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Field Trip Guide to Serpentinite, Silica-Carbonate Alteration, and Related Hydrothermal Activity in the Clear Lake Region, California

Description: This guide is designed to familiarize scientists with the geology, structure, alteration, and fluids typical of California serpentinites for purposes of carbon dioxide sequestration (Lackner et al., 1995). Goff et al. (1997) and Goff and Lackner (1998) describe the geology and geochemistry of some of the serpentinites from this area. Mechanisms of silica-carbonate alteration were outlined by Barnes et al. (1973). Donnelly-Nolan et al. (1993) most recently reviewed relations between regional hydrothermal alteration and Quarternary volcanic activity. Stanley et al. (1998) summarized geophysical characteristics of the region.
Date: June 1, 1999
Creator: Goff, Fraser & Guthrie, George
Partner: UNT Libraries Government Documents Department

Summary of Research through Phase II/Year 2 of Initially Approved 3 Phase/3 Year Project - Establishing the Relationship between Fracture-Related Dolomite and Primary Rock Fabric on the Distribution of Reservoirs in the Michigan Basin

Description: This final scientific/technical report covers the first 2 years (Phases I and II of an originally planned 3 Year/3 Phase program). The project was focused on evaluating the relationship between fracture-related dolomite and dolomite constrained by primary rock fabric in the 3 most prolific reservoir intervals in the Michigan Basin. The characterization of select dolomite reservoirs was the major focus of our efforts in Phases I and II of the project. Structural mapping and log analysis in the Dundee (Devonian) and Trenton/Black River (Ordovician) suggest a close spatial relationship among gross dolomite distribution and regional-scale, wrench fault-related NW-SE and NE-SW structural trends. A high temperature origin for much of the dolomite in these 2 studied intervals (based upon fluid inclusion homogenization temperatures and stable isotopic analyses,) coupled with persistent association of this dolomite in reservoirs coincident with wrench fault-related features, is strong evidence for these reservoirs being influenced by hydrothermal dolomitization. In the Niagaran (Silurian), there is a general trend of increasing dolomitization shelfward, with limestone predominant in more basinward positions. A major finding is that facies types, when analyzed at a detailed level, are directly related to reservoir porosity and permeability in these dolomites which increases the predictability of reservoir quality in these units. This pattern is consistent with our original hypothesis of primary facies control on dolomitization and resulting reservoir quality at some level. The identification of distinct and predictable vertical stacking patterns within a hierarchical sequence and cycle framework provides a high degree of confidence at this point that the results should be exportable throughout the basin. Much of the data synthesis and modeling for the project was scheduled to be part of Year 3/Phase III, but the discontinuation of funding after Year 2 precluded those efforts. Therefore, the results presented in this document are not final, ...
Date: September 30, 2007
Creator: Grammer, G.
Partner: UNT Libraries Government Documents Department

Creating a Geologic Play Book for Trenton-Black River Appalachian Basin Exploration

Description: Preliminary isopach and facies maps, combined with a literature review, were used to develop a sequence of basin geometry, architecture and facies development during Cambrian and Ordovician time. The main architectural features--basins, sub basins and platforms--were identified and mapped as their positions shifted with time. This is significant because a better understanding of the control of basin geometry and architecture on the distribution of key facies and on subsequent reservoir development in Ordovician carbonates within the Trenton and Black River is essential for future exploration planning. Good exploration potential is thought to exist along the entire platform margin, where clean grainstones were deposited in skeletal shoals from Indiana thorough Ohio and Ontario into Pennsylvania. The best reservoir facies for the development of hydrothermal dolomites appears to be these clean carbonates. This conclusion is supported by observations taken in existing fields in Indiana, Ontario, Ohio and New York. In contrast, Trenton-Black River production in Kentucky and West Virginia has been from fractured, but non-dolomitized, limestone reservoirs. Facies maps indicate that these limestones were deposited under conditions that led to a higher argillaceous content than the cleaner limestones deposited in higher-energy environments along platform margins. However, even in the broad area of argillaceous limestones, clean limestone buildups have been observed in eastern outcrops and, if present and dolomitized in the subsurface, may provide additional exploration targets. Structure and isopach maps developed as part of the structural and seismic study supported the basin architecture and geometry conclusions, and from them some structural control on the location of architectural features may be inferred. This portion of the study eventually will lead to a determination of the timing relative to fracturing, dolomitization and hydrocarbon charging of reservoirs in the Trenton and Black River carbonates. The focus of this effort will shift in the next few ...
Date: September 30, 2005
Creator: Patchen, Douglas G.; Smith, Taury; Riley, Ron; Baranoski, Mark; Harris, David; Hickman, John et al.
Partner: UNT Libraries Government Documents Department

