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Preliminary Thermal Modeling of HI-Storm 100S-218 Version B Storage Modules at Hope Creek Cuclear Power Station ISFSI

Description: As part of the Used Fuel Disposition Campaign of the U. S. Department of Energy, Office of Nuclear Energy (DOE-NE) Fuel Cycle Research and Development, a consortium of national laboratories and industry is performing visual inspections and temperature measurements of selected storage modules at various locations around the United States. This report documents thermal analyses in in support of the inspections at the Hope Creek Nuclear Generating Station ISFSI. This site utilizes the HI-STORM100 vertical storage system developed by Holtec International. This is a vertical storage module design, and the thermal models are being developed using COBRA-SFS (Michener, et al., 1987), a code developed by PNNL for thermal-hydraulic analyses of multi assembly spent fuel storage and transportation systems. This report describes the COBRA-SFS model in detail, and presents pre-inspection predictions of component temperatures and temperature distributions. The final report will include evaluation of inspection results, and if required, additional post-test calculations, with appropriate discussion of results.
Date: August 30, 2013
Creator: Cuta, Judith M. & Adkins, Harold E.
Partner: UNT Libraries Government Documents Department

Parametric Thermal Analysis for Codisposal Waste Package Canister

Description: The engineering viability of disposal of aluminum-clad, aluminum-based spent nuclear fuel (Al-SNF) in a geologic repository requires a thermal analysis to provide the temperature history of the waste form. Calculated temperatures are used to demonstrate compliance with criteria for waste acceptance into the Mined Geologic Disposal System and as input to assess the chemical and physical behavior of the waste form within the waste package (WP).A thermal analysis methodology was developed to calculate peak temperatures and temperature profiles of Al-SNF in the DOE spent nuclear fuel canister within a codisposal WP. A two-dimensional baseline model with conduction and radiation coupled heat transport was developed to evaluate the thermal performance of Al-SNF directly stored in a canister in a codisposal WP over the range of possible heat loads and boundary conditions. In addition, a conduction model and a detailed model which includes convection were developed to identify the dominant cooling mechanism under the present WP configuration, to investigate physical cooling mechanism in detail, and to estimate the conservatism imbedded in the baseline model.The results of the baseline model showed that the direct disposal configuration with a helium-filled WP satisfied the present waste acceptance criteria (WAC) for the WP design in terms of the peak temperature criterion, Tmax {lt} 350 degrees C, under the reference boundary conditions. A period of 10 years` cooling time for the decay heat loads of the SNF and the High-level Waste Glass Log (HWGL) regions was used as one of the reference design conditions.
Date: September 1, 1998
Creator: Lee, S.Y. & Sindelar, R.L.
Partner: UNT Libraries Government Documents Department

W-320 Project thermal modeling

Description: This report summarizes the results of thermal analysis performed to provide a technical basis in support of Project W-320 to retrieve by sluicing the sludge in Tank 241-C-106 and to transfer into Tank 241-AY-102. Prior theraml evaluations in support of Project W-320 safety analysis assumed the availability of 2000 to 3000 CFM, as provided by Tank Farm Operations, for tank floor cooling channels from the secondary ventilation system. As this flow availability has no technical basis, a detailed Tank 241-AY-102 secondary ventilation and floor coating channel flow model was developed and analysis was performed. The results of the analysis show that only about 150 cfm flow is in floor cooLing channels. Tank 241-AY-102 thermal evaluation was performed to determine the necessary cooling flow for floor cooling channels using W-030 primary ventilation system for different quantities of Tank 241-C-106 sludge transfer into Tank 241-AY-102. These sludge transfers meet different options for the project along with minimum required modification of the ventilation system. Also the results of analysis for the amount of sludge transfer using the current system is presented. The effect of sludge fluffing factor, heat generation rate and its distribution between supernatant and sludge in Tank 241-AY-102 on the amount of sludge transfer from Tank 241-C-106 were evaluated and the results are discussed. Also transient thermal analysis was performed to estimate the time to reach the steady state. For a 2 feet sludge transfer, about 3 months time will be requirad to reach steady state. Therefore, for the purpose of process control, a detailed transient thermal analysis using GOTH Computer Code will be required to determine transient response of the sludge in Tank 241-AY-102. Process control considerations are also discussed to eliminate the potential for a steam bump during retrieval and storage in Tanks 241-C-106 and 241-AY-102 respectively.
Date: March 18, 1997
Creator: Sathyanarayana, K.
Partner: UNT Libraries Government Documents Department

Finite element thermal analysis of 155-mm projectile exudtion inside a hot gun tube.

