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Comparison of the results of short-term static tests and single-pass flow-through tests with LRM glass.

Description: Static dissolution tests were conducted to measure the forward dissolution rate of LRM glass at 70 C and pH(RT) 11.7 {+-} 0.1 for comparison with the rate measured with single-pass flow-through (SPFT) tests in an interlaboratory study (ILS). The static tests were conducted with monolithic specimens having known geometric surface areas, whereas the SPFT tests were conducted with crushed glass that had an uncertain specific surface area. The error in the specific surface area of the crushed glass used in the SPFT tests, which was calculated by modeling the particles as spheres, was assessed based on the difference in the forward dissolution rates measured with the two test methods. Three series of static tests were conducted at 70 C following ASTM standard test method C1220 using specimens with surfaces polished to 600, 800, and 1200 grit and a leachant solution having the same composition as that used in the ILS. Regression of the combined results of the static tests to the affinity-based glass dissolution model gives a forward rate of 1.67 g/(m{sup 2}d). The mean value of the forward rate from the SPFT tests was 1.64 g/(m{sup 2}d) with an extended uncertainty of 1.90 g/(m{sup 2}d). This indicates that the calculated surface area for the crushed glass used in the SPFT tests is less than 2% higher than the actual surface area, which is well within the experimental uncertainties of measuring the forward dissolution rate using each test method. These results indicate that the geometric surface area of crushed glass calculated based on the size of the sieves used to isolate the fraction used in a test is reliable. In addition, the C1220 test method provides a means for measuring the forward dissolution rate of borosilicate glasses that is faster, easier, and more economical than the SPFT test method.
Date: January 29, 2007
Creator: Ebert, W. L. & Engineering, Chemical
Partner: UNT Libraries Government Documents Department

Spent nuclear fuel project surface area estimates for N-Reactor fuel in the K East basin

Description: Spent N-reactor fuel will be moved from wet to dry storage at Hanford Washington. The majority ofthis fuel exists as intact fuel assemblies, however, small amounts ofscrap will be included. Varying amounts of uranium metal are exposed in these fuel assemblies, depending upon the amount of mechanical damage sustained by the zircaloy cladding. The total exposed uranium surface area in each storage pool is estimated through the release of radioisotopes to the storage pools. The exposed uranium surface area of individual fuel assemblies in the K-East basin were estimated through the results of a camera survey. The exposed uranium surface area of scrap is estimated from the known particle side range and an estimated log normal particle size distribution. This document uses the radioisotope release calculations, the estimated scrap surface area, and the carnera survey results to estimate the ``worst case`` amount of surface area that could exist in a given ``MCO`` container containing 4 levels of fuel assemblies and one scrap basket. The total exposed uranium metal surface area for this ``worst case`` was 120,000 cm{sup 2}.
Date: September 30, 1996
Creator: Cooper, T.D.
Partner: UNT Libraries Government Documents Department

MOISTURE AND SURFACE AREA MEASUREMENTS OF PLUTONIUM-BEARING OXIDES

Description: To ensure safe storage, plutonium-bearing oxides are stabilized at 950 C for at least two hours in an oxidizing atmosphere. Stabilization conditions are expected to decompose organic impurities, convert metals to oxides, and result in moisture content below 0.5 wt%. During stabilization, the specific surface area is reduced, which minimizes readsorption of water onto the oxide surface. Plutonium oxides stabilized according to these criteria were sampled and analyzed to determine moisture content and surface area. In addition, samples were leached in water to identify water-soluble chloride impurity content. Results of these analyses for seven samples showed that the stabilization process produced low moisture materials (< 0.2 wt %) with low surface area ({le} 1 m{sup 2}/g). For relatively pure materials, the amount of water per unit surface area corresponded to 1.5 to 3.5 molecular layers of water. For materials with chloride content > 360 ppm, the calculated amount of water per unit surface area increased with chloride content, indicating hydration of hygroscopic salts present in the impure PuO{sub 2}-containing materials. The low moisture, low surface area materials in this study did not generate detectable hydrogen during storage of four or more years.
Date: September 28, 2009
Creator: Crowder, M.; Duffey, J.; Livingston, R.; Scogin, J.; Kessinger, G. & Almond, P.
Partner: UNT Libraries Government Documents Department

