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Fiber Optical Micro-detectors for Oxygen Sensing in Power Plants

Description: A reflection mode fiber optic oxygen sensor that can operate at high temperatures for power plant applications is being developed. The sensor is based on the {sup 3}O{sub 2} quenching of the red emission from hexanuclear molybdenum chloride clusters. Our approach towards immobilizing the potassium salt of the molybdenum cluster, K{sub 2}Mo{sub 6}Cl{sub 14}, at the far end of an optical fiber is to embed the cluster in a thermally cured sol-gel matrix particle. Due to the improved mechanical properties of this approach high temperature sensor measurements were performed up to 100 C. These are promising results for a high temperature fiber optical oxygen sensor based on molybdenum chloride clusters.
Date: September 30, 2006
Creator: Baker, Gregory L.; Ghosh, Ruby N.; Osborn, D. J. & Zhang, Po
Partner: UNT Libraries Government Documents Department

Microseismic monitoring of the B-sand hydraulic fracture experiment at the DOE/GRI multi-site project

Description: Six hydraulic-fracture injections into a fluvial sandstone at a depth of 4500 ft were monitored with multi-level triaxial seismic receivers in two wells, resulting in maps of the growth and final geometry of each fracture based upon microseismic activity. These diagnostic images show that the hydraulic fractures are highly contained for smaller-volume KCl-water injections, but height growth is significant for the larger-volume, higher-rate, higher-viscosity treatments. Fracture lengths for most injections are similar. Final results are also compared with fracture models.
Date: November 1996
Creator: Warpinski, N. R.; Wright, T. B.; Peterson, R. E. & Branagan, P. T.
Partner: UNT Libraries Government Documents Department

Re-Evaluation of Chemical Potential of Imperial Irrigation District Well No. 1

Description: The chemical potential of the brine from I.I.D. Well No. 1 was evaluated and reported in Rogers Engineering Coo, Inc. March 1962 Flow Test Report. This evaluation considered only the recovery of sodium chloride, as the prime salable product and alternately as the raw material for conversion to salable chlorine and caustic. Both cases showed low net revenue relative to the estimated capital investment required. The subsequent three month well flow test indicates continued production of a consistent type brine can be expected from this well. Based on the flow and composition data established during this test period, chemical production potential has been examined. The separation and sale of high quality potassium chloride appears attractive. Attached are sketches of each of the two production schemes considered with estimates of capital and operating costs and revenue.
Date: April 1, 1963
Partner: UNT Libraries Government Documents Department

Phase equilibria in the system H{sub 2}O-NaCl-KCl-MgCl{sub 2} relevant to salt cake processing

Description: One waste product in recycling of Al is salt cake, a mixture of Al, salts, and residue oxides. Several methods have been proposed to recycle salt cake, one involving high-temperature leaching of salts from the salt cake. The salt composition can be approximated as a mixture predominantly of NaCl and KCl salts, with lesser amounts of Mg chloride. In order to better assess the feasibility of recycling salt cake, an experimental study was conducted of phase equilibria in the system H{sub 2}O-NaCl-KCl-MgCl{sub 2} at pressure (P), temperature (T), and composition conditions appropriate for high- temperature salt cake recycling. These experiments were designed to evaluate the effect of small amounts (2-10 wt%) of MgCl{sub 2} on solubilities of halite (NaCl) and sylvite (KCl) in saturated solutions (30-50 wt% NaCl+KCl; NaCl:KCl = 1:1 and 3:1) at elevated P and T.
Date: February 1, 1997
Creator: Bodnar, R.J.; Vityk, M.O.; Hryn, J.N. & Mavrogenes, J.
Partner: UNT Libraries Government Documents Department

Protein-salt binding data from potentiometric titrations of lysozyme in aqueous solutions containing KCl

