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Development of Zinc/Bromine Batteries for Load-Leveling Applications: Phase 2 Final Report

Description: This report documents Phase 2 of a project to design, develop, and test a zinc/bromine battery technology for use in utility energy storage applications. The project was co-funded by the U.S. Department of Energy Office of Power Technologies through Sandia National Laboratories. The viability of the zinc/bromine technology was demonstrated in Phase 1. In Phase 2, the technology developed during Phase 1 was scaled up to a size appropriate for the application. Batteries were increased in size from 8-cell, 1170-cm{sup 2} cell stacks (Phase 1) to 8- and then 60-cell, 2500-cm{sup 2} cell stacks in this phase. The 2500-cm{sup 2} series battery stacks were developed as the building block for large utility battery systems. Core technology research on electrolyte and separator materials and on manufacturing techniques, which began in Phase 1, continued to be investigated during Phase 2. Finally, the end product of this project was a 100-kWh prototype battery system to be installed and tested at an electric utility.
Date: October 1, 1999
Creator: CLARK,NANCY H. & EIDLER,PHILLIP
Partner: UNT Libraries Government Documents Department

Initial test results from the RedFlow 5 kW, 10 kWh zinc-bromide module, phase 1.

Description: In this paper the performance results of the RedFlow zinc-bromide module (ZBM) Gen 2.0 are reported for Phase 1 of testing, which includes initial characterization of the module. This included physical measurement, efficiency as a function of charge and discharge rates, efficiency as a function of maximum charge capacity, duration of maximum power supplied, and limited cycling with skipped strip cycles. The goal of this first phase of testing was to verify manufacturer specifications of the zinc-bromide flow battery. Initial characterization tests have shown that the ZBM meets the manufacturer's specifications. Further testing, including testing as a function of temperature and life cycle testing, will be carried out during Phase 2 of the testing, and these results will be issued in the final report, after Phase 2 testing has concluded.
Date: February 1, 2012
Creator: Ferreira, Summer Rhodes & Rose, David Martin
Partner: UNT Libraries Government Documents Department

A smart control system for electric vehicle batteries

Description: A smart control system for electric vehicle (EV) batteries was designed and its performance was evaluated. The hardware for the system was based on the Motorola MC68HC11ENB micro controller. A zinc bromide (Zn/Br{sub 2}) battery was chosen since it is a good candidate as an EV battery and has a large number of user variable parameters that affect its performance. The flexibility of the system arises from the fact that the system can be programmed to do a wide variety of jobs. The use of real time interrupts and other features makes the system safe for use along with the battery systems. Test data indicates that real time control of the different parameters can increase the performance of the battery by 15%. In addition to optimizing the performance of the battery the control system incorporates essential safety features.
Date: December 31, 1993
Creator: Arikara, M.P.; Dickinson, B.E. & Branum, B.
Partner: UNT Libraries Government Documents Department

Utility battery storage systems. Program report for FY95

Description: Sandia National Laboratories, New Mexico, conducts the Utility Battery Storage Systems Program, which is sponsored by the U.S. Department of Energy`s Office of Utility Technologies. The goal of this program is to assist industry in developing cost-effective battery systems as a utility resource option by 2000. Sandia is responsible for the engineering analyses, contracted development, and testing of rechargeable batteries and systems for utility energy storage applications. This report details the technical achievements realized during fiscal year 1995.
Date: March 1, 1996
Creator: Butler, P.C.
Partner: UNT Libraries Government Documents Department

Comparison of advanced battery technologies for electric vehicles

Description: Battery technologies of different chemistries, manufacture and geometry were evaluated as candidates for use in Electric Vehicles (EV). The candidate batteries that were evaluated include four single cell and seven multi-cell modules representing four technologies: Lead-Acid, Nickel-Cadmium, Nickel-Metal Hydride and Zinc-Bromide. A standard set of testing procedures for electric vehicle batteries, based on industry accepted testing procedures, and any tests which were specific to individual battery types were used in the evaluations. The batteries were evaluated by conducting performance tests, and by subjecting them to cyclical loading, using a computer controlled charge--discharge cycler, to simulate typical EV driving cycles. Criteria for comparison of batteries were: performance, projected vehicle range, cost, and applicability to various types of EVs. The four battery technologies have individual strengths and weaknesses and each is suited to fill a particular application. None of the batteries tested can fill every EV application.
Date: December 1993
Creator: Dickinson, B. E.; Lalk, T. R. & Swan, D. H.
Partner: UNT Libraries Government Documents Department

