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The development of precipitated iron catalysts with improved stability

Description: The objective of this program is to identify the chemical principles governing the deactivation of precipitated iron catalysts during Fischer-Tropsch synthesis and to use these chemical principles in the design of catalysts suitable for slurry reactors. The performance targets are 88% CO+H{sub 2} conversion with less than 1% deactivation/day for 1 month and a methane and ethane selectivity of no more than 7% (based on hydrocarbons and oxygenates only) at a space velocity of at least 2 normal li… more
Date: May 6, 1992
Creator: Abrevaya, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Photoinduced Charge Separation by Polymer-Bound Chromophores

Description: This project has examined the photodynamic behavior of water-soluble polymers that have covalently linked hydrophobic chromophores spaced along the chains. These polymeric systems have been examined for photoinduced charge separation with electron-accepting ions having different total charge. Focus has been on the excited singlet (S{sub 1}) state formed by laser flash absorption. The effects of pH and ionic strength -- factors that govern the conformational nature of the polymer in solution -- … more
Date: September 1, 1991
Creator: Rodgers, M. A. J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Solar-thermal energy conversion and storage: cyclohexane dehydrogenation. Progress report, 30 September 1977-30 June 1978

Description: The objective of this project is to provide research support for the benzene/cyclohexane heat pipe development program at Sandia. The kinetics of the cyclohexane decomposition (energy collection) reaction over a commercially available naphtha reforming catalyst (RD-150, Englehard Industries) in the temperature range 400 to 800/sup 0/F and pressures of 1 to 40 atmospheres were measured. Significant amounts of side products such as toluene and butane were identified at temperatures above 550/sup … more
Date: July 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Importance of the specific heat anomaly in the design of binary Rankine cycle power plants

Description: The transposed critical temperature (TPCT) is shown to be an extremely important thermodynamic property in the selection of working fluids and turbine states for geothermal power plants operating on a closed organic (binary) Rankine cycle. When the optimum working fluid composition and process states are determined for specified source and sink conditions, turbine inlet states consistently lie adjacent to the working fluids' TPCT line for all resource temperatures, constraints, and cost and eff… more
Date: May 1, 1980
Creator: Pope, W.L.; Doyle, P.A.; Fulton, R.L. & Silvester, L.F.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

Vacuum ultraviolet electronic properties of liquids. Annual progress report, 1 November 1979-31 October 1980

Description: Areas covered are: optical and dielectric properties of hexamethyl-phosphoric triamide; photoemission from uv irradiated liquids; photon and photoelectron mean free paths in liquids; properties of Kapton films; and uv transmission of polycyclic organic molecules. (GHT)
Date: January 1, 1980
Creator: Painter, L.R.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Development of a mathematical model of a packed column for benzene removal from salt solutions

Description: A mathematical model of a packed column was developed to describe the removal of benzene from radioactive salt solutions at the Savannah River Site. The model was developed from existing, generalized mass transfer correlations for randomly dumped packing, and the correlations were adapted for structured packing. Thermophysical data specific to the solutions of interest were incorporated into the model. Verification of the code was completed using operating data from stripping columns at other l… more
Date: January 1, 1989
Creator: Georgeton, G.K.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
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Establishment of viscometer capability for geopressured fluids. Project 61024 final report, November 19, 1978-December 31, 1979

Description: The feasibility of modifying the IGT capillary viscometer for the measurement of methane-saturated brines at 10,000 psi and 200/sup 0/C was evaluated. The viscometer was cleaned, modified, reassembled and pressure treated. The density cells were calibrated to a precision of approximately 7%. The viscosity of pure value was measured and the best value obtained was 6% below values reported in the literature. The operation of the viscometer was time-consuming and required meticulous cleaning betwe… more
Date: October 1, 1980
Creator: Rockar, E. & Randolph, P.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Energy from biological processes

Description: This assessment responds to a request by the Senate Committee on Commerce, Science, and Transportation for an evaluation of the energy potential of various sources of plant and animal matter (biomass). This report complements an earlier OTA report on the Application of Solar Technology to Today's Energy Needs in evaluating the major solar energy resources available to the United States. The findings also will serve as part of the material to be used in an upcoming OTA assessment of synthetic fu… more
Date: July 1, 1980
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