Geology and Geothermal Potential North of Wells, Nevada

Description: The geology north of Wells, Nevada is dominated by approximately 2150 m of Tertiary lacustrine siltstones and conglomerates. The sediments are cut by a high-angle, range-bounding fault and several associated step faults. Hydrothermal alteration and silicification are associated with the high-angle faults. Two ages of Quaternary sediments locally overlie the Tertiary sediments. Lithologic and well log analyses define numerous potential aquifers in the Tertiary sediments. The shallowest of these aquifers is overlain by a tuffaceous siltstone which appears to act as an aquitard for hot water moving through the aquifers. Three possible subsurface hydrologic models can be constructed to explain the spatial relationships of the thermal water near Wells. Cost-effective steps taken to expedite geothermal development in the area might include deepening of an existing domestic well in the city of Wells to at least 180 m in order to penetrate the tuffaceous siltstone aquitard, running borehole logs for all existing wells, and conducting a shallow temperature-probe survey in the Tertiary sediments north of Wells.
Date: November 1, 1982
Creator: Jewell, Paul W.
Partner: UNT Libraries Government Documents Department

Uranium (VI) and Neptunium (V) Transport Fractured, Hydrothermally Altered Concrete

Description: In a high level waste repository in which temperatures are elevated due to waste decay, concrete structures will be subjected to hydrothermal conditions that will alter their physical and chemical properties. Virtually no studies have examined the interaction of hydrothermally altered concrete with radionuclides. We present the results of experiments in which soluble and colloid-associated actinides, uranium (U) and neptunium (Np), were eluted into a fractured, hydrothermally altered concrete core. Although the fluid residence time in the fracture was estimated to be on the order of 1 minute, U and Np were below detection (10{sup -9}-10{sup -8} M) in the effluent from the core, for both soluble and colloid-associated species. Inorganic colloids and latex microspheres were similarly immobilized within the core. Post-test analysis of the core identified the immobilized U and Np at or near the fracture surface, with a spatial distribution similar to that of the latex microspheres. Because hydrothermal alteration followed fracturing, the growth of crystalline calcium silicate hydrate and clay mineral alteration products on, and possibly across the fracture, resulted in a highly reactive fracture that was effective at capturing both soluble and colloidal radionuclides. Comparison of results from batch experiments [1] with these experiments indicate that partitioning of U and Np to the solid phase, and equilibration of the incoming fluid with the concrete, occurs rapidly in the fractured system. Transport of U through the concrete may be solubility and/or sorption limited; transport of Np appears to be limited primarily by sorption.
Date: November 4, 1999
Creator: Matzen, S.L.; Beiriger, J.M.; Torretto, P.C. & Zhao, P.
Partner: UNT Libraries Government Documents Department

Characterizing the dealumination of environmentally relevant zeolites using IR, NMR and neutron diffraction techniques

Description: Results of characterization studies monitoring the sequential chemical bond breaking events, local site symmetry, and long range structural modifications of specific zeolites (H-ZSM-5, TS-1) during hydrothermal treatment of these catalyst materials are described. These characterization techniques include infrared spectroscopy of selected probe molecules, magic angle spinning NMR spectroscopy, and powder neutron diffraction. Information regarding selected examples from each of these techniques is presented and the inherent strengths of each is discussed. The experimental insight into the chemical and structural modifications of high surface area microporous catalyst materials as a function of deactivation conditions (hydrothermal conditioning) is highlighted.
Date: July 1, 1997
Creator: Paffett, M.T.; Szanyi, J.; Jacubinas, R.M.; Ott, K.C.; VonDreele, R.; Hughes, C.D. et al.
Partner: UNT Libraries Government Documents Department

