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Stress and phase transformation phenomena in oxide films

Description: In situ optical methods are reviewed for characterization of phase transformation processes and evaluation of residual stress in solution- deposited metastable oxide films. Such low density films most often are deposited as disordered phases making them prone to crystallization and attendant densification when subjected to increased temperature and/or applied pressure. Inherent stress imparted during film deposition and its evolution during the transformation are evaluated from phonon frequency shifts seen in Raman spectra (TiO{sub 2}) or from changes in the laser-induced fluorescence emission spectra for films containing rare earth (Sm{sup +3}:Y{sub 3}Al{sub 5}O{sub 12}) or transition metal (Cr{sup +3}:Al{sub 2}O{sub 3}) dopants. The data in combination with measured increases in line intensities intrinsic to the evolving phase are used to follow crystallization processes in thin films. In general, film deposition parameters are found to influence the crystallite ingrowth kinetics and the magnitude of stress and stress relaxation in the film during the transformation. The utility of these methods to probe crystallization phenomena in oxide films will be addressed.
Date: April 1, 1992
Creator: Exarhos, G. J. & Hess, N. J.
Partner: UNT Libraries Government Documents Department

Comparison of effectiveness of sub-slab ventilation systems for indoor radon mitigation: A numerical study; Comparaison a l`aide d`un outil numerique de l`efficacite des systemes de ventilation active du sol limitant la penetration du radon dans l`habitat

Description: The functioning of an active sub-slab ventilation system (SVS) has been studied successfully with the help of a previously evaluated numerical model. The parameters explored are the permeability of the sub-slab and the gravel placed beneath it, the amplitude of applied pressure at the installation point of the system and the functioning method: depressurization or pressurization. The mechanisms contributing to the success of the two systems are identified. This numerical study shows that the presence of a layer of gravel beneath the sub-slab considerably improves the performance of the SVS. Considered separately from the extremely permeable sub-slabs, the depressurization systems perform better than the pressurization systems. 17 refs. [Francais] Le fonctionnement des Systemes de Ventilation active du Sol (SVS) a ete etudie a l`aide d`un outil numerique precedemment evalue avec succes. Les parametres explores sont les permeabilites du sol et du gravier place sous plancher bas, l`amplitude de la pression appliquee au point d`installation du systeme, et le mode de fonctionnement: Depressurisation ou Pressurisation. Les mecanismes contribuant au succes des deux systemes sont identifies. Cette etude numerique montre que la presence d`une couche de gravier sous plancher bas ameliore de facon considerable les performances des SVS. Mis a part le cas des sols extremement permeables, les systemes de Depressurisation ont de meilleures performances que les systemes de Pressurisation. 17 refs.
Date: April 1, 1992
Creator: Bonnefous, Y. C.; Gadgil, A. J. & Allard, F.
Partner: UNT Libraries Government Documents Department

SSC 50 mm collider dipole cryostat design

Description: The cryostat of a Superconducting Super Collider (SSC) dipole magnet consists of all magnet components except the magnet assembly itself. It serves to support the magnet accurately and reliably within the vacuum vessel, provide all required cryogenic piping, and to insulate the cold mass from heat radiated and conducted from the environment. It must function reliably during storage, shipping and handling, normal magnet operation, quenches, and seismic excitations, and must be manufacturable at low cost. The major components of the cryostat are the vacuum vessel, thermal shields, multilayer insulation system, cryogenic piping, interconnections, and suspension system. The overall design of a cryostat for superconducting accelerator magnets requires consideration of fluid flow, proper selection of materials for their thermal and structural performance at both ambient and operating temperature, and knowledge of the environment to which the magnets will be subjected over the course of their expected operating life. This paper describes the design of the current SSC dipole magnet cryostat and includes discussions on the structural and thermal considerations involved in the development of each of the major systems.
Date: April 1, 1992
Creator: Nicol, T. H.
Partner: UNT Libraries Government Documents Department

