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A Compilation and Evaluation of Mechanical, Thermal, and Electrical Properties of Selected Polymers

Description: From Abstract: "This compilation abstracts original experimental data on the mechanical, thermal, and electrical properties of six commercially available polymers. The data are also summarized and a brief description of each polymer is included."
Date: September 1973
Creator: Schramm, R. E.; Clark, A. F. & Reed, R. P.
Partner: UNT Libraries Government Documents Department

Development of a Simplified Fracture Toughness Tool for Polymers

Description: This thesis presents research toward the development of a simple inexpensive fracture toughness tool for polymeric materials. Experiments were conducted to test the specimen configuration and the fracture toughness tool against an established ASTM standard for polymer fracture toughness, D5045, and a commonly used four-point bend method. The materials used in this study were polycarbonate and high density polyethylene. Reductions in both the production time and the variability resulting from the preparation of the specimens were addressed through the use of specially designed fixtures. The effects from the razor cut depths used in the chevron notch were compared to the fracture toughness values obtained in order to determine the effect upon the validity of the fracture toughness.
Date: August 1997
Creator: Marnock, Patrick J. (Patrick Joseph)
Partner: UNT Libraries

Theoretical and Experimental Investigations Concerning Microgels of Varied Spherical Geometries

Description: Polymer gels have been studied extensively due to their ability to simulate biological tissues and to swell or collapse reversibly in response to external stimuli. This work presents a variety of studies using poly-N-isopropylacrylamide (PNIPA) hydrogels. The projects have been carried out both in the lab of Dr. Zhibing Hu and in collaboration with others outside of UNT: (1) an analysis of the swelling kinetics of microgel spherical shells prepared using a novel design of microfluidic devices; (2) a comparison of the drug-release rates between nanoparticle structures having either core or core-with-shell (core-shell) designs; (3) an investigation into the thermodynamics of swelling for microgels of exceedingly small size.
Date: August 2012
Creator: Wahrmund, Joshua Joseph
Partner: UNT Libraries

Definition of Brittleness: Connections Between Mechanical and Tribological Properties of Polymers.

Description: The increasing use of polymer-based materials (PBMs) across all types of industry has not been matched by sufficient improvements in understanding of polymer tribology: friction, wear, and lubrication. Further, viscoelasticity of PBMs complicates characterization of their behavior. Using data from micro-scratch testing, it was determined that viscoelastic recovery (healing) in sliding wear is independent of the indenter force within a defined range of load values. Strain hardening in sliding wear was observed for all materials-including polymers and composites with a wide variety of chemical structures-with the exception of polystyrene (PS). The healing in sliding wear was connected to free volume in polymers by using pressure-volume-temperature (P-V-T) results and the Hartmann equation of state. A linear relationship was found for all polymers studied with again the exception of PS. The exceptional behavior of PS has been attributed qualitatively to brittleness. In pursuit of a precise description of such, a quantitative definition of brittleness has been defined in terms of the elongation at break and storage modulus-a combination of parameters derived from both static and dynamic mechanical testing. Furthermore, a relationship between sliding wear recovery and brittleness for all PBMs including PS is demonstrated. The definition of brittleness may be used as a design criterion in selecting PBMs for specific applications, while the connection to free volume improves also predictability of wear behavior.
Date: August 2008
Creator: Hagg Lobland, Haley E.
Partner: UNT Libraries

Cyclization Phenomena in the Sol-Gel Polymerization of a,w-Bis(triethoxysilyl)alkanes and Incorporation of the Cyclic Structures into Network Silsesquioxane Polymers

Description: Intramolecular cyclizations during acid-catalyzed, sol-gel polymerizations of ct,co- bis(tietioxysilyl)aWmes substintidly lengtien gelties formonomers witietiylene- (l), propylene- (2), and butylene-(3)-bridging groups. These cyclizations reactions were found, using mass spectrometry and %i NMR spectroscopy, to lead preferentially to monomeric and dimeric products based on six and seven membered disilsesquioxane rings. 1,2- Bis(triethoxysilyl)ethane (1) reacts under acidic conditions to give a bicyclic drier (5) that is composed of two annelated seven membered rings. Under the same conditions, 1,3- bis(triethoxysilyl)propane (2), 1,4-bis(triethoxysilyl)butane (3), and z-1,4- bis(triethoxysilyl)but-2-ene (10) undergo an intramolecular condensation reaction to give the six membemd and seven membered cyclic disilsesquioxanes 6, 7, and 11. Subsequently, these cyclic monomers slowly react to form the tricyclic dirners 8,9 and 12. With NaOH as polymerization catalyst these cyclic silsesquioxanes readily ~aeted to afford gels that were shown by CP MAS z%i NMR and infr=d spectroscopes to retain some cyclic structures. Comparison of the porosity and microstructwe of xerogels prepared from the cyclic monomers 6 and 7 with gels prepared directly from their acyclic precursors 2 and 3, indicate that the final pore structure of the xerogels is markedly dependent on the nature of the precursor. In addition, despite the fact that the monomeric cyclic disilsesquioxane species can not be isolated from 1-3 under basic conditions due to their rapid rate of gelation, spectroscopic techniques also detected the presence of the cyclic structures in the resulting polymeric gels.
Date: January 4, 1999
Creator: Alam, T.M.; Carpenter, J.P.; Dorhout, P.K.; Greaves, J.; Loy, D.A.; Shaltout, R. et al.
Partner: UNT Libraries Government Documents Department

