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The Gas That Wouldn't Burn

Description: Article describing how Alpha Chi Sigma members were involved with the events described on a pictured Kansas historical marker relating to the discovery of helium in a deposit of natural gas.
Date: Summer 2012
Creator: Marshall, James L., 1940- & Marshall, Virginia R.
Partner: UNT College of Arts and Sciences

Agent-based modeling of complex infrastructures

Description: Complex Adaptive Systems (CAS) can be applied to investigate complex infrastructures and infrastructure interdependencies. The CAS model agents within the Spot Market Agent Research Tool (SMART) and Flexible Agent Simulation Toolkit (FAST) allow investigation of the electric power infrastructure, the natural gas infrastructure and their interdependencies.
Date: June 2001
Creator: North, M. J.
Partner: UNT Libraries Government Documents Department

Synthetic drilling fluids - a pollution prevention opportunity for the oil and gas industry

Description: Offshore oil and gas operators use specialized drilling fluids, referred to as {open_quotes}muds,{close_quotes} to help maintain well control and to remove drill cuttings from the hole. Historically, either water-based muds (WBMs) or oil-based muds (OBMs) have been used for offshore wells. Recently, the drilling industry has developed several types of synthetic-based muds (SBMs) that combine the desirable operating qualities of OBMs with the lower toxicity and environmental impact qualities of WBMs. This report describes the operational, environmental, and economic features of all three types of muds and discusses potential EPA regulatory barriers to wider use of SBMs.
Date: December 31, 1995
Creator: Veil, J.A.; Burke, C.J. & Moses, D.O.
Partner: UNT Libraries Government Documents Department

Increased emphasis on toxics control in oil and gas industry NPDES permits

Description: The 1987 amendments to the Clean Water Act emphasized stricter control of toxics in wastewater discharges. Although state and U.S. Environmental Protection Agency permit writers have had the authority to incorporate strict water quality-based controls in permits, they did not widely use this authority in the past. However, general permits proposed in the past year by Region VI for discharges into the territorial seas of Louisiana and by Region X for coastal and offshore discharges in Alaska are much stricter than their predecessors. The Region VI permit requires numerical produced water limits on arsenic, lead, benzene, total phenols, radium, and whole effluent toxicity. The Region X permit requires numerical produced water limits on copper, arsenic, zinc, total aromatic hydrocarbons, total aqueous hydrocarbons, and whole effluent toxicity. The additional requirements increase the cost of complying with the permit, present more opportunities for exceeding one of the permit limits, and serve as a precedent for future permits. The industry should be prepared to accept the additional costs of these requirements or develop data to convince the regulatory agencies that the increased level of monitoring and permit limits is not necessary to protect water quality. Regulatory agencies should be receptive to new data provided by the industry and flexible in setting additional toxics controls.
Date: October 1, 1996
Creator: Veil, J.A.
Partner: UNT Libraries Government Documents Department

Fossil fuel conversion -- Measurement and modeling

Description: The main objective of this program is to understand the chemical and physical mechanisms in coal conversion processes and incorporate this knowledge in computer-aided reactor engineering technology for the purposes of development, evaluation, design, scale up, simulation, control and feedstock evaluation in advanced coal conversion devices. To accomplish this objective, this program will: (1) provide critical data on the physical and chemical processes in fossil fuel gasifier and combustors; (2) further develop a set of comprehensive codes; and (3) apply these codes to model various types of combustors and gasifier (fixed-bed, transport reactor, and fluidized-bed for coal and gas turbines for natural gas). Results are presented on the devolatilization of large coal particles; transport reactor modeling; fluidized bed model; nitrogen evolution from small and large coal particles; modeling of hydrogen cyanide and ammonia release during coal pyrolysis; oxidation rates for large coal particles at high pressures; advanced fixed-bed model development and evaluation; application of ACERC combustion and gasification codes to AFR diagnostic capabilities to systems of interest to METC; and submodel for lean premixed combustion of natural gas in industrial gas turbines.
Date: November 1, 1995
Creator: Solomon, P.R.; Smoot, L.D.; Serio, M.A.; Hamblen, D.G.; Brewster, B.S. & Radulovic, P.T.
Partner: UNT Libraries Government Documents Department

