (1) Institutional actions and decisions that are beyond the control of the power plant. Such actions can include changes in local administrative policies that can affect the use of reclaimed water, inaccurate growth projections regarding the amount of water that will be available when needed, and agency workloads and other priorities that can cause delays in the permitting and approval processes. (2) Developing, cultivating, and maintaining institutional relationships with the purveyor(s) of the alternative water source, typically a municipal wastewater treatment plant (WWTP), and with the local political organizations that can influence decisions regarding the use of the alternative source. Often ...
Date: August 3, 2011
Creator: Elcock, D. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Potential impacts of nanotechnology on energy transmission applications and needs.

Description: The application of nanotechnologies to energy transmission has the potential to significantly impact both the deployed transmission technologies and the need for additional development. This could be a factor in assessing environmental impacts of right-of-way (ROW) development and use. For example, some nanotechnology applications may produce materials (e.g., cables) that are much stronger per unit volume than existing materials, enabling reduced footprints for construction and maintenance of electricity transmission lines. Other applications, such as more efficient lighting, lighter-weight materials for vehicle construction, and smaller batteries having greater storage capacities may reduce the need for long-distance transport of energy, and possibly reduce the need for extensive future ROW development and many attendant environmental impacts. This report introduces the field of nanotechnology, describes some of the ways in which processes and products developed with or incorporating nanomaterials differ from traditional processes and products, and identifies some examples of how nanotechnology may be used to reduce potential ROW impacts. Potential environmental, safety, and health impacts are also discussed.
Date: November 30, 2007
Creator: Elcock, D. & Division, Environmental Science
Item Type: Report
Partner: UNT Libraries Government Documents Department

Roadmapping or development of future investments in environmental science and technology

Description: This paper will summarize efforts in roadmapping SCFA technical targets, which could be used for selection of future projects. The timely lessons learned and insights will be valuable to other programs desiring to roadmap large amounts of workscope, but unsure how to successfully complete it, by adequately defining a strategy to develop alternatives and core technologies to ensure needed environmental technologies are available and allow delivery of viable alternatives. In early FY02, Los Alamos National Laboratory's Environmental Science and Waste Technology Program Office was working jointly with Idaho National Environmental Engineering Laboratory to define and develop science and technology mini-roadmaps. We were defining and developing these mini-roadmaps to provide direction and guidance for DOE's Environmental Management's (DOE-EM) Subsurface Contaminants Focus Area (SCFA) in their development of target technologies. DOE EM's Strategic Plan for Science and Technology provides guidance for meeting science and technology needs with a view of the desired future and the long-term strategy to attain it. Program and technology mini-roadmapping were to be used to establish priorities, set program and project direction, and identify the high-priority science and technology need areas according to this document. In the past, EM science and technology needs collection is achieved through the DOE Site Technology Coordination Groups (STCG) across the complex. A future system for needs collection has not been defined. However, there is a need for gap analyses and a technical approach for the prioritization of these needs for DOE-EM to be strategic and successful in their technology research, development, demonstration, and deployments. To define the R&D projects needed to solve particular problems and select the project with the largest potential payoff will require analysis for project selection. Mini-roadmaps could be used for setting goals and priorities for future program planning and development of future investments in environmental science and technology, ...
Date: January 1, 2002
Creator: Wilburn, D. (Dianne)
Item Type: Article
Partner: UNT Libraries Government Documents Department

BEST: Bilingual environmental science training: Kindergarten level

Description: This booklet is one of a series of bilingual guides to environmental-science learning activities for students to do at home. Lesson objectives, materials required, procedure, vocabulary, and subjects integrated into the lesson are described in English for each lesson. A bilingual glossary, alphabetized by English entries, with Spanish equivalents in both English and Spanish, follows the lesson descriptions, and is itself followed by a bibliography of English-language references. This booklet includes descriptions of six lessons covering the senses of touch and sight, the sense of smell, how to distinguish living and non-living things, cell structures, the skeletal system, and the significance of food groups. 8 figs.
Date: March 1, 1996
Item Type: Report
Partner: UNT Libraries Government Documents Department

Synchrotron Environmental Science-I Workshop Report.