Gibbsite to Boehmite Transformation in Strongly Caustic and Nitrate Environments

Description: The transformation of gibbsite to boehmite in strongly caustic solutions was studied using quantitative X-ray diffraction, Fourier transform infrared spectroscopy, and transmission electron microscopy techniques. Under hydrothermal conditions we identified two transformation mechanisms; dehydration and in-situ nucleation and dissolution and nucleation. If the reaction container was not completely sealed, dehydration of gibbsite followed by in-situ nucleation of boehmite was the preferred mechanism. Boehmite produced fibrous boehmite particles within the amorphous matrix of the decomposed gibbsite particles, which exhibited a poorly crystalline structure and smaller size than the initial gibbsite particles. In a closed environment, the preferred mechanism was the dissolution of gibbsite along (001) planes. The final boehmite particles were not morphologically related to the initial gibbsite particles and could be many times larger than the gibbsite particles.
Date: November 26, 2002
Creator: Hobbs, D.T.
Partner: UNT Libraries Government Documents Department

HYDROGEOLOGY OF THE THERMAL LANDSLIDE

Description: The large Thermal Landslide overlies the initial area of geothermal development at The Geysers. The landslide is waterbearing while the underlying Franciscan formation bedrock units are essentially non-waterbearing except where affected by hydrothermal alteration. Perched ground water moving through the landslide is heated prior to discharge as spring flow.
Date: January 22, 1985
Creator: Vantine, J.
Partner: UNT Libraries Government Documents Department

Hydrothermal alteration at the Roosevelt Hot Springs thermal area, Utah: Petrographic characterization of the alteration to 2 kilometers depth

Description: Hydrothermal alteration in drill cuttings from Thermal Power drillhole 14-2, Roosevelt Hot Springs Thermal area, has been studied petrographically. The hole is sited in alluvium approximately 1.6 km southeast of the old Resort and was rotary drilled to a depth of 1866.0 m. The exact hole location is 2310 FNL, 350 FWL, Sec. 2, Twp 27S, Rge 9W, elevation 1908.5 m. Core was extracted from 792.5 to 795.5 m. Thin sections were made from samples at 15.2 m intervals of drill cuttings collected at 1.5 or 3.0 m intervals during drilling. Thin sections were made of 1.5 or 3.0 m intervals from 274.3 to 304.8 m, 487.9 to 581.2 m, and 868.7 to 899.2 m. These intervals were chosen for close spaced sampling on the basis of increases in temperature, porosity, conductivity and acoustic velocity shown in geophysical logs. A total of 153 thin sections of cuttings were made, and an additional 9 sections were made from the core. Depths of thin section samples are listed in the appendix. A visual estimate of the percentage of each rock type was made for each thin section.
Date: April 1, 1978
Creator: Ballantyne, J.M. & Parry, W.T.
Partner: UNT Libraries Government Documents Department

Task 3.16 -- Low-cost coal-water fuel for entrained-flow gasification. Semi-annual report, July 1--December 31, 1995

Description: Continued interest in gasification technologies has led to the need for more technological advances in the area of fuel cleanup and fuel feed systems, which invariably affect the other components comprised by gasification systems. Some entrained-flow gasifiers require the fuel to be a slurry form or a coal-water fuel (CWF). Recent technological advances at the Energy and Environmental Research Center (EERC) have led to potential means for improving efficiency and air toxics control for gasifiers that utilize CWF. Highly reactive low-rank coals present an attractive CWF gasification feedstock. Hydrothermally treating low-rank coals allows a CWF to be formulated that has an elevated solids content, which reduces the amount of water fed to the gasifier, thereby decreasing the amount of oxygen needed to gasify the coal. Preliminary measurements show that the process would increase the solids content from 53 to 63 wt%, giving a 20% improvement in energy density. The specific objective of this research project is to assess the potential process efficiency and pollution control benefits that may result from applying the hydrothermal, or hot-water-drying (HWD), process to low-rank coals as related to entrained-flow gasification systems. Project emphasis is on identifying more efficient coal dewatering and CWF formulation methods prior to gasification.
Date: January 1, 1998
Creator: Anderson, C.M.
Partner: UNT Libraries Government Documents Department