Fracturing Fluid Characterization Facility (FFCF): Recent advances

Description: The objectives of this project are: (1)Investigate fluid rheological behavior, dynamic fluid leak-off behavior, and proppant transport characteristics of various fracturing fluids used for stimulating oil and gas bearing formations. (2) Develop new information for characterizing the behavior of fracturing fluids under conditions more representative of the behavior in actual fractures. (3) Continue utilizing the advanced capabilities of the high pressure simulator (HPS) to perform near-term research and development activities and not to construct a large-scale simulator that was proposed originally. This paper describes equipment enhancements, data acquisition and instrumentation upgrades, R&D test results, and future research planned for the Fracturing Fluid Characterization Facility.
Date: July 1, 1995
Creator: Shah, S.N. & Fagan, J.E.
Partner: UNT Libraries Government Documents Department

New Technology for America`s Electric Power Industry. Emissions reduction in gas turbines

Description: Argonne National Laboratory is examining alternatives to straight natural gas firing. Research has shown that the addition of certain catalytic agents, such as in hydrogen co-firing, shows promise. When hydrogen co-firing is used in tandem with steam injection, a decrease in both CO and NO{sub x} emissions has been observed. In-process hydrogen production and premixing with the natural gas fuel are also being explored.
Date: April 1, 1995
Partner: UNT Libraries Government Documents Department

Oil field waste disposal costs at commercial disposal facilities

Description: The exploration and production segment of the U.S. oil and gas industry generates millions of barrels of nonhazardous oil field wastes annually. In most cases, operators can dispose of their oil fields wastes at a lower cost on-site than off site and, thus, will choose on-site disposal. However, a significant quantity of oil field wastes are still sent to off-site commercial facilities for disposal. This paper provides information on the availability of commercial disposal companies in different states, the treatment and disposal methods they employ, and how much they charge. There appear to be two major off-site disposal trends. Numerous commercial disposal companies that handle oil field wastes exclusively are located in nine oil-and gas-producing states. They use the same disposal methods as those used for on-site disposal. In addition, the Railroad Commission of Texas has issued permits to allow several salt caverns to be used for disposal of oil field wastes. Twenty-two other oil- and gas-producing states contain few or no disposal companies dedicated to oil and gas industry waste. The only off-site commercial disposal companies available handle general industrial wastes or are sanitary landfills. In those states, operators needing to dispose of oil field wastes off-site must send them to a local landfill or out of state. The cost of off-site commercial disposal varies substantially, depending on the disposal method used, the state in which the disposal company is located, and the degree of competition in the area.
Date: October 1, 1997
Creator: Veil, J.A.
Partner: UNT Libraries Government Documents Department

Greenhouse gas emission impacts of alternative-fueled vehicles: Near-term vs. long-term technology options

Description: Alternative-fueled vehicle technologies have been promoted and used for reducing petroleum use, urban air pollution, and greenhouse gas emissions. In this paper, greenhouse gas emission impacts of near-term and long-term light-duty alternative-fueled vehicle technologies are evaluated. Near-term technologies, available now, include vehicles fueled with M85 (85% methanol and 15% gasoline by volume), E85 (85% ethanol that is produced from corn and 15% gasoline by volume), compressed natural gas, and liquefied petroleum gas. Long-term technologies, assumed to be available around the year 2010, include battery-powered electric vehicles, hybrid electric vehicles, vehicles fueled with E85 (ethanol produced from biomass), and fuel-cell vehicles fueled with hydrogen or methanol. The near-term technologies are found to have small to moderate effects on vehicle greenhouse gas emissions. On the other hand, the long-term technologies, especially those using renewable energy (such as biomass and solar energy), have great potential for reducing vehicle greenhouse gas emissions. In order to realize this greenhouse gas emission reduction potential, R and D efforts must continue on the long-term technology options so that they can compete successfully with conventional vehicle technology.
Date: May 20, 1997
Creator: Wang, M.Q.
Partner: UNT Libraries Government Documents Department

Field verification of new and novel fracture stimulation technologies for the revitalization of existing underground gas storage wells

