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Composition of vapors from boiling nitric acid solutions

Description: From abstract: "The composition of vapors from aqueous nitric acid solutions boiling at 200 mm mercury total pressure is established for solutions containing between - and 67.5 w/o nitric acid. The volatility characteristics of low concentrations of chloride in the same concentration range of nitric acid have been measured in solutions boiling at 200 mm mercury. The effects of chloride concentration and pressure of boiling are evaluated. A spectrophotometric method of the determination of chloride in nitric acid solutions is described."
Date: February 9, 1955
Creator: Crooks, R. C.; Wilson, R. Q.; Bearse, A. E. & Filbert, Robert B.
Partner: UNT Libraries Government Documents Department

Corrosion in a nitric acid concentrator

Description: From introduction: "The study's objectives were to determine the approximate rate of general corrosion so as to reveal; any abnormal corrosion occurring during processing operations; to determine the suitability of a large variety of alloys and plastics as materials of construction; and to ascertain process conditions which would minimize corrosion."
Date: January 9, 1956
Creator: Meyer, Fred H.
Partner: UNT Libraries Government Documents Department

Distribution of Uranium at Low Acid : Low Uranium Concentrations into 4-1/2 Percent TBP-AMSCO

Description: Report wherein acid free uranyl nitrate hexahydrate was distributed into 4-1/2 percent TBP-Amsco 125-90W and combined with various concentrations of acid in order to study the distribution of uranium and hydrolysis effects.
Date: August 23, 1956
Creator: Andelin, Robert L.; Anderson, Edward L. & McVey, W. H.
Partner: UNT Libraries Government Documents Department

THE FIRST ISOLATION OF AMERICIUM IN THE FORM OF PURE COMPOUNDS - THE SPECIFIC ALPHA-ACTIVITY AND HALF-LIFE OF Am241

Description: The microgram scale isolation and preparation of pure compounds of americium is described. Data are presented to show that the alpha-half-life of the isotope Am{sup 241} is 490 {+-} 14 years. The absorption spectrum of Am(III) in 1M nitric acid in the range 3500-8000 mu is given. The wave lengths of 10 of the most prominent lines in the copper spark emission spectrum of americium are given to the nearest 0.01 {angstrom}. Evidence is presented to show that the potential for the Am(III)-Am(IV) couple in acid solution is more negative than -2v and that the potential for the Am(II)-Am(III) couple is more positive than +0.9v.
Date: July 20, 1950
Creator: Cunningham, B.B. & Asprey, L.B.
Partner: UNT Libraries Government Documents Department

A MATHEMATICAL MODEL FOR THE SOLVENT EXTRACTION OF URANYL NITRATE AND NITRIC ACID

Description: A generalized least-squares technique can be used to calculate equilibrium constants in solvent extraction equilibria by minimizing the difference between observed and calculated distribution ratios. The method was successfully applied to the extraction of uranyl nitrate and nitric acid by TBP dissolved in an inert diluent. (auth)
Date: July 10, 1962
Creator: Lietzke, M.H. & Stoughton, R.W.
Partner: UNT Libraries Government Documents Department

Study of Dispersant Agents for Thorium Oxide

Description: S>A preliminary study of dispersing agents for thorium oxide was completed and several of the dispersants have possible uses. Also many of the industrial dispersing agents tested are not usable with thorium oxide due to induced behavior causing balling and caking. The effects of nitric acid concentration were observed to also effect each dispersing agent. (auth)
Date: August 1, 1959
Creator: Bate, L. C. & Leddicotte, G. W.
Partner: UNT Libraries Government Documents Department

THE REACTION OF ZIRCONIUM WITH URANIUM DIOXIDE

Description: An investigation of the causes of observed explosive reaction of zirconium-coated uranium dioxide on dissolution in nitric acid was conducted. It was concluded that such a reaction is to be expected. Possible but unconfirmed methods of alleviating the problem are suggested. (J.R.D.)
Date: June 11, 1957
Creator: Robinson, M.T.
Partner: UNT Libraries Government Documents Department

The Nitric Acid Leaching of Uranium Dioxide in a Recirculating Dissolver

Description: A brief study of the nitric acid leaching of sheared Zircaloy and stainless-steel-clad UO/sub 2/ fuels was carried out. The study was intended to demonstrate the leaching process and the use of a removable dissolver canister for transport and charge duty. In addition, the effect of sheared element length on leaching time cycles was studied. (L.T.W.)
Date: October 20, 1960
Creator: Smith, P. W.
Partner: UNT Libraries Government Documents Department