Up-Scaling Geochemical Reaction Rates for Carbon Dioxide (CO2) in Deep Saline Aquifers

Description: Geochemical reactions in deep subsurface environments are complicated by the consolidated nature and mineralogical complexity of sedimentary rocks. Understanding the kinetics of these reactions is critical to our ability to make long-term predictions about subsurface processes such as pH buffering, alteration in rock structure, permeability changes, and formation of secondary precipitates. In this project, we used a combination of experiments and numerical simulation to bridge the gap between our knowledge of these reactions at the lab scale and rates that are meaningful for modeling reactive transport at core scales. The focus is on acid-driven mineral dissolution, which is specifically relevant in the context of CO2-water-rock interactions in geological sequestration of carbon dioxide. The project led to major findings in three areas. First, we modeled reactive transport in pore-network systems to investigate scaling effects in geochemical reaction rates. We found significant scaling effects when CO2 concentrations are high and reaction rates are fast. These findings indicate that the increased acidity associated with geological sequestration can generate conditions for which proper scaling tools are yet to be developed. Second, we used mathematical modeling to investigate the extent to which SO2, if co-injected with CO2, would acidify formation brines. We found that there exist realistic conditions in which the impact on brine acidity will be limited due to diffusion rate-limited SO2 dissolution from the CO2 phase, and the subsequent pH shift may also be limited by the lack of availability of oxidants to produce sulfuric acid. Third, for three Viking sandstones (Alberta sedimentary basin, Canada), we employed backscattered electron microscopy and energy dispersive X-ray spectroscopy to statistically characterize mineral contact with pore space. We determined that for reactive minerals in sedimentary consolidated rocks, abundance alone is not a good predictor of mineral accessible surface area, and should not be used in reactive transport ...
Date: February 28, 2013
Creator: Peters, Catherine A
Partner: UNT Libraries Government Documents Department

Progress towards a PETN Lifetime Prediction Model

Description: Dinegar (1) showed that decreases in PETN surface area causes EBW detonator function times to increase. Thermal aging causes PETN to agglomerate, shrink, and densify indicating a ''sintering'' process. It has long been a concern that the formation of a gap between the PETN and the bridgewire may lead to EBW detonator failure. These concerns have led us to develop a model to predict the rate of coarsening that occurs with age for thermally driven PETN powder (50% TMD). To understand PETN contributions to detonator aging we need three things: (1) Curves describing function time dependence on specific surface area, density, and gap. (2) A measurement of the critical gap distance for no fire as a function of density and surface area for various wire configurations. (3) A model describing how specific surface area, density and gap change with time and temperature. We've had good success modeling high temperature surface area reduction and function time increase using a phenomenological deceleratory kinetic model based on a distribution of parallel nth-order reactions having evenly spaced activation energies where weighing factors of the reactions follows a Gaussian distribution about the reaction with the mean activation energy (Figure 1). Unfortunately, the mean activation energy derived from this approach is high (typically {approx}75 kcal/mol) so that negligible sintering is predicted for temperatures below 40 C. To make more reliable predictions, we've established a three-part effort to understand PETN mobility. First, we've measured the rates of step movement and pit nucleation as a function of temperature from 30 to 50 C for single crystals. Second, we've measured the evaporation rate from single crystals and powders from 105 to 135 C to obtain an activation energy for evaporation. Third, we've pursued mechanistic kinetic modeling of surface mobility, evaporation, and ripening.
Date: September 11, 2006
Creator: Burnham, A K; Overturf III, G E; Gee, R; Lewis, P; Qiu, R; Phillips, D et al.
Partner: UNT Libraries Government Documents Department