Description: Attendees of the Synchrotrons Environmental Science 1 (SES-1) workshop represented a broad spectrum of environmental science research areas and expertise in all of the current synchrotrons techniques (X-ray scattering and diffraction, X-ray absorption spectroscopy, and two- and three-dimensional X-ray imaging). These individuals came together to discuss current measurement obstacles in environmental research and, more specifically, ways to overcome such obstacles by applying synchrotrons radiation techniques. Significant obstacles in measurement affect virtually all of the research issues described. Attendees identified synchrotrons approaches of potential value in their research. A number of the environmental research studies discussed are currently being addressed with some success by synchrotron-based approaches. Nevertheless, improvements in low-Z measurement capabilities are needed to facilitate the use of synchrotrons radiation methodologies in environmental research.
Date: July 8, 1999
Item Type: Report
Partner: UNT Libraries Government Documents Department

Health and Environmental Science: A Brief Review

Description: The detonation of the first atomic bomb heralded the beginning of a new age. Almost everyone agreed that the enormous energy released by the "atomic reaction" would create opportunities and problems far larger than man faced in previous history. However, few foresaw the explosion of knowledge that would also be part of this new age.
Date: September 27, 1982
Item Type: Report
Partner: UNT Libraries Government Documents Department

Environmental Science Program at the Advanced Light Source

Description: Synchrotron Radiation (SR)-based techniques have become an essential and fundamental research tool in Molecular Environmental Science (MES) research. MES is an emerging scientific field that has largely evolved from research interactions at the U.S. Department of Energy (U.S. DOE) SR laboratories in response to the pressing need for understanding fundamental molecular-level chemical and biological processes that involve the speciation, properties, and behavior of contaminants, within natural systems. The role of SR-based investigations in MES and their impact on environmental problems of importance to society has been recently documented in Molecular Environmental Science: An Assessment of Research Accomplishment, Available Synchrotron Radiation Facilities, and Needs (EnviroSync, 2003).
Date: June 1, 2005
Creator: Hubbard, Susan; Shuh, David & Nico, Peter
Item Type: Report
Partner: UNT Libraries Government Documents Department

Molecular Environmental Science and Synchrotron Radiation Facilities An Update of the 1995 DOE-Airlie Report on Molecular Environmental Science

Description: This workshop was requested by Dr. Robert Marianelli, Director of the DOE-BES Chemical Sciences Division, to update the findings of the Workshop on Molecular Environmental Sciences (MES) held at Airlie, VA, in July 1995. The Airlie Workshop Report defined the new interdisciplinary field referred to as Molecular Environmental Science (MES), reviewed the synchrotron radiation methods used in MES research, assessed the adequacy of synchrotron radiation facilities for research in this field, and summarized the beam time requirements of MES users based on a national MES user survey. The objectives of MES research are to provide information on the chemical and physical forms (speciation), spatial distribution, and reactivity of contaminants in natural materials and man-made waste forms, and to develop a fundamental understanding of the complex molecular-scale environmental processes, both chemical and biological, that affect the stability, transformations, mobility, and toxicity of contaminant species. These objectives require parallel studies of ''real'' environmental samples, which are complicated multi-phase mixtures with chemical and physical heterogeneities, and of simplified model systems in which variables can be controlled and fundamental processes can be examined. Only by this combination of approaches can a basic understanding of environmental processes at the molecular-scale be achieved.
Date: May 7, 1999
Creator: Bargar, John R
Item Type: Report
Partner: UNT Libraries Government Documents Department

Investigation of contaminant sources at Navarre, Kansas.

Description: The results of the 2006 investigation of contaminant sources at Navarre, Kansas, clearly demonstrate the following: {sm_bullet} Sources of carbon tetrachloride contamination were found on the Navarre Co-op property. These sources are the locations of the highest concentrations of carbon tetrachloride found in soil and groundwater at Navarre. The ongoing groundwater contamination at Navarre originates from these sources. {sm_bullet} The sources on the Co-op property are in locations where the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) never conducted grain storage operations. {sm_bullet} No definitive sources of carbon tetrachloride were identified on the portion of the current Co-op property formerly used by the CCC/USDA. {sm_bullet} The source areas on the Co-op property are consistent with the locations of the most intense Co-op operations, both historically and at present. The Co-op historically stored carbon tetrachloride for retail sale and used it as a grain fumigant in these locations. {sm_bullet} The distribution patterns of other contaminants (tetrachloroethene and nitrate) originating from sources on the Co-op property mimic the carbon tetrachloride plume. These other contaminants are not associated with CCC/USDA operations. {sm_bullet} The distribution of carbon tetrachloride at the Co-op source areas, particularly the absence of contamination in soils at depths less than 20 ft below ground level, is consistent with vertical migration into the subsurface through a conduit (well Co-op 2), with subsequent lateral migration through the subsurface. {sm_bullet} The groundwater flow direction, which is toward the west-northwest, is not consistent with migration of carbon tetrachloride in groundwater from the former CCC/USDA property to the source areas on the Co-op property. {sm_bullet} The absence of soil and groundwater contamination along surface drainage pathways on the former CCC/USDA property is not consistent with migration of carbon tetrachloride in surface water runoff from the former CCC/USDA property to the source areas ...
Date: November 5, 2007
Creator: LaFreniere, L. M. & Division, Environmental Science
Item Type: Report
Partner: UNT Libraries Government Documents Department