Wet Chemical Oxidation of Organic Waste Using Nitric-Phosphoric Acid Technology

Description: Experimental progress has been made in a wide range of areas which support the continued development of the nitric-phosphoric acid oxidation process for combustible, solid organic wastes. An improved understanding of the overall process operation has been obtained, acid recovery and recycle systems have been studied, safety issues have been addressed, two potential final waste forms have been tested, preliminary mass flow diagrams have been prepared, and process flowsheets have been developed. The flowsheet developed is essentially a closed-loop system which addresses all of the internally generated waste streams. The combined activities aim to provide the basis for building and testing a 250-400 liter pilot-scale unit. Variations of the process now must be evaluated in order to address the needs of the primary customer, SRS Solid Waste Management. The customer is interested in treating job control waste contaminated with Pu-238 for shipment to WIPP. As a result, variations for feed preparation, acid recycle, and final form manufacturing must be considered to provide for simpler processing to accommodate operations in high radiation and contamination environments. The purpose of this program is to demonstrate a nitric-phosphoric acid destruction technology which can treat a heterogeneous waste by oxidizing the solid and liquid organic compounds while decontaminating noncombustible items.
Date: October 6, 1998
Creator: Pierce, R.A.
Partner: UNT Libraries Government Documents Department

The FB-Line and F-Canyon HAN/Nitric Acid Decomposition Study

Description: Separations requested SRTC study the autocatalytic decomposition of the hydroxylamine nitrate which may occur in the presence of concentrated nitric acid with respect to making-up cold feed solutions. The data obtained from this study will provide Separations an envelope within which safe operations can be conducted.
Date: August 19, 1998
Creator: Hang, T.
Partner: UNT Libraries Government Documents Department

Comparative Metagenomics of Freshwater Microbial Communities

Description: Previous analyses of a microbial metagenome from uranium and nitric-acid contaminated groundwater (FW106) showed significant environmental effects resulting from the rapid introduction of multiple contaminants. Effects include a massive loss of species and strain biodiversity, accumulation of toxin resistant genes in the metagenome and lateral transfer of toxin resistance genes between community members. To better understand these results in an ecological context, a second metagenome from a pristine groundwater system located along the same geological strike was sequenced and analyzed (FW301). It is hypothesized that FW301 approximates the ancestral FW106 community based on phylogenetic profiles and common geological parameters; however, even if is not the case, the datasets still permit comparisons between healthy and stressed groundwater ecosystems. Complex carbohydrate metabolism has been almost entirely lost in the stressed ecosystem. In contrast, the pristine system encodes a wide diversity of complex carbohydrate metabolism systems, suggesting that carbon turnover is very rapid and less leaky in the healthy groundwater system. FW301 encodes many (~;;160+) carbon monoxide dehydrogenase genes while FW106 encodes none. This result suggests that the community is frequently exposed to oxygen from aerated rainwater percolating into the subsurface, with a resulting high rate of carbon metabolism and CO production. When oxygen levels fall, the CO then serves as a major carbon source for the community. FW301 appears to be capable of CO2 fixation via the reductive carboxylase (reverse TCA) cycle and possibly acetogenesis, activities; these activities are lacking in the heterotrophic FW106 system which relies exclusively on respiration of nitrate and/or oxygen for energy production. FW301 encodes a complete set of B12 biosynthesis pathway at high abundance suggesting the use of sodium gradients for energy production in the healthy groundwater community. Overall comparative analysis suggests that the introduction of contaminants is accompanied by a decrease in biodiversity, loss of nutrient ...
Date: May 17, 2010
Creator: Hemme, Chris; Deng, Ye; Tu, Qichao; Fields, Matthew; Gentry, Terry; Wu, Liyou et al.
Partner: UNT Libraries Government Documents Department

IMPACT OF NUCLEAR MATERIAL DISSOLUTION ON VESSEL CORROSION

Description: Different nuclear materials require different processing conditions. In order to maximize the dissolver vessel lifetime, corrosion testing was conducted for a range of chemistries and temperature used in fuel dissolution. Compositional ranges of elements regularly in the dissolver were evaluated for corrosion of 304L, the material of construction. Corrosion rates of AISI Type 304 stainless steel coupons, both welded and non-welded coupons, were calculated from measured weight losses and post-test concentrations of soluble Fe, Cr and Ni.
Date: October 1, 2012
Creator: Mickalonis, J.; Dunn, K. & Clifton, B.
Partner: UNT Libraries Government Documents Department

Vapor space characterization of waste Tank 241-C-107: Results from samples collected on 9/29/94

Description: This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-C-107 (referred to as Tank C-107). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH{sub 3}), nitrogen dioxide (NO{sub 2}), nitric oxide (NO), and water vapor (H{sub 2}O). Sampling for sulfur oxides (SO{sub x}) was not requested. Organic compounds were also quantitatively determined. Twenty organic tentatively identified compounds (TICs) were observed above the detection limit of (ca.) 10 ppbv, but standards for most of these were not available at the time of analysis, and the reported concentrations are semiquantitative estimates. In addition, the authors looked for the 55 TO-14 extended analytes. Of these, 3 were observed above the 5-ppbv detection limit. The 10 organic analytes with the highest estimated concentrations are listed in Summary Table 1 and account for approximately 96% of the total organic components in Tank C-107. Two permanent gases, carbon dioxide and nitrous oxide, were also detected.
Date: November 1, 1995
Creator: Pool, K.H.; Clauss, T.W. & Ligotke, M.W.
Partner: UNT Libraries Government Documents Department