Description: Improved, more efficient natural gas transmission and deliverability systems will be essential for meeting the expected growth in U.S. gas demand in coming decades. Role of gas storage will be important. The most cost-effective means for providing the additional seasonal storage capacity and peak-day deliverability is to improve efficiency of the existing gas storage system (370 gas storage facilities and 17,000 gas storage wells). Up to 5 new fracture stimulation techniques will be field tested. Test sites have been acquired for the 1995 RD&D program.
Date: July 1, 1995
Creator: Reeves, S.R.
Partner: UNT Libraries Government Documents Department

Optimization of a CNG series hybrid concept vehicle

Description: Compressed Natural Gas (CNG) has favorable characteristics as a vehicular fuel, in terms of fuel economy as well as emissions. Using CNG as a fuel in a series hybrid vehicle has the potential of resulting in very high fuel economy (between 26 and 30 km/liter, 60 to 70 mpg) and very low emissions (substantially lower than Federal Tier II or CARB ULEV). This paper uses a vehicle evaluation code and an optimizer to find a set of vehicle parameters that result in optimum vehicle fuel economy. The vehicle evaluation code used in this analysis estimates vehicle power performance, including engine efficiency and power, generator efficiency, energy storage device efficiency and state-of-charge, and motor and transmission efficiencies. Eight vehicle parameters are selected as free variables for the optimization. The optimum vehicle must also meet two perfect requirements: accelerate to 97 km/h in less than 10 s, and climb an infinitely long hill with a 6% slope at 97 km/h with a 272 kg (600 lb.) payload. The optimizer used in this work was originally developed in the magnetic fusion energy program, and has been used to optimize complex systems, such as magnetic and inertial fusion devices, neutron sources, and mil guns. The optimizer consists of two parts: an optimization package for minimizing non-linear functions of many variables subject to several non-linear equality and/or inequality constraints and a programmable shell that allows interactive configuration and execution of the optimizer. The results of the analysis indicate that the CNG series hybrid vehicle has a high efficiency and low emissions. These results emphasize the advantages of CNG as a near-term alternative fuel for vehicles.
Date: September 22, 1995
Creator: Aceves, S.M.; Smith, J.R.; Perkins, L.J.; Haney, S.W. & Flowers, D.L.
Partner: UNT Libraries Government Documents Department

FUEL PROCESSING FOR FUEL CELLS: EFFECTS ON CATALYST DURABILITY AND CARBON FORMATION

Description: On-board production of hydrogen for fuel cells for automotive applications is a challenging developmental task. The fuel processor must show long term durability and under challenging conditions. Fuel processor catalysts in automotive fuel processors will be exposed to large thermal variations, vibrations, exposure to uncontrolled ambient conditions, and various impurities from ambient air and from fuel. For the commercialization of fuel processors, the delineation of effects on catalyst activity and durability are required. We are studying fuels and fuel constituent effects on the fuel processor system as part of the DOE Fuel Cells for Transportation program. Pure fuel components are tested to delineate the fuel component effect on the fuel processor and fuel processor catalysts. Component blends are used to simulate ''real fuels'', with various fuel mixtures being examined such as reformulated gasoline and naptha. The aliphatic, napthenic, olefin and aromatic content are simulated to represent the chemical kinetics of possible detrimental reactions, such as carbon formation, during fuel testing. Testing has examined the fuel processing performance of different fuel components to help elucidate the fuel constituent effects on fuel processing performance and upon catalyst durability. Testing has been conducted with vapor fuels, including natural gas and pure methane. The testing of pure methane and comparable testing with natural gas (97% methane) have shown some measurable differences in performance in the fuel processor. Major gasoline fuel constituents, such as aliphatic compounds, napthanes, and aromatics have been compared for their effect on the fuel processing performance. Experiments have been conducted using high-purity compounds to observe the fuel processing properties of the individual components and to document individual fuel component performance. The relative carbon formation of different fuel constituents have been measured by monitoring carbon via in situ laser optics, and by monitoring carbon buildup on the catalyst surface. The fuel processing ...
Date: May 2001
Creator: Borup, R.; Inbody, M.; Morton, B. & Brown, L.
Partner: UNT Libraries Government Documents Department