Phase 1 Final status survey plan for the West Valley demonstration project.

Description: This plan provides the technical basis and associated protocols to support Phase 1 final status survey (FSS) data collection and interpretation as part of the West Valley Demonstration Project Phase 1 Decommissioning Plan process. This plan is consistent with the Multi-Agency Radiation Survey and Site Investigation Manual (MARSSIM). The Phase 1 Decommissioning Plan provides the relevant derived concentration guideline levels (DCGLs) for the Phase 1 radionuclides of interest. This plan includes protocols that will be applied to the deep excavations planned for Waste Management Area (WMA) 1 and WMA 2, for surface soils outside the WMA 1 and WMA 2 excavations that do not have contamination impacts at depths greater than one meter, and for areas that are used for Phase 1 contaminated soil lay-down purposes. All excavated and lay-down areas will be classified as MARSSIM Class 1 areas. Surface soils that have not been excavated, are not expected to exceed DCGLs, and do not have contamination impacts at depths greater than one meter will be divided into either Class 1 or Class 2 areas depending on the expected potential for surface soil contamination in those areas. The plan uses gamma scans combined with biased soil samples to address DCGLemc concerns. The plan uses systematic soil sampling combined with area factors to address DCGLw and DCGLemc concerns. The Sign test will be used to statistically evaluate DCGLw compliance. If the results from the characterization sampling and analysis plan (CSAP) data collection indicate that background may be a significant issue for Sign test implementation, the Wilcoxon rank sum (WRS) test will be used instead to demonstrate DCGLw compliance. A reference area will be selected on the basis of CSAP data results if the WRS test becomes a necessity. The WMA 1 excavation footprint includes approximately 476 foundation pilings that will be ...
Date: May 31, 2011
Creator: Johnson, R. L. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Phase 1 Characterization sampling and analysis plan West Valley demonstration project.

Description: The Phase 1 Characterization Sampling and Analysis Plan (CSAP) provides details about environmental data collection that will be taking place to support Phase 1 decommissioning activities described in the Phase 1 Decommissioning Plan for the West Valley Demonstration Project, Revision 2 (Phase I DP; DOE 2009). The four primary purposes of CSAP data collection are: (1) pre-design data collection, (2) remedial support, (3) post-remediation status documentation, and (4) Phase 2 decision-making support. Data collection to support these four main objectives is organized into two distinct data collection efforts. The first is data collection that will take place prior to the initiation of significant Phase 1 decommissioning activities (e.g., the Waste Management Area [WMA] 1 and WMA 2 excavations). The second is data collection that will occur during and immediately after environmental remediation in support of remediation activities. Both data collection efforts have a set of well-defined objectives that encompass the data needs of the four main CSAP data collection purposes detailed in the CSAP. The main body of the CSAP describes the overall data collection strategies that will be used to satisfy data collection objectives. The details of pre-remediation data collection are organized by WMA. The CSAP contains an appendix for each WMA that describes the details of WMA-specific pre-remediation data collection activities. The CSAP is intended to expand upon the data collection requirements identified in the Phase 1 Decommissioning Plan. The CSAP is intended to tightly integrate with the Phase 1 Final Status Survey Plan (FSSP). Data collection described by the CSAP is consistent with the FSSP where appropriate and to the extent possible.
Date: June 30, 2011
Creator: Johnson, R. L. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

ARM mobile facility surface meteorology (MET) handbook.