Review of storage battery system cost estimates

Description: Cost analyses for zinc bromine, sodium sulfur, and lead acid batteries were reviewed. Zinc bromine and sodium sulfur batteries were selected because of their advanced design nature and the high level of interest in these two technologies. Lead acid batteries were included to establish a baseline representative of a more mature technology.
Date: April 1, 1986
Creator: Brown, D.R. & Russell, J.A.
Partner: UNT Libraries Government Documents Department

Overview of the US Department of Energy Utility Battery Storage Systems Program

Description: The US Department of Energy (DOE) is sponsoring the Utility Battery Storage Systems Program at Sandia National Laboratories and its contractors. This program is specifically aimed at developing battery energy storage systems for electric utility applications commencing in the mid to late 1990s. One factory-integrated utility battery system and three battery technologies: sodium/sulfur, zinc/bromine, and lead-acid are being developed under this program. In the last few years the emphasis of this program has focused on battery system development. This emphasis has included greater interactions with utilities to define application requirements. Recent activities have identified specific applications of battery energy storage in certain utility systems and quantified the value of these applications to these utility companies. In part due to these activities, battery energy storage is no longer regarded by utilities as a load-leveling resource only, but as a multifunction, energy management resource.
Date: August 1, 1993
Creator: Eaton, R.; Akhil, A.; Butler, P. C. & Hurwitch, J.
Partner: UNT Libraries Government Documents Department

Advanced batteries for electric vehicle applications

Description: A technology assessment is given for electric batteries with potential for use in electric powered vehicles. Parameters considered include: specific energy, specific power, energy density, power density, cycle life, service life, recharge time, and selling price. Near term batteries include: nickel/cadmium and lead-acid batteries. Mid term batteries include: sodium/sulfur, sodium/nickel chloride, nickel/metal hydride, zinc/air, zinc/bromine, and nickel/iron systems. Long term batteries include: lithium/iron disulfide and lithium- polymer systems. Performance and life testing data for these systems are discussed. (GHH)
Date: August 1, 1993
Creator: Henriksen, G.L.
Partner: UNT Libraries Government Documents Department

Development of zinc-bromine batteries for utility energy storage. First annual report, 1 September 1978-31 August 1979. [8-kWh submodule]

Description: Development work on the Zn/Br battery is reported. A major improvement was the use of a bipolar cell design; this design is superior with respect to cost, performance, and simplicity. A cost and design study for an 80-kWh module resulted in a cost estimate of $54/kWh(1979$) for purchased materials and components, on the basis of 2500 MWh of annual production. A cell submodule (nominal 2 kWh) of full-sized electrodes (1 ft/sup 2/) accrued over 200 continuous cycles in a hands-off, automatic routine with efficiencies in the range of 53 to 56%. Initial testing of a full-sized 8-kWh submodule demonstrated energy efficiencies of 65 to 67%. 23 figures, 10 tables. (RWR)
Date: May 1, 1980
Creator: Putt, R.; Attia, A.J.; Lu, P.Y. & Heyland, J.H.
Partner: UNT Libraries Government Documents Department

Utility Battery Storage Systems Program report for FY93

Description: Sandia National Laboratories, New Mexico, conducts the Utility Battery Storage Systems Program, which is sponsored by the US Department of Energy`s Office of Energy Management. In this capacity, Sandia is responsible for the engineering analyses, contract development, and testing of rechargeable batteries and systems for utility-energy-storage applications. This report details the technical achievements realized during fiscal year 1993.
Date: February 1, 1994
Creator: Butler, P. C.
Partner: UNT Libraries Government Documents Department