Conversion economics for Alaska North Slope natural gas

Description: For the Prudhoe Bay field, this preliminary analysis provides an indication that major gas sales using a gas pipeline/LNG plant scenario, such as Trans Alaska Gas System, or a gas-to-liquids process with the cost parameters assumed, are essentially equivalent and would be viable and profitable to industry and beneficial to the state of Alaska and the federal government. The cases are compared for the Reference oil price case. The reserves would be 12.7 BBO for the base case without major gas sales, 12.3 BBO and 20 Tcf gas for the major gas sales case, and 14.3 BBO for the gas-to-liquids conversion cases. Use of different parameters will significantly alter these results; e.g., the low oil price case would result in the base case for Prudhoe Bay field becoming uneconomic in 2002 with the operating costs and investments as currently estimated.
Date: July 1, 1995
Creator: Thomas, C.P. & Robertson, E.P.
Partner: UNT Libraries Government Documents Department

The synthesis and characterization of new iron coordination complexes utilizing an asymmetric coordinating chelate ligand

Description: A binuclear, unsymmetric coordinating ligand that is an effective metal chelator has been designed and synthesized. The new ligand has been shown to react readily with iron(II)/(III) forming a variety of coordination complexes. The binuclear complexes are of significant interest since they represent proof-of-principle for the development of coordinatively asymmetric, binuclear metal chelate compounds. Although this structural type of chelator now appears to be common in biological systems, it has not been previously described for inorganic coordination chemistry. The isolation of oxidation products will be helpful in establishing reaction mechanism(s) of these complexes with molecular oxygen. It is expected that this ligand and derivatives of it will play an important role in the development of bioinorganic complexes that aim to mimic enzyme active sites that function by substrate interaction at only one metal site of a multimetal active site.
Date: July 1, 1995
Creator: Watkins, B.E. & Satcher, J.H.
Partner: UNT Libraries Government Documents Department

ERC Program Overview

Description: The carbonate fuel cell promises highly efficient, cost-effective, environmentally superior power generation from pipeline natural gas, coal gas, biogas, and other gaseous and liquid fuels. ERC has been engaged in the development of this unique technology since the late 1970s, primarily focusing on the development of the Direct Fuel Cell (DFC) technology [1-6] pioneered by ERC. The DFC design incorporates the unique internal reforming feature which allows utilization of a hydrocarbon fuel directly in the fuel cell without requiring any external reforming reactor and associated heat exchange equipment. This approach provides upgrading of waste heat to chemical energy; thereby, it contributing to higher overall efficiency for conversion of fuel energy to electricity with low levels of environmental emissions. Among the internal reforming options, ERC has selected the Indirect Internal Reforming (IIR) - Direct Internal Reforming (DIR) combination as its baseline design. ERC plans to offer commercial DFC power plants in various sizes, initially focusing on the MW-scale units. The plan is to offer standardized, packaged MW-scale DFC power plants operating on natural gas or other hydrocarbon-containing fuels for commercial sale by the end of the decade. These power plants, which can be shop-fabricated and sited near the user, are ideally suited for distributed generation, industrial cogeneration, and uninterrupted power for military bases. After gaining experience from the early MW-scale power plants, and with maturing of the technology, ERC expects to introduce larger power plants operating on natural gas and/or coal gas or other fuels in the beginning of the 21st century. ERC has completed a technology program for product design verification, a predecessor of the current program, where the power plant design as well as the technology development were carried out to support a full-size field demonstration. These activities culminated in 130 kW stack tests in ERC's subscale power plant, ...
Date: August 1, 1996
Creator: Maru, H.; Farooque, M.; Carlson, G.; Patel, P.; Yuh, C.; Bentley, C. et al.
Partner: UNT Libraries Government Documents Department