Description: The Atmospheric Radiation Measurement (ARM) Mobile Facility Surface Meteorology station (MET) uses mainly conventional in situ sensors to obtain 1-min statistics of surface wind speed, wind direction, air temperature, relative humidity (RH), barometric pressure, and rainrate. Additional sensors may be added to or removed from the base set of sensors depending upon the deployment location, climate regime, or programmatic needs. In addition, sensor types may change depending upon the climate regime of the deployment. These changes/additions are noted in Section 3.
Date: April 1, 2006
Creator: Ritsche, M. T. & Division, Environmental Science
Item Type: Report
Partner: UNT Libraries Government Documents Department

Monitoring plan for Everest, Kansas.

Description: This transmittal is a response to your request of January 22, 2009, for a letter work plan outlining a program of annual groundwater and surface water monitoring at Everest, Kansas. Once yearly, they propose to conduct surface water sampling at the 5 locations shown in Figure 1 and groundwater sampling in the 16 wells identified in Figure 2. The wells will be sampled according to the low-flow procedure. The next sampling event is planned for April 2009. The surface water and groundwater samples collected will be preserved, shipped, and analyzed for volatile organic compounds as in previous work at Everest. Results will be reported to the KDHE. This monitoring program will continue until identified plume conditions at the site indicate a technical justification to change the monitoring program.
Date: March 23, 2009
Creator: LaFreniere, L. M. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Recommendations for new monitoring wells at Everest, Kansas.

Description: On February 15, 2007, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) submitted Recommendations for Remedial Action at Everest, Kansas. Those Recommendations were accepted by the Kansas Department of Health and Environment (KDHE) in a letter to the CCC/USDA dated March 5, 2007. The approved Recommendations document outlines a plan for systematic groundwater sampling and monitoring at Everest to provide data necessary for the critical evaluation of remedial options - including a phytoremediation alternative - for restoration of the groundwater and protection of the surface waters of the intermittent creek at this site. Phase I of the KDHE-approved monitoring plan includes the following activities: (1) Groundwater sampling at existing monitoring wells, with analyses for volatile organic compounds (VOCs) and selected biodegradation parameters; (2) Sampling of surface waters along the intermittent creek for VOCs analyses; and (3) Periodic manual measurement and automated recording of groundwater and surface water levels in the vicinity of the intermittent creek. The locations selected for groundwater and surface water sampling and analyses under the approved monitoring program were determined in consultation with the KDHE. As a result of subsequent discussions among representatives of the KDHE, the CCC/USDA, and Argonne regarding the technical program at Everest, the CCC/USDA seeks KDHE approval for the installation of up to four new permanent monitoring wells along the upper reach of the intermittent creek west of the Nigh property, as shown in Figure 1. The proposed new well locations lie progressively downgradient in the anticipated direction of future groundwater and contaminant movement; all of the recommended points lie at least 2,000 ft upgradient, however, of the confirmed area of groundwater discharge to the creek identified near Highway 73. The proposed new wells will supplement the existing network of groundwater and surface water monitoring points identified in the KDHE-approved ...
Date: May 3, 2007
Creator: LaFreniere, L. M. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Recommendations for Remedial Action at Everest, Kansas.

Description: On September 7, 2005, the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) presented a Scoping Memo (Argonne 2005) for preliminary consideration by the Kansas Department of Health and Environment (KDHE). This document suggested possible remedial options for the carbon tetrachloride contamination in groundwater at Everest, Kansas. The suggested approaches were discussed by representatives of the KDHE, the CCC/USDA, and Argonne at the KDHE office in Topeka on September 8-9, 2005, along with other technical and logistic issues related to the Everest site. In response to these discussions, the KDHE recommended (KDHE 2005) evaluation of several remedial processes, either alone or in combination, as part of a Corrective Action Study (CAS) for Everest. The primary remedial processes suggested by the KDHE included the following: (1) Hydraulic control by groundwater extraction with aboveground treatment; (2) Air sparging-soil vapor extraction (SVE) in large-diameter boreholes; and (3) Phytoremediation. As a further outcome of the 2005 meeting and as a precursor to the proposed CAS, the CCC/USDA completed the following supplemental investigations at Everest to address several specific technical concerns discussed with the KDHE: (1) Construction of interpretive cross sections at strategic locations selected by the KDHE along the main plume migration pathway, to depict the hydrogeologic characteristics affecting groundwater flow and contaminant movement (Argonne 2006a); (2) A field investigation in early 2006 (Argonne 2006c), as follows: (a) Installation and testing of a production well and associated observation points, at locations approved by the KDHE, to determine the response of the Everest aquifer to groundwater extraction near the Nigh property; (b) Groundwater sampling for the analysis of volatile organic compounds (VOCs) and the installation of additional permanent monitoring points at locations selected by the KDHE, to further constrain the existing contaminant plume; and (c) Resampling of all existing permanent monitoring points for ...
Date: February 15, 2007
Creator: LaFreniere, L. M. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Annual report of groundwater monitoring at Centralia, Kansas, in 2009.