Integration of advanced nuclear materials separation processes

Description: This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project has examined the fundamental chemistry of plutonium that affects the integration of hydrothermal technology into nuclear materials processing operations. Chemical reactions in high temperature water allow new avenues for waste treatment and radionuclide separation.Successful implementation of hydrothermal technology offers the potential to effective treat many types of radioactive waste, reduce the storage hazards and disposal costs, and minimize the generation of secondary waste streams. The focus has been on the chemistry of plutonium(VI) in solution with carbonate since these are expected to be important species in the effluent from hydrothermal oxidation of Pu-containing organic wastes. The authors investigated the structure, solubility, and stability of the key plutonium complexes. Installation and testing of flow and batch hydrothermal reactors in the Plutonium Facility was accomplished. Preliminary testing with Pu-contaminated organic solutions gave effluent solutions that readily met discard requirements. A new effort in FY 1998 will build on these promising initial results.
Date: December 31, 1998
Creator: Jarvinen, G.D.; Worl, L.A.; Padilla, D.D.; Berg, J.M.; Neu, M.P.; Reilly, S.D. et al.
Partner: UNT Libraries Government Documents Department

The partitioning of uranium and neptunium onto hydrothermally altered concrete

Description: Cementitious materials that are used to construct the ground support for high-level repositories have a high probability of interacting with radionuclide-bearing fluids derived from failed waste packages. Cementitious materials provide a highly alkaline environment; pore fluids in concrete can have pH {gt} 10 for thousands to hundreds of thousands of years. Studies have shown that fresh concrete and cement phases strongly retard or immobilize certain actinides. Consequently, cementitious materials may serve as a barrier to the release of the radionuclides to the far field. However, the effect of thermal alteration of these materials, which may occur in high-level repositories, on their interaction with radionuclides has not been addressed. In contrast to retardation, colloidal silica-enriched particles that are abundant in the pore fluids of cementitious materials may facilitate radionuclide migration through the near-field into the adjacent geological environment. Due to the uncertainties of these two opposite effects, it is important to investigate the interaction of actinides with cementitious materials under varying conditions. It is expected that cementitious materials in high-level waste repositories will be subjected to and altered by hot dry and/or humid conditions forhundreds to thousands of years by the time they interact with radionuclide-bearing fluids. After alteration, the chemical and mineralogical properties of these materials will be significantly different from that of the as-placed or fresh concrete. To assess the effect that this alteration would have on radionuclide interactions, samples of hardened concrete (untreated concrete) were hydrothermally heated at 200 C for 8 months (treated concrete). The concrete used in the experiments consisted of portland cement with an aggregate of dolomitic limestone. X-ray diffraction analysis has shown that portlandite and amorphous calcium silicate hydrate gels were converted to the crystalline calcium silicate hydrate minerals tobermorite, xonotlite, and scawtite, and clay minerals by the hydrothermal treatment. Calcite, dolomite, and quartz ...
Date: October 14, 1999
Creator: Zhao, P.; Allen, P.G.; Sylwester, E.R. & Viani, B.E.
Partner: UNT Libraries Government Documents Department

Hydrothermal processing of radioactive combustible waste

Description: Hydrothermal processing has been demonstrated for the treatment of radioactive combustible materials for the US Department of Energy. A hydrothermal processing system was designed, built and tested for operation in a plutonium glovebox. Presented here are results from the study of the hydrothermal oxidation of plutonium and americium contaminated organic wastes. Experiments show the destruction of the organic component to CO{sub 2} and H{sub 2}O, with 30 wt.% H{sub 2}O{sub 2} as an oxidant, at 540 C and 46.2 MPa. The majority of the actinide component forms insoluble products that are easily separated by filtration. A titanium liner in the reactor and heat exchanger provide corrosion resistance for the oxidation of chlorinated organics. The treatment of solid material is accomplished by particle size reduction and the addition of a viscosity enhancing agent to generate a homogeneous pumpable mixture.
Date: September 1, 1998
Creator: Worl, L. A.; Buelow, S. J.; Harradine, D.; Le, L.; Padilla, D. D. & Roberts, J. H.
Partner: UNT Libraries Government Documents Department

