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Comparison of calculated and experimental results of fragmenting cylinder experiments

Description: The Grady-Kipp fragmentation model provides a physically based method for determining the fracture and breakup of materials under high loading rates. Recently, this model has been implemented into the CTH Shock Physics Code and has been used to simulate several published experiments. Materials studied in this paper are AerMet 100 steel and a 90% tungsten alloy. The experimental geometry consists of a right circular cylinder filled with an explosive main charge that is initiated at its center. The sudden expansion of the resulting detonation products causes fracture of the cylinder. Strain rates seen in the cylinder are on the order of 10{sup 4} s{sup {minus}1}. The average fragment sizes calculated with the Grady-Kipp fragmentation model successfully replicate the mean fragment size obtained from the experimental fragment distribution. When Poisson statistics are applied to the calculated local average fragment sizes, good correlation is also observed with the shape of the experimental cumulative fragment distribution. The experimental fragmentation results, CTH numerical simulations, and correlation of these numerical results with the experimental data are described.
Date: June 2, 2000
Partner: UNT Libraries Government Documents Department

A photon shield capsule design for an {sup 241}Am/Be ({alpha},n) source using high density tungsten alloy

Description: A photon shield capsule made of high density tungsten alloy was designed for a 400 GBq {sup 241}Am/Be ({alpha},n) NIST-traceable source using Monte Carlo calculations. The {sup 241}Am/Be ({alpha},n) source replaces a {sup 239}Pu/Be ({alpha},n) source used in the Los Alamos Neutron Well for dose rate calibrations of portable and fixed neutron rem meters. Potential operator exposure due to {sup 241}Am photon emission (E{sub {gamma}} = 59.5 keV, Y{sub {gamma}} = 0.357 {gamma} d{sup -1}) is a major practical concern in using this type of source. This has been recognized by the International Organization for Standardization (ISO 8529:1989), which recommends wrapping the source in a 1 mm thick lead shield. However, the optimum photon shield capsule design depends on source construction and other considerations. These considerations include minimizing source spectrum degradation and inelastic gamma production from shielding, structural integrity, toxicity, and cost effectiveness of available materials and construction. Investigations of several materials and combinations using stainless steel, high density tungsten alloy (composed of 90%W, 6% Ni and 4% Cu) and lead with various capsule thicknesses were simulated using the Los Alamos Monte Carlo N-Particle Transport Code. The final design was based on a 2 mm thick capsule using the high density tungsten alloy. This material resulted in a small change in the neutron spectrum accompanied with only a slight increase in inelastic gamma production, and unobservable 59.5 keV photon emissions compared to the bare {sup 241}Am/Be ({alpha},n) source.
Date: January 1, 1997
Creator: Clement, R.S.; Hsu, H.H.; Olsher, R.S. & Aikin, D.J.
Partner: UNT Libraries Government Documents Department

Directed light fabrication of refractory metals and alloys

Description: This report covers deposition of refractory pure metals and alloys using the Directed Light Fabrication (DLF) process and represents progress in depositing these materials through September 1998. In extending the DLF process technology to refractory metals for producing fully dense, structurally sound deposits, several problems have become evident. (1) Control of porosity in DLF-deposited refractory metal is difficult because of gases, apparently present in commercially purchased refractory metal powder starting materials. (2) The radiant heat from the molten pool during deposition melts the DLF powder feed nozzle. (3) The high reflectivity of molten refractory metals, at the Nd-YAG laser wavelength (1.06{micro}m), produces damaging back reflections to the optical train and fiber optic delivery system that can terminate DLF processing. (4) The current limits on the maximum available laser power to prevent back reflection damage limit the parameter range available for densification of refractory metals. The work to date concentrated on niobium, W-25Re, and spherodized tungsten. Niobium samples, made from hydride-dehydride powder, had minimal gas porosity and the deposition parameters were optimized; however, test plates were not made at this time. W-25Re samples, containing sodium and potassium from a precipitation process, were made and porosity was a problem for all samples although minimized with some process parameters. Deposits made from potassium reduced tungsten that was plasma spherodized were made with minimized porosity. Results of this work indicate that further gas analysis of starting powders and de-gassing of starting powders and/or gas removal during deposition of refractory metals is required.
Date: May 30, 1999
Creator: Fonseca, J.C.; Lewis, G.K.; Dickerson, P.G. & Nemec, R.B.
Partner: UNT Libraries Government Documents Department

