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Liquefaction of coals using ultra-fine particle, unsupported catalysts: In situ generation by rapid expansion of supercritical fluid solutions

Description: The program objective is to generate ultra-fine catalyst particles (20 to 400 {Angstrom} in size) and quantify their potential for improving coal dissolution in the solubilization stage of two-stage catalytic-catalytic liquefaction systems. In the first quarterly report for this program the concept behind our approach was detailed, the structure of the program was presented, key technical issues were identified, preliminary designs were outlined, and technical progress was discussed. All progre… more
Date: September 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Fusion utilization projections in the United States energy economy

Description: The following topics are discussed in some detail in this report: (1) applications of fusion energy, (2) fusion implementation in the US energy system, (3) reactor performance requirements, (4) technology for electric applications, and (5) technology for synthetic fuel/chemical applications. (MOW)
Date: November 1, 1979
Creator: Powell, J.R. & Fillo, J.A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Coal Technology Program. Progress report for November 1977

Description: A block of Pittsburgh seam bituminous coal and a block of Wyodak subbituminous coal were pyrolyzed under reducing gas in support of in situ gasification. Information from previously completed block pyrolysis of bituminous coal under an argon atmosphere show that differences in evolved gas result from differences in heating rates. Compared to block pyrolysis at 0.3 C/sup 0//min, block pyrolysis at 3 C/sup 0//min produces less gas but gas with a higher heating value, yielding a higher overall pyr… more
Date: January 1, 1978
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Exploratory research on solvent refined coal liquefaction. Annual technical progress report, January 1-December 31, 1979

Description: This report summarizes the progress of the Exploratory Research on Solvent Refined Coal Liquefaction project by The Pittsburg and Midway Coal Mining Co.'s Merriam Laboratory during 1979. In a series of experiments with varying feed gas composition, low levels (5 to 10 mole %) of carbon monoxide had little effect on the SRC II processing of Pittsburgh Seam coal (Powhatan No. 5 Mine) while higher levels (20 to 40 mole %) resulted in a general degradation of operability and reduced oil yields. Add… more
Date: September 1, 1980
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Enthalpy measurement of coal-derived liquids. Combined quarterly technical progress reports, April-June 1979 and July-September 1979. [Effect of association]

Description: Enthalpy measurements on a coal-derived naphtha and middle distillate, both produced by the SRC-II process, were made using flow calorimetry. The accuracy of the measurements, as reported by Omid, was within +- 1% of the measured enthalpy differences, ..delta..H. Experimental data for the naphtha were obtained over a pressure range of 100-300 psia and temperatures from 148/sup 0/ to 456/sup 0/F. The middle distillate enthalpy measurements were made in the pressure and temperature ranges of 130 … more
Date: 1979~
Creator: Kidnay, A. J. & Yesavage, V. F.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Liquefaction of coals using ultra-fine particle, unsupported catalysts: In situ generation by rapid expansion of supercritical fluid solutions

Description: The purpose of this program is to design and fabricate an experimental ultra-fine particle generation system; use this system to generate ultra-fine, iron compound, catalyst particles; and to access the ability of these ultra-fine catalyst particles to improve the performance of the solubilization stage of two-stage, catalytic-catalytic liquefaction processes. The effort applied to this program during this reporting period was devoted to experimental design and fabrication tasks.
Date: September 1, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Uranium hexafluoride: Safe handling, processing, and transporting: Conference proceedings

Description: This conference seeks to provide a forum for the exchange of information and ideas of the safety aspects and technical issue related to the handling of uranium hexafluoride. By allowing operators, engineers, scientists, managers, educators, and others to meet and share experiences of mutual concern, the conference is also intended to provide the participants with a more complete knowledge of technical and operational issues. The topics for the papers in the proceedings are widely varied and inc… more
Date: January 1, 1988
Creator: Strunk, W.D. & Thornton, S.G. (eds.)
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

Flash hydropyrolysis of coal. Quarterly report No. 2, April 1--June 30, 1977

Description: With the combination of low hydrogen to coal ratio, high coal feed rate and larger total quantity of coal fed, considerable liquid product is being condensed and collected. Experimental runs conducted at 750/sup 0/C and 800/sup 0/C at pressures up to 3000 psi of hydrogen show overall hydrocarbon yields and particularly gaseous hydrocarbon yields to increase with pressure to approximately 60 percent at 3000 psi. At 750/sup 0/C approximately one third (20 percent) of this yield is in the form of … more
Date: July 1, 1977
Creator: Fallon, P
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Process and analytical studies of enhanced low severity co-processing using selective coal pretreatment