Enhanced sludge processing of HLW: Hydrothermal oxidation of chromium, technetium, and complexants by nitrate. 1998 annual progress report

Description: 'The objective of this project is to develop the scientific basis for hydrothermal separation of chromium from High Level Waste (HLW) sludges. The worked is aimed at attaining a fundamental understanding of chromium speciation, oxidation/reduction and dissolution kinetics, reaction mechanisms, and transport properties under hydrothermal conditions in both simple and complex salt solutions that will ultimately lead to an efficient chromium leaching process. This report summarizes the research over the first 1.5 years of a 3 year project. The authors have examined the dissolution of chromium hydroxide using different oxidants as a function of temperature and alkalinity. The results and possible applications to HLW sludges are discussed'
Date: June 1, 1998
Creator: Buelow, S.J. & Robinson, J.M.
Partner: UNT Libraries Government Documents Department

Acid-base behavior in hydrothermal processing of wastes. 1997 annual progress report

Description: 'A major obstacle to the development of hydrothermal technology for treating DOE wastes has been a lack of scientific knowledge of solution chemistry, thermodynamics and transport phenomena. The progress over the last year is highlighted in the following four abstracts from manuscripts which have been submitted to journals. The authors also have made considerable progress on a spectroscopic study of the acid-base equilibria of Cr(VI). They have utilized novel spectroscopic indicators to study acid-base equilibria up to 380 C. Until now, very few systems have been studied at such high temperatures, although this information is vital for hydrothermal processing of wastes. The pH values of aqueous solutions of boric acid and KOH were measured with the optical indicator 2-naphthol at temperatures from 300 to 380 C. The equilibrium constant Kb-l for the reaction B(OH)3 + OH{sup -} = B(OH){sup -4} was determined from the pH measurements and correlated with a modified Born model. The titration curve for the addition of HCl to sodium borate exhibits strong acid-strong base behavior even at 350 C and 24.1 MPa. At these conditions, aqueous solutions of sodium borate buffer the pH at 9.6 t 0.25. submitted to Ind. Eng. Chem. Res. Acetic Acid and HCl Acid-base titrations for the KOH-acetic acid or NH{sub 3} -acetic acid systems were monitored with the optical indicator 2-naphthoic acid at 350 C and 34 MPa, and those for the HCl;Cl- system with acridine at 380 C and up to 34 MPa (5,000 psia ). KOH remains a much stronger base than NH,OH at high temperature. From 298 K to the critical temperature of water, the dissociation constant for HCl decreases by 13 orders of magnitude, and thus, the basicity of Cl{sup -} becomes significant. Consequently, the addition of NaCl to HCl raises the pH. The pH titration curves ...
Date: January 1, 1997
Partner: UNT Libraries Government Documents Department

Experimental constraints on the chemical evolution of icy satellites

Description: The inferred internal structure of large icy satellites hinges on the degree to which their rock component has been hydrated: this is due to the low density of hydrated silicates relative to anhydrous silicates. Accordingly, interior models of icy satellites have varied greatly in their estimates of ice thickness due to uncertainties in the density of the underlying rock. Furthermore, as both H{sub 2}O (potentially liquid) and organic materials are likely to be present, icy moons have been postulated to be possible hosts for extraterrestrial life; therefore, the stability of organic material under relevant hydrothermal conditions is an important issue. For example, Ganymede, Titan, and Triton are similar in that high pressure hydrothermal processing of silicates has likely been important in their chemical evolution. With mean densities between 1.8 and 2.1 g/cm{sup 3}, compositional models of these bodies incorporate approximately 50--80% silicate minerals by weight, with ices constituting the remaining mass. Moment of inertia constraints on the internal structure of Ganymede demonstrate that differentiation between rock and ice has occurred: such differentiation has also likely occurred in Titan and Triton. During accretion and differentiation (which could be ongoing), the silicate fraction of their interiors would have interacted with aqueous fluids at moderate to high temperatures and pressures. Indeed, a strong magnetic field appears to be generated by Ganymede implying that interior temperatures are high enough (in excess of 1,000 K) to maintain a liquid iron alloy in this satellite. High temperature/pressure hydrothermal processing at rock-water interfaces would profoundly influence the bulk mineralogy and internal structure of these bodies: the degree of hydration of the rocky fraction of these bodies has been a source of ongoing uncertainty. Surprisingly few phase equilibria data exist for compositions of relevance to hydrothermal interactions on icy satellites, and thermodynamic calculations have provided the best insights ...
Date: January 18, 2000
Creator: Scott, H P; Williams, Q & Ryerson, F J
Partner: UNT Libraries Government Documents Department