Description: The high firing rates of new and developing cannons create higher operating temperatures than projectiles experience. Higher temperatures in-bore bring the possibility of high explosive exudation from chambered shells during misfire, hang-fire, or hold-fire. The development of a finite element thermal model to predict high explosive exudation inside a hot gun tube brings an improved level of insight to existing physical test results. The MI98 towed howitzer and M107 155-mm shell are modeled to compare to physical test results from Morales 1997 and Zimmerman 1980. During creation of the model special focus is taken to simulate the heat flow between the contact of the rotating band and cannon wall. A strong correlation between test results and model is seen with both reports and validates the model setup. Model results suggest that time to exudation predicted by Morales and Zimmerman may be too conservative.
Date: May 1, 2003
Creator: Kan, Yih-Renn & Shelton, Timothy R.
Partner: UNT Libraries Government Documents Department


Description: The 3013 containers are designed in accordance with the DOE-STD-3013-2004 and are qualified to store plutonium (Pu) bearing materials for 50 years. The U.S. Department of Energy (DOE) certified Model 9975 shipping package is used to transport the 3013 containers to the K-Area Material Storage (KAMS) facility at the Savannah River Site (SRS) and to store the containers until the plutonium can be properly dispositioned. Detailed thermal analyses to support the storage in the KAMS facility are given in References 2, 3, and 4. The analyses in this paper serve to provide non-accident condition, non-bounding, specific 3013 container temperatures for use in the surveillance activities. This paper presents a methodology where critical component temperatures are estimated using numerical methods over a range of package and storage parameters. The analyses include factors such as ambient storage temperature and the content weight, density, heat generation rate, and fill height, that may impact the thermal response of the packages. Statistical methods are used to develop algebraic equations for ease of computations to cover the factor space. All computations were performed in BTU-FT-Hr-{sup o}F units.
Date: November 10, 2009
Creator: Gupta, N.
Partner: UNT Libraries Government Documents Department


Description: The work reported here is an investigation of the sensitivity of component temperatures of a storage system, including fuel cladding temperatures, in response to age-related changes that could degrade the design-basis thermal behavior of the system. Three specific areas of interest were identified for this study. • degradation of the canister backfill gas from pure helium to a mixture of air and helium, resulting from postulated leakage due to stress corrosion cracking (SCC) of canister welds • changes in surface emissivity of system components, resulting from corrosion or other aging mechanisms, which could cause potentially significant changes in temperatures and temperature distributions, due to the effect on thermal radiation exchange between components • changes in fuel and basket temperatures due to changes in fuel assembly position within the basket cells in the canister The purpose of these sensitivity studies is to provide a realistic example of how changes in the physical properties or configuration of the storage system components can affect temperatures and temperature distributions. The magnitudes of these sensitivities can provide guidance for identifying appropriate modeling assumptions for thermal evaluations extending long term storage out beyond 50, 100, 200, and 300 years.
Date: August 15, 2013
Creator: Cuta, Judith M.; Suffield, Sarah R.; Fort, James A. & Adkins, Harold E.
Partner: UNT Libraries Government Documents Department

Comparison of buffered chemical polished and electropolished 3.9 GHz cavities

Description: Five 3.9 GHz 9 cell cavities have been measured for the DESY FLASH module. These cavities were BCP processed and reached gradients of typically about 25 MV/m with Q drop starting at about 20 MV/m. Recently a few one cell cavities have been processed with EP and at least one has tested to a gradient of 30 MV/m with Q drop starting at about 25 MV/m. We will compare the results and give an update to the thermal analysis in relation to global thermal breakdown at 3.9 GHz.
Date: October 1, 2009
Creator: Edwards, Helen; Cooper, Charlie A.; Ge, Mingqi; Gonin, Ivan V.; Harms, Elvin R.; Khabiboulline, Timergali N. et al.
Partner: UNT Libraries Government Documents Department

Thermal analysis of SC quadrupoles in accelerator interaction regions

Description: This paper presents results of a thermal analysis and operation margin calculation performed for NbTi and Nb{sub 3}Sn low-beta quadrupoles in collider interaction regions. Results of the thermal analysis for NbTi quadrupoles are compared with the relevant experimental data. An approach to quench limit measurements for Nb{sub 3}Sn quadrupoles is discussed.
Date: September 1, 2006
Creator: Novitski, Igor & Zlobin, Alexander V.
Partner: UNT Libraries Government Documents Department

Thermal rocketing and the Laser Geodynamic Satellite (LAGEOS-1)

