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A Decision-Making Model for Safe and Effective Use of Functional Analysis Procedures

Description: While functional analysis provides the standard methodology for the assessment of problem behavior, procedures still pose potential risk when assessing severe problem behavior. Previous studies have examined several strategies to improve the efficiency of and reduce risks related to the functional analysis process. The purpose of the present series of studies was to replicate and extend previous research on the assessment and treatment of severe problem behavior for one participant diagnosed with an intellectual disability. By incorporating strategies within a systematic decision-making framework, functional analysis procedures were implemented to conduct the assessment of precursors, determine maintaining contingencies for severe problem behavior, and evaluate the effects of a treatment based on the results of a functional analysis.
Date: August 2017
Creator: Vega, Gabrielle M.
Partner: UNT Libraries

User's Guide for Hysteretic Capillary Pressure and Relative Permeability Functions in iTOUGH2

Description: The precursor of TOUGH2, TOUGH, was originally developed with non-hysteretic characteristic curves. Hysteretic capillary pressure functions were implemented in TOUGH in the late 1980s by Niemi and Bodvarsson (1988), and hysteretic capillary pressure and relative permeability functions were added to iTOUGH2 about ten years later by Finsterle et al. (1998). Recently, modifications were made to the iTOUGH2 hysteretic formulation to make it more robust and efficient (Doughty, 2007). Code development is still underway, with the ultimate goal being a hysteretic module that fits into the standard TOUGH2 (Pruess et al., 1991) framework. This document provides a user's guide for the most recent version of the hysteretic code, which runs within iTOUGH2 (Finsterle, 1999a,b,c). The current code differs only slightly from what was presented in Doughty (2007), hence that document provides the basic information on the processes being modeled and how they are conceptualized. This document focuses on a description of the user-specified parameters required to run hysteretic iTOUGH2. In the few instances where the conceptualization differs from that of Doughty (2007), the features described here are the current ones. Sample problems presented in this user's guide use the equation-of-state module ECO2N (Pruess, 2005). The components present in ECO2N are H{sub 2}O, NaCl, and CO{sub 2}. Two fluid phases and one solid phase are considered: an aqueous phase, which primarily consists of liquid H2O and may contain dissolved NaCl and CO{sub 2}; a supercritical phase which primarily consists of CO{sub 2}, but also includes a small amount of gaseous H{sub 2}O; and a solid phase consisting of precipitated NaCl. Details of the ECO2N formulation may be found in Pruess (2005). The aqueous phase is the wetting phase and is denoted ''liquid'', whereas the supercritical phase is the non-wetting phase and is denoted ''gas''. The hysteretic formalism may be applied to other ...
Date: August 1, 2009
Creator: Doughty, C.A.
Partner: UNT Libraries Government Documents Department

Primary Cilia in the Oligodendrocyte Lineage

Description: oligodendrocytes migrate from the corpus callosum into the overlying cortex. The incidence of cilia did not change markedly across age groups, and did not vary consistently with the number of processes per cell, which was used as an indication of the maturation stage of OPCs and young OLs. The mean percent of Olig1 immunopositive (Olig1+) cells having cilia across ages was 33.1% + 16.5%, with all ages combined. In O4+ cells of these mice, 56.7 + 3.6% had primary cilia. If it is the case that adult OLs do not have cilia, the point in the lineage when primary cilia are lost is still unknown. Adult mice that had been injected with cyclopamine to block cilia-dependent Shh signaling were examined to determine whether the rate of generating new OPCs was influenced. In the CC of control mice, the numerical density of Olig1+/BrdU+ cells was 1.29 + 0.07/mm2 was reduced to 0.68 + 0.38/mm2 in the cyclopamine-injected group, and the numerical density of all BrdU+ cells (including both Olig1+ and Olig1- cells) of 4.55 + 1.50/mm2 in the control group was reduced to 3.14 + 1.27/mm2 in the cyclopamine-injected group. However, there were only 2 mice in each group and the differences were not statistically significant.
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Date: May 2013
Creator: Hao, Yung-Chia
Partner: UNT Libraries

Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

Description: Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.
Date: April 4, 2010
Creator: Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu & Somorjai, Gabor A.
Partner: UNT Libraries Government Documents Department

Different precursor populations revealed by microscopic studies of bulk damage in KDP and DKDP crystals

Description: We present experimental results aiming to reveal the relationship between damage initiating defect populations in KDP and DKDP crystals under irradiation at different wavelengths. Our results indicate that there is more than one type of defects leading to damage initiation, each defect acting as damage initiators over a different wavelength range. Results showing disparities in the morphology of damage sites from exposure at different wavelengths provides additional evidence for the presence of multiple types of defects responsible for damage initiation.
Date: October 31, 2005
Creator: DeMange, P; Negres, R A; Radousky, H B & Demos, S G
Partner: UNT Libraries Government Documents Department

Aqueous Ln(III) Luminescence Agents Derived from a Tasty Precursor

Description: The synthesis, aqueous stability and photophysical properties are reported for a novel tetradentate ligand derived from maltol, a commonly used flavor enhancer. In aqueous solution, this chelate forms stable complexes with Ln(III) cations, and sensitized emission was observed from Eu(III), Yb(III), and Nd(III). A comparison with recently reported and structurally analogous ligands reveals a slightly higher basicity but lower complex stability with Eu(III) [pEu = 14.7 (1)]. A very poor metal centered quantum yield with Eu(III) was observed ({Phi}{sub tot} = 0.04%), which can be rationalized by the similar energy of the ligand triplet state and the Eu(III) {sup 5}D{sub 0} emissive level. Instead, sensitized emission from the Yb(III) and Nd(III) cations was observed, which emit in the Near Infra-Red (NIR).
Date: June 2, 2008
Creator: Jocher, C.J.; Moore, E.G.; Pierce, J.D. & Raymond, K.N.
Partner: UNT Libraries Government Documents Department

Size-selection initiation model extended to include shape and random factors

Description: The Feit-Rubenchik size-selection damage model has been extended in a number of ways. More realistic thermal deposition profiles have been added. Non-spherical shapes (rods and plates) have been considered, with allowance for their orientation dependence. Random variations have been taken into account. An explicit form for the change of absorptivity with precursor size has been added. A simulation tool called GIDGET has been built to allow adjustment of the many possible parameters in order to fit experimental data of initiation density as a function of fluence and pulse duration. The result is a set of constraints on the possible properties of initiation precursors.
Date: November 2, 2005
Creator: Trenholme, J B; Feit, M D & Rubenchik, A M
Partner: UNT Libraries Government Documents Department

Preparation of Size-tunable, Highly Monodisperse PVP-Protected Pt-nanoparticles by Seed-mediated Growth

Description: We demonstrate a preparative method which produces highly-monodisperse Pt-nanoparticles of tunable size without the external addition of seed particles. Hexachloroplatinic acid is dosed slowly to an ethylene glycol solution at 120 C and reduced in the presence of a stabilizing polymer poly-N-vinylpyrollidone (PVP). Slow addition of the Pt-salt first will first lead to the formation of nuclei (seeds) which then grow further to produce larger particles of any desired size between 3 and 8nm. The amount of added hexachloroplatinic acid precursor controls the size of the final nanoparticle product. TEM was used to determine size and morphology and to confirm the crystalline nature of the nanoparticles. Good reproducibility of the technique was demonstrated. Above 7nm, the particle shape and morphology changes suddenly indicating a change in the deposition selectivity of the Pt-precursor from (100) towards (111) crystal faces and breaking up of larger particles into smaller entities.
Date: April 2, 2008
Creator: Koebel, Matthias Michael; Jones, Louis C. & Somorjai, Gabor A.
Partner: UNT Libraries Government Documents Department

Can Cavitation Be Anticipated?