Enhanced sludge processing of HLW: Hydrothermal oxidation of chromium, technetium, and complexants by nitrate. 1997 mid-year progress report

Description: 'Treatment of High Level Waste (HLW) is the second most costly problem identified by OEM. In order to minimize costs of disposal, the volume of HLW requiring vitrification and long term storage must be reduced. Methods for efficient separation of chromium from waste sludges, such as the Hanford Tank Wastes (HTW), are key to achieving this goal since the allowed level of chromium in high level glass controls waste loading. At concentrations above 0.5 to 1.0 wt.% chromium prevents proper vitrification of the waste. Chromium in sludges most likely exists as extremely insoluble oxides and minerals, with chromium in the plus III oxidation state [1]. In order to solubilize and separate it from other sludge components, Cr(III) must be oxidized to the more soluble Cr(VI) state. Efficient separation of chromium from HLW could produce an estimated savings of $3.4B[2]. Additionally, the efficient separation of technetium [3], TRU, and other metals may require the reformulation of solids to free trapped species as well as the destruction of organic complexants. New chemical processes are needed to separate chromium and other metals from tank wastes. Ideally they should not utilize additional reagents which would increase waste volume or require subsequent removal. The goal of this project is to apply hydrothermal processing for enhanced chromium separation from HLW sludges. Initially, the authors seek to develop a fundamental understanding of chromium speciation, oxidation/reduction and dissolution kinetics, reaction mechanisms, and transport properties under hydrothermal conditions in both simple and complex salt solutions. The authors also wish to evaluate the potential of hydrothermal processing for enhanced separations of technetium and TRU by examining technetium and TRU speciation at hydrothermal conditions optimal for chromium dissolution.'
Date: June 1, 1997
Creator: Buelow, S.
Partner: UNT Libraries Government Documents Department

Acid-base behavior in hydrothermal processing of wastes. 1998 annual progress report

Description: 'A new technology, hydrothermal oxidation (also called supercritical water oxidation), is being developed to treat high level nuclear wastes. Nitrates are reduced to nitrogen; furthermore, phosphates, alumina sludge, and chromium are solubilized, and the sludge is reconstituted as fine oxide particles. A major obstacle to development of this technology has been a lack of scientific knowledge of chemistry in hydrothermal solution above 350 C, particularly acid-base behavior, and transport phenomena, which is needed to understand corrosion, metal-ion complexation, and salt precipitation and recovery. The objective is to provide this knowledge with in-situ UV-vis spectroscopic measurements and fully molecular computer simulation. A major objective of the experimental studies has been to determine the equilibria for Cr(VI) up to 420 C as this is a key species to be removed from nuclear wastes. A wide range of concentrations of KOH and perchloric acid were utilized to manipulate the acid-base equilibria and to understand the effects of ion solvation and ion pairing. The second system is the equilibria between nitric acid, nitrous acid, nitrogen dioxide, nitrite and nitrate ions and oxygen. For both of these systems, chemical equilibria has not been measured previously in hydrothermal solution at these temperatures. On the theoretical side, the authors have focused on the study of the transport properties of aqueous ions in supercritical water. The motivation for these studies is two fold. First, although transport coefficients are fundamental to solution chemistry reaction rates, the behavior of such transport properties over wide ranges of density and temperature are not well established experimentally, particularly at the densities typically of interest (< 0.5 g/cc). Second, due to practical challenges, ionic association equilibria in SCW is typically accessed via measurements of conductivity followed by analysis through a theoretical model that incorporates ion pairing. The results of these analyses in the interesting ...
Date: June 1, 1998
Creator: Johnson, K.P. & Rossky, P.J.
Partner: UNT Libraries Government Documents Department