Alternative processing methods for tungsten-base composite materials

Description: Tungsten composite materials contain large amounts of tungsten distributed in a continuous matrix phase. Current commercial materials include the tungsten-nickel-iron with cobalt replacing some or all of the iron, and also tungsten-copper materials. Typically, these are fabricated by liquid-phase sintering of blended powders. Liquid-phase sintering offers the advantages of low processing costs, established technology, and generally attractive mechanical properties. However, liquid-phase sintering is restricted to a very limited number of matrix alloying elements and a limited range of tungsten and alloying compositions. In the past few years, there has been interest in a wider range of matrix materials that offer the potential for superior composite properties. These must be processed by solid-state processes and at sufficiently low temperatures to avoid undesired reactions between the tungsten and the matrix phase. These processes, in order of decreasing process temperature requirements, include hot-isostatic pressing (HIPing), hot extrusion, and dynamic compaction. The HIPing and hot extrusion processes have also been used to improve mechanical properties of conventional liquid-phase-sintered materials. Results of laboratory-scale investigations of solid-state consolidation of a variety of matrix materials, including titanium, hafnium, nickel aluminide, and steels are reviewed. The potential advantages and disadvantages of each of the possible alternative consolidation processes are identified. Postconsolidation processing to control microstructure and macrostructure is discussed, including novel methods of controlling microstructure alignment.
Date: December 31, 1995
Creator: Ohriner, E.K. & Sikka, V.K.
Partner: UNT Libraries Government Documents Department

Chemical vapor deposition of refractory ternary nitrides for advanced diffusion barriers

Description: Refractory ternary nitride films for diffusion barriers in microelectronics have been grown using chemical vapor deposition. Thin films of titanium-silicon-nitride, tungsten-boron-nitride, and tungsten-silicon-nitride of various compositions have been deposited on 150 mm Si wafers. The microstructure of the films are either fully amorphous for the tungsten based films, or nauocrystalline TiN in an amorphous matrix for titanium-silicon-nitride. All films exhibit step coverages suitable for use in future microelectronics generations. Selected films have been tested as diffusion barriers between copper and silicon, and generally perform extremely weH. These fiIms are promising candidates for advanced diffusion barriers for microelectronics applications. The manufacturing of silicon wafers into integrated circuits uses many different process and materials. The manufacturing process is usually divided into two parts: the front end of line (FEOL) and the back end of line (BEOL). In the FEOL the individual transistors that are the heart of an integrated circuit are made on the silicon wafer. The responsibility of the BEOL is to wire all the transistors together to make a complete circuit. The transistors are fabricated in the silicon itself. The wiring is made out of metal, currently aluminum and tungsten, insulated by silicon dioxide, see Figure 1. Unfortunately, silicon will diffuse into aluminum, causing aluminum spiking of junctions, killing transistors. Similarly, during chemical vapor deposition (CVD) of tungsten from ~fj, the reactivity of the fluorine can cause "worn-holes" in the silicon, also destroying transistors. The solution to these problems is a so-called diffusion barrier, which will allow current to pass from the transistors to the wiring, but will prevent reactions between silicon and the metal.
Date: September 22, 1998
Creator: Custer, Jonathan S.; Fleming, James G.; Roherty-Osmun, Elizabeth & Smith, Paul Martin
Partner: UNT Libraries Government Documents Department