ADVANCED STEAM GENERATORS

Description: Concerns about climate change have encouraged significant interest in concepts for ultra-low or ''zero''-emissions power generation systems. In some proposed concepts, nitrogen is removed from the combustion air and replaced with another diluent such as carbon dioxide or steam. In this way, formation of nitrogen oxides is prevented, and the exhaust stream can be separated into concentrated CO{sub 2} and steam or water streams. The concentrated CO{sub 2} stream could then serve as input to a CO{sub 2} sequestration process or utilized in some other way. Some of these concepts are illustrated in Figure 1. This project is an investigation of one approach to ''zero'' emission power generation. Oxy-fuel combustion is used with steam as diluent in a power cycle proposed by Clean Energy Systems, Inc. (CES) [1,2]. In oxy-fuel combustion, air separation is used to produce nearly pure oxygen for combustion. In this particular concept, the combustion temperatures are moderated by steam as a diluent. An advantage of this technique is that water in the product stream can be condensed with relative ease, leaving a pure CO{sub 2} stream suitable for sequestration. Because most of the atmospheric nitrogen has been separated from the oxidant, the potential to form any NOx pollutant is very small. Trace quantities of any minor pollutants species that do form are captured with the CO{sub 2} or can be readily removed from the condensate. The result is a nearly zero-emission power plant. A sketch of the turbine system proposed by CES is shown in Figure 2. NETL is working with CES to develop a reheat combustor for this application. The reheat combustion application is unusual even among oxy-fuel combustion applications. Most often, oxy-fuel combustion is carried out with the intent of producing very high temperatures for heat transfer to a product. In the reheat case, ...
Date: November 6, 2001
Creator: Richards, George A.; Casleton, Kent H.; Lewis, Robie E.; Rogers, William A.; Woike, Mark R. & Willis, Brian P.
Partner: UNT Libraries Government Documents Department

The modeling of a laboratory natural gas-fired furnace with a higher-order projection method for unsteady combustion

Description: A higher-order, embedded boundary projection method for axisymmetric, unsteady, low-Mach number combustion is used to model a natural gas flame from a 300 kW IFRF burner in the Burner Engineering Research Laboratory (BERL) at Sandia National Laboratory under hot wall conditions. The numerical predictions presented are the late simulated-time results of a computation of unsteady flow in the furnace. The predictions are compared both with measurements completed in the BERL as part of the GRI SCALING 400 Project and with results from a steady-state axisymmetric reacting flow code in order to evaluate the combustion model and the numerical method. The results compare favorably with the experimental data.
Date: February 1, 1996
Creator: Pember, R.B.; Colella, P.; Howell, L.H. & Almgren, A.S.
Partner: UNT Libraries Government Documents Department

Seismic data acquisition through tubing

Description: We have collected good quality crosswell seismic data through production tubing in active oil fields at realistic interwell distances (300 ft). The data were collected at the Aera Cymric field (1998) and at a Chevron site (1997); both located in the Central Valley of California. The Aera data were used to produce travel-time tomographic images of the interwell region. Both sites have similar geology, namely siliceous shale (diatomite) with moderate to highly attenuating reservoir rocks. In addition we confirmed modeling predictions that typical tubing attenuation losses are on the order of 12 dB. We expect that the use of stronger sources and tube wave suppression will allow for crosswell imaging at realistic distances even for low Q or high noise situations. We are searching for an industrial partner now for a data collection in the gas wells of the San Juan Basin or South Texas.
Date: July 1, 1999
Creator: Buettner, H M & Jervis, M
Partner: UNT Libraries Government Documents Department

Microseismic monitoring of the B-sand hydraulic fracture experiment at the DOE/GRI multi-site project

Description: Six hydraulic-fracture injections into a fluvial sandstone at a depth of 4500 ft were monitored with multi-level triaxial seismic receivers in two wells, resulting in maps of the growth and final geometry of each fracture based upon microseismic activity. These diagnostic images show that the hydraulic fractures are highly contained for smaller-volume KCl-water injections, but height growth is significant for the larger-volume, higher-rate, higher-viscosity treatments. Fracture lengths for most injections are similar. Final results are also compared with fracture models.
Date: November 1996
Creator: Warpinski, N. R.; Wright, T. B.; Peterson, R. E. & Branagan, P. T.
Partner: UNT Libraries Government Documents Department

Constraints on elastic parameters and implications for lithology on VTI media

Description: Energy considerations provide constraints on elastic stiffnesses in media exhibiting transverse isotropy with a vertical axis of symmetry. If the anisotropy is due to thin layers, additional constraints hold. The constraints can be used to provide insight into the mechanisms causing the anisotropy, which in turn gives information about the lithology. These ideas are illustrated by some examples of anisotropic sedimentary rocks and sediments from the literature.
Date: June 2, 1995
Creator: Berge, P.A.
Partner: UNT Libraries Government Documents Department