In-situ time resolved synchrotron powder diffraction studies of synthesis and chemical reactions

Description: Equipment for time and temperature dependent powder diffraction has been developed, especially in order to be able to study hydrothermal syntheses of zeolites. The system is very versatile and has so far been used to study e.g. hydrothermal syntheses of zeolites and aluminophosphates, syntheses of layered phosphates, formation of Sorel cements, dehydration and phase transformations of zeolites, solid state synthesis of lanthanum manganites, ion exchange of zeolites using molten salt, and oxidation/reduction of lanthanum manganites at high temperatures. The sample is contained in quartz capillaries and is heated using a stream of hot air. External pressure can be applied allowing hydrothermal syntheses at temperatures up to 200 C to be performed. Controlled atmosphere is obtained by flowing gas or a mixture of gases through the capillary.
Date: September 1, 1995
Creator: Norby, P.
Partner: UNT Libraries Government Documents Department

Reactions of Attapulgite and Sepiolite in High-Temperature Drilling Fluids

Description: The fibrous clay minerals attapulgite and sepiolite have been subjected to hydrothermal reactions between 149 C (300 F) and 427 C (800 F). A 4% suspension of each of these clays was autoclaved for 16 to 24 hours with and without the addition of salts of NaCl and KC1 at 1% concentration. These fibrous clay minerals start to convert at 204 C (400 F) to a smectite with a lamellar morphology. In fact, attapulgite converts more readily than sepiolite, and the attapulgite-to-smectite transformation is fully completed at 316 C (600 F), whereas 20% to 50% of the sepiolite remains intact at this temperature. The conversion of the fibrous double- and triple-chain silicates of attapulgite and sepiolite to a layered silicate, such as smectite, favorably affects the rheology of the drilling fluids based on these clays. The mechanism of the conversion is, however, different for these fibrous clays. Attapulgite dissolves first and then smectite precipitates whereas this mechanism takes place for sepiolite at 316 C (600 F). Both attapulgite and sepiolite, and their reaction products, have been examined with an analytical electron microscope (JEM-100CX) in TEM, STEM, SEM, and SAD modes. The intensities of the characteristic X-ray spectra for the elements Mg, Al, Si, Fe, Ca, and K are measured. These observations indicate that (1) significant chemical differences exist between the fibrous clays and the smectites formed from them and (2) morphological features of the smectites vary with the temperature and with the presence of the salts in the system.
Date: January 1, 1981
Creator: Guven, N.; Carney, L. L. & Lee, L-J
Partner: UNT Libraries Government Documents Department

Geological Results from Drilling in the Poihipi (Western) Sector of the Wairakei Geothermal Field, NZ

Description: Four wells drilled into the Poihipi Sector on the Western margin of the Wairakei geothermal field have found a similar lithostratigraphy to that encountered in wells previously drilled in the general area. Young pumice breccias overly the Huka Falls Formation, with the latter containing intercalations of the Rautehuia Breccia. This in turn overlies ignimbrites and tuffaceous sediments of the Waiora Formation, which contains flows of Haparangi Rhyolite. This sequence is cut by steeply dipping normal faults which strike to the northeast and for the most part dip towards the northwest. Hydrothermal alteration is virtually limited to the Waiora and Haparangi units where a sequence of interlayered illite-smectite and illite clays are found along with chlorite, quartz, pyrite and calcite. There is a minor occurrence of zeolites. Despite large changes in the area's hydrology in response to exploitation, changes in alteration are limited to a comparatively deep occurrence of kaolinite and minor overprinting of epidote by illitic clay.
Date: January 1, 1995
Creator: Bogie, I.; Lawless, J.V. & MacKenzie, K.M.
Partner: UNT Libraries Government Documents Department

Application of magnetic method to assess the extent of high temperature geothermal reservoirs

