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The development of precipitated iron catalysts with improved stability

Description: The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal li… more
Date: May 6, 1992
Creator: Abrevaya, H.
Partner: UNT Libraries Government Documents Department
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Modeling studies on the precipitation of Kr after implantation into metals

Description: A rate-theory approach is applied to interpreting observations on the precipitation of Kr injected into Ni at temperatures between 25 and 560/degree/C. At temperatures of 400/degree/C or higher, the implanted Kr precipitates evolve into a bi-modal size distribution containing small solid precipitates and an additional population of larger, faceted bubbles. The calculations explore the dependence of the observed bi-modal distribution on the maximum size of the solid Kr precipitates and the effec… more
Date: February 1, 1988
Creator: Rest, J.
Partner: UNT Libraries Government Documents Department
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NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: The primary objective of the project is to examine the relations between the catalytic and magnetic properties of the copper-cobalt higher alcohol synthesis catalysts. We have undertaken to investigate the magnetic character by studying the Nuclear Quadrupole resonance of copper and (Zerofield) Nuclear Magnetic Resonance of cobalt in copper cobalt catalysts.
Date: December 17, 1991
Partner: UNT Libraries Government Documents Department
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Drilling fluid/formation interaction at simulated in situ geothermal conditions. Final report

Description: Interaction of drilling fluids with a geothermal reservoir formation can result in significant permeability impairment and therefore reduced well productivity. This interaction is studied under simulated in situ geothermal conditions of overburden stress, pore fluid pressure, temperature, and pore fluid chemistry. Permeability impairment of an East Mesa KGRA reservoir material is evaluated as a function of stagnation time, drilling fluid, and temperature. Results indicate that all of these para… more
Date: July 1, 1980
Creator: Enniss, D. O.; Bergosh, J. L.; Butters, S. W. & Jones, A. H.
Partner: UNT Libraries Government Documents Department
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NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: The primary objective of the project is to examine the relations between the catalytic and magnetic properties of the copper-cobalt higher alcohol synthesis catalysts. We have undertaken to investigate the magnetic character by studying the Nuclear Quadrupole resonance of copper and (Zerofield) Nuclear Magnetic Resonance of cobalt in copper cobalt catalysts.
Date: January 14, 1992
Partner: UNT Libraries Government Documents Department
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Environmental radiation safety: source term modification by soil aerosols. Interim report

Description: The goal of this project is to provide information useful in estimating hazards related to the use of a pure refractory oxide of /sup 238/Pu as a power source in some of the space vehicles to be launched during the next few years. Although the sources are designed and built to withstand re-entry into the earth's atmosphere, and to impact with the earth's surface without releasing any plutonium, the possibility that such an event might produce aerosols composed of soil and /sup 238/PuO/sub 2/ ca… more
Date: August 1, 1980
Creator: Moss, O.R.; Allen, M.D.; Rossignol, E.J. & Cannon, W.C.
Partner: UNT Libraries Government Documents Department
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New computer-controlled precipitator at the Savannah River Plant

Description: A new plutonium triflouride preciptation facility was successfully started up on the first attempt May 13, 1987 at the Savannah River Plant (SRP). This new facility provided a 75% reduction in radiation exposure, a substantial improvement in process performance, and elimination of the major SRP process bottleneck. This was accomplished through sound engineering, improved process control, process automation, and extensive testing of components, assemblies, and entire system prior to ''… more
Date: January 1, 1988
Creator: Moore, E. N.; Robbins, C. C. & Murdock, D. W.
Partner: UNT Libraries Government Documents Department
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Conditioning of geothermal brine effluents for injection: use of coagulants

Description: The use of various chemical coagulants and flocculants with spent geothermal brine for enhancing the removal of colloidal solids prior to injection was studied. Brine at 80 to 85/sup 0/C was obtained from the injection line of the SDG and E/DOE Geothermal Loop Experimental Facility during a period of operation with Magmamax No. 1 Fluid. The solids consist primarily of an iron-rich amorphous silica and heavy metal sulfides, principally lead. Standard jar testing equipment was used to carry out t… more
Date: February 1, 1978
Creator: Quong, R.; Shoepflin, F. & Stout, N.D.
Partner: UNT Libraries Government Documents Department
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Characterization of Oil and Gas Reservoir Heterogeneity

Description: The ultimate objective of this cooperative research project is to characterize Alaskan petroleum reservoirs in terms of their reserves, physical and chemical properties, geologic configuration in relation to lithofacies and structure, and development potential. The project has two tasks: Task 1 is a geological description of the reservoirs including petrophysical properties, i.e., porosity, permeability, permeability variation, formation depth, temperature, and net pay, facies changes and reser… more
Date: January 1, 1992
Creator: Sharma, G. D.
Partner: UNT Libraries Government Documents Department
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Sb interactions with TaC precipitates and Cu in ion-implanted. cap alpha. -Fe

Description: The interactions of Sb with the other species implanted into Fe to form Fe-Ta-C-Sb and Fe-Cu-Sb alloys have been examined with transmission electron microscopy and Rutherford backscattering following annealing at 873/sup 0/K. Trapping of Sb at TaC precipitates is observed in the former alloy just as was previously observed in Fe-Ti-C-Sb. In Fe-Cu-Sb, Sb interactions are governed by the atomic ratio of Sb to Cu. For ratios between 0.2 to 0.4, the compound ..beta..-Cu/sub 3/Sb was observed to for… more
Date: January 1, 1980
Creator: Follstaedt, D. M. & Myers, S. M.
Partner: UNT Libraries Government Documents Department
open access

The development of precipitated iron catalysts with improved stability

Description: The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal li… more
Date: May 6, 1992
Creator: Abrevaya, H.
Partner: UNT Libraries Government Documents Department
open access