A Baroclinic Model of turbulent dusty flows

Description: The problem considered here is the numerical simulation of the turbulent dusty flow induced by explosions over soil surfaces. Some of the unresolved issues are: (1) how much dust is scoured from such surfaces; (2) where does the dust go in the boundary layer; (3) what is the dusty boundary layer height versus time; (4) what are the dusty boundary layer profiles; (5) how much of the dust mass becomes entrained into the dust stem; and (6) where does the dust go in the buoyant cloud? The author proposes a Baroclinic Model for flows with large density variations that actually calculates the turbulent mixing and transport of dust on an adaptive grid. The model is based on the following idealizations: (1) a loose dust bed; (2) an instantaneous shock fluidization of the dust layer; (3) the dust and air are in local equilibrium (so air viscosity enforces the no-slip condition); (4) the dust-air mixture is treated as a continuum dense fluid with zero viscosity; and (5) the turbulent mixing is dominated by baroclinically-generated vorticity. These assumptions lead to an inviscid set of conservation laws for the mixture, which are solved by means of a high-order Godunov algorithm for gasdynamics. Adaptive Mesh Refinement (AMR) is used to capture the turbulent mixing processes on the grid. One of the unique characteristics of these flows is that mixing occurs because vorticity is produced by an inviscid, baroclinic mechanism. A number of examples are presented to illustrate these baroclinic effects including shock interactions with dense-gas layers and dust beds, and dusty wall jets of airblast precursors. The conclusion of these studies is that dusty boundary layers grow because of mass entrainment from the fluidized bed (and not because of viscous wall drag) as proven by the Mass Integral Equation.
Date: April 1, 1992
Creator: Kuhl, A. L.
Partner: UNT Libraries Government Documents Department

Stress and phase transformation phenomena in oxide films

Description: In situ optical methods are reviewed for characterization of phase transformation processes and evaluation of residual stress in solution- deposited metastable oxide films. Such low density films most often are deposited as disordered phases making them prone to crystallization and attendant densification when subjected to increased temperature and/or applied pressure. Inherent stress imparted during film deposition and its evolution during the transformation are evaluated from phonon frequency shifts seen in Raman spectra (TiO{sub 2}) or from changes in the laser-induced fluorescence emission spectra for films containing rare earth (Sm{sup +3}:Y{sub 3}Al{sub 5}O{sub 12}) or transition metal (Cr{sup +3}:Al{sub 2}O{sub 3}) dopants. The data in combination with measured increases in line intensities intrinsic to the evolving phase are used to follow crystallization processes in thin films. In general, film deposition parameters are found to influence the crystallite ingrowth kinetics and the magnitude of stress and stress relaxation in the film during the transformation. The utility of these methods to probe crystallization phenomena in oxide films will be addressed.
Date: April 1, 1992
Creator: Exarhos, G.J. & Hess, N.J.
Partner: UNT Libraries Government Documents Department

SSC 50 mm collider dipole cryostat design

Description: The cryostat of a Superconducting Super Collider (SSC) dipole magnet consists of all magnet components except the magnet assembly itself. It serves to support the magnet accurately and reliably within the vacuum vessel, provide all required cryogenic piping, and to insulate the cold mass from heat radiated and conducted from the environment. It must function reliably during storage, shipping and handling, normal magnet operation, quenches, and seismic excitations, and must be manufacturable at low cost. The major components of the cryostat are the vacuum vessel, thermal shields, multilayer insulation system, cryogenic piping, interconnections, and suspension system. The overall design of a cryostat for superconducting accelerator magnets requires consideration of fluid flow, proper selection of materials for their thermal and structural performance at both ambient and operating temperature, and knowledge of the environment to which the magnets will be subjected over the course of their expected operating life. This paper describes the design of the current SSC dipole magnet cryostat and includes discussions on the structural and thermal considerations involved in the development of each of the major systems.
Date: April 1, 1992
Creator: Nicol, T.H.
Partner: UNT Libraries Government Documents Department