Description: The major problem with cavitation in pumps and hydraulic systems is that there is no effective (conventional) method for detecting or predicting its inception. The traditional method of recognizing cavitation in a pump is to declare the event occurring when the total head drops by some arbitrary value (typically 3%) in response to a pressure reduction at the pump inlet. However, the device is already seriously cavitating when this happens. What is actually needed is a practical method to detect impending rather than incipient cavitation. Whereas the detection of incipient cavitation requires the detection of features just after cavitation starts, the anticipation of cavitation requires the detection and identification of precursor features just before it begins. Two recent advances that make this detection possible. The first is acoustic sensors with a bandwidth of 1 MHz and a dynamic range of 80 dB that preserve the fine details of the features when subjected to coarse vibrations. The second is the application of Bayesian parameter estimation which makes it possible to separate weak signals, such as those present in cavitation precursors, from strong signals, such as pump vibration. Bayesian parameter estimation derives a model based on cavitation hydrodynamics and produces a figure of merit of how well it fits the acquired data. Applying this model to an anticipatory engine should lead to a reliable method of anticipating cavitation before it occurs. This paper reports the findings of precursor features using high-performance sensors and Bayesian analysis of weak acoustic emissions in the 100-1000kHz band from an experimental flow loop.
Date: April 25, 1999
Creator: Allgood, G.O.; Dress, W.B.; Hylton, J.O. & Kercel, S.W.
Partner: UNT Libraries Government Documents Department

Vapor Phase Transport Synthesis of Zeolites from Sol-Gel Precursors

Description: A study of zeolite crystallization from sol-gel precursors using the vapor phase transport synthesis method has been performed. Zeolites (ZSM-5, ZSM-48, Zeolite P, and Sodalite) were crystallized by contacting vapor phase organic or organic-water mixtures with dried sodium silicate and dried sodium alumino-silicate gels. For each precursor gel, a ternary phase system of vapor phase organic reactant molecules was explored. The vapor phase reactant mixtures ranged from pure ethylene diamene, triethylamine, or water, to an equimolar mixture of each. In addition, a series of gels with varied physical and chemical properties were crystallized using the same vapor phase solvent mixture for each gel. The precursor gels and the crystalline products were analyzed via Scanning Electron Microscopy, Electron Dispersive Spectroscopy, X-ray mapping, X-ray powder diffraction, nitrogen surface area, Fourier Transform Infrared Spectroscopy, and thermal analyses. The product phase and purity as a function of the solvent mixture, precursor gel structure, and precursor gel chemistry is discussed.
Date: July 14, 2000
Partner: UNT Libraries Government Documents Department

Solventless sol-gel chemistry through ring-opening polymerization of bridged disilaoxacyclopentanes

Description: Disilaoxacyclopentanes have proven to be excellent precursors to sol-gel type materials. These materials have shown promise as precursors for encapsulation and microelectronics applications. The polymers are highly crosslinked and are structurally similar to traditional sol-gels, but unlike typical sol-gels they are prepared without the use of solvents and water, they have low VOC's and show little shrinkage during processing.
Date: April 4, 2000
Partner: UNT Libraries Government Documents Department

Hydrazine N Source for Growth of GaInNAs for Solar Cells

Description: We evaluate hydrazine (Hy) as a nitrogen precursor source for the growth of GaNAs and GaInNAs for application in 1-eV solar cells lattice-matched to GaAs, and compare it to the more commonly used dimethylhydrazine (DMHy). The incorporation efficiency of N into the GaNAs alloy is found to be one to two orders of magnitude higher with Hy than with DMHy. This high N incorporation makes convenient the growth of GaNAs at higher growth temperatures, Tg=650 C, and arsine flows, AsH3/III=44, than are generally possible with the use of DMHy. GaInNAs and GaNAs solar cells are grown under these growth conditions and compared to a GaAs cell grown under the same conditions to determine the extent to which the poor minority-carrier properties routinely observed for the N-containing material can be attributed to the growth conditions. Finally, the background carrier concentrations for Hy- and DMHy-grown material are compared, and little difference is found between the two sources..
Date: May 25, 1999
Creator: Friedman, D. J.; Geisz, G. F.; Kurtz, S. R.; Norman, A. G. (National Renewable Energy Laboratory) & Yeh, Y. C. M. (TECSTAR, Inc.)
Partner: UNT Libraries Government Documents Department


