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State of the art of pressurized fluidized bed combustion systems

Description: This report was prepared at the request of the Tennessee Valley Authority (TVA) to clarify the development status of the pressurized fluidized bed combustor (PFBC) and to place in perspective the problems which are yet to be solved before commercialization of the concept is practical. This report, in essence, supersedes the interim report published in 1979, Assessment of the State of the Art of Pressurized Fluidized Bed Combustion Systems. A brief overview of the PFBC concept is included citing… more
Date: September 1, 1980
Creator: Graves, R.L.
Partner: UNT Libraries Government Documents Department
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Cadmium sulfide/copper sulfide heterojunction cell research. Final report, February 26, 1979-July 15, 1980

Description: Extensive modifications were made to the multi-source deposition apparatus. These include the installation of a larger vacuum chamber on the existing system. The new chamber provides improved inter-source shielding, an improved substrate mounting and heating system, and a vacuum interlock for introducing substrates. CdS resistivity control by both In doping and off-stoichiometric deposition has been investigated. Indium doping has been achieved both by diffusion from a pre-deposited In layer an… more
Date: June 30, 1980
Creator: Thornton, J. A. & Cornog, D. G.
Partner: UNT Libraries Government Documents Department
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Potential effects of maternal contribution on egg and larva population dynamics of striped bass: Integrated individual-based model and directed field sampling

Description: We have used a bioenergetically-driven, individual-based model (IBM) of striped bass as a framework for synthesizing available information on population biology and quantifying, in a relative sense, factors that potentially affect year class success. The IBM has been configured to simulate environmental conditions experienced by several striped bass populations; i.e., in the Potomac River, MD; in Hudson River, NY; in the Santee-Cooper River System, SC, and; in the San Joaquin-Sacramento River S… more
Date: January 1, 1991
Creator: Cowan, J.H., Jr. (Maryland Univ., Solomons, MD (United States). Chesapeake Biological Lab.) & Rose, K.A. (Oak Ridge National Lab., TN (United States))
Partner: UNT Libraries Government Documents Department
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Internal magnetic fields in hcp-iron

Description: The magnetic behavior of hcp-Fe (epsilon iron) has been investigated by the Moessbauer Effect over a wide range of temperature T, pressure P, and applied magnetic field H/sub 0/. The internal field H/sub i/ of the induced moment is given by H/sub i/ = 0.20 +- .01 H/sub 0/ and is independent of T and P. Enhanced paramagnetism is suggested as the most likely origin for a contribution of this magnitude to H/sub i/.
Date: January 1, 1982
Creator: Taylor, R. D.; Cort, G. & Willis, J. O.
Partner: UNT Libraries Government Documents Department
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Thermo-chemical energy conversion and storage. Final report

Description: Research support for the cyclohexane/benzene heat pipe development program at Sandia Laboratories is reported. The apparent kinetics of the gas-phase catalytic dehydrogenation of cyclohexane to benzene in an internally recirculated (gradientless) reactor over the temperature range from 500 to 800/sup 0/F at 1 atm at various space velocities was studied. A kinetic model was developed based on a reversible mass-action rate expression and a catalyst effectiveness factor which is able to correlate … more
Date: September 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Partner: UNT Libraries Government Documents Department
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Organic iodine removal from simulated dissolver off-gas streams using silver-exchanged mordenite

Description: The removal of methyl iodide by absorption onto silver mordenite was studied using a simulated off-gas from the fuel dissolution step of a nuclear fuel reprocessing plant. The methyl iodide absorption of silver mordenite was examined for the effects of NO/sub x/, humidity, iodine concentration, filter temperature, and filter pretreatment. The highest iodine loading achieved in these tests has been 34 mg CH/sub 3/I per g of substrate, approximately five times less than the elemental iodine loadi… more
Date: January 1, 1980
Creator: Jubin, R. T.
Partner: UNT Libraries Government Documents Department
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Thermodynamics of natural and industrial waters

