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Connecticut State University System Initiative for Nanotechnology-Related Equipment, Faculty Development and Curriculum Development

Description: DOE grant used for partial fulfillment of necessary laboratory equipment for course enrichment and new graduate programs in nanotechnology at the four institutions of the Connecticut State University System (CSUS). Equipment in this initial phase included variable pressure scanning electron microscope with energy dispersive x-ray spectroscopy elemental analysis capability [at Southern Connecticut State University]; power x-ray diffractometer [at Central Connecticut State University]; a spectrophotometer and spectrofluorimeter [at Eastern Connecticut State University; and a Raman Spectrometer [at Western Connecticut State University]. DOE's funding was allocated for purchase and installation of this scientific equipment and instrumentation. Subsequently, DOE funding was allocated to fund the curriculum, faculty development and travel necessary to continue development and implementation of the System's Graduate Certificate in Nanotechnology (GCNT) program and the ConnSCU Nanotechnology Center (ConnSCU-NC) at Southern Connecticut State University. All of the established outcomes have been successfully achieved. The courses and structure of the GCNT program have been determined and the program will be completely implemented in the fall of 2013. The instrumentation has been purchased, installed and has been utilized at each campus for the implementation of the nanotechnology courses, CSUS GCNT and the ConnSCU-NC. Additional outcomes for this grant include curriculum development for non-majors as well as faculty and student research.
Date: March 28, 2013
Creator: Broadbridge, Christine C.
Partner: UNT Libraries Government Documents Department

"Bottom-up" meets "top-down" : self-assembly to direct manipulation of nanostructures on length scales from atoms to microns.

Description: This document is the final SAND Report for the LDRD Project 102660 - 'Bottomup' meets 'top-down': Self-assembly to direct manipulation of nanostructures on length scales from atoms to microns - funded through the Strategic Partnerships investment area as part of the National Institute for Nano-Engineering (NINE) project.
Date: April 1, 2009
Creator: Swartzentruber, Brian Shoemaker
Partner: UNT Libraries Government Documents Department

Homometallic and Heterometallic Antiferromagnetic Rings: Magnetic Properties Studied by Nuclear Magnetic Resonance

Description: The aim of the present thesis is to investigate the local magnetic properties of homometallic Cr{sub 8} antiferromagnetic (AFM) ring and the changes occurring by replacing one Cr{sup 3+} ion with diamagnetic Cd{sup 2+} (Cr{sub 7}Cd) and with Ni{sup 2+} (Cr{sub 7}Ni). In the heterometallic ring a redistribution of the local magnetic moment is expected in the low temperature ground state. We have investigated those changes by both {sup 53}Cr-NMR and {sup 19}F-NMR. We have determined the order of magnitude of the transferred hyperfine coupling constant {sup 19}F - M{sup +} where M{sup +} = Cr{sup 3+}, Ni{sup 2+} in the different rings. This latter result gives useful information about the overlapping of the electronic wavefunctions involved in the coordinative bond.
Date: May 9, 2012
Creator: Casadei, Cecilia
Partner: UNT Libraries Government Documents Department

The Big Group of People Looking at How to Control Putting the Parts of the Air That Are the Same as What You Breathe Out Into Small Spaces in Rocks

Description: Representing the Nanoscale Control of Geologic CO2 (NCGC), this document is one of the entries in the Ten Hundred and One Word Challenge. As part of the challenge, the 46 Energy Frontier Research Centers were invited to represent their science in images, cartoons, photos, words and original paintings, but any descriptions or words could only use the 1000 most commonly used words in the English language, with the addition of one word important to each of the EFRCs and the mission of DOE energy. The mission of NCGC is to build a fundamental understanding of molecular-to-pore-scale processes in fluid-rock systems, and to demonstrate the ability to control critical aspects of flow, transport, and mineralization in porous rock media as applied to the injection and storage of carbon dioxide (CO2) in subsurface reservoirs.
Date: July 18, 2013
Creator: Stack, Andrew
Partner: UNT Libraries Government Documents Department