Description: This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory. LAGEOS is the most accurately tracked satellite in orbit. It is a totally passive, dense spherical satellite covered with 426 cube corner reflectors. Besides its great utility in measuring the Earth`s length of day and polar wobble, this satellite can be used to measure, for the first time, the general relativistic frame-dragging effect. Of the five dominant error sources in such an experiment, the largest one involves surface interaction of thermal forces (thermal rocketing) and its influence on the orbital nodal precession. The project objective was to enhance an already available theoretical model (computer code) developed at Los Alamos based on new optical-spin data obtained at the University of Maryland. The project objective was met and the enhanced code will serve as the new spin-dynamics model for future LAGEOS satellite missions.
Date: August 1, 1997
Creator: Miller, W.A.
Partner: UNT Libraries Government Documents Department

Computational studies of the potential energy surface for O(¹D) + H₂S: Characterization of pathways involving H₂SO, HOSH, and H₂OS

Description: Article on computational studies of the potential energy surface for O(¹D) + H₂S and the characterization of pathways involving H₂SO, HOSH, and H₂OS.
Date: December 1, 1994
Creator: Goumri, Abdellatif; Rocha, John-David Ray; Laakso, Dianna; Smith, C. E. & Marshall, Paul
Partner: UNT College of Arts and Sciences

Constraining hydrologic models using thermal analysis

Description: Starting with regional geographic, geologic, hydrologic, geophysical, and meteorological data for the Tono area in Gifu, Japan, we develop a numerical model to simulate subsurface flow and transport in a 4 km by 6 km by 3 km thick fractured granite rock mass overlain by sedimentary layers. Individual fractures are not modeled explicitly. Rather, continuum permeability and porosity distributions are assigned stochastically, based on well-test data and fracture density measurements. The primary goal of the study is to simulate steady-state groundwater flow through the site, then calculate travel times to the model boundaries from specified monitoring points. The lateral boundaries of the model follow topographic features such as ridgelines and rivers. Assigning lateral boundary conditions is a major point of uncertainty in model construction. We evaluate two models with opposing boundary conditions: mostly closed and mostly open boundaries. The two models show vastly different spatial distributions of groundwater flow, so we would like to find a means of choosing the more realistic model. Surface recharge is much larger for the closed model, but field recharge data are of too limited spatial extent to provide a definitive model constraint. Temperature profiles in 16 boreholes show consistent trends with conduction-dominated (linear) temperature profiles below depths of about 300 m. The open and closed models predict strongly different temperature versus depth profiles; with the closed model showing a strong convective signature produced by widespread surface recharge effects to the depth. The open model shows more linear temperature profiles, better agreeing with measurements from the field. Based on this data we can eliminate from consideration the closed model, at least in its present form in which surface recharge penetrates deep into the model.
Date: December 12, 2002
Creator: Doughty, Christine & Karasaki, Kenzi
Partner: UNT Libraries Government Documents Department

Uncertainty analysis of thermocouple measurements used in normal and abnormal thermal environment experiments at Sandia's Radiant Heat Facility and Lurance Canyon Burn Site.

Description: It would not be possible to confidently qualify weapon systems performance or validate computer codes without knowing the uncertainty of the experimental data used. This report provides uncertainty estimates associated with thermocouple data for temperature measurements from two of Sandia's large-scale thermal facilities. These two facilities (the Radiant Heat Facility (RHF) and the Lurance Canyon Burn Site (LCBS)) routinely gather data from normal and abnormal thermal environment experiments. They are managed by Fire Science & Technology Department 09132. Uncertainty analyses were performed for several thermocouple (TC) data acquisition systems (DASs) used at the RHF and LCBS. These analyses apply to Type K, chromel-alumel thermocouples of various types: fiberglass sheathed TC wire, mineral-insulated, metal-sheathed (MIMS) TC assemblies, and are easily extended to other TC materials (e.g., copper-constantan). Several DASs were analyzed: (1) A Hewlett-Packard (HP) 3852A system, and (2) several National Instrument (NI) systems. The uncertainty analyses were performed on the entire system from the TC to the DAS output file. Uncertainty sources include TC mounting errors, ANSI standard calibration uncertainty for Type K TC wire, potential errors due to temperature gradients inside connectors, extension wire uncertainty, DAS hardware uncertainties including noise, common mode rejection ratio, digital voltmeter accuracy, mV to temperature conversion, analog to digital conversion, and other possible sources. Typical results for 'normal' environments (e.g., maximum of 300-400 K) showed the total uncertainty to be about {+-}1% of the reading in absolute temperature. In high temperature or high heat flux ('abnormal') thermal environments, total uncertainties range up to {+-}2-3% of the reading (maximum of 1300 K). The higher uncertainties in abnormal thermal environments are caused by increased errors due to the effects of imperfect TC attachment to the test item. 'Best practices' are provided in Section 9 to help the user to obtain the best measurements possible.
Date: April 1, 2004
Creator: Nakos, James Thomas
Partner: UNT Libraries Government Documents Department

Vapor-liquid phase behavior of the iodine-sulfur water-splitting process : LDRD final report for FY03.