Key results of battery performance and life tests at Argonne National Laboratory

Description: Advanced battery technology evaluations are performed under simulated electric vehicle operating conditions at Argonne National Laboratory`s & Diagnostic Laboratory (ADL). The ADL provide a common basis for both performance characterization and life evaluation with unbiased application of tests and analyses. This paper summarizes the performance characterizations and life evaluations conducted in 1991 on twelve single cells and eight 3- to 360-cell modules that encompass six battery technologies (Na/S, Li/MS, Ni/MH, Zn/Br, Ni/Fe, and Pb-Acid). These evaluations were performed for the Department of Energy, Office of Transportation Technologies, Electric and Hybrid Propulsion Division. The results measure progress in battery R & D programs, compare battery technologies, and provide basic data for modeling and continuing R & D to battery users, developers, and program managers.
Date: December 31, 1991
Creator: DeLuca, W. H.; Gillie, K. R.; Kulaga, J. E.; Smaga, J. A.; Tummillo, A. F. & Webster, C. E.
Partner: UNT Libraries Government Documents Department

Exploratory Battery Technology Development and Testing Report for 1989

Description: Sandia National Laboratories, Albuquerque, has been designated as Lead Center for the Exploratory Battery Technology Development and Testing Project, which is sponsored by the US Department of Energy's Office of Energy Storage and Distribution. In this capacity, Sandia is responsible for the engineering development of advanced rechargeable batteries for both mobile and stationary energy storage applications. This report details the technical achievements realized in pursuit of the Lead Center's goals during calendar year 1989. 4 refs., 84 figs., 18 tabs.
Date: December 1990
Creator: Magnani, Nicholas J.; Diegle, Ronald B.; Braithwaite, Jeffrey W.; Bush, Donald M.; Freese, James M.; Akhil, Abbas A. et al.
Partner: UNT Libraries Government Documents Department

An assessment of research and development leadership in advanced batteries for electric vehicles

Description: Due to the recently enacted California regulations requiring zero emission vehicles be sold in the market place by 1998, electric vehicle research and development (R&D) is accelerating. Much of the R&D work is focusing on the Achilles` heel of electric vehicles -- advanced batteries. This report provides an assessment of the R&D work currently underway in advanced batteries and electric vehicles in the following countries: Denmark, France, Germany, Italy, Japan, Russia, and the United Kingdom. Although the US can be considered one of the leading countries in terms of advanced battery and electric vehicle R&D work, it lags other countries, particularly France, in producing and promoting electric vehicles. The US is focusing strictly on regulations to promote electric vehicle usage while other countries are using a wide variety of policy instruments (regulations, educational outreach programs, tax breaks and subsidies) to encourage the use of electric vehicles. The US should consider implementing additional policy instruments to ensure a domestic market exists for electric vehicles. The domestic is the largest and most important market for the US auto industry.
Date: February 1, 1994
Creator: Bruch, V. L.
Partner: UNT Libraries Government Documents Department

Battery testing at Argonne National Laboratory

Description: Argonne National Laboratory`s Analysis & Diagnostic Laboratory (ADL) tests advanced batteries under simulated electric and hybrid vehicle operating conditions. The ADL facilities also include a post-test analysis laboratory to determine, in a protected atmosphere if needed, component compositional changes and failure mechanisms. The ADL provides a common basis for battery performance characterization and life evaluations with unbiased application of tests and analyses. The battery evaluations and post-test examinations help identify factors that limit system performance and life, and the most-promising R&D approaches for overcoming these limitations. Since 1991, performance characterizations and/or life evaluations have been conducted on eight battery technologies (Na/S, Li/S, Zn/Br, Ni/MH, Ni/Zn, Ni/Cd, Ni/Fe, and lead-acid). These evaluations were performed for the Department of Energy`s. Office of Transportation Technologies, Electric and Hybrid Propulsion Division (DOE/OTT/EHP), and Electric Power Research Institute (EPRI) Transportation Program. The results obtained are discussed.
Date: March 25, 1993
Creator: DeLuca, W. H.; Gillie, K. R.; Kulaga, J. E.; Smaga, J. A.; Tummillo, A. F. & Webster, C. E.
Partner: UNT Libraries Government Documents Department

