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Assessment of research and development (R and D) needs in ammonia safety and environmental control

Description: This report characterizes the ammonia industry operations, reviews current knowledge of ammonia release and subsequent impacts, summarizes the status of release prevention and control methods and identify research and development needs for safety and environmental control. Appendices include: accidental spills and human exposure; adiabatic mixing of liquid nitrogen and air; fire and explosion hazards; and environmental impact rating tables. (PSB)
Date: September 1, 1981
Creator: Brenchley, D.L.; Athey, G.F. & Bomelburg, H.J.
Partner: UNT Libraries Government Documents Department
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Correlation of alluvial deposits at the Nevada Test Site

Description: Because characteristics of rock layers and problems in drilling must be studied before radioactive waste can be safely contained, an evaluation was made of methods for correlating alluvial deposits at Yucca Flat of the Nevada Test Site (NTS). Although correlation of Tertiary volcanic tuff beds at the NTS has been successfully achieved, correlation of stratigraphic zones in the overlying alluvium has posed technical difficulties. We have evaluated several methods for correlating alluvial deposit… more
Date: September 30, 1977
Creator: Grothaus, B. & Howard, N.
Partner: UNT Libraries Government Documents Department
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Analysis of Paraho oil shale products and effluents: an example of the multi-technique approach

Description: Inorganic analysis of solid, liquid and gaseous samples from the Paraho Semiworks Retort was completed using a multitechnique approach. The data were statistically analyzed to determine both the precision of each method and to see how closely the various techniques compared. The data were also used to determine the redistribution of 31 trace and major elements in the various effluents, including the offgas for the Paraho Retort operating in the direct mode. The computed mass balances show that … more
Date: June 10, 1979
Creator: Fruchter, J. S.; Wilkerson, C. L.; Evans, J. C. & Sanders, R. W.
Partner: UNT Libraries Government Documents Department
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Alkali sorber (RABSAM), September 1, 1990--August 30, 1991

Description: The objective of this work is to develop a regenerable activated-bauxite sorber alkali monitor that requires no high-temperature/high-pressure sampling line for the reliable in situ measurement of alkali-vapor concentration in the exhaust from the pressurized fluidized-bed combustion of coal. 11 refs., 2 figs., 1 tab.
Date: January 1, 1991
Creator: Lee, S. H. D. & Swift, M. W.
Partner: UNT Libraries Government Documents Department
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Resource capture by single leaves

Description: Leaves show a variety of strategies for maximizing CO{sub 2} and light capture. These are more meaningfully explained if they are considered in the context of maximizing capture relative to the utilization of water, nutrients and carbohydrates reserves. There is considerable variation between crops in their efficiency of CO{sub 2} and light capture at the leaf level. Understanding of these mechanisms indicate some ways in which efficiency of resource capture could be level cannot be meaningfull… more
Date: May 1, 1992
Creator: Long, S.P.
Partner: UNT Libraries Government Documents Department
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Tumor production in Syrian hamsters following inhalation of PuO/sub 2/--ZrO/sub 2/ aerosol

Description: Syrian golden hamsters of both sexes were exposed to aerosols of ZrO/sub 2/ containing PuO/sub 2/. The starting material in the aerosol generator also had a small amount of /sup 57/Co added as a tracer. The mixture of all three constituents was nebulized and the droplets passed through a heating column at 1000/sup 0/C. Aerosol sampling was accomplished with a cascade impactor and electrostatic precipitator. The median aerodynamic diameters in all inhalation runs were approximately 2 ..mu..m wit… more
Date: January 1, 1978
Creator: Thomas, R. G. & Smith, D. M.
Partner: UNT Libraries Government Documents Department
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A Novel Coal Feeder for Production of Low Sulfur Fuel

Description: During the past three months, the coal feeding system has been tested and currently undergoing evaluation at the University of Cincinnati. The system consists primarily of an auger feed tube which is used to both convey and provide desulfurization of a high sulfur coal feedstock. The coal is conveyed at temperatures ranging from 350 to 550{degrees}C and under normal atmospheric pressure. Under these mild processing conditions, the coal partially pyrolizes and emits sulfur in the form of hydroge… more
Date: January 1, 1990
Creator: Khang, S. J. & Keener, T. C.
Partner: UNT Libraries Government Documents Department
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Redox reactions involving chromium, plutonium, and manganese in soils