Description: The most effective general formulations of thermodynamic equations for multicomponent aqueous solutions are discussed with respect to various ranges of temperature, pressure and composition with emphasis on solutes important in natural or industrial waters. A familiar equation in molality and in excess Gibbs energy is very successful up to 300{degree}C and ionic strength 6 mol{center dot}kg{sup {minus}1}, and can often be extended to 350{degree}C or above at high pressure and in favorable cases… more
Date: August 1, 1991
Creator: Pitzer, K.S.
Partner: UNT Libraries Government Documents Department
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Thermophysical properties of argon

Description: The entire report consists of tables of thermodynamic properties (including sound velocity, thermal conductivity and diffusivity, Prandtl number, density) of argon at 86 to 400/degree/K, in the form of isobars over 0.9 to 100 bars. (DLC)
Date: February 1, 1988
Creator: Jaques, A.
Partner: UNT Libraries Government Documents Department
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Feasibility Studies of in-Situ Coal Gasification in the Warrior Coal Field. Quarterly Report

Description: Studies in support of in-situ gasification involved experiments in bench-scale combustors where three parameters were varied independently: initial fuel bed temperature, applied air flow and water vapor influx rate. Methods for measuring the thermal conductivity of solids at high temperatures were evaluated and measurements of the thermal conductivity and thermal diffusivity were made over a temperature range for several samples of coke. (LTN)
Date: January 1, 1980
Creator: Douglas, George W. & McKinley, Marvin D.
Partner: UNT Libraries Government Documents Department
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Enthalpy measurement of coal-derived liquids. Combined quarterly technical progress reports, April-June 1979 and July-September 1979. [Effect of association]

Description: Enthalpy measurements on a coal-derived naphtha and middle distillate, both produced by the SRC-II process, were made using flow calorimetry. The accuracy of the measurements, as reported by Omid, was within +- 1% of the measured enthalpy differences, ..delta..H. Experimental data for the naphtha were obtained over a pressure range of 100-300 psia and temperatures from 148/sup 0/ to 456/sup 0/F. The middle distillate enthalpy measurements were made in the pressure and temperature ranges of 130 … more
Date: 1979~
Creator: Kidnay, A. J. & Yesavage, V. F.
Partner: UNT Libraries Government Documents Department
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Effects of catalytic mineral matter on CO/CO sub 2 , temperature and burning time for char combustion

Description: The temperature of a char particle burning in an oxygen containing atmosphere is the product of a strongly coupled balance between particle size and physical properties, heat transfer from the particle, surface reactivity, CO/CO{sub 2} ratio and gas phase diffusion in the surrounding boundary layer and within the particle. CO{sub 2}/CO ratios can be strongly influenced by catalytic material in the carbon and by the char temperature. In this program we are measuring the CO{sub 2}/CO ratio for bo… more
Date: May 4, 1992
Creator: Longwell, J. P.; Sarofim, A. F.; Lee, Chun-Hyuk & Modestino, A. J.
Partner: UNT Libraries Government Documents Department
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Molecular interactions in dilute supercritical mixtures: Molecular dynamics investigation

Description: We performed a series of molecular dynamics simulations aimed at investigating the nature of the microstructure around solute molecules in a supercritical solvent, in the limit of infinite dilution (no solute-solute interactions). The choice of model system (pyrene in supercritical carbon dioxide) and state conditions (5--20 moles/liter; 37{degrees}C and 75{degrees}C) was done so as to match corresponding fluorescence experiments performed at Georgia Tech. 18 refs., 3 figs.
Date: January 1, 1991
Creator: Debenedetti, P.G.
Partner: UNT Libraries Government Documents Department
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Low strain diameter expansion of internally pressurized Zircaloy-4 tubing at high temperatures