Flowing-electrolyte-battery testing and evaluation

Description: A laboratory to evaluate the performance and cycle life of flowing electrolyte battery systems has been established at Sandia National Laboratories. Four unique flow batteries are being tested in the laboratory using a four-variable two-level factorial experimental plan. Two Exxon zinc bromine batteries and one Gould zinc bromine battery are under test. One NASA Redox battery is on test. This paper describes results obtained to date from the test program. Cycle history, efficiency values, and general performance observations for these batteries are reported. The factorial test program and available statistical results are also discussed.
Date: January 1, 1982
Creator: Butler, P.C.; Miller, D.W. & Verardo, A.E.
Partner: UNT Libraries Government Documents Department

Key results of battery performance and life tests at Argonne National Laboratory

Description: Advanced battery technology evaluations are performed under simulated electric vehicle operating conditions at Argonne National Laboratory's Diagnostic Laboratory (ADL). The ADL provide a common basis for both performance characterization and life evaluation with unbiased application of tests and analyses. This paper summarizes the performance characterizations and life evaluations conducted in 1991 on twelve single cells and eight 3- to 360-cell modules that encompass six battery technologies (Na/S, Li/MS, Ni/MH, Zn/Br, Ni/Fe, and Pb-Acid). These evaluations were performed for the Department of Energy, Office of Transportation Technologies, Electric and Hybrid Propulsion Division. The results measure progress in battery R D programs, compare battery technologies, and provide basic data for modeling and continuing R D to battery users, developers, and program managers.
Date: January 1, 1991
Creator: DeLuca, W.H.; Gillie, K.R.; Kulaga, J.E.; Smaga, J.A.; Tummillo, A.F. & Webster, C.E.
Partner: UNT Libraries Government Documents Department

Results of advanced battery technology evaluations for electric vehicle applications

Description: Advanced battery technology evaluations are performed under simulated electric-vehicle operating conditions at the Analysis & Diagnostic Laboratory (ADL) of Argonne National Laboratory. The ADL results provide insight Into those factors that limit battery performance and life. The ADL facilities include a test laboratory to conduct battery experimental evaluations under simulated application conditions and a post-test analysis laboratory to determine, In a protected atmosphere if needed, component compositional changes and failure mechanisms. This paper summarizes the performance characterizations and life evaluations conducted during 1991--1992 on both single cells and multi-cell modules that encompass eight battery technologies [Na/S, Li/MS (M=metal), Ni/MH, Ni/Cd, Ni/Zn, Ni/Fe, Zn/Br, and Pb-acid]. These evaluations were performed for the Department of Energy, Office of Transportation Technologies, Electric and Hybrid Propulsion Division, and the Electric Power Research Institute. The ADL provides a common basis for battery performance characterization and life evaluations with unbiased application of tests and analyses. The results help identify the most-promising R&D approaches for overcoming battery limitations, and provide battery users, developers, and program managers with a measure of the progress being made in battery R&D programs, a comparison of battery technologies, and basic data for modeling.
Date: September 1, 1992
Creator: DeLuca, W. H.; Gillie, K. R.; Kulaga, J. E.; Smaga, J. A.; Tummillo, A. F. & Webster, C. E.
Partner: UNT Libraries Government Documents Department

Battery testing at Argonne National Laboratory

Description: Argonne National Laboratory's Analysis Diagnostic Laboratory (ADL) tests advanced batteries under simulated electric and hybrid vehicle operating conditions. The ADL facilities also include a post-test analysis laboratory to determine, in a protected atmosphere if needed, component compositional changes and failure mechanisms. The ADL provides a common basis for battery performance characterization and life evaluations with unbiased application of tests and analyses. The battery evaluations and post-test examinations help identify factors that limit system performance and life, and the most-promising R D approaches for overcoming these limitations. Since 1991, performance characterizations and/or life evaluations have been conducted on eight battery technologies (Na/S, Li/S, Zn/Br, Ni/MH, Ni/Zn, Ni/Cd, Ni/Fe, and lead-acid). These evaluations were performed for the Department of Energy's. Office of Transportation Technologies, Electric and Hybrid Propulsion Division (DOE/OTT/EHP), and Electric Power Research Institute (EPRI) Transportation Program. The results obtained are discussed.
Date: March 25, 1993
Creator: DeLuca, W.H.; Gillie, K.R.; Kulaga, J.E.; Smaga, J.A.; Tummillo, A.F. & Webster, C.E.
Partner: UNT Libraries Government Documents Department