Development of a Catalyst/Sorbent for Methane Reforming

Description: This project led to the further development of a combined catalyst and sorbent for improving the process technology required for converting CH{sub 4} and/or CO into H{sub 2} while simultaneously separating the CO{sub 2} byproduct all in a single step. The new material is in the form of core-in-shell pellets such that each pellet consists of a CaO core surrounded by an alumina-based shell capable of supporting a Ni catalyst. The Ni is capable of catalyzing the reactions of steam with CH{sub 4} or CO to produce H{sub 2} and CO{sub 2}, whereas the CaO is capable of absorbing the CO{sub 2} as it is produced. The absorption of CO{sub 2} eliminates the reaction inhibiting effects of CO{sub 2} and provides a means for recovering the CO{sub 2} in a useful form. The present work showed that the lifecycle performance of the sorbent can be improved either by incorporating a specific amount of MgO in the material or by calcining CaO derived from limestone at 1100 C for an extended period. It also showed how to prepare a strong shell material with a large surface area required for supporting an active Ni catalyst. The method combines graded particles of {alpha}-alumina with noncrystalline alumina having a large specific surface area together with a strength promoting additive followed by controlled calcination. Two different additives produced good results: 3 {micro}m limestone and lanthanum nitrate which were converted to their respective oxides upon calcination. The oxides partially reacted with the alumina to form aluminates which probably accounted for the strength enhancing properties of the additives. The use of lanthanum made it possible to calcine the shell material at a lower temperature, which was less detrimental to the surface area, but still capable of producing a strong shell. Core-in-shell pellets made with the improved shell ...
Date: December 31, 2008
Creator: Shans, B.H.; Wheelock, T.D.; Satrio, Justinus; Albrecht, Karl; Keeley, Tanya Harris Janine; Silva, Ben et al.
Partner: UNT Libraries Government Documents Department

Closeout of Advanced Boron and Metal Loaded High Porosity Carbons.

Description: The Penn State effort explored the development of new high-surface-area materials for hydrogen storage, materials that could offer enhancement in the hydrogen binding energy through a direct chemical modification of the framework in high specific-surface-area platforms. The team chemically substituted boron into the hexagonal sp2 carbon framework, dispersed metal atoms bound to the boro-carbon structure, and generated the theory of novel nanoscale geometries that can enhance storage through chemical frustration, sheet curvature, electron deficiency, large local fields and mixed hybridization states. New boro-carbon materials were synthesized by high temperature plasma, pyrolysis of boron-carbon precursor molecules, and post-synthesis modification of carbons. Hydrogen uptake has been assessed, and several promising leads have been identified, with the requirement to simultaneously optimize total surface area while maintaining the enhanced hydrogen binding energies already demonstrated.
Date: May 1, 2011
Creator: Eklund, Peter C.; Chung, T. C. Mike; Foley, Henry C. & Crespi, Vincent H.
Partner: UNT Libraries Government Documents Department

Effect of Grinding on the Stucture of Glassy Carbon

Description: An earlier suggestion that various allotropic forms of carbon preexist as micron size crystallites in glassy carbon was investigated. Samples previously heated only to 1000 C and thinned by crushing (grinding) or by ion melting and observed using transmission electron diffraction and microscopy gave single crystal or spotty ring patterns for the former but only diffuse rings for the latter. Wide range X-ray diffraction, small angle X-ray scattering, density and surface area measurements of as received plate and ground material show that grinding flattens the internal pore structure of the material, decreasing the specific surface area by 25 percent and increasing the radius of gyration by about 8 percent, It is concluded that the spot patterns indicating crystalline forms result from strain relief during grinding.
Date: December 1, 1979
Creator: Baker, D. F.; Bragg, R. H. & Rao, A. S.
Partner: UNT Libraries Government Documents Department

Effect of Precipitation Conditions on the Specific Surface Area of Neptunium Oxide

Description: Neptunium oxalate was precipitated under nominal and bounding HB-Line flowsheet conditions. The nominal case represents expected normal HB-Line operation. The bounding case represents process flowsheet extremes that could occur which are anticipated to decrease particle size and increase surface area. The neptunium oxalate produced under bounding conditions was used to validate the effectiveness of HB-Line calcination conditions. The maximum specific surface area of the neptunium oxide (NpO2) used in gas generation testing was 5.34 m2/g. Experiments were conducted to verify that even under bounding precipitation conditions the SSA of NpO2 produced would remain within the range evaluated during gas generation testing. The neptunium oxalate from nominal and bounding precipitation conditions was calcined at 600 degrees Celsius and 625 degrees Celsius, respectively, to form NpO2. Samples from each batch of neptunium oxalate were calcined for one, two, or four hours. Results indicate that the SSA of NpO2 continues to decrease between one and four hours. After two hours of calcination at 625 degrees Celsius, the SSA of NpO2 from the bounding case meets the surface area requirements for limiting moisture uptake.
Date: June 1, 2004
Creator: HILL, BENJAMINC.
Partner: UNT Libraries Government Documents Department