Description: The purpose of this DOE-funded effort is to develop technologies for carbon products from coal-derived feed-stocks. Carbon products can include precursor materials such as solvent extracted carbon ore (SECO) and synthetic pitch (Synpitch). In addition, derived products include carbon composites, fibers, foams and others.
Date: December 12, 2005
Creator: Dadyburjor, Dady; Chen, Chong; Kennel, Elliot B.; Magean, Liviu; Stansberry, Peter G.; Stiller, Alfred H. et al.
Partner: UNT Libraries Government Documents Department

Seedless Polyol Synthesis and CO Oxidation Activity of Monodisperse (111) and (100)-Oriented Rhodium Nanocrystals in Sub-10 nm Sizes

Description: Monodisperse sub-10 nm (6.5 nm) sized Rh nanocrystals with (111) and (100) surface structures were synthesized by a seedless polyol reduction in ethylene glycol, with poly(vinylpyrrolidone) as a capping ligand. When using [Rh(Ac){sub 2}]{sub 2} as the metal precursor, (111)-oriented Rh nanopolyhedra containing 76% (111)-twined hexagons (in 2D projection) were obtained; whereas, when employing RhCl{sub 3} as the metal precursor in the presence of alkylammonium bromide, such as tetramethylammonium bromide and trimethyl(tetradecyl)ammonium bromide, (100)-oriented Rh nanocubes were obtained with 85% selectivity. The {l_brace}100{r_brace} faces of the Rh nanocrystals are stabilized by chemically adsorbed Br{sup -} ions from alkylammonium bromides, which led to (100)-oriented nanocubes. Monolayer films of the (111)-oriented Rh nanopolyhedra and (100)-oriented Rh nanocubes were deposited on silicon wafers in a Langmuir-Blodgett trough to make model 2D nanoarray catalysts. These nanocatalysts were active for CO oxidation by O{sub 2}, and the turnover frequency was independent of nanoparticle shape, consistent with that previously observed for Rh(111) and Rh(100) single crystals.
Date: March 15, 2010
Creator: Zhang, Yawen; Grass, Michael E.; Huang, Wenyu & Somorjai, Gabor A.
Partner: UNT Libraries Government Documents Department

Controlled Assembly of Heterobinuclear Sites on Mesoporous Silica: Visible Light Charge-Transfer Units with Selectable Redox Properties

Description: Mild synthetic methods are demonstrated for the selective assembly of oxo-bridged heterobinuclear units of the type TiOCrIII, TiOCoII, and TiOCeIII on mesoporous silica support MCM-41. One method takes advantage of the higher acidity and, hence, higher reactivity of titanol compared to silanol OH groups towards CeIII or CoII precursor. The procedure avoids the customary use of strong base. The controlled assembly of the TiOCr system exploits the selective redox reactivity of one metal towards another (TiIII precursor reacting with anchored CrVI centers). The observed selectivity for linking a metal precursor to an already anchored partner versus formation of isolated centers ranges from a factor of six (TiOCe) to complete (TiOCr, TiOCo). Evidence for oxo bridges and determination of the coordination environment of each metal centers is based on K-edge EXAFS (TiOCr), L-edge absorption spectroscopy (Ce), and XANES measurements (Co, Cr). EPR, optical, FT-Raman and FT-IR spectroscopy furnish additional details on oxidation state and coordination environment of donor and acceptor metal centers. In the case of TiOCr, the integrity of the anchored group upon calcination (350 oC) and cycling of the Cr oxidation state is demonstrated. The binuclear units possess metal-to-metal charge-transfer transitions that absorb deep in the visible region. The flexible synthetic method for assembling the units opens up the use of visible light charge transfer pumps featuring donor or acceptor metals with selectable redox potential.
Date: June 4, 2008
Creator: Frei, Heinz; Han, Hongxian & Frei, Heinz
Partner: UNT Libraries Government Documents Department