Corner rounding in EUV photoresist: tuning through molecular weight, PAG size, and development time

Description: In this paper, the corner rounding bias of a commercially available extreme ultraviolet photoresist is monitored as molecular weight, photoacid generator (PAG) size, and development time are varied. These experiments show that PAG size influences corner biasing while molecular weight and development time do not. Large PAGs are shown to exhibit less corner biasing, and in some cases, lower corner rounding, than small PAGs. In addition, heavier resist polymers are shown to exhibit less corner rounding than lighter ones.
Date: December 31, 2009
Creator: Anderson, Christopher; Daggett, Joe & Naulleau, Patrick
Partner: UNT Libraries Government Documents Department

Development of a General Shocked-Materials-Response Description for Simulations

Description: This report outlines broad modeling issues pertaining to polymeric materials behavior under detonation conditions. Models applicable system wide are necessary to cope with the broad range of polymers and complex composite forms that can appear in Laboratory weapons systems. Nine major topics are discussed to span the breadth of materials, forms, and physical phenomena encountered when shocking polymers and foams over wide ranges of temperatures, pressures, shock strengths, confinement conditions, and geometries. The recommendations for directions of more intensive investigation consider physical fidelity, computational complexity, and application over widely varying physical conditions of temperature, pressure, and shock strength.
Date: July 1, 2000
Creator: Valone, Steven M.
Partner: UNT Libraries Government Documents Department

Development of high energy polymers systems: 6th monthly status report

Description: The major objective of the current program is the preparation of high energy hydroxyl-terminated polyester prepolymers from combinations of energetic diols and dicarboxylic acid chlorides. The initial work was based on the reactions of 4,4-dinitropimeloyl chloride (DNPCl) with 2,2,8,8-tetranitro-4,6-dioxa-1,9-nonanediol (DINOL) and 3(dinitrofluoro- ethoxy)-1,2-propanediol (REX-18). In an effort to develop a smooth and rapid polyester polymerization method, reactions between DNPCl and both DINOL and REX-18 have been carried out in THF containing pyridine. It was expected that the pyridine would act as an HCl acceptor, permitting room temperature polymerizations. This was indeed shown to be the case. In fact, when the glycol and DNPCl were dissolved in THF and pyridine added rapidly, a very exothermic reaction took place, with copious quantities of pyridine hydrochloride being precipitated. Slow addition of pyridine to the reaction mixture also resulted in an exotherm. In both cases, brown polymers were produced and they were very difficult to work-up. The next series of polymerizations will be carried out at 0{degrees}C in an effort to control the polymerizations more carefully and avoid color formation. The diacid chloride of 2-fluoro-2,2-dinitroethoxyfumaric acid has apparently been synthesized. Reactions of the acid with thionyl chloride at 50-60{degrees} for several days followed by a one-hour reflux produced a white solid. It was filtered, washed with hexane and dried in a vacuum dessicator over KOH. The powder melted at 104-106{degrees}. After it is recrystallized, it will be submitted for elemental analyses. Should it prove to be the diacid chloride, it will be reacted with DINOL and REX-18.
Date: July 9, 1969
Creator: Lawton, E.A.
Partner: UNT Libraries Government Documents Department

Interfacial Widths of Conjugated Polymer Bilayers

Description: The interfaces of conjugated polyelectrolyte (CPE)/poly[2-methoxy-5-(2{prime}-ethylhexyloxy)-p-phenylene vinylene] (MEH-PPV) bilayers cast from differential solvents are shown by resonant soft X-ray reflectivity (RSoXR) to be very smooth and sharp. The chemical interdiffusion due to casting is limited to less than 0.6 nm, and the interface created is thus nearly 'molecularly' sharp. These results demonstrate for the first time and with high precision that the nonpolar MEH-PPV layer is not much disturbed by casting the CPE layer from a polar solvent. A baseline is established for understanding the role of interfacial structure in determining the performance of CPE-based polymer light-emitting diodes. More broadly, we anticipate further applications of RSoXR as an important tool in achieving a deeper understanding of other multilayer organic optoelectronic devices, including multilayer photovoltaic devices.
Date: August 13, 2009
Creator: NCSU; Berkeley, UC; UCSB; Source, Advanced Light; Garcia, Andres; Yan, Hongping et al.
Partner: UNT Libraries Government Documents Department