DEVELOPMENT OF MESOPOROUS MEMBRANE MATERIALS FOR CO2 SEPARATION

Description: The huge emissions of carbon dioxide from fossil fuel fired power plants and industrial plants over the last century have resulted in an increase of the atmospheric carbon dioxide concentration. Climatological modeling work has predicted severe climate disruption as a result of the trapping of heat due to CO{sub 2}. As an attempt to address this global warming effect, DOE has initiated the Vision 21 concept for future power plants. We first synthesized mesoporous aluminosilicates that have high surface area and parallel pore channels for membrane support materials. Later we synthesized microporous aluminosilicates as the potential thin membrane materials for selective CO{sub 2} adsorption. The pore size is controlled to be less that 1 nm so that the adsorption of CO{sub 2} on the pore wall will block the passage of N{sub 2}. Mesoporous and precipitated alumina were synthesized as the base material for CO{sub 2} adsorbent. The porous alumina is doped with Ba to enhance its CO{sub 2} affinity due to the basicity of Ba. It is shown by gas chromatograph (GC) that the addition of Ba enhances the separation CO{sub 2} from N{sub 2}. It was found that mesoporous alumina has larger specific surface area and better selectivity of CO{sub 2} than precipitated alumina. Ba improves the affinity of mesoporous alumina with CO{sub 2}. Phase may play an important role in selective adsorption of CO{sub 2}. It is speculated that mesoporous alumina is more reactive than precipitated alumina creating the xBaO {center_dot}Al{sub 2}O{sub 3} phase that may be more affinitive to CO{sub 2} than N{sub 2}. On the other hand, the barium aluminates phase (Ba{sub 3}Al{sub 2}O{sub 6}) in the mesoporous sample does not help the adsorption of CO{sub 2}. Microporous aluminosilicate was chosen as a suitable candidate for CO{sub 2}/N{sub 2} separation because the pore size is ...
Date: March 25, 2003
Creator: Shih, Wei-Heng; Patil, Tejas & Zhao, Qiang
Partner: UNT Libraries Government Documents Department

Structural Formation Studies of UV-Catalyzed Gels and Aerogels byLight Scattering

Description: The skeletal structure of aerogel is determined before, during, and after the gel is formed. Supercritical drying of aerogel largely preserves the pore structure that is determined near the time of gelation. To better understand these gel formation mechanisms we carried out measurements of the time evolution of light scattering in a series of gels prepared without conventional acid or base catalysis. Instead, ultraviolet light was used to catalyze the formation of silica gels made from the hydrolysis of tetraethylorthosilicate and partly prehydrolyzed tetraethylorthosilicate in ethanol. Time evolution of light scattering provides information regarding the rate and geometrical nature of the assembly of the primary silica particles formed in the sol. UV-catalyzed gels show volumetric growth typical of acid-catalyzed gels, except when UV exposure is discontinued at the gel point, where gels then show linear chain formation typical of base-catalyzed gels. Long term UV exposure leads to coarsening of the pore network, a decrease in the clarity of the aerogel, and an increase in the surface area of the aerogel. Additionally, UV exposure up to the gel point leads to increased crystallinity in the final aerogel.
Date: April 1, 1998
Creator: Hunt, Arlon J. & Ayers, Michael R.
Partner: UNT Libraries Government Documents Department