Bend Ductility of Tungsten Heavy Alloys

Description: A bend ductility test is used to indicate the formability of tungsten heavy alloys sheet. The primary test bends a notchless Charpy impact specimen to a bend angle of approximately 100C. This can be augmented by a bend-completion test. Finite element modeling as well as strain-gaged bend specimens elucidate the strain distribution in the specimen as a function of material thickness and bend angle. The bend ductilities of 70%W, 807.W and 90%W alloys are characterized. As expected, decreasing thickness or tungsten content enhances bend ductility. Oxidation is not detrimental; therefore, controlled atmosphere is not required for cooling. The potentially detrimental effects of mechanical working (e.g., rolling, roller-leveling, grit blasting, and peening) and machining (e.g., cutting and sanding) are illustrated.
Date: November 1992
Creator: Gurwell, W. E.; Garnich, M. R.; Dudder, G. B. & Lavender, C. A.
Partner: UNT Libraries Government Documents Department

LCLS Heavy Met Outgassing Tests

Description: A Heavy Met that is 95% tungsten, 3% nickel and 2% iron and sintered to 100% density and is Ultra High Vacuum (UHV) compatible is proposed for use as the X-ray slit in the Front End Enclosure and the Fixed Mask for the Linac Coherent Light Source (LCLS). The Heavy Met was tested in the LLNL Vacuum Sciences and Engineering Lab (VSEL) to determine its outgassing rate and its overall compatibility with the vacuum requirements for LCLS.
Date: December 1, 2010
Creator: Kishiyama, K. I.
Partner: UNT Libraries Government Documents Department

High temperature materials technology research for advanced thermionic systems. Quarterly progress report, October 1, 1993--December 31, 1993

Description: The effort was concentrated on two aspects of modeling of deformation in refractory alloy single crystals: deformation map in a tube with a [111] axial orientation and creep retardation due to solution strengthening (both effects are important in bcc single crystalline refractory alloys for high temperature emitters). Lattice misfit parameters are given between tungsten and 3 solutes (Re, Nb, Hf). 3 figs, 10 refs, 1 tab.
Date: December 31, 1993
Creator: Zee, R. H. & Rose, M. F.
Partner: UNT Libraries Government Documents Department

Fracture behavior of W based materials. Final report

Description: This report describes the results of a program to investigate the fracture properties of tungsten based materials. In particular, the role of crack velocity on crack instability was determined in a W-Fe-Ni-Co ``heavy alloy`` and pure polycrystalline tungsten. A considerable effort was expended on the development of an appropriate crack velocity gage for use on these materials. Having succeeded in that, the gage technology was employed to determine the crack velocity response to the applied level of stress intensity factor at the onset of crack instability in pre-cracked specimens. The results were also correlated to the failure mode observed in two material systems of interest. Major results include: (1) unstable crack velocity measurements on metallic specimens which require high spatial resolution require the use of brittle, insulating substrates, as opposed to the ductile, polymer based substrates employed in low spatial resolution measurements; and (2) brittle failure modes, such as cleavage, are characterized by relatively slow unstable crack velocities while evidence of high degrees of deformation are associated with failures which proceed at high unstable crack velocities. This latter behavior is consistent with the predictions of the modeling of Hack et al and may have a significant impact on the interpretation of fractographs in general.
Date: September 30, 1991
Creator: Hack, J. E.
Partner: UNT Libraries Government Documents Department

High-density metals and metallic composites for improved fragmentation submunitions

Description: The fragmentation of cases (50.8-mm-id) made of tungsten, a tungsten alloy, and depleted uranium (D-38) can be controlled, and velocities greater than 1 mm/$mu$s can be achieved for lethal size fragment weights. Fragmentation was controlled by internal grooves, by internal screens, and by a spheroid-in-weak- matrix scheme. A thin polymer liner was used inside of a grooved tungsten case in one experiment; this system performed exceptionally well. The ease of fabricating cases with D-38 or with the tungsten-alloy spheroid-in-matrix scheme offers an attractive advantage over tungsten and tungsten alloy.
Date: August 1975
Creator: Craig, B. G.; Honnell, R. E.; Lederman, G. F., Jr. & Sandstrom, D. J.
Partner: UNT Libraries Government Documents Department

Design analysis of a composite L5-80 slit for x-ray beamlines at the Advanced Photon Source

