Description: Summary: The activity coefficient of Pu(Cl04)4 was measured in perchloric acid solutions. The procedure used was to measure the extraction of the neutral plutonium(IV)-TTA chelate into benzene-TTA solutions at different perchloric acid concentrations. Equations are presented which show the relation of the extraction coefficients, obtained in the above manner, to the activity coefficient of plutonium(IV) per-chlorate. The activity coefficient of Pu(Cl0~)4 is similar to that of a strong acid, e.g., perchloric acid, in that its value increases rapidly when the perchloric acid concentration becomes greater than 2M. The distribution coefficient of TTA between benzene and aqueous perchloric acid solutions was found first to decrease slightly and then to increase two fold as the perchloric acid was varied from 0.01 to 6M. The activity coefficient of the uranous-TTA chelate in benzene was calculated from the results of solubility measurements. The values of the activity coefficient of UK4 are,within experimental error, identical with the values of the activity coefficient of TTA itself.
Date: November 1948
Creator: Connick, R. E. & Reas, W. H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department