Effects of room furnishings and air speed on particle depositionrates indoors

Description: Particle deposition to surfaces plays an important role in determining exposures to indoor particles. However, the effects of furnishings and air speed on these rates have not been well characterized. In this study, experiments were performed in an isolated room (volume = 14.2 m{sup 3}) using three different indoor furnishing levels (bare, carpeted and fully furnished) and four different airflow conditions. Deposition loss rates were determined by generating a short burst of polydispersed particles, then measuring the size-resolved (0.5-10 {micro}m) concentration decay rate using an aerodynamic particle sizer. Increasing the surface area from bare (35 m{sup 2} nominal surface area) to fully furnished (12 m{sup 2} additional surface area) increased the deposition loss rate by as much as a factor of 2.6, with the largest increase seen for the smallest particles. Increasing the mean airspeed from < 5 cms/s to 19 cm/s, by means of increasing fan speed, increased the deposition rate for all particle sizes studied by factors ranging from 1.3 to 2.4, with larger particles exhibiting greater effects than smaller particles. The significant effect of particle size and room conditions on deposition loss rates argues against using a single first-order loss-rate coefficient to represent deposition for integrated mass measurements (PM{sub 2.5} or PM{sub 10}).
Date: June 1, 2002
Creator: Thatcher, Tracy L.; Lai, Alvin C.K.; Moreno-Jackson, Rosa; Sextro, Richard G. & Nazaroff, William W.
Partner: UNT Libraries Government Documents Department

Synthesis and properties of Chitosan-silica hybrid aerogels

Description: Chitosan, a polymer that is soluble in dilute aqueous acid, is derived from chitin, a natural polyglucosamide. Aquagels where the solid phase consists of both chitosan and silica can be easily prepared by using an acidic solution of chitosan to catalyze the hydrolysis and condensation of tetraethylorthosilicate. Gels with chitosan/TEOS mass ratios of 0.1-1.1 have been prepared by this method. Standard drying processes using CO{sub 2} give the corresponding aerogels. The amount of chitosan in the gel plays a role in the shrinkage of the aerogel during drying. Gels with the lowest chitosan/silica ratios show the most linear shrinkage, up to 24%, while those with the highest ratios show only a 7% linear shrinkage. Pyrolysis at 700 C under nitrogen produces a darkened aerogel due to the thermal decomposition of the chitosan, however, the aerogel retains its monolithic form. The pyrolyzed aerogels absorb slightly more infrared radiation in the 2-5 {micro}m region than the original aerogels. B.E.T. surface areas of these aerogels range from 470-750 m{sup 2}/g. Biocompatibility screening of this material shows a very high value for hemolysis, but a low value for cytotoxicity.
Date: June 1, 2001
Creator: Ayers, Michael R. & Hunt, Arlon J.
Partner: UNT Libraries Government Documents Department

High-Power Electrostatic Discharges in PETN: Threshold and Scaling Experiments

Description: There is a considerable set of data establishing the safety of PETN-based detonators that are insulted by electrostatic discharge (ESD) from a human body. However, the subject of ESD safety has garnered renewed interest because of the sparse data on high-power, low-impedance discharges that result when the source is a metallic object such as a tool. Experiments on as-built components, using pin-to-cap fault circuits through PETN-based detonators, showed significant evidence of a power dependence but with a very broad energy threshold and some uncertainty in the breakdown path. We have performed a series of experiments using a well-defined arc discharge path and a well-characterized source that is capable of independent variation of energy and power. Studies include threshold variation with power, arc length, powder surface area, and surface vs. bulk discharge paths. We find that an energy threshold variation with power does not appear to exist in the tested range of fractions to tens of MW, and that there are many subtleties to proper energy and power bookkeeping. We also present some test results for PBX 9407.
Date: March 5, 2010
Creator: Liou, W; McCarrick, J F; Hodgin, R L & Phillips, D F
Partner: UNT Libraries Government Documents Department

Hydrogen Production via a Commercially Ready Inorganic membrane Reactor

Description: One of the technical barriers for ceramic membranes is its scale up potential. The conventional ceramic membranes/modules originally developed for liquid phase applications are costly and not suitable for high temperature applications. One of the objectives under this project is the development of a ceramic membrane/module, which is economical and suitable for high temperature applications proposed under this project (200-300 C). During this period, we initiated the fabrication of a prototype ceramic membrane module which can be (1) qualified for the proposed application temperature, and (2) cost acceptable for large scale applications. A prototype ceramic membrane bundle (3-inch diameter and 35-inch L) has been prepared, which passes the temperature stability requirement. It also meets the low end of the burst pressure requirement, i.e., 500-750 psi. In the next period, we will continue the improvement of this prototype module to upgrade its burst pressure to 1000 to 1500 psi range. In addition, bench-top experimental study has been conducted in this period to verify satisfactorily the simulated results for the process scheme developed in the last report, which took into the consideration of streamlining the pre- and post-treatment. The sensitivity analysis indicates that membrane surface area requirement is a key operating parameter based upon the criteria of the CO conversion, hydrogen recovery and CO impurity level. A preliminary optimization study has been performed in this period based upon the key operating parameters determined above. Our result shows that at 40 bar feed pressure a nearly complete CO conversion and >95% hydrogen recovery can be achieved with the CO impurity level at {approx}3500 ppm. If the hydrogen recovery ratio is lowered, the CO impurity level can be reduced further. More comprehensive optimization study will be performed in the 2nd half of Yr III to focus on the reduction of the CO impurity level ...
Date: May 31, 2006
Creator: Liu, Paul K.T.
Partner: UNT Libraries Government Documents Department