Description: White-beam slits are precision high-heat-load devices used on beamlines of the Advanced Photon Source (APS) to trim and shape the incoming x-rays beam before the beam is transmitted to other optical components. At the APS, the insertion devices that generate the x-ray are very powerful. For example, the heat flux associated with an x- ray beam generated by Undulator A will be on the order of 207 W/mm{sup 2} at the L5-80 slit location (about 27.5 m away from the insertion device) at normal incidence. The total power is about 5.3 kW. The optical slits with micron-level precision are very challenging to design under such heat flux and total power considerations. A novel three-metal composite slit has been designed to meet the diverse thermal, structural, and precision requirements. A closed form solution, and a commercial code, ANSYS, have been used for the analysis of the optimized design for the slit set.
Date: December 31, 1996
Creator: Nian, H.L.T.; Kuzay, T.M. & Shu, D.
Partner: UNT Libraries Government Documents Department

0.5 μm E/D AlGaAs/GaAs heterostructure field effect transistor technology with DFET threshold adjust implant

Description: A doped-channel heterostructure field effect transistor (H-FET) technology has been developed with self-aligned refractory gate processing and using both enhancement- and depletion-mode transistors. D-HFET devices are obtained with a threshold voltage adjust implant into material designed for E-HFET operation. Both E- and D-HFETs utilize W/WSi bilayer gates, sidewall spacers, and rapid thermal annealing for controlling short channel effects. The 0.5 {mu}m E- HFETs (D-HFETs) have been demonstrated with transconductance of 425 mS/mm (265-310 mS/mm) and f{sub t} of 45-50 GHz. Ring oscillator gate delays of 19 ps with a power of 0.6 mW have been demonstrated using direct coupled FET logic. These results are comparable to previous doped-channel HFET devices and circuits fabricated by selective reactive ion etching rather than ion implantation for threshold voltage adjustment.
Date: April 1997
Creator: Baca, A. G.; Sherwin, M. E.; Zolper, J. C.; Shul, R. J.; Briggs, R. D.; Heise, J. A. et al.
Partner: UNT Libraries Government Documents Department

Simulation of armor penetration by tungsten rods: ALEGRA validation report

Description: Results from simulations of the impact and penetration of tungsten alloy rods into thick rolled armor plates are presented. The calculations were performed with the CTH and ALEGRA computer codes using the DOE massively parallel TFLOPS computer co-developed by Sandia National Laboratory and Intel Corporation. Comparisons with experimental results are presented. Agreement of the two codes with each other and with the empirical results for penetration channel depth and radius is very close. Other shock physics and penetration features are also compared to simulation results.
Date: November 1, 1997
Creator: Carroll, D.E.; Hertel, E.S. Jr. & Trucano, T.G.
Partner: UNT Libraries Government Documents Department

High temperature materials technology research for advanced thermionic systems. Quarterly progress report, March 1, 1995--June 30, 1995

Description: The concept of shift factor was used successfully to develop a model which described the role of solid solution atoms in dispersion strengthened tungsten alloys. This shift factor separates the solid solution strengthening effect of Re in the creep of W-Re-HfC materials. The creep of the alloys is expressed by the modified Lagneborg`s creep model in the following form: {dot {var_epsilon}} = A`(b/G{sup 3}kT)D{sub L}exp({minus} 580000eC{sup 1/2}/T)({sigma} {minus}{sigma}{sub p}){sup 4} (1955 K{le}T{le}2500 K), where D{sub L} is the lattice diffusion coefficient of tungsten.
Date: December 1, 1995
Creator: Zee, R.H. & Rose, M.F.
Partner: UNT Libraries Government Documents Department