NQR-NMR studies of higher alcohol synthesis Cu-Co catalysts

Description: Copper and cobalt are the key elements in syngas conversion catalyst systems used for higher alcohol synthesis. Their proximity and synergy sensitively control the selectivity and efficiency of the process. It is believed that their outer electronic charge distribution which is responsible for their electrical and magnetic properties might be governing their catalytic properties also. To examine the correlation between catalytic and magnetic properties, a series of copper cobalt catalysts (Co/C… more
Date: January 14, 1991
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Methane oxidation over dual redox catalysts

Description: Review and analysis of the literature data on electron transfer itself and electron transfer oxidation of alkyl radicals was done in order to understand the mechanism by which methyl radical can be oxidized to CH{sub 3}{sup +} and further substituted by OH{sup {minus}} to form methanol. This allowed to compare and classify the various possible reaction patterns, understand the mechanism and circumstances of operation of each of them and select those which can be involved in oxidation of methyl … more
Date: March 1, 1989
Creator: Klier, Kamil; Herman, Richard G. & Sojka, Zvigniew
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Energy Program annual report

Description: The national economy is particularly dependent on efficient electrical generation and transportation. Electrical demand continues to grow and will increasingly rely on coal and nuclear fuels. The nuclear power industry still has not found a solution to the problem of disposing of the waste produced by nuclear reactors. Although coal is in ample supply and the infrastructure is in place for its utilization, environmental problems and improved conversion processes remain technical challenges. In … more
Date: February 1, 1988
Creator: Borg, I.Y. (ed.)
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Energy and protein production from pulp mill wastes. Progress report, June 15, 1977--September 15, 1977

Description: Experiments conducted during this past quarter demonstrated the decided difference both in amount and composition of the gas produced from the fermentation of ozonated versus unozonated yeast-plant SSL. Gas from ozonated SSL averaged over 80% methane content while unozonated effluent was mostly carbon dioxide. Gas production rates and retention time studies indicated that the fermentation was substrate-limited. Preliminary tests using supplemental carbon sources have verified this. The success … more
Date: September 15, 1977
Creator: Jurgensen, M. F. & Patton, J. T.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Thermo-chemical energy conversion and storage. Final report

Description: Research support for the cyclohexane/benzene heat pipe development program at Sandia Laboratories is reported. The apparent kinetics of the gas-phase catalytic dehydrogenation of cyclohexane to benzene in an internally recirculated (gradientless) reactor over the temperature range from 500 to 800/sup 0/F at 1 atm at various space velocities was studied. A kinetic model was developed based on a reversible mass-action rate expression and a catalyst effectiveness factor which is able to correlate … more
Date: September 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

H-Area Seepage Basins

Description: During the third quarter of 1990 the wells which make up the H-Area Seepage Basins (H-HWMF) monitoring network were sampled. Laboratory analyses were performed to measure levels of hazardous constituents, indicator parameters, tritium, nonvolatile beta, and gross alpha. A Gas Chromatograph Mass Spectrometer (GCMS) scan was performed on all wells sampled to determine any hazardous organic constituents present in the groundwater. The primary contaminants observed at wells monitoring the H-Area Se… more
Date: December 1, 1990
Creator: Stejskal, G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Kilowatt Isotope Power System: component report for the Ground Demonstration System Accumulator

Description: The Model Number ORC1A3A01 System Accumulator for the Kilowatt Isotope Power System was expulsion tested and demonstrated to be in compliance with the requirements of Sundstrand Explusion Test Procedure, TP 400. Test requirements of TP 400 were extracted from the Kilowatt Isotope Power System, Ground Demonstration System Test Plan.
Date: January 31, 1978
Creator: Brainard, E.L.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Development of BEACON technology. Quarterly report, April-June 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. Experiments were continued this quarter with the objective of improving the carbon deposition efficiency using a Paraho retort off-gas mixture. Analysis has shown that the use of the Paraho off-gas to make hydrogen would be att… more
Date: March 1, 1983
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Cationically polymerizable monomers derived from renewable sources