Relationship of regional water quality to aquifer thermal energy storage

Description: Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to … more
Date: November 1, 1983
Creator: Allen, R.D.
Partner: UNT Libraries Government Documents Department
open access

The development of precipitated iron catalysts with improved stability

Description: The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal li… more
Date: May 6, 1992
Creator: Abrevaya, H.
Partner: UNT Libraries Government Documents Department
open access

General Chemistry Division quarterly report, July--September 1977

Description: Analytical research and development work is reported on multielement analysis, time-resolved spectroscopy, fluorescence analysis, ionization potential of NP, excited state chemistry, polarized x ray sources, potentiometric titration of Na, determination of TATB in DMSO, determination of nitrobenzene in TATB, analysis of explosive composites, mass spectrometer automation, mass spectra calculation, solids formation in geothermal brine, water quality laboratory automation, aerosol coagulation, and… more
Date: November 30, 1977
Creator: Harrar, J.E. (ed.)
Partner: UNT Libraries Government Documents Department
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Status of /sup 241/Am recovery and purification at Los Alamos Scientific Laboratory

Description: Americium recovery was initiated at Los Alamos Scientific Laboratory (LASL) in the late 1940's. The early procedures separated gram quantities of americium from large amounts of impurities including plutonium and the rare earths. Ion exchange procedures were developed for further purification. Until recently, no routine processing of americium has been done at LASL for several years. The increasing demand for americium in oil-well logging instruments and other uses led LASL to develop and insta… more
Date: January 1, 1980
Creator: Ramsey, H. D.; Clifton, D. G.; Hayter, S. W.; Penneman, R. A. & Christensen, E. L.
Partner: UNT Libraries Government Documents Department
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Effects of silica redistribution on performance of high-level nuclear waste repositories in saturated geologic formations

Description: Evaluation of the thermohydrological conditions near high-level waste packages is needed for the design of the waste canister and for overall repository design and performance assessment. Most available studies in this area have assumed that the hydrologic properties of the host rock do not change in response to the thermal, mechanical or chemical effects caused by waste emplacement. However, the ramifications of this simplifying assumption have not been substantiated. We have studied dissoluti… more
Date: November 1, 1985
Creator: Verma, A. & Pruess, K.
Partner: UNT Libraries Government Documents Department
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Silver recovery system data

Description: In August of 1990 the Savannah River Site Photography Group began testing on a different type of silver recovery system. This paper describes the baseline study and the different phases of installation and testing of the system.
Date: August 26, 1991
Creator: Boulineau, B.
Partner: UNT Libraries Government Documents Department
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Damage-rate gradient effects on radiation-induced segregation and phase stability in irradiated alloys

Description: Recent studies have shown that significant compositional redistribution in irradiated alloys can be induced by the gradients in the atomic displacement rates resulting from nonuniform defect production, in addition to the commonly-observed solute segregation at defect sinks. This process gives rise to complex local phase transformations during light-ion bombardment or irradiation with focused electron beams in the high-voltage electron microscope. Results of our theoretical and experimental inv… more
Date: July 1, 1985
Creator: Lam, N.Q. & Okamoto, P.R.
Partner: UNT Libraries Government Documents Department
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Microstructure and tensile properties of heavily irradiated 5052-0 aluminum alloy

Description: During neutron irradiation of an aluminum 2.2% magnesium solid solution alloy in the High Flux Isotope Reactor to fast and thermal fluences > 10/sup 27/ neutrons (n)m/sup 2/ at 328/sup 0/K (0.35 T/sub m/) about seven percent insoluble, transmutant silicon was produced. Some of this silicon reacted with the dissolved magnesium to form a fine precipitate of Mg/sub 2/Si. A tight dislocation structure was also created. The alloy showed good resistance to cavity formation. Tension tests at 323, 373,… more
Date: January 1, 1980
Creator: Farrell, K.
Partner: UNT Libraries Government Documents Department
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Composition of eta carbide in Hastelloy N after aging 10,000 hr at 815/sup 0/C

Description: The composition of the eta carbide in Hastelloy N containing 0.7 wt percent Si in the alloy approaches M/sub 12/C, rather than M/sub 6/C as indicated in the alloy literature. The silicon content of the eta phase in this case was about 25 at. percent, much higher than has been observed in less highly alloyed material. The data do not permit a definition of the limiting compositions of the phases.
Date: November 1, 1977
Creator: Leitnaker, J. M.; Potter, G. A.; Bradley, D. J.; Franklin, J. C. & Laing, W. R.
Partner: UNT Libraries Government Documents Department
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Removal of silica from spent geothermal brine

Description: Preliminary survey experiments conducted at the LLL Salton Sea Geothermal Test Site in April and May, 1977 are reported. The addition of caustic to raise the brine pH to approximately 6 precipitated silica and other materials. The addition of flocculating agents, such as ferric hydroxide, aids settling and filtration. Small-scale pilot plant studies are recommended.
Date: December 1, 1977
Creator: Ryon, R.W. & Hill, J.H.
Partner: UNT Libraries Government Documents Department
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Laboratory-scale evaluations of alternative plutonium precipitation methods

Description: Plutonium(III), (IV), and (VI) carbonate; plutonium(III) fluoride; plutonium(III) and (IV) oxalate; and plutonium(IV) and (VI) hydroxide precipitation methods were evaluated for conversion of plutonium nitrate anion-exchange eluate to a solid, and compared with the current plutonium peroxide precipitation method used at Rocky Flats. Plutonium(III) and (IV) oxalate, plutonium(III) fluoride, and plutonium(IV) hydroxide precipitations were the most effective of the alternative conversion methods t… more
Date: February 8, 1984
Creator: Martella, L. L.; Saba, M. T. & Campbell, G. K.
Partner: UNT Libraries Government Documents Department
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