Proceedings of the Tungsten Workshop for Hard Target Weapons Program

Description: The purpose of this meeting was to review and exchange information and provide technical input for improving technologies relevant to the Hard Target Weapons Program. This workshop was attended by representatives from 17 organizations, including 4 Department of Defense (DoD) agencies, 8 industrial companies, and 5 laboratories within DOE. Hard targets are defined as reinforced underground structures that house enemy forces, weapon systems, and support equipment. DOE-ORO and Martin Marietta Energy Systems, Inc. (Energy Systems) have been involved in advanced materials research and development (R&D) for several DOE and DoD programs. These programs are conducted in close collaboration with Eglin AFB, Department of the Army`s Picatinny Arsenal, and other DoD agencies. As part of this ongoing collaboration, Eglin AFB and Oak Ridge National Laboratory planned and conducted this workshop to support the Hard Target Weapons Program. The objectives of this workshop were to (1) review and identify the technology base that exists (primarily due to anti-armor applications) and assess the applicability of this technology to the Hard Target Weapons Program requirements; (2) determine future directions to establish the W materials, processing, and manufacturing technologies suitable for use in fixed, hard target penetrators; and (3) identify and prioritize the potential areas for technical collaboration among the participants.
Date: June 1, 1995
Creator: Mackiewicz-Ludtka, G.; Hayden, H.W. & Davis, R.M.
Partner: UNT Libraries Government Documents Department

Liquid-metal embrittlement of refractory metals by molten plutonium

Description: Embrittlement by molten plutonium of the refractory metals and alloys W-25 wt % Re, tantalum, molybdenum, and Ta-10 wt % W was studied. At 900/sup 0/C and a strain rate of 10/sup -4/ s/sup -1/, the materials tested may be ranked in order of decreasing susceptibility to liquid-plutonium embrittlement as follows: molybdenum, W-25 wt % Re, Ta-10 wt % W, and tantalum. These materials exhibited a wide range in susceptibility. Embrittlement was found to exhibit a high degree of temperature and strain-rate dependence, and we present arguments that strongly support a stress-assisted, intergranular, liquid-metal corrosion mechanism. We also believe microstructure plays a key role in the extent of embrittlement. In the case of W-25 wt % Re, we have determined that a dealloying corrosion takes place in which rhenium is selectively withdrawn from the alloy.
Date: July 1, 1980
Creator: Lesuer, D.R.; Bergin, J.B.; McInturff, S.A. & Kuhn, B.A.
Partner: UNT Libraries Government Documents Department

Evaluation of the feasibility of joining titanium alloy to heavymet tungsten alloy

Description: Information is presented on a program to select and evaluate methods of brazing and/or explosively welding Ti-6Al-4V titanium alloy to Heavymet, a tungsten-base metal containing up to about 20% alloying elements (nickel, copper, etc.) to improve its ductility and other mechanical properties. Designs permitting the reliable production of joints between these base metals were of interest too. While this investigation was primarily concerned with an engineering study of the problems associated with joining these base metals in the required configuration, limited experimental studies were conducted also. The joining methods are reviewed individually. Recommendations for developing a viable titanium-tungsten joining procedure are discussed.
Date: June 7, 1978
Partner: UNT Libraries Government Documents Department

A study of the electrochemical behavior in tungsten and caustic solutions and platinum/iridium in chloride solutions, informal report

Description: Platinum/iridium and tungsten wires were electronically etched in chloride and caustic solution, respectively, to produce tips with high aspect ratio. A direct relationship between the meniscus and the aspect ratio of etched tips was established. Scanning electron micrographs indicated that higher aspect ratios were obtained by changing the geometry of the meniscus during the etch either by an increase in the applied a.c. voltage or with the addition of a nonpolar layer above the electrolytic solution during the etching process. Above the breakdown voltage, two possible mechanisms appeared to control the etching process by expediting chemical dissolution: cavitation and sparking. Cavitation caused erosion due to the force of evolved gases against the electrode and sparking attacked the surface by vaporizing the metal. Sparking commenced on both wires near 24V. This voltage corresponded to a minimum in the plot of total etch time versus voltage. From light emission studies, sparking on Pt/Ir was associated with the ionization of Pt, Ir, Ca, and Cl. A compositional analysis of insoluble black particles produced during a.c. and d.c. etching of Pt/Ir revealed Pt and Ir as the major constituents of the product. The sparking process was shown to have a potential use in micromachining.
Date: November 22, 1994
Creator: Vitus, C. M.; Isaacs, H. S. & Schroeder, V.
Partner: UNT Libraries Government Documents Department