Description: Tests of closed-end, internally pressurized, Zircaloy-4 tubing specimens were utilized to develop low strain creep characteristics as a function of time at temperatures in the range of 1475/sup 0/F to 2000/sup 0/F (802/sup 0/C to 1093/sup 0/C) and hoop stresses in the range of 250 to 2500 psi for use in loss-of-coolant accident (LOCA) analyses. The strain rate above the start of the alpha to beta phase transformation region, approximately 1490/sup 0/F (810/sup 0/C), was found to be sensitive to… more
Date: March 1978
Creator: White, L.S. & Busby, C.C.
Partner: UNT Libraries Government Documents Department
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Mechanical strength and stability of lithium aluminate

Description: Pacific Northwest Laboratory (PNL) investigated the strength and resistance to thermal shock of lithium aluminate annular pellets. The room temperature, axial compressive fracture strength of pellets made at Westinghouse Advanced Energy Systems (WAES) varied from 80 to 133 ksi. The strength at 430{degrees}C (806{degrees}F) was to 30 to 40% lower. The strength at 900{degrees}C (1652{degrees}F) showed a wide variation with one measurement near 90 ksi. These strength values are consistent with oth… more
Date: June 1, 1992
Creator: Brimhall, J.L.
Partner: UNT Libraries Government Documents Department
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Research on oil recovery mechanisms in heavy oil reservoirs

Description: The goal of the Stanford University Petroleum Research Institute is to conduct research directed toward increasing the recovery of heavy oils. Presently, SUPRI is working in five main directions: To assess the influence of different reservoir conditions (temperature and pressure) on the absolute and relative permeability to oil and water and on capillary pressure; To evaluate the effect of different reservoir parameters on the in-situ combustion process. This project includes the study of the k… more
Date: January 1, 1991
Creator: Brigham, W.E.; Aziz, K. & Ramey, H.J. Jr.
Partner: UNT Libraries Government Documents Department
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Direct conversion of light hydrocarbon gases to liquid fuel

Description: The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product … more
Date: January 1, 1991
Creator: Foral, M.J.
Partner: UNT Libraries Government Documents Department
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Elastic constants and the structural phase transition in La sub 2-x Sr sub x CuO sub 4

Description: Resonant ultrasound spectroscopy is used to measure the temperature dependence of all six elastic moduli of La{sub 2-x}Sr{sub x}CuO{sub 4}. A giant softening (> 50% reduction) in the in-plane shear modulus, c{sub 66}, is observed and is attributed to the tetragonal-orthorhombic structural phase transition in this material. This phase transition and the corresponding softening is examined with a simple anharmonic mechanical model and a macroscopic Ginsburg-Landau formalism exploiting the full sy… more
Date: January 1, 1991
Creator: Sarrao, J.L.; Lei, Ming; Stekel, A.; Bell, T.M.; Leisure, R. G.; Sham, L.J. et al.
Partner: UNT Libraries Government Documents Department
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Flash hydropyrolysis of coal. Quarterly report No. 2, April 1--June 30, 1977

Description: With the combination of low hydrogen to coal ratio, high coal feed rate and larger total quantity of coal fed, considerable liquid product is being condensed and collected. Experimental runs conducted at 750/sup 0/C and 800/sup 0/C at pressures up to 3000 psi of hydrogen show overall hydrocarbon yields and particularly gaseous hydrocarbon yields to increase with pressure to approximately 60 percent at 3000 psi. At 750/sup 0/C approximately one third (20 percent) of this yield is in the form of … more
Date: July 1, 1977
Creator: Fallon, P
Partner: UNT Libraries Government Documents Department
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Kilowatt isotope power system. Component test procedure for the ground demonstration system radiator bypass valve

Description: This test procedure provides a detailed description of the verification methods which shall be used in the developmental program to be conducted on the Kilowatt Isotope Power System (KIPS) Radiator Bypass Valve, to fulfill the requirements of the Ground Demonstration System Design Criteria. The test objective is to demonstrate the bypass flow characteristics of the valve as a function of the Jet Condensor Inlet Temperature. To accomplish the test objective the pump discharge temperature (TPO) w… more
Date: April 1, 1977
Partner: UNT Libraries Government Documents Department
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