Environmentally friendly polysilane photoresists

Description: Several novel polysilanes synthesized by the free-radical hydrosilation of oligomeric polyphenylsilane or poly(p-tert- butylphenylsilane) were examined for lithographic behavior. This recently developed route into substituted polysilanes has allowed for the rational design of a variety of polysilanes with a typical chemical properties such as alcohol and aqueous base solubility. Many of the polysilane resists made could be developed in aqueous sodium carbonate and bicarbonate solutions. These materials represent environmentally friendly polysilane resists in both their synthesis and processing.
Date: December 31, 1995
Creator: Beach, J.V.; Loy, D.A.; Hsiao, Yu-Ling & Waymouth, R.M.
Partner: UNT Libraries Government Documents Department

Exciton and biexciton signatures in femotosecond transient absorption of {pi}-conjugated oligomers

Description: The authors report femotosecond transient-absorption studies of a five-ring oligomer of polyphenylenevinylene (PPV) prepared in two different forms: as solid-state films and dilute solutions. Both types of samples exhibit a photoinduced absorption (PA) band with dynamics which closely match those of the stimulated emission (SE), demonstrating unambiguously that these features originate from the same species, namely from intrachain singlet excitons. Photo-chemical degradation of the solid-state samples is demonstrated to dramatically shorten the SE dynamics above a moderate incident pump fluence, whereupon the dynamics of the SE and the long-wavelength PA no longer coincide. In contrast to solutions, solid-state films exhibit an additional short-wavelength PA band with pump-independent dynamics, indicating the efficient formation of non-emissive inter-chain excitons. Correlations in the subpicosecond dynamics of the two PA features, as well as the pump intensity-dependence provide strong evidence that the formation of inter-chain excitons is mediated by intrachain two-exciton states. At high pump levels, the authors see a clear indication of interaction between excited states also in dilute solutions. This is manifested as a superlinear pump-dependence and shortening of the decay dynamics of the SE. They attribute this behavior to the formation of biexcitons resulting from coherent interaction between two excitons on a single chain.
Date: October 1, 1997
Creator: Klimov, V.; McBranch, D.; Barashkov, N. & Ferraris, J.
Partner: UNT Libraries Government Documents Department

A comparison of drive mechanisms for precision motion controlled stages

Description: This abstract presents a comparison of two drive mechanisms, a Rohlix{reg_sign} drive and a polymer nut drive, for precision motion controlled stages. A single-axis long-range stage with a 50 mm traverse combined with a short-range stage with a 16 {micro}m traverse at a operational bandwidth of 2.2 kHz were developed to evaluate the performance of the drives. The polymer nut and Rohlix{reg_sign} drives showed 4 nm RMS and 7 nm RMS positioning capabilities respectively, with traverses of 5 mm at a maximum velocity of 0.15 mm{sup -}s{sup -1} with the short range stage operating at a 2.2 kHz bandwidth. Further results will be presented in the subsequent sections.
Date: March 22, 2006
Creator: Buice, E S; Yang, H; Otten, D; Smith, S T; Hocken, R J; Trumper, D L et al.
Partner: UNT Libraries Government Documents Department

Hypotheses for Scratch Behavior of Polymer Systems that Recover

Description: Scratch recovery is a desirable property of many polymer systems. The reason why some materials have demonstrated excellent scratch recovery while others do not has been a mystery. Explaining the scratch resistance based upon the hardness of a material or its crosslink density is incorrect. In this thesis, novel polymers were tested in an attempt to discover materials that show excellent scratch recovery - one of the most important parameters in determining the wear of a material. Several hypotheses were developed in an attempt to give an accurate picture of how the chemical structure of a polymer affects its scratch recovery. The results show that high scratch recovery is a complex phenomenon not solely dependent upon the presence of electronegative atoms such as fluorine.
Date: May 2002
Creator: Bujard, Bernard
Partner: UNT Libraries