Description: Melanin production by S. algae BrY occurred during late/post-exponential growth in lactate-basal-salts liquid medium supplemented with tyrosine or phenylalanine. The antioxidant ascorbate inhibited melanin production, but not production of the melanin precursor, homogentisic acid. In the absence of ascorbate, melanin production was inhibited by the 4-hydroxyplenylpyruvate dioxygenase inhibitor, sulcotrione and Fe(II) (>0.2mM). These data support the hypothesis that pigment production by S. algae BrY was a result the conversion of tyrosine or phenylalanine to homogentisic acid which was excreted, auto-oxidized and self-polymerized to form pyomelanin. The inverse relationship between Fe(II) concentration and pyomelanin production has implications that pyomelanin may play a role in iron assimilation under Fe(II) limiting conditions.
Date: November 29, 2006
Creator: Turick, C; Frank Caccavo, F; Jr., J & Louis S. Tisa, L
Partner: UNT Libraries Government Documents Department

Calcium Carbonate Storage in Amorphous Form and Its Template-Induced Crystallization

Description: Calcium carbonate crystallization in organisms often occurs through the transformation from the amorphous precursor. It is believed that the amorphous phase could be temporarily stabilized and stored, until its templated transition to the crystalline form is induced. Here we develop a bio-inspired crystallization strategy that is based on the above mechanism. Amorphous calcium carbonate (ACC) spherulitic particles are formed and stabilized on a self-assembled monolayer (SAM) of hydroxy-terminated alkanethiols on Au surface. The ACC is stored as a reservoir for ions and is induced to crystallize on command by introducing a secondary surface that is functionalized with carboxylic acid-terminated SAM. This secondary surface acts as a template for oriented and patterned nucleation. Various oriented crystalline arrays and micropatterned films are formed. We also show that the ACC phase can be doped with foreign ions (e.g. Mg) and organic molecules (e.g. dyes) and that these dopants later function as growth modifiers of calcite crystals and become incorporated into the crystals during the transformation process of ACC to calcite. We believe that our strategy opens the way of using a stabilized amorphous phase as a versatile reservoir system that can be converted in a highly controlled fashion to a crystalline form upon contacting the nucleating template.
Date: August 31, 2007
Creator: Han, T Y & Aizenberg, J
Partner: UNT Libraries Government Documents Department

The eukaryotic translation elongation factor eEF1A2 induces neoplastic properties and mediates tumorigenic effects of ZNF217 in precursor cells of human ovarian carcinomas

Description: Ovarian epithelial carcinomas (OEC) frequently exhibit amplifications at the 20q13 locus which is the site of several oncogenes, including the eukaryotic elongation factor EEF1A2 and the transcription factor ZNF217. We reported previously that overexpressed ZNF217 induces neoplastic characteristics in precursor cells of OEC. Unexpectedly, ZNF217, which is a transcriptional repressor, enhanced expression of eEF1A2. In this study, array comparative genomic hybridization, single nucleotide polymorphism and Affymetrix analysis of ZNF217-overexpressing cell lines confirmed consistently increased expression of eEF1A2 but not of other oncogenes, and revealed early changes in EEF1A2 gene copy numbers and increased expression at crisis during immortalization. We defined the influence of eEF1A2 overexpression on immortalized ovarian surface epithelial cells, and investigated interrelationships between effects of ZNF217 and eEF1A2 on cellular phenotypes. Lentivirally induced eEF1A2 overexpression caused delayed crisis, apoptosis resistance and increases in serum-independence, saturation densities, and anchorage independence. siRNA to eEF1A2 reversed apoptosis resistance and reduced anchorage independence in eEF1A2-overexpressing lines. Remarkably, siRNA to eEF1A2 was equally efficient in inhibiting both anchorage independence and resistance to apoptosis conferred by ZNF217 overexpression. Our data define neoplastic properties that are caused by eEF1A2 in nontumorigenic ovarian cancer precursor cells, and suggest that eEF1A2 plays a role in mediating ZNF217-induced neoplastic progression.
Date: April 25, 2008
Creator: Sun, Yu; Wong, Nicholas; Guan, Yinghui; Salamanca, Clara M.; Cheng, Jung Chien; Lee, Jonathan M. et al.
Partner: UNT Libraries Government Documents Department

Calculations of precursor propagation in dispersive dielectrics.