Description: An existing method for potentiometric titrations of proteins was improved, tested and applied to titrations of the enzyme hen-egg-white lysozyme in aqueous solutions containing KCl at ionic strengths from 0.1 M to 2.0 M at 25 C. Information about the protein`s net charge dependence on pH and ionic strength were obtained and salt binding numbers for the system were calculated using a linkage concept. For the pH range 2.5--11.5, the net charge slightly but distinctly increases with increasing ionic strength between 0.1 M and 2.0 M. The differences are most distinct in the pH region below 5. Above pH 11.35, the net charge decreases with increasing ionic strength. Preliminary calculation of binding numbers from titration curves at 0.1 M and 1.0 M showed selective association of chloride anions and expulsion of potassium ions at low pH. Ion-binding numbers from this work will be used to evaluate thermodynamic properties and to correlate crystallization or precipitation phase-equilibrium data in terms of a model based on the integral-equation theory of fluids which is currently under development.
Date: March 1, 1997
Creator: Engmann, J.; Blanch, H.W. & Prausnitz, J.M.
Partner: UNT Libraries Government Documents Department

Concentration and precipitation of NaCl and KCl from salt cake leach solutions by electrodialysis

Description: Electrodialysis was investigated for cost-effective recovery of salt from salt cake leach solutions. (Salt cake is a waste stream generated by the aluminum industry during treatment of aluminum drosses and scrap.) We used a pilot-scale electrodialysis stack of 5 membrane pairs, each with an effective area of 0.02 m{sup 2}. The diluate stream contained synthetic NaCl, KCl,mixtures of NaCl and KCl, and actual salt cake leach solutions (mainly NaCl and KCl, with small amounts of MgCl{sub 2}). We concentrated and precipitated NaCl and KCl salts from the concentrate steam when the initial diluate stream concentration was 21.5 to 28.8 wt% NaCl and KCl. We found that water transferring through the membranes was a significant factor in overall efficiency of salt recovery by electrodialysis.
Date: February 9, 1997
Creator: Sreenivasarao, K; Patsiogiannis, F. & Hryn, J.N.
Partner: UNT Libraries Government Documents Department

Uranium isotopic composition and uranium concentration in special reference material SRM A (uranium in KCl/LiCl salt matrix)

Description: To help assure that analysis data of known quality will be produced in support of demonstration programs at the Fuel Conditioning Facility at Argonne National Laboratory-West (Idaho Falls, ID), a special reference material has been prepared and characterized. Designated SRM A, the material consists of individual units of LiCl/KCl eutectic salt containing a nominal concentration of 2.5 wt. % enriched uranium. Analyses were performed at Argonne National Laboratory-East (Argonne, IL) to determine the uniformity of the material and to establish reference values for the uranium concentration and uranium isotopic composition. Ten units from a batch of approximately 190 units were analyzed by the mass spectrometric isotope dilution technique to determine their uranium concentration. These measurements provided a mean value of 2.5058 {+-} 0.0052 wt. % U, where the uncertainty includes estimated limits to both random and systematic errors that might have affected the measurements. Evidence was found of a small, apparently random, non-uniformity in uranium content of the individual SRM A units, which exhibits a standard deviation of 0.078% of the mean uranium concentration. Isotopic analysis of the uranium from three units, by means of thermal ionization mass spectrometry with a special, internal-standard procedure, indicated that the uranium isotopy is uniform among the pellets with a composition corresponding to 0.1115 {+-} 0.0006 wt. % {sup 234}U, 19.8336 {+-} 0.0059 wt. % {sup 235}U, 0.1337 {+-} 0.0006 wt. % {sup 236}U, and 79.9171 {+-} 0.0057 wt. % {sup 238}U.
Date: July 1, 1997
Creator: Graczyk, D.G.; Essling, A.M.; Sabau, C.S.; Smith, F.P.; Bowers, D.L. & Ackerman, J.P.
Partner: UNT Libraries Government Documents Department

Production of high specific activity silicon-32

Description: This is the final report of a three-year, Laboratory Directed Research and Development Project (LDRD) at Los Alamos National Laboratory (LANL). There were two primary objectives for the work performed under this project. The first was to take advantage of capabilities and facilities at Los Alamos to produce the radionuclide {sup 32}Si in unusually high specific activity. The second was to combine the radioanalytical expertise at Los Alamos with the expertise at the University of California to develop methods for the application of {sup 32}Si in biological oceanographic research related to global climate modeling. The first objective was met by developing targetry for proton spallation production of {sup 32}Si in KCl targets and chemistry for its recovery in very high specific activity. The second objective was met by developing a validated field-useable, radioanalytical technique, based upon gas-flow proportional counting, to measure the dynamics of silicon uptake by naturally occurring diatoms.
Date: December 31, 1998
Creator: Phillips, D. R. & Brzezinski, M. A.
Partner: UNT Libraries Government Documents Department