Volume and surface area of a spherical harmonic surface approximation to a NIF implosion core defined by HGXI/GXD images from the equator and pole

Description: A solid object, such as a simplified approximation to an implosion core defined by the 17% intensity contour, can be described by a sum of spherical harmonics, following the notation of Butkov (Mathematical Physics, ISBN 0-201-00727-4, 1968; there are other notations so care is required), with Pl(x) being the usual (apparently standard) Legendre polynomial. For the present purposes, finding the volume and surface area of an implosion core defined by P0, P2, P4, M0, and M4, I will restrict the problem to consider only A{sub 00}, A{sub 20}, A{sub 40}, and A{sub 44}, with the phase angle set to eliminate the sin(m{phi}) term. Once the volume and surface area are determined, I will explore how these coefficients relate to measured quantities A0, A2/A0, A4/A0, M0, and M4/M0.
Date: October 26, 2011
Creator: Koch, J A
Partner: UNT Libraries Government Documents Department

Supported Molten Metal Catalysis. A New Class of Catalysts

Description: We describe a new class of heterogeneous catalysts called supported molten metal catalysis (SMMC), in which molten metal catalysts are dispersed as nanodroplets on the surface of porous supports, allowing much larger active surface area than is possible in conventional contacting techniques for catalytic metals that are molten under reaction conditions, thus greatly enhancing their activity and potential utility. Specific examples of different types of reactions are provided to demonstrate the broad applicability of the technique in designing active, selective, and stable new catalysts. It is shown that dispersing the molten metal on a support in the suggested manner can enhance the rate of a reaction by three to four orders of magnitude as a result of the concomitant increase in the active surface area. New reaction examples include {gamma}-Al{sub 2}O{sub 3} supported molten Te (melting point 450 C) and Ga (MP 30 C) catalysts for bifunctional methylcyclohexane dehydrogenation. These catalysts provide activity similar to conventional Pt-based catalysts for this with better resistance to coking. In addition, results are described for a controlled pore glass supported molten In (MP 157 C) catalyst for the selective catalytic reduction of NO with ethanol in the presence of water, demonstrating activities superior to conventional catalysts for this reaction. A discussion is also provided on the characterization of the active surface area and dispersion of these novel supported catalysts. It is clear based on the results described that the development of new active and selective supported molten metal catalysts for practical applications is entirely plausible.
Date: June 2, 2006
Creator: Datta, Ravindra; Singh, Ajeet; Serban, Manuela & Halasz, Istvan
Partner: UNT Libraries Government Documents Department

SURFACE AREA, VOLUME, MASS, AND DENSITY DISTRIBUTIONS FOR SIZED BIOMASS PARTICLES

Description: This semi-annual technical progress report describes work performed at Morehouse College under DOE Grant No. DE-FC26-04NT42130 during the period July 01, 2005 to December 31, 2005 which covers the third six months of the project. Presently work is in progress to characterize surface area, volume, mass, and density distributions for sized biomass particles. During this reporting period, Morehouse continued to obtain additional mean mass measurements for biomass particles employing the gravimetric technique measurement system that was set up in the last reporting period. Simultaneously, REM, our subcontractor, has obtained raw data for surface area, volume, and drag coefficient to mass ratio (C{sub d}/m) information for several biomass particles employing the electrodynamic balance (EDB) measurement system that was calibrated in the last reporting period. Preliminary results of the mean mass and the shape data obtained are reported here, and more data collection is in progress.
Date: January 1, 2006
Creator: Sampath, Ramanathan
Partner: UNT Libraries Government Documents Department