Electron Diffraction Determination of Nanoscale Structures

Description: Dominant research results on adsorption on gold clusters are reviewed, including adsorption of H{sub 2}O and O{sub 2} on gold cluster cations and anions, kinetics of CO adsorption to middle sized gold cluster cations, adsorption of CO on Au{sub n}{sup +} with induced changes in structure, and H{sub 2}O enhancement of CO adsorption.
Date: March 1, 2013
Creator: Parks, Joel H
Partner: UNT Libraries Government Documents Department

Characterization and Properties of Metallic Iron and Iron-Oxide Nanoparticles: Spectroscopy, Electrochemistry, and Kinetics

Description: There are reports that nano-sized zero-valent iron (Fe0) exhibits greater reactivity than micro-sized particles of Fe0, and it has been suggested that the higher reactivity of nano-Fe0 may impart advantages for groundwater remediation or other environmental applications. However, most of these reports are preliminary in that they leave a host of potentially significant (and often challenging) material or process variables either uncontrolled or unresolved. In an effort to better understand the reactivity of nano-Fe0, we have used a variety of complementary techniques to characterize two widely studied nano-Fe0 preparations:  one synthesized by reduction of goethite with heat and H2 (FeH2) and the other by reductive precipitation with borohydride (FeBH). FeH2 is a two-phase material consisting of 40 nm α-Fe0 (made up of crystals approximately the size of the particles) and Fe3O4 particles of similar size or larger containing reduced sulfur; whereas FeBH is mostly 20−80 nm metallic Fe particles (aggregates of <1.5 nm grains) with an oxide shell/coating that is high in oxidized boron. The FeBH particles further aggregate into chains. Both materials exhibit corrosion potentials that are more negative than nano-sized Fe2O3, Fe3O4, micro-sized Fe0, or a solid Fe0 disk, which is consistent with their rapid reduction of oxygen, benzoquinone, and carbon tetrachloride. Benzoquinonewhich presumably probes inner-sphere surface reactionsreacts more rapidly with FeBH than FeH2, whereas carbon tetrachloride reacts at similar rates with FeBH and FeH2, presumably by outer-sphere electron transfer. Both types of nano-Fe0 react more rapidly than micro-sized Fe0 based on mass-normalized rate constants, but surface area-normalized rate constants do not show a significant nano-size effect. The distribution of products from reduction of carbon tetrachloride is more favorable with FeH2, which produces less chloroform than reaction with FeBH.
Date: December 1, 2005
Creator: Nurmi, JT; Tratnyek, PG; Sarathy, V; Baer, DR; Amonette, JE; Pecher, K et al.
Partner: UNT Libraries Government Documents Department

Scientific Evaluation of Nanomaterials of TiO{sub 2} and Related Derivatives in a Variety of Applications

Description: Altair Nanotechnolgies, Inc. (Altair) has performed and hereby reports on research and development of novel nanomaterials for applications in 1) advanced power storage devices, 2) sensors for chemical, biological and radiological agents and on an 3) investigation into mechanisms of living cell-nanoparticle interactions that will allow predictions of health and safety issues and potentially result in novel agents for remediation of chemical and biological hazards. The project was organized around four distinct objectives. Two of the objectives are focused on developments designed to dramatically improve the performance of rechargeable Li-Ion batteries. These efforts are based on extensions of Altair's proprietary TiO{sub 2} nanoparticles and nanoparticle aggregates in the form of lithium titanate spinel, lithium manganates and lithium cobaltates. A third objective leverages the core Altair nanomaterials technology to develop a unique (nanosensor) platform for the error-free, "lab on a chip" detection of chemical, biological and radiological agents for hazardous materials remediation and threat detection. The innovative approach taken by the Altair/Western Michigan team develops individual nanosensor elements built upon a construct that includes a target-specific receptor molecule coupled through a signal transducing nanomolecule to a gold, TiO{sub 2} or SiO{sub 2} nanoparticle coated with a high density of strongfluorescing molecules for signal amplification The final objective focuses on interaction mechanisms between cells and nanoparticles with the goal of understanding how specific chemical and physical properties of these nanoparticles influence that interaction. The effort will examine a range of microbes that have environmental or societal importance.
Date: September 30, 2008
Creator: Spitler, Timothy M; Stewart, Matthew; Pasquier, Aurelien Du; Coleman, Michael; Gunasinghe, Thushara; Manev, Veselin et al.
Partner: UNT Libraries Government Documents Department