Synthesis and Study of Engineered Heterogenous Polymer Gels

Description: This dissertation studies physical properties and technological applications of engineered heterogenous polymer gels. Such gels are synthesized based on modulation of gel chemical nature in space. The shape memory gels have been developed in this study by using the modulated gel technology. At room temperature, they form a straight line. As the temperature is increased, they spontaneously bend or curl into a predetermined shape such as a letter of the alphabet, a numerical number, a spiral, a square, or a fish. The shape changes are reversible. The heterogenous structures have been also obtained on the gel surface. The central idea is to cover a dehydrated gel surface with a patterned mask, then to sputter-deposit a gold film onto it. After removing the mask, a gold pattern is left on the gel surface. Periodical surface array can serve as gratings to diffract light. The grating constant can be continuously changed by the external environmental stimuli such as temperature and electric field. Several applications of gels with periodic surface arrays as sensors for measuring gel swelling ratio, internal strain under an uniaxial stress, and shear modulus have been demonstrated. The porous NIPA gels have been synthesized by suspension technique. Microstructures of newly synthesized gels are characterized by both SEM and capillary test and are related to their swelling and mechanical properties. The heterogenous porous NIPA gel shrink about 35,000 times faster than its counterpart--the homogeneous NIPA gel. Development of such fast responsive gels can result in sensors and devices applications. A new gel system with built-in anisotropy is studied. This gel system consists of interpenetrated polymer network (IPN) gels of polyacrylamide (PAAM) and N-isopropylacrylamide (NIPA). The swelling property of the anisotropy IPN gels along the pre-stressing direction is different from that along other directions, in contrast to conventional gels which swell isotropically. ...
Date: August 1998
Creator: Chen, Yuanye
Partner: UNT Libraries

Synthesis and characterization of crystalline assembly of poly Nisopropylacry-lamide)-co-acrylic acid nanoparticles.

Description: In this study, crystalline poly(N-isopropylacrylamide-co-acrylic acid) (PNIPAm-co-AAc) nanoparticle network in organic solvents was obtained by self assembling precursor particles in acetone/epichlorohydrin mixture at room temperature followed by inter-sphere crosslinking at ~98 °C. The crystals thus formed can endure solvent exchanges or large distortions under a temporary compressing force with the reoccurrence of crystalline structures. In acetone, the crystals were stable, independent of temperature, while in water crystals could change their colors upon heating or changing pH values. By passing a focused white light beam through the crystals, different colors were displayed at different observation angles, indicating typical Bragg diffraction. Shear moduli of the gel nanoparticle crystals were measured in the linear stress-yield ranges for the same gel crystals in both acetone and water. Syntheses of particles of different sizes and the relationship between particle size and the color of the gel nanoparticle networks at a constant solid content were also presented. Temperature- and pH- sensitive crystalline PNIPAm-co-AAc hydrogel was prepared using osmosis crosslinking method. Not only the typical Bragg diffraction phenomenon was observed for the hydrogel but also apparent temperature- and pH- sensitive properties were performed. The phase behavior of PNIPAm nanoparticles dispersed in water was also investigated using a thermodynamic perturbation theory combined with lightscattering and spectrometer measurements. It was shown how the volume transition of PNIPAM particles affected the interaction potential and determined a novel phase diagram that had not been observed in conventional colloids. Because both particle size and attractive potential depended on temperature, PNIPAM aqueous dispersion exhibited phase transitions at a fixed particle number density by either increasing or decreasing temperature. The phase transition of PNIPAm-co-AAc colloids was also studied. The results from the comparison between pure PNIPAm and charged PNIPAm colloids showed that the introducing of carboxyl (-COOH) group not only contributed to the synthesis ...
Date: December 2004
Creator: Zhou, Bo
Partner: UNT Libraries

Long Term Property Prediction of Polyethylene Nanocomposites

Description: The amorphous fraction of semicrystalline polymers has long been thought to be a significant contributor to creep deformation. In polyethylene (PE) nanocomposites, the semicrystalline nature of the maleated PE compatibilizer leads to a limited ability to separate the role of the PE in the nanocomposite properties. This dissertation investigates blown films of linear low-density polyethylene (LLDPE) and its nanocomposites with montmorillonite-layered silicate (MLS). Addition of an amorphous ethylene propylene copolymer grafted maleic anhydride (amEP) was utilized to enhance the interaction between the PE and the MLS. The amorphous nature of the compatibilizer was used to differentiate the effect of the different components of the nanocomposites; namely the matrix, the filler, and the compatibilizer on the overall properties. Tensile test results of the nanocomposites indicate that the addition of amEP and MLS separately and together produces a synergistic effect on the mechanical properties of the neat PE Thermal transitions were analyzed using differential scanning calorimetry (DSC) to determine if the observed improvement in mechanical properties is related to changes in crystallinity. The effect of dispersion of the MLS in the matrix was investigated by using a combination of X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM). Mechanical measurements were correlated to the dispersion of the layered silicate particles in the matrix. The nonlinear time dependent creep of the material was analyzed by examining creep and recovery of the films with a Burger model and the Kohlrausch-Williams-Watts (KWW) relation. The effect of stress on the nonlinear behavior of the nanocomposites was investigated by analyzing creep-recovery at different stress levels. Stress-related creep constants and shift factors were determined for the material by using the Schapery nonlinear viscoelastic equation at room temperature. The effect of temperature on the tensile and creep properties of the nanocomposites was analyzed by examining tensile and creep-recovery behavior of ...
Date: December 2008
Creator: Shaito, Ali Al-Abed
Partner: UNT Libraries