SURFACE AREA, VOLUME, MASS, AND DENSITY DISTRIBUTIONS FOR SIZED BIOMASS PARTICLES

Description: This semi-annual technical progress report describes work performed at Morehouse College under DOE Grant No. DE-FC26-04NT42130 during the period January 01, 2006 to June 30, 2006 which covers the fourth six months of the project. Presently work is in progress to characterize surface area, volume, mass, and density distributions for sized biomass particles. During this reporting period, Morehouse completed obtaining additional mean mass measurements for biomass particles employing the gravimetric technique measurement system that was set up in a previous reporting period. Simultaneously, REM, our subcontractor, has completed obtaining raw data for surface area, volume, and drag coefficient to mass ratio (Cd/m) information for 9 more biomass particles employing the electrodynamic balance (EDB) measurement system that was calibrated before in this project. Results of the mean mass data obtained to date are reported here, and analysis of the raw data collected by REM is in progress.
Date: June 30, 2006
Creator: Sampath, Ramanathan
Partner: UNT Libraries Government Documents Department

LITERATURE REVIEW OF PUO2 CALCINATION TIME AND TEMPERATURE DATA FOR SPECIFIC SURFACE AREA

Description: The literature has been reviewed in December 2011 for calcination data of plutonium oxide (PuO{sub 2}) from plutonium oxalate Pu(C{sub 2}O{sub 4}){sub 2} precipitation with respect to the PuO{sub 2} specific surface area (SSA). A summary of the literature is presented for what are believed to be the dominant factors influencing SSA, the calcination temperature and time. The PuO{sub 2} from Pu(C{sub 2}O{sub 4}){sub 2} calcination data from this review has been regressed to better understand the influence of calcination temperature and time on SSA. Based on this literature review data set, calcination temperature has a bigger impact on SSA versus time. However, there is still some variance in this data set that may be reflecting differences in the plutonium oxalate preparation or different calcination techniques. It is evident from this review that additional calcination temperature and time data for PuO{sub 2} from Pu(C{sub 2}O{sub 4}){sub 2} needs to be collected and evaluated to better define the relationship. The existing data set has a lot of calcination times that are about 2 hours and therefore may be underestimating the impact of heating time on SSA. SRNL recommends that more calcination temperature and time data for PuO{sub 2} from Pu(C{sub 2}O{sub 4}){sub 2} be collected and this literature review data set be augmented to better refine the relationship between PuO{sub 2} SSA and its calcination parameters.
Date: March 6, 2012
Creator: Daniel, G.
Partner: UNT Libraries Government Documents Department

Effects of stabilization temperature on surface area and grain size of representative plutonium materials.

Description: Calcination at 400-1000C is used throughout the Department of Energy (DOE) complex to stabilize plutonium material for transportation and storage . The objectives of this stabilization are to remove moisture and other potentially water-producing phases, and to ensure that readsorption will not occur before material is placed in welded containers .Such moisture may threaten the integrity of containers through pressurization with radiolytically generated hydrogen. It is also considered valuable to reduce the fine (respirable) fraction of the material to mitigate potential impact of accidents.
Date: January 1, 2003
Creator: Boak, J. M. (Jeremy M.); Dale, D. J. (Deborah J.) & Eller, P. G. (Phillip Gary)
Partner: UNT Libraries Government Documents Department

EFFECT OF PRETREATMENT ON PT-CO/C CATHODE CATALYSTS FOR THE OXYGEN-REDUCTION REACTION

Description: In order to reduce the precious metal loading without sacrificing activity and stability, a new method for the preparation of bimetallic catalysts is proposed. Currently, Pt-alloy particles, with 2 to 3 nm in diameter, are loaded on high surface area carbon supports. Of the Pt loaded, only the surface atoms interact with the reactants. In order to increase the Pt utilization per metal particle the new process for catalyst preparation will incorporate a non-noble transition metal core coated with a skin layer of Pt deposited on high surface area carbon. The effect of reducing agent strength during synthesis was also explored. It was determined that the Co addition has a higher impact on catalyst when used with NaBH4 as reducing agent as compared to NaCOOH.
Date: May 13, 2009
Creator: Fox, E.
Partner: UNT Libraries Government Documents Department