Results of advanced batter technology evaluations for electric vehicle applications

Description: Advanced battery technology evaluations are performed under simulated electric-vehicle operating conditions at the Analysis Diagnostic Laboratory (ADL) of Argonne National Laboratory. The ADL results provide insight Into those factors that limit battery performance and life. The ADL facilities include a test laboratory to conduct battery experimental evaluations under simulated application conditions and a post-test analysis laboratory to determine, In a protected atmosphere if needed, component compositional changes and failure mechanisms. This paper summarizes the performance characterizations and life evaluations conducted during 1991--1992 on both single cells and multi-cell modules that encompass eight battery technologies (Na/S, Li/MS (M=metal), Ni/MH, Ni/Cd, Ni/Zn, Ni/Fe, Zn/Br, and Pb-acid). These evaluations were performed for the Department of Energy, Office of Transportation Technologies, Electric and Hybrid Propulsion Division, and the Electric Power Research Institute. The ADL provides a common basis for battery performance characterization and life evaluations with unbiased application of tests and analyses. The results help identify the most-promising R D approaches for overcoming battery limitations, and provide battery users, developers, and program managers with a measure of the progress being made in battery R D programs, a comparison of battery technologies, and basic data for modeling.
Date: January 1, 1992
Creator: DeLuca, W. H.; Gillie, K. R.; Kulaga, J. E.; Smaga, J. A.; Tummillo, A. F. & Webster, C. E.
Partner: UNT Libraries Government Documents Department

Data base on batteries, power-conditioning equipment, and photovoltaic arrays. Final report

Description: The objective of this study was to compile an up-to-date comprehensive data base for research, design, and development of photovoltaic systems, primarily in the areas of applications and battery technology, and secondarily in the area of power conditioning and photovoltaic array technology. This volume contains the data base used to develop the end-use scenarios and identify the R and D needed for batteries to be used in photovoltaic power systems. In addition to its specific application to the present study, this data base is intended to provide state-of-the-art information to manufacturers of the various components of photovoltaic power systems, system designers, and researchers in this field. An extensive literature search was conducted to obtain technical data on batteries, power conditioners, and photovoltaic arrays. The data obtained from published technical literature and direct communication with manufacturers and developers are compiled. Principles of operation, types of systems, performance characteristics, test data, and cost data are included for each of the components. (WHK)
Date: February 1, 1981
Creator: Podder, A; Kapner, M & Morse, T
Partner: UNT Libraries Government Documents Department

Analysis of batteries for use in photovoltaic systems. Final report

Description: An evaluation of 11 types of secondary batteries for energy storage in photovoltaic electric power systems is given. The evaluation was based on six specific application scenarios which were selected to represent the diverse requirements of various photovoltaic systems. Electrical load characteristics and solar insulation data were first obtained for each application scenario. A computer-based simulation program, SOLSIM, was then developed to determine optimal sizes for battery, solar array, and power conditioning systems. Projected service lives and battery costs were used to estimate life-cycle costs for each candidate battery type. The evaluation considered battery life-cycle cost, safety and health effects associated with battery operation, and reliability/maintainability. The 11 battery types were: lead-acid, nickel-zinc, nickel-iron, nickel-hydrogen, lithium-iron sulfide, calcium-iron sulfide, sodium-sulfur, zinc-chlorine, zinc-bromine, Redox, and zinc-ferricyanide. The six application scenarios were: (1) a single-family house in Denver, Colorado (photovoltaic system connected to the utility line); (2) a remote village in equatorial Africa (stand-alone power system); (3) a dairy farm in Howard County, Maryland (onsite generator for backup power); (4) a 50,000 square foot office building in Washington, DC (onsite generator backup); (5) a community in central Arizona with a population of 10,000 (battery to be used for dedicated energy storage for a utility grid-connected photovoltaic power plant); and (6) a military field telephone office with a constant 300 W load (trailer-mounted auxiliary generator backup). Recommendations for a research and development program on battery energy storage for photovoltaic applications are given, and a discussion of electrical interfacing problems for utility line-connected photovoltaic power systems is included. (WHK)
Date: February 1, 1981
Creator: Podder, A & Kapner, M
Partner: UNT Libraries Government Documents Department