Description: Plutonium speciation in soils is discussed. Chromium was selected as a model for studying soil Pu. Similarities between Cr and Pu are pointed out, and a hypotheses concerning Pu speciation in soils is presented. Findings from Cr oxidation studies that may be relevant to the problem of Pu oxidation in soils are discussed. (JGB)
Date: January 1, 1979
Creator: Amacher, M.C. & Baker, D.E.
Partner: UNT Libraries Government Documents Department
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(Environmental investigation of ground water contamination at Wright-Patterson Air Force Base, Ohio)

Description: This report presents information concerning field procedures employed during the monitoring, well construction, well purging, sampling, and well logging at the Wright-Patterson Air Force Base. Activities were conducted in an effort to evaluate ground water contamination.
Date: October 1, 1991
Partner: UNT Libraries Government Documents Department
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Characterization of solids in the Three Mile Island Unit 2 Reactor defueling water: Addendum

Description: Shortly after ORNL/TM-10362 was issued, it was discovered that a series of 31 figures had been inadvertently omitted. These figures, which consist of scanning electron microscope (SEM) photographs and energy-dispersive X-ray fluorescence scans, provide significant information about the results obtained in the tests performed with water sample W3. This Addendum includes these figures. Details of and comments on the SEM photographs may be found in ORNL/TM-10362.
Date: March 1, 1988
Creator: Campbell, D.O.
Partner: UNT Libraries Government Documents Department
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NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: Copper and cobalt are the key elements in syngas conversion catalyst systems used for higher alcohol synthesis. Their proximity and synergy sensitively control the selectivity and efficiency of the process. It is believed that their outer electronic charge distribution which is responsible for their electrical and magnetic properties might be governing their catalytic properties also. To examine the correlation between catalytic and magnetic properties, a series of copper cobalt catalysts (Co/C… more
Date: January 14, 1991
Partner: UNT Libraries Government Documents Department
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High temperature ceramic membrane reactors for coal liquid upgrading

Description: In this project we intend to study a novel process concept, i.e, the use of ceramic membranes reactors in upgrading of coal derived liquids. Membrane reactors have been used in a number of catalytic reaction processes in order to overcome the limitations on conversion imposed by thermodynamic equilibrium. They have, furthermore, the inherent capability for combining reaction and separation in a single step. Thus they offer promise for improving and optimizing yield, selectivity and performance … more
Date: January 1, 1992
Creator: Tsotsis, T.T.
Partner: UNT Libraries Government Documents Department
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Final Report of Modeling of CWM Droplet Combustion

Description: The objective of the present study was to develop a one-dimensional, unsteady state model for coal-water mixture droplet combustion, and to compare the characteristic times for the various processes, such as water vaporization, devolatilization and char oxidation with available experimental data. A water film surrounding a spherical coal particle is considered to undergo vaporization by heat transfer from the hot air. After the water vaporization is complete, devolatilization begins. This proce… more
Date: October 1, 1983
Creator: Pandalai, Krish; Aggarwal, Suresh & Sirignano, William
Partner: UNT Libraries Government Documents Department
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Measurements of the dependence of damage thresholds on laser wavelength, pulse duration and film thickness

Description: Results of three experiments will be described. We used 351-nm and 355-nm pulses with durations of 0.6, 1, 5 and 9 ns measure thresholds for a variety of anti-reflectance and high reflectance coatings. The functional form t/sup m/, with t the pulse duration, was used to scale fluence thresholds measured at 0.6 ns to those measured at 9.0 ns. Values of the coefficient m ranged from 0.10 to 0.51. The average value was 0.30. In the second experiment, we measured thresholds at 1064 nm, 527 nm and 3… more
Date: March 1, 1984
Creator: Rainer, F.; Vercimak, C.L.; Milam, D.; Carniglia, C.K. & Tuttle Hart, T.
Partner: UNT Libraries Government Documents Department
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Irradiation experiment for lithium ceramics