Description: The extent of thermally altered rocks in high temperature geothermal reservoirs hosted by young volcanic rocks can be assessed from magnetic surveys. Magnetic anomalies associated with many geothermal field in New Zealand and Indonesia can be interpreted in terms of thick (up to 1 km) demagnetized reservoir rocks. Demagnetization of these rocks has been confirmed by core studies and is caused by hydrothermal alteration produced from fluid/rock interactions. Models of the demagnetized Wairakei (NZ) and Kamojang (Indonesia) reservoirs are presented which include the productive areas. Magnetic surveys give fast and economical investigations of high temperature prospects if measurements are made from the air. The magnetic interpretation models can provide important constraints for reservoir models. Magnetic ground surveys can also be used to assess the extent of concealed near surface alteration which can be used in site selection of engineering structures.
Date: January 26, 1995
Creator: Soengkono, S. & Hochstein, M.P.
Partner: UNT Libraries Government Documents Department

GPK-2 re-entry and deepening -- a technical report

Description: Between mid February to end of May 1999 (in 104 days) the well GPK2 at the Soultz HDR site was successfully re-entered and deepened from 3876 m to a final depth of 5084 m and fully completed. Re-entry included the pulling of the existing 321 1 m long internal 9 5/8-inch by 7-inch casing string, fishing of a submersible pump and some 150 m of 2 3/8-inch tubing, sealing of a major loss zone and opening of a 6 1/4-inch well section in granite (3211-3876 m) to 8 1/2-inch hole size. The well was extended to 5048 m in 8 1/2'' hole size and again completed with a floating 9 5/8-inch by 7-inch casing string. The casing shoe is at 4431 m. A bottom hole core was taken in the depth range 5048-5051 m. The core recovery was app. 40%. A pilot hole in 6 1/4-inch was drilled from 5051-5084 m for in situ stress measurements using the hydraulic fracturing technique. The re-entry and deepening of the well GPK2 was accompanied by several technical developments. New casing packer elements based on inflatable metal shells were developed in a close cooperation between SOCOMINE and MeSy GmbH (patent pending). These packer elements were successfully integrated into the completion of the well. The full weight of the casing string is supported by these elements which are filled with and imbedded in cement. High temperature cementing strategies (up to 170-190 C) for the complex saline fluids encountered in Soultz (High Magnesium Resistant Cements) were developed in a cooperation between Schlumberger Dowell (Vechta), SOCOMINE, SII of Houston, Ruhr-University Bochum, BGR Hannover and IFP Paris. The development of several high temperature logging tools (200 C range, 6-arm caliper, PTF probe) was initiated with CSMA (Cornwall) during the preparation of the deepening of GPK2. Initial scientific investigations ...
Date: January 1, 1999
Creator: Baumgartner, J.; Gerard, A.; Barla, R. & Socomine, S.A.
Partner: UNT Libraries Government Documents Department

Hydrothermally altered and fractured granite as an HDR reservoir in the EPS-1 borehole, Alsace,

Description: As part of the European Hot Dry Rocks Project, a second exploration borehole, EPS-1, has been cored to a depth of 2227 m at Soultz-sous-Forets (France). The target was a granite beginning at 1417 m depth, overlain by post-Paleozoic sedimentary cover. Structural analysis and petrographic examination of the 800-m porphyritic granite core, have shown that this rock has undergone several periods of hydrothermal alteration and fracturing. More than 3000 natural structures were recorded, whose distribution pattern shows clusters where low-density fracture zones (less than 1 per meter) alternate with zones of high fracture density (more than 20 per meter). Vein alteration, ascribed to paleohydrothermal systems, developed within the hydrothermally altered and highly fractured zones, transforming primary biotite and plagioclase into clay minerals. One of these zones at 2.2 km depth produced a hot-water outflow during coring, indicating the existence of a hydrothermal reservoir. Its permeability is provided by the fracture network and by secondary porosity of the granitic matrix resulting from vein alteration. This dual porosity in the HDR granite reservoir must be taken into account in the design of the heat exchanger, both for modeling the water-rock interactions and for hydraulic testing.
Date: January 1, 1992
Creator: Genter, A. & Traineau, H.
Partner: UNT Libraries Government Documents Department