Non-Equilibrium Nanoscale Self-Organization

Description: Self-organized one- and two-dimensional arrays of nanoscale surface features ("ripples" and "dots") sometimes form spontaneously on initially flat surfaces eroded by a directed ion beam in a process called "sputter patterning". Experiments on this sputter patterning process with focused and unfocused ion beams, combined with theoretical advances, have been responsible for a number of scientific advances. Particularly noteworthy are (i) the discovery of propagative, rather than dissipative, behavior under some ion erosion conditions, permitting a pattern to be fabricated at a large length scale and propagated over large distances while maintaining, or even sharpening, the sharpest features; (ii) the first demonstration of guided self-organization of sputter patterns, along with the observation that defect density is minimized when the spacing between boundaries is near an integer times the natural spatial period; and (iii) the discovery of metastability of smooth surfaces, which contradicts the nearly universally accepted linear stability theory that predicts that any surface is linearly unstable to sinusoidal perturbations of some wave vector.
Date: March 9, 2006
Creator: Aziz, Michael J
Partner: UNT Libraries Government Documents Department

PATCHY SILICA-COATED SILVER NANOWIRES AS SERS SUBSTRATES

Description: We report a class of core-shell nanomaterials that can be used as efficient surface-enhancement Raman scattering (SERS) substrates. The core consists of silver nanowires, prepared through a chemical reduction process, that are used to capture 4- mercaptobenzoic acid (4-MBA), a model analyte. The shell was prepared through a modified Stöber method and consists of patchy or full silica coats. The formation of silica coats was monitored via transmission electron microscopy, UV-visible spectroscopy and phase-analysis light scattering for measuring effective surface charge. Surprisingly, the patchy silica coated silver nanowires are better SERS substrate than silver nanowires; nanomolar concentration of 4-MBA can be detected. In addition, “nano-matryoshka” configurations were used to quantitate/explore the effect of the electromagnetic field at the tips of the nanowire (“hot spots”) in the Raman scattering experiment.
Date: March 29, 2013
Creator: Murph, S. & Murphy, C.
Partner: UNT Libraries Government Documents Department

METALLIC AND HYBRID NANOSTRUCTURES: FUNDAMENTALS AND APPLICATIONS

Description: This book chapter presents an overview of research conducted in our laboratory on preparation, optical and physico-chemical properties of metallic and nanohybrid materials. Metallic nanoparticles, particularly gold, silver, platinum or a combination of those are the main focus of this review manuscript. These metallic nanoparticles were further functionalized and used as templates for creation of complex and ordered nanomaterials with tailored and tunable structural, optical, catalytic and surface properties. Controlling the surface chemistry on/off metallic nanoparticles allows production of advanced nanoarchitectures. This includes coupled or encapsulated core-shell geometries, nano-peapods, solid or hollow, monometallic/bimetallic, hybrid nanoparticles. Rational assemblies of these nanostructures into one-, two- and tridimensional nano-architectures is described and analyzed. Their sensing, environmental and energy related applications are reviewed.
Date: May 2, 2012
Creator: Murph, S.
Partner: UNT Libraries Government Documents Department