Description: In September 2005, periodic sampling of groundwater was initiated by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) in the vicinity of a grain storage facility formerly operated by the CCC/USDA at Centralia, Kansas. The sampling at Centralia is being performed on behalf of the CCC/USDA by Argonne National Laboratory, in accord with a monitoring program approved by the Kansas Department of Health and Environment (KDHE). The objective is to monitor levels of carbon tetrachloride contamination identified in the groundwater at Centralia (Argonne 2003, 2004, 2005a). Under the KDHE-approved monitoring plan (Argonne 2005b), the groundwater was sampled twice yearly from September 2005 until September 2007 for analyses for volatile organic compounds (VOCs), as well as measurement of selected geochemical parameters to aid in the evaluation of possible natural contaminant degradation (reductive dechlorination) processes in the subsurface environment. The results from the two-year sampling program demonstrated the presence of carbon tetrachloride contamination at levels exceeding the KDHE Tier 2 risk-based screening level (RBSL) of 5 {micro}g/L for this compound in a localized groundwater plume that has shown little movement. The relative concentrations of chloroform, the primary degradation product of carbon tetrachloride, suggested that some degree of reductive dechlorination or natural biodegradation was taking place in situ at the former CCC/USDA facility on a localized scale. The CCC/USDA subsequently developed an Interim Measure Conceptual Design (Argonne 2007b), proposing a pilot test of the Adventus EHC technology for in situ chemical reduction (ISCR). The proposed interim measure (IM) was approved by the KDHE in November 2007 (KDHE 2007). Implementation of the pilot test occurred in November-December 2007. The objective was to create highly reducing conditions that would enhance both chemical and biological reductive dechlorination in the injection test area (Argonne 2009a). The KDHE (2008a) has requested that sitewide monitoring continue ...
Date: October 19, 2010
Creator: LaFreniere, L. M. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department

Annual report of groundwater monitoring at Centralia, Kansas, in 2010.

Description: In September 2005, periodic sampling of groundwater was initiated by the Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) in the vicinity of a grain storage facility formerly operated by the CCC/USDA at Centralia, Kansas. The sampling at Centralia is performed on behalf of the CCC/USDA by Argonne National Laboratory, in accord with a monitoring program approved by the Kansas Department of Health and Environment (KDHE). The objective is to monitor levels of carbon tetrachloride contamination identified in the groundwater at Centralia (Argonne 2003, 2004, 2005a). Under the KDHE-approved monitoring plan (Argonne 2005b), the groundwater was sampled twice yearly from September 2005 until September 2007 for analyses for volatile organic compounds (VOCs), as well as measurement of selected geochemical parameters to aid in the evaluation of possible natural contaminant degradation processes (reductive dechlorination) in the subsurface environment (Argonne 2006, 2007a, 2008a). The results from the two-year sampling program demonstrated the presence of carbon tetrachloride contamination at levels exceeding the KDHE Tier 2 risk-based screening level (RBSL) of 5 {micro}g/L for this compound, in a localized groundwater plume that has shown little movement. The relative concentrations of chloroform, the primary degradation product of carbon tetrachloride, suggested that some degree of reductive dechlorination or natural biodegradation was talking place in situ at the former CCC/USDA facility on a localized scale. The CCC/USDA subsequently developed an Interim Measure Conceptual Design (Argonne 2007b), proposing a pilot test of the Adventus EHC technology for in situ chemical reduction (ISCR). The proposed interim measure (IM) was approved by the KDHE in November 2007 (KDHE 2007). Implementation of the pilot test occurred in November-December 2007. The objective was to create highly reducing conditions that would enhance both chemical and biological reductive dechlorination in the injection test area (Argonne 2009a). The KDHE (2008a) requested that sitewide ...
Date: March 16, 2011
Creator: LaFreniere, L. M. (Environmental Science Division)
Item Type: Report
Partner: UNT Libraries Government Documents Department