Description: Solid breeder materials are required in D-T fusion reactor blankets to convert fusion neutrons to tritium and thermal energy while providing some neutron shielding for the magnets. Lithium compounds such as Li/sub 2/O, LiAlO/sub 2/, Li/sub 4/SiO/sub 4/ and Li/sub 2/ZrO/sub 3/ have been proposed as solid breeder materials. Tritium is necessary to maintain the fuel supply for the D-T fusion reaction. No high burnup irradiation performance data is available for these materials in a neutron environ… more
Date: March 1, 1982
Creator: Hollenberg, G.W.
Partner: UNT Libraries Government Documents Department
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Phosphate-bonded glass cements for geothermal wells. Final report

Description: Calcium aluminosilicate glasses were found to react with phosphoric acid in three ways depending upon silica content. Above 55% SiO/sub 2/ they are insoluble while below 50% they dissolve readily. The transition compositions release calcium and aluminum ions and a silica gel phase replaces the glass. Activation energies in the order of 10 kcal/mole are associated with the dissolution. Equilibrium studies in the systems CaO-P/sub 2/O/sub 5/-H/sub 2/O, Al/sub 2/O/sub 3/-P/sub 2/O/sub 5/-H/sub 2/O… more
Date: September 1, 1979
Creator: Rockett, T.J.
Partner: UNT Libraries Government Documents Department
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Recovery of plutonium and americium from chloride salt wastes by solvent extraction

Description: Plutonium and americium can be recovered from aqueous waste solutions containing a mixture of HCl and chloride salt wastes by the coupling of two solvent extraction systems: tributyl phosphate (TBP) in tetrachloroethylene (TCE) and octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO) in TCE. In the flowsheet developed, the salt wastes are dissolved in HCl, the Pu(III) is oxidized to the IV state with NaClO/sub 2/ and recovered in the TBP-TCE cycle, and the Am is then removed from t… more
Date: January 1, 1987
Creator: Reichley-Yinger, L. & Vandegrift, G.F.
Partner: UNT Libraries Government Documents Department
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Evidence of former higher temperatures from alteration minerals, Bostic 1-A well, Mountain Home, Idaho

Description: Cuttings from the silicic volcanics in the Bostic 1-A well near Mountain Home, Idaho have been examined petrographically with the assistance of x-ray diffraction and electron microprobe analyses. Results indicate that these rocks have been subjected to much higher temperatures than were observed in the well in 1974, when a static temperature log was run. It is not known to what extent the alternation may be due to greater depth of burial in the past, or whether it resulted from an early hydroth… more
Date: January 1, 1982
Creator: Arney, B.
Partner: UNT Libraries Government Documents Department
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Pacific Northwest Laboratory Report on Fusion Energy Research, April 1977 - June 1977

Description: The development of economic data for fusion power plants continued in a study estimating the potential impact of a shortage of materials important in fusion plant construction. In studies developing heat transfer and fluid flow design tools for fusion reactor blankets, preconceptual design studies were initiated to identify the potential design limits of water cooling in the first wall of Tokamak Next Step (TNS) concepts. In surface effects research clean gold samples were irradiated in the Uni… more
Date: July 1, 1977
Partner: UNT Libraries Government Documents Department
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State-of-the-art for evaluating the potential impact of flooding on a radioactive waste repository

Description: This report is a review of the state-of-the-art for evaluating the potential impact of flooding on a deep radioactive-waste repository, namely, for predicting the future occurrence of catastrophic flooding and for estimating the effect of such flooding on waste containment characteristics. Several detrimental effects are identified: flooding can increase groundwater seepage velocities through a repository within the framework of the existing hydrologic system and thus increase the rate of radio… more
Date: July 16, 1980
Partner: UNT Libraries Government Documents Department
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Thermodynamic model for calorimetric and phase coexistence properties of coal derived fluids

Description: On September 1, 1989 work was initiated on a project to extend the available vapor-liquid equilibrium (VLE) model for coal fluids to allow satisfactory predictions of excess enthalpies of coal liquids at high pressures. The available vapor liquid equilibrium model was developed with support from previous grant from DOE-PETC (Grant no. DE-FG22-89PC90541). The current project also involves measurement of some model compound VLE data and chromatographic characterization of coal liquids for distrib… more
Date: October 1, 1991
Creator: Kabadi, V. N.
Partner: UNT Libraries Government Documents Department
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