Description: The objective of this project is to make use of products obtained from renewable plant sources as monomers for the direct production of polymers which can be used for a wide range of plastic applications. In this report is described progress in the synthesis and polymerization of cationically polymerizable monomers and oligomers derived from botanical oils, terpenes, natural rubber, and lignin. Nine different botanical oils were obtained from various sources, characterized and then epoxidized. … more
Date: October 1, 1991
Creator: Crivello, J. V.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Molecular interactions in dilute supercritical mixtures: Molecular dynamics investigation

Description: We performed a series of molecular dynamics simulations aimed at investigating the nature of the microstructure around solute molecules in a supercritical solvent, in the limit of infinite dilution (no solute-solute interactions). The choice of model system (pyrene in supercritical carbon dioxide) and state conditions (5--20 moles/liter; 37{degrees}C and 75{degrees}C) was done so as to match corresponding fluorescence experiments performed at Georgia Tech. 18 refs., 3 figs.
Date: January 1, 1991
Creator: Debenedetti, P.G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Size selective synergism by crown ethers in the extraction of alkali metals by di(2-ethylhexyl) phosphoric acid

Description: Although the macrocyclic polyethers, known as crown ethers, complex metal ions and do so preferentially according to the size correspondance between the ion and the crown ether cavity, their usefulness as liquid-liquid extraction reagents has been limited by the necessity of solubilizing the anion in the organic phase. The common mineral acid anions are difficult to transfer to the organic phase and organophilic anions are expensive or impractical. A method is described that avoids this problem… more
Date: January 1, 1980
Creator: McDowell, W.J.; Kinard, W.F. & Shoun, R.R.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

Comparative mutagenesis of human cells in vivo and in vitro

Description: This report discusses measuring methods of point mutations; high density cell cultures for low dose studies; measurement and sequence determination of mutations in DNA; the mutational spectra of styrene oxide and ethlyene oxide in TK-6 cells; mutational spectrum of Cr in human lymphoblast cells; mutational spectra of radon in TK-6 cells; and the mutational spectra of smokeless tobacco. (CBS)
Date: May 1, 1992
Creator: Thilly, W.G.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Research on oil recovery mechanisms in heavy oil reservoirs

Description: The goal of the Stanford University Petroleum Research Institute is to conduct research directed toward increasing the recovery of heavy oils. Presently, SUPRI is working in five main directions: To assess the influence of different reservoir conditions (temperature and pressure) on the absolute and relative permeability to oil and water and on capillary pressure; To evaluate the effect of different reservoir parameters on the in-situ combustion process. This project includes the study of the k… more
Date: January 1, 1991
Creator: Brigham, W.E.; Aziz, K. & Ramey, H.J. Jr.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Direct conversion of light hydrocarbon gases to liquid fuel

Description: The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product … more
Date: January 1, 1991
Creator: Foral, M.J.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
open access

Methane entrained in geopressured aquifers, Texas Gulf Coast

Description: Six tests of geopressured aquifers have yielded between 3.6 to 4.5 m/sup 3//m/sup 3/ (20 to 25 scf/bbl) of gas. These low gas concentrations are attributed to high salinities, that in all tests exceeded 100,000 mg/l, but undersaturated conditions cannot be ruled out completely. Research efforts are designed to delineate the geographic and stratigraphic variations in salinity and to recognize regional and local trends so that zones of lower salinity and higher gas concentration can be identified… more
Date: July 1, 1980
Creator: Morton, R. A.
Item Type: Refine your search to only Article
Partner: UNT Libraries Government Documents Department
open access

Application of direct contact heat exchangers to geothermal power production cycles. Project review, December 1, 1974--May 31, 1977

Description: Work performed on the development of direct contact heat exchanger power cycles for geothermal applications is reviewed. The period covered in the report is from the inception of the project in 1974 through May 31, 1977. Results from a large experimental program on heat exchanger develpment as well as from many analyses of components and cycle performance and economics are given. A number of working fluids and operating conditions have been considered, and no major obstacles for the implementat… more
Date: January 1, 1977
Creator: Jacobs, H. R.; Boehm, R. F. & Hansen, A. C.
Item Type: Refine your search to only Report
Partner: UNT Libraries Government Documents Department
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