Description: The present study is a numerical investigation of the propagation of electromagnetic transients in dispersive media. It considers propagation in water using Debye and composite Rocard-Powles-Lorentz models for the complex permittivity. The study addresses this question: For practical transmitted spectra, does precursor propagation provide any features that can be used to advantage over conventional signal propagation in models of dispersive media of interest? A companion experimental study is currently in progress that will attempt to measure the effects studied here.
Date: August 1, 2003
Creator: Bacon, Larry Donald
Partner: UNT Libraries Government Documents Department

The early stages of microstructural development of the colony structure in Bi-2223 tapes.

Description: The current protocol for processing (Bi,Pb)2Sr2Ca2Cu3010-(B i-2223) multifilamentary tapes involves the in situ formation of the primary phase from a suitable mixture of precursor phases. As such, the developments during the first few minutes of heat treatment determine to a large extent the efficiency of primary phase development, competing secondary phase development, texture evolution, and grain-to-grain connectivity. This work documents the development of the liquid phase, secondary phases, defects which may affect alignment and reaction kinetics, and the precipitation of Bi-2223 from the liquid phase.
Date: January 1, 2001
Creator: Holesinger, T. G. (Terry G.)
Partner: UNT Libraries Government Documents Department


Description: The purpose of this DOE-funded effort is to develop technologies for carbon products from coal-derived feedstocks. Carbon products can include precursor materials such as solvent extracted carbon ore (SECO) and synthetic pitch (Synpitch). In addition, derived products include carbon composites, fibers, foams and others. Key milestones included producing hydrogenated coal in the Hydrotreating Facility for the first time. The facility is now operational, although digital controls have not yet been completely wired. In addition, ultrasound is being used to investigate enhanced dissolution of coal. Experiments have been carried out.
Date: February 23, 2006
Creator: Dadyburjor, Dady; Chen, Chong; Kennel, Elliot B.; Magean, Liviu; Stansberry, Peter G.; Stiller, Alfred H. et al.
Partner: UNT Libraries Government Documents Department

Characteristics of CoxTi1-xO2 thin films deposited by MOCVD

Description: This paper deals with the growth and characterization of ferromagnetic cobalt doped TiO{sub 2} thin films deposited by liquid precursor metal organic chemical vapor deposition (MOCVD) using a new combination of the source materials Co(TMHD){sub 3}, tetrahydrofuran (THF), and titanium isopropoxide (TIP). An array of experiments reveals the intrinsic ferromagnetic nature of the grown films, and suggests that the magnetism is not generated by oxygen vacancies.
Date: May 9, 2008
Creator: McClure, A.; Kayani, A.; Idzerda, Y.U.; Arenholz, E. & Cruz, E.
Partner: UNT Libraries Government Documents Department

Microwave Plasma Chemical Vapor Deposition of Nano-Structured Sn/C Composite Thin-Film Anodes for Li-ion Batteries

Description: In this paper we report results of a novel synthesis method of thin-film composite Sn/C anodes for lithium batteries. Thin layers of graphitic carbon decorated with uniformly distributed Sn nanoparticles were synthesized from a solid organic precursor Sn(IV) tert-butoxide by a one step microwave plasma chemical vapor deposition (MPCVD). The thin-film Sn/C electrodes were electrochemically tested in lithium half cells and produced a reversible capacity of 440 and 297 mAhg{sup -1} at C/25 and 5C discharge rates, respectively. A long term cycling of the Sn/C nanocomposite anodes showed 40% capacity loss after 500 cycles at 1C rate.
Date: February 1, 2008
Creator: Stevenson, Cynthia; Marcinek, M.; Hardwick, L.J.; Richardson, T.J.; Song, X. & Kostecki, R.
Partner: UNT Libraries Government Documents Department