Description: This report summarizes the results of a one-year LDRD project that was undertaken to better understand the equilibrium behavior of the iodine-water-hydriodic acid system at elevated temperature and pressure. We attempted to extend the phase equilibrium database for this system in order to facilitate development of the iodine-sulfur water-splitting process to produce hydrogen to a commercial scale. The iodine-sulfur cycle for thermochemical splitting of water is recognized as the most efficient such process and is particularly well suited to coupling to a high-temperature source of process heat. This study intended to combine experimental measurements of vapor-liquid-liquid equilibrium and equation-of-state modeling of equilibrium solutions using Sandia's Chernkin software. Vapor-liquid equilibrium experiments were conducted to a limited extent. The Liquid Chernkin software that was developed as part of an earlier LDRD project was enhanced and applied to model the non-ideal behavior of the liquid phases.
Date: January 1, 2004
Creator: Bradshaw, Robert W.; Larson, Richard S. & Lutz, Andrew E.
Partner: UNT Libraries Government Documents Department

Validation and uncertainty quantification of Fuego simulations of calorimeter heating in a wind-driven hydrocarbon pool fire.

Description: The objective of this work is to perform an uncertainty quantification (UQ) and model validation analysis of simulations of tests in the cross-wind test facility (XTF) at Sandia National Laboratories. In these tests, a calorimeter was subjected to a fire and the thermal response was measured via thermocouples. The UQ and validation analysis pertains to the experimental and predicted thermal response of the calorimeter. The calculations were performed using Sierra/Fuego/Syrinx/Calore, an Advanced Simulation and Computing (ASC) code capable of predicting object thermal response to a fire environment. Based on the validation results at eight diversely representative TC locations on the calorimeter the predicted calorimeter temperatures effectively bound the experimental temperatures. This post-validates Sandia's first integrated use of fire modeling with thermal response modeling and associated uncertainty estimates in an abnormal-thermal QMU analysis.
Date: December 1, 2009
Creator: Domino, Stefan Paul; Figueroa, Victor G.; Romero, Vicente Jose; Glaze, David Jason; Sherman, Martin P. & Luketa-Hanlin, Anay Josephine
Partner: UNT Libraries Government Documents Department

Case study for model validation : assessing a model for thermal decomposition of polyurethane foam.

Description: A case study is reported to document the details of a validation process to assess the accuracy of a mathematical model to represent experiments involving thermal decomposition of polyurethane foam. The focus of the report is to work through a validation process. The process addresses the following activities. The intended application of mathematical model is discussed to better understand the pertinent parameter space. The parameter space of the validation experiments is mapped to the application parameter space. The mathematical models, computer code to solve the models and its (code) verification are presented. Experimental data from two activities are used to validate mathematical models. The first experiment assesses the chemistry model alone and the second experiment assesses the model of coupled chemistry, conduction, and enclosure radiation. The model results of both experimental activities are summarized and uncertainty of the model to represent each experimental activity is estimated. The comparison between the experiment data and model results is quantified with various metrics. After addressing these activities, an assessment of the process for the case study is given. Weaknesses in the process are discussed and lessons learned are summarized.
Date: October 1, 2004
Creator: Dowding, Kevin J.; Leslie, Ian H. (New Mexico State University, Las Cruces, NM); Hobbs, Michael L.; Rutherford, Brian Milne; Hills, Richard Guy (New Mexico State University, Las Cruces, NM) & Pilch, Martin M.
Partner: UNT Libraries Government Documents Department