Description: This report describes progress on research during the eleventh quarter of this contract dealing with applications of coal pretreatment techniques in coal/oil co-processing and direct hydroliquefaction. The objectives of the project are to investigate various coal pretreatment techniques and to determine the effect of these pretreatment procedures on the reactivity of the coal. Reactivity enhancement will be evaluated under both direct hydroliquefaction and co-processing conditions. Coal convers… more
Date: 1991-06~
Creator: Baldwin, R. M.; Gaur, S. & Miller, R. L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Novel nanodispersed coal liquefaction catalysts: Molecular design via microemulsion-based synthesis

Description: The objective of this project is to pursue the development of highly dispersed and inexpensive catalysts for improved coal solubilization and upgrading of coal liquids. A novel study of the synthesis of liquefaction catalysts of nanometer size will be carried out. It is based on the molecular design of reverse micelles (microemulsions). These surfactant-stabilized, metal bearing microdrops offer unique opportunities for synthesizing very small particles by providing a cage-like effect that limi… more
Date: April 1, 1991
Creator: Osseo-Asare, K. & Radovic, L.R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Critical Technology List update. Final technical report

Description: ICRC has reviewed and updated its List of critical technology. The List comprises all proposed SRC-I Demonstration Plant equipment whose use has been determined to involve some degree of potential safety, performance, or environmental risk. ICRC has subjected equipment on the Critical Technology c to special technical review to ensure the highest possible level of quality and lowest cost commensurate with acceptable overall risks. Equipment or equipment systems still considered to be high risk … more
Date: March 1, 1983
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Characterization of carbonaceous materials using extraction with supercritical pentane

Description: The use of carbonaceous adsorbents is limited by irreversible adsorption of some compounds so the use of supercritical pentane as an extracting solvent was examined. Carbon black appeared to be broken down slowly, but continuously, by the penane. To see if other types of carbon behaved similarly, high purity graphite, technical grade graphites, active carbons, and charcoals were examined. The extracts were characterized by uv spectroscopy, packed column chromatography using flame ionization and… more
Date: May 30, 1980
Creator: Fetzer, J.C.; Graham, J.A.; Arrendale, R.R.; Klee, M.S. & Rogers, L.B.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Heavy recycle solvent studies in two-stage coal liquefaction. Final technical report, September 1, 1982-December 30, 1983

Description: The objective of this program has been to study the chemistry of the components with high boiling points in a direct coal liquefaction recycle solvent and to identify those components which lead to higher overall yields and improved product stability in the initial coal dissolution step of direct coal liquefaction processes. The major conclusions are: -454 C recycle solvent is primarily aromatic hydrocarbons (73%) and contains almost no asphaltenes; +454 C recycle solvent is primarily asphalten… more
Date: January 10, 1984
Creator: Longanbach, J. R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Research guidance studies to assess gasoline from coal by methanol-to-gasoline and Sasol-type Fischer--Tropsch technologies

Description: The primary purpose of this study is to provide a technical and economic comparison between the commercial Fischer-Tropsch technology and the new Mobil methanol-to-gasoline technology for the production of motor gasoline. Several technical sensitivity cases are also part of the study and will be included in the final report. Two conceptual plant complexes - Base Case I: Mobil Technology and Base Case II: Fischer-Tropsch Technology--have been developed. They are self-supporting, grass roots faci… more
Date: September 1, 1977
Creator: Schreiner, M.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Two-stage process for conversion of synthesis gas to high quality transportation fuels. Quarterly report, 8 June-30 September 1983

Description: The design of two large hot-flow models, to be used for slurry bubble-column hydrodynamic studies, is described. Scoping experiments were performed in smaller models to study the effects of feed-gas distributor type, column diameter, and liquid medium on gas holdup and bubble sizes. In addition, a literature review of bubble-column hydrodynamics is presented. Modifications to improve the operation and flexibility of the existing two stage pilot plant have been designed and construction initiate… more
Date: November 1, 1983
Creator: Kuo, J.C.W.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Novel nanodispersed coal liquefaction catalysts: Molecular design via microemulsion-based synthesis