Nanorods of Silicon and Germanium with Well-Defined Shapes and Sizes

Description: We have made number of important discoveries along the major goals of the project, namely i) electrodeposition of germanium thin films from clusters, ii) synthesis of cluster-based surfactants with long hydrocarbon chains and micelles made of them, iii) grafting of Ge{sub 9}-clusters onto self assembled films of siloxanes attached to glass substrates, iv) doping of Ge{sub 9}-clusters, and v) expanding the clusters to ten-atom cages of Ge{sub 10}{sup 2-}.
Date: May 3, 2012
Creator: Sevov, Slavi C.
Partner: UNT Libraries Government Documents Department

Final Report: Algorithms for Diffractive Microscopy

Description: The phenomenal coherence and brightness of x-ray free-electron laser light sources, such as the LCLS at SLAC, have the potential of revolutionizing the investigation of structure and dynamics in the nano-domain. However, this potential will go unrealized without a similar revolution in the way the data are analyzed. While it is true that the ambitious design parameters of the LCLS have been achieved, the prospects of realizing the most publicized goal of this instrument — the imaging of individual bio-particles — remains daunting. Even with 10{sup 12} photons per x-ray pulse, the feebleness of the scattering process represents a fundamental limit that no amount of engineering ingenuity can overcome. Large bio-molecules will scatter on the order of only 10{sup 3} photons per pulse into a detector with 106 pixels; the diffraction “images” will be virtually indistinguishable from noise. Averaging such noisy signals over many pulses is not possible because the particle orientation cannot be controlled. Each noisy laser snapshot is thus confounded by the unknown viewpoint of the particle. Given the heavy DOE investment in LCLS and the profound technical challenges facing single-particle imaging, the final two years of this project have concentrated on this effort. We are happy to report that we succeeded in developing an extremely efficient algorithm that can reconstruct the shapes of particles at even the extremes of noise expected in future LCLS experiments with single bio-particles. Since this is the most important outcome of this project, the major part of this report documents this accomplishment. The theoretical techniques that were developed for the single-particle imaging project have proved useful in other imaging problems that are described at the end of the report.
Date: October 8, 2010
Creator: Elser, Veit
Partner: UNT Libraries Government Documents Department

Plasmon Mapping in Metallic Nanostructures and its Application to Single Molecule Surface Enhanced Raman Scattering: Imaging Electromagnetic Hot-Spots and Analyte Location

Description: A major component of this proposal is to elucidate the connection between optical and electron excitation of plasmon modes in metallic nanostructures. These accomplishments are reported: developed a routine protocol for obtaining spatially resolved, low energy EELS spectra, and resonance Rayleigh scattering spectra from the same nanostructures.; correlated optical scattering spectra and plasmon maps obtained using STEM/EELS.; and imaged electromagnetic hot spots responsible for single-molecule surface-enhanced Raman scattering (SMSERS).
Date: July 16, 2013
Creator: Camden, Jon P
Partner: UNT Libraries Government Documents Department

Ion Beam Nanosculpting and Materials Science with Single Nanopores

Description: Work is reported in these areas: Nanopore studies; Ion sculpting of metals; High energy ion sculpting; Metrology of nanopores with single wall carbon nanotube probes; Capturing molecules in a nanopore; Strand separation in a nanopore; and DNA molecules and configurations in solid-state nanopores.
Date: October 3, 2009
Creator: Golovchenko, J. A. & Branton, D.
Partner: UNT Libraries Government Documents Department

Nanotechnology and Environmental, Health, and Safety: Issues for Consideration

Description: This report: identifies the potential environmental, health, and safety opportunities and challenges of nanotechnology; explains the importance of addressing nanotechnology EHS concerns; identifies and discusses nanotechnology EHS issues; and summarizes options for Congressional action, including the nanotechnology EHS-related provisions of selected legislation.
Date: January 20, 2011
Creator: Sargent, John F., Jr.
Partner: UNT Libraries Government Documents Department