An atlas of thermal data for biomass and other fuels

Description: Biomass is recognized as a major source of renewable energy. In order to convert biomass energy to more useful forms, it is necessary to have accurate scientific data on the thermal properties of biomass. This Atlas has been written to supply a uniform source of that information. In the last few decades Thermal analysis (TA) tools such as thermogravimetry, differential thermal analysis, thermo mechanical analysis, etc. have become more important. The data obtained from these techniques can provide useful information in terms of reaction mechanism, kinetic parameters, thermal stability, phase transformation, heat of reaction, etc. for gas-solid and gas-liquid systems. Unfortunately, there are no ASTM standards set for the collection of these types of data using TA techniques and therefore, different investigators use different conditions which suit their requirements for measuring this thermal data. As a result, the information obtained from different laboratories is not comparable. This Atlas provides the ability to compare new laboratory results with a wide variety of related data available in the literature and helps ensure consistency in using these data.
Date: June 1, 1995
Creator: Gaur, S. & Reed, T.B.
Partner: UNT Libraries Government Documents Department

Thermal-Structural Analysis of the MacArthur Maze Freeway Collapse

Description: At approximately 3:41 AM on the morning of April 29, 2007, a tractor-trailer rig carrying 8,600 gallons (32.6 m{sup 3}) of fuel overturned on Interstate 880 in Oakland, CA. The resultant fire weakened the surrounding steel superstructure and caused a 50-yard (45.7 m) long section of the above connecting ramp from Interstate 80 to Interstate 580 to fail in approximately 18 minutes. In this study, we performed a loosely-coupled thermal-structural finite element analysis of the freeway using the LLNL Engineering codes NIKE3D, DYNA3D and TOPAZ3D. First, we applied an implicit structural code to statically initialize the stresses and displacements in the roadway at ambient conditions due to gravity loading. Next, we performed a thermal analysis by approximating the tanker fire as a moving box region of uniform temperature. This approach allowed for feasible calculation of the fire-to-structure radiative view factors and convective heat transport. We used a mass scaling methodology in the thermal analysis to reduce the overall simulation time so an explicit structural analysis could be used, which provided a more computationally efficient simulation of structural failure. Our approach showed structural failure of both spans due to thermal softening under gravity loading at approximately 20 minutes for a fixed fire temperature of 1200 C and fixed thermal properties. When temperature-dependent thermal properties were applied, the south and north spans collapsed at approximately 10 minutes and 16 minutes, respectively. Finally, we performed a preliminary fully-coupled analysis of the system using the new LLNL implicit multi-mechanics code Diablo. Our investigation shows that our approach provides a reasonable first-order analysis of the system, but improved modeling of the transport properties and the girder-box beam connections is required for more accurate predictions.
Date: February 26, 2008
Creator: Noble, C. R.; Wemhoff, A. P. & McMichael, L. D.
Partner: UNT Libraries Government Documents Department

Studies of ionic liquids in lithium-ion battery test systems

Description: In this work, thermal and electrochemical properties of neat and mixed ionic liquid - lithium salt systems have been studied. The presence of a lithium salt causes both thermal and phase-behavior changes. Differential scanning calorimeter DSC and thermal gravimetric analysis TGA were used for thermal analysis for several imidazolium bis(trifluoromethylsulfonyl)imide, trifluoromethansulfonate, BF{sub 4}, and PF{sub 6} systems. Conductivities and diffusion coefficient have been measured for some selected systems. Chemical reactions in electrode - ionic liquid electrolyte interfaces were studied by interfacial impedance measurements. Lithium-lithium and lithium-carbon cells were studied at open circuit and a charged system. The ionic liquids studied include various imidazolium systems that are already known to be electrochemically unstable in the presence of lithium metal. In this work the development of interfacial resistance is shown in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell as well as results from some cycling experiments. As the ionic liquid reacts with the lithium electrode the interfacial resistance increases. The results show the magnitude of reactivity due to reduction of the ionic liquid electrolyte that eventually has a detrimental effect on battery performance.
Date: June 1, 2006
Creator: Salminen, Justin; Prausnitz, John M. & Newman, John
Partner: UNT Libraries Government Documents Department

Thermal Analysis of Irradiation Experiments in the ATR

Description: Reactor material testing in the INL's Advanced Test Reactor (ATR) involves modeling and simulation of each experiment to accurately determine the irradiation temperature. This paper describes thermal analysis of capsule experiments using gas gap temperature control and provides data on recent material tests that validate the modeling results. Static capsule experiments and lead-out capsule experiments are discussed. The source of temperature variation in capsule experiments and ways to mitigate these variations are also explained. Two examples of instrumented lead-out capsule experiments, TMIST-1 and UCSB-2, are presented. A comparison of measured and calculated temperatures is used to validate the thermal models and to ascertain the accuracy of the calculated temperature.
Date: September 1, 2012
Creator: Murray, Paul
Partner: UNT Libraries Government Documents Department