Evaluation of Fiber Separators for Use in Thermal Batteries

Description: Fiberglass tape and borosilicate filter discs impregnated with molten LiCl-KCl eutectic were examined for potential use as separators for high-temperature LiSi/LiCl-KCl/FeS{sub 2} thermal batteries. Test discs were punched from these materials and evaluated at 400 C in single cells at a steady-state current of 63 mA/cm{sup 2}. The performance generally improved with electrolyte loading for most of the materials. Better results were obtained with the filter discs than with the tape. The best overall results were obtained with Whatman GF/A discs. Active lives for cells with these separators were about 85% of the standard cells with pressed-powder separators. More work with other materials and electrolytes over a wider temperature range is underway, along with 5-cell-battery tests.
Date: September 8, 1999
Creator: GUIDOTTI,RONALD A. & REINHARDT,FREDERICK W.
Partner: UNT Libraries Government Documents Department

Novel Self-Thickening Chemicals for Improved Conformance Control

Description: The objective of this project is to identify single chemical agents that exhibit a desirable rheological property whereby if such a chemical is dissolved in salt water it increases the solution viscosity significantly with time. We term that behavior as 'self-thickening' and have nicknamed this as 'T85 technology'. As detailed in the original project proposal, such single chemical products can be applied to advantage as agents for selectively slowing or blocking high flow water channels in subsurface oil reservoirs. The net effect is a decrease in water and an increase in oil flow and production. The initial testing has focused on five different synthetic co-polymers that have two or more chemical groups. These chemicals were dissolved at a concentration of 2500 ppm into different salt solutions (sodium chloride, potassium chloride, and calcium chloride) that encompass a range of dissolved salt concentrations. For the sodium chloride and potassium chloride solutions the salt concentration ranged from 1-5 wt%. The calcium chloride dihydrate sample concentrations ranged from 0.1-1 wt%. One set of samples being aged at 25 C and a second set at 50 C. Viscosity measurements versus aging time show two of these agents may exhibit apparent self-thickening behavior under certain salinity and temperature conditions. Generally the effect is greater in lower salinity NaCl brines and at 25 C. Preliminary flow experiments confirm that the aged fluids exhibit increased effective viscosity while flowing through a porous medium (sand pack). These flow tests include the case of the chemical fluid being aged on the bench before injection into a sand pack, and also a second series of sand packs where fresh chemical fluid is injected and allowed to age in-situ. Thus, the results of the static ageing tests together with the flow tests are a technical validation of the T85 concept.
Date: July 18, 2011
Creator: Patrick J. Shuler, Ph.D.
Partner: UNT Libraries Government Documents Department

REACTIONS OF SODIUM PEROXIDE WITH COMPONENTS OF LEGACY PLUTONIUM MATERIALS

Description: Plutonium oxide (PuO{sub 2}) calcined at >900 C resists dissolution in nitric acid (HNO{sub 3})-potassium fluoride (KF) solutions, a common method for their dissolution. The Savannah River National Laboratory (SRNL) has developed an alternate method for large samples of PuO{sub 2}-bearing materials using sodium peroxide (Na{sub 2}O{sub 2}) fusion as a pretreatment. The products of the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} have been reported in the literature. As part of the SRNL development effort, additional data about the reaction between Na{sub 2}O{sub 2} and PuO{sub 2} were required. Also needed were data concerning the reaction of Na{sub 2}O{sub 2} with other components that may be present in the feed materials. Sodium peroxide was reacted with aluminum metal (Al), beryllium metal (Be), graphite, potassium chloride (KCl), magnesium chloride (MgCl{sub 2}), and calcium chloride (CaCl{sub 2}). The paper reports and discusses the reaction products of these and related compounds with Na{sub 2}O{sub 2}.
Date: October 4, 2011
Creator: Pierce, R.; Missimer, D. & Crowder, M.
Partner: UNT Libraries Government Documents Department