Description: The objective of this project is to pursue the development of highly dispersed and inexpensive catalysts for improved coal solubilization and upgrading of coal liquids. A novel study of the synthesis of liquefaction catalysts of nanometer size will be carried out. It is based on the molecular design of reverse micelles (microemulsions). These surfactant-stabilized, metal-bearing microdrops offer unique opportunities for synthesizing very small particles by providing a cage-like effect that limi… more
Date: July 1, 1991
Creator: Osseo-Asare, K. & Radovic, L.R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Coal liquefaction process streams characterization and evaluation

Description: This study was designed to demonstrate the use of two different methods for the separation of direct coal liquefaction process- derived materials into defined fractions. The two methods, liquid chromatography (LC) and supercritical fluid extraction (SFE), were employed to determine if the same or complementary information could be obtained by the two methods. The primary objective was to evaluate the potential of supplementing or replacing the conventional LC method with SFE and in so doing to … more
Date: January 1, 1992
Creator: Taylor, L. T.; Hellgeth, J. W. & Sequeira, A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Novel nanodispersed coal liquefaction catalysts: Molecular design via microemulsion-based synthesis

Description: The objective of this project is to pursue the development of highly dispersed and inexpensive catalysts for improved coal solubilization and upgrading of coal liquids. A novel study of the synthesis of liquefaction catalysts of nanometer size will be carried out. It is based on the molecular design of reverse micelles (microemulsions). These surfactant-stabilized, metal-bearing microdrops offer unique opportunities for synthesizing very small particles by providing a cage-like effect that limi… more
Date: April 1, 1992
Creator: Osseo-Asare, K.; Boakye, E.; Vaidyanathan, N. & Radovic, L.R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Quarterly technical progress report, October 1-December 30, 1983

Description: Several new initiatives were begun in coal preparation, including a project to develop a liquid CO/sub 2/ coalescence process that will produce a superclean coal containing less than 1% ash. Another new project in this area is focusing on chemical coal cleaning for the removal of harmful trace elements, such as arsenic, lead, and zinc. Milestones were reached in both of our major electron beam flue gas cleanup projects. In the area of coal-water mixtures, our major industrial contracts are now … more
Date: April 1, 1984
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Solvent Refined Coal-II (SRC-II) detailed environmental plan

Description: This document describes environmental research which will: aid in the development of an environmentally acceptable SRC-II process; and provide data for environmental assessment of the process. The SRC-II process is described, criteria for selection of samples to undergo environmental analyses are given, and approximate timelines are presented for obtaining pertinent samples. At this time, the SRC-II process is at the pilot-plant stage of development and a demonstration facility is scheduled to … more
Date: October 1, 1980
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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Superacid Catalyzed Coal Conversion Chemistry. 1st and 2nd Quarterly Technical Progress Reports, September 1, 1983-March 30, 1984. [Model Compound Consisting of 2 Benzene Rings Connected With Various Bridging Units Such as Alkylidene, Ether, Sulfide, Etc]

Description: In our laboratories we have previously developed a mild coal conversion process. This involves the use of a superacid system consisting of HF and BF/sub 3/ in presence of hydrogen and/or a hydrogen donor solvent. In order to understand the chemistry involved in the process of depolymerization of coal by the HF:BF/sub 3/:H/sub 2/ system we are carrying out a systematic study of a number of coal model compounds. The model compounds selected for present study have two benzene rings connected with … more
Date: January 1, 1984
Creator: Olah, G.A.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Anaerobic bioprocessing of low-rank coals

Description: The overall goal of this project is to find biological methods to remove carboxylic functionalities from low-rank coals and to assess the properties of the modified coal towards coal liquefaction. The main objectives for this quarter were: (1) continuation of microbial consortia development and maintenance, (2) crude enzyme study using best decarboxylating organisms, (3) decarboxylation of lignite, demineralized Wyodak coal and model polymers, and (4) characterization of biotreated coals.
Date: April 15, 1992
Creator: Jain, M. K.; Narayan, R. & Han, O.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Evaluation of Wastewater Treatment Requirements for Thermochemical Biomass Liquefaction

Description: Biomass can provide a substantial energy source. Liquids are preferred for use as transportation fuels because of their high energy density and handling ease and safety. Liquid fuel production from biomass can be accomplished by any of several different processes including hydrolysis and fermentation of the carbohydrates to alcohol fuels, thermal gasification and synthesis of alcohol or hydrocarbon fuels, direct extraction of biologically produced hydrocarbons such as seed oils or algae lipids,… more
Date: April 1, 1992
Creator: Elliott, D. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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