Micro-mechanical modeling of perforating shock damage

Description: Shaped charge jet induced formation damage from perforation treatments hinders productivity. Manifestation of this damage is in the form of grain fragmentation resulting in fines that plug up pore throats along with the breakdown of inter-grain cementation. The authors use the Smooth Particle Hydrodynamic (SPH) computational method as a way to explicitly model, on a grain pore scale, the dynamic interactions of grains and grain/pores to calculate the damage resulting from perforation type stress wave loading. The SPH method is a continuum Lagrangian, meshless approach that features particles. Clusters of particles are used for each grain to provide representation of a grain pore structure that is similar to x-ray synchrotron microtomography images. Numerous damage models are available to portray fracture and fragmentation. In this paper the authors present the results of well defined impact loading on a grain pore structure that illustrate how the heterogeneity affects stress wave behavior and damage evolution. The SPH approach easily accommodates the coupling of multi-materials. Calculations for multi-material conditions with the pore space treated as a void, fluid filled, and/or clay filled show diverse effects on the stress wave propagation behavior and damage. SPH comparisons made with observed damage from recovered impacted sandstone samples in gas gun experiments show qualitatively the influence of stress intensity. The modeling approach presented here offers a unique way in concert with experiments to define a better understanding of formation damage resulting from perforation completion treatments.
Date: November 17, 1997
Creator: Swift, R.P.; Krogh, K.E.; Behrmann, L.A. & Halleck, P.M.
Partner: UNT Libraries Government Documents Department

Reservoir fracture mapping using microearthquakes: Austin chalk, Giddings field, TX and 76 field, Clinton Co., KY

Description: Patterns of microearthquakes detected downhole defined fracture orientation and extent in the Austin chalk, Giddings field, TX and the 76 field, Clinton Co., KY. We collected over 480 and 770 microearthquakes during hydraulic stimulation at two sites in the Austin chalk, and over 3200 during primary production in Clinton Co. Data were of high enough quality that 20%, 31% and 53% of the events could be located, respectively. Reflected waves constrained microearthquakes to the stimulated depths at the base of the Austin chalk. In plan view, microearthquakes defined elongate fracture zones extending from the stimulation wells parallel to the regional fracture trend. However, widths of the stimulated zones differed by a factor of five between the two Austin chalk sites, indicating a large difference in the population of ancillary fractures. Post-stimulation production was much higher from the wider zone. At Clinton Co., microearthquakes defined low-angle, reverse-fault fracture zones above and below a producing zone. Associations with depleted production intervals indicated the mapped fractures had been previously drained. Drilling showed that the fractures currently contain brine. The seismic behavior was consistent with poroelastic models that predicted slight increases in compressive stress above and below the drained volume.
Date: November 1, 1996
Creator: Phillips, W.S.; Rutledge, J.T.; Gardner, T.L.; Fairbanks, T.D.; Miller, M.E. & Schuessler, B.K.
Partner: UNT Libraries Government Documents Department

Thermoacoustic natural gas liquefier

Description: Cryenco and Los Alamos are collaborating to develop a natural-gas-powered natural-gas liquefier that will have no moving parts and require no electrical power. It will have useful efficiency, remarkable reliability, and low cost. The liquefaction of natural gas, which occurs at only 115 Kelvin at atmospheric pressure, has previously required rather sophisticated refrigeration machinery. The 1990 invention of the thermoacoustically driven orifice pulse-tube refrigerator (TA-DOPTR) provides cryogenic refrigeration with no moving parts for the first time. In short, this invention uses acoustic phenomena to produce refrigeration from heat. The required apparatus consists of nothing more than helium-filled heat exchangers and pipes, made of common materials, without exacting tolerances. In the Cryenco-Los Alamos collaboration, the authors are developing a version of this invention suitable for use in the natural-gas industry. The project is known as acoustic liquefier for short. The present program plans call for a two-phase development. Phase 1, with capacity of 500 gallon per day (i.e., approximately 40,000 scfd, requiring a refrigeration power of about 7 kW), is large enough to illuminate all the issues of large-scale acoustic liquefaction without undue cost, and to demonstrate the liquefaction of 60--70% of input gas, while burning 30--40%. Phase 2 will target versions of approximately 10{sup 6} scfd = 10,000 gallon per day capacity. In parallel with both, they continue fundamental research on the technology, directed toward increased efficiency, to build scientific foundations and a patent portfolio for future acoustic liquefiers.
Date: May 1997
Creator: Swift, G. W.
Partner: UNT Libraries Government Documents Department