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Testing program for determining the mechanical properties of concrete to temperatures of 621/sup 0/C

Description: Concrete temperatures in a Liquid Metal Fast Breeder Reactor (LMFBR) in excess of normal code limits can result from postulated large sodium spills in equipment cells. Elevated temperature concrete property data which may have application for providing a basis for the design and evaluation of such postulated accident conditions is limited. Data thus needed to be developed commensurate with LMFBR plant applications for critical physical and mechanical concrete properties under prototypic thermal… more
Date: January 1, 1980
Creator: Oland, C.B.; Naus, D.J. & Robinson, G.C.
Partner: UNT Libraries Government Documents Department
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Thermo-chemical energy conversion and storage. Final report

Description: Research support for the cyclohexane/benzene heat pipe development program at Sandia Laboratories is reported. The apparent kinetics of the gas-phase catalytic dehydrogenation of cyclohexane to benzene in an internally recirculated (gradientless) reactor over the temperature range from 500 to 800/sup 0/F at 1 atm at various space velocities was studied. A kinetic model was developed based on a reversible mass-action rate expression and a catalyst effectiveness factor which is able to correlate … more
Date: September 1, 1978
Creator: Ritter, A.B.; DeLancey, G.B.; Schneider, J. & Silla, H.
Partner: UNT Libraries Government Documents Department
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Thermodynamics of natural and industrial waters

Description: The most effective general formulations of thermodynamic equations for multicomponent aqueous solutions are discussed with respect to various ranges of temperature, pressure and composition with emphasis on solutes important in natural or industrial waters. A familiar equation in molality and in excess Gibbs energy is very successful up to 300{degree}C and ionic strength 6 mol{center dot}kg{sup {minus}1}, and can often be extended to 350{degree}C or above at high pressure and in favorable cases… more
Date: August 1, 1991
Creator: Pitzer, K.S.
Partner: UNT Libraries Government Documents Department
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Oxidation/gasification of carbon residue on retorted oil shale. Final report

Description: Studies of the oxidation and gasification of oil shale char were extended to an investigation of the effects of mineral catalysis. Six shales with differing mineral compositions were studied, including samples from the saline zone in the Western Colorado and from the Antrim shales of Michigan. Oxidation kinetics data, corrected for mass transfer effects, were compared for all six samples. A high assay shale from Utah and a sample from the saline zone were found to have the highest oxidation rat… more
Date: January 16, 1984
Creator: Thomson, W. J.
Partner: UNT Libraries Government Documents Department
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Development of passive electronic components for instrumentation of improved geothermal logging tools and components. Annual progress report

Description: Short term objectives for well-logging instrumentation are circuits which can operate at temperatures in the range 275/sup 0/C to 350/sup 0/C; the medium term goal is operation up to 500/sup 0/C, and the long term goal is to achieve operation at 1000/sup 0/C. It is apparent that useful electronic circuits will require the combination of both passive components and active devices. In order to meet the compatibility requirements, the basic technology which has been selected in this project is the… more
Date: October 20, 1977
Creator: Raymond, L.S.; Hamilton, D.J. & Kerwin, W.J.
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, April-June 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. Experiments were continued this quarter with the objective of improving the carbon deposition efficiency using a Paraho retort off-gas mixture. Analysis has shown that the use of the Paraho off-gas to make hydrogen would be att… more
Date: March 1, 1983
Partner: UNT Libraries Government Documents Department
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Advanced materials for geothermal energy processes

Description: The primary goal of the geothermal materials program is to ensure that the private sector development of geothermal energy resources is not constrained by the availability of technologically and economically viable materials of construction. This requires the performance of long-term high risk GHTD-sponsored materials R and D. Ongoing programs described include high temperature elastomers for dynamic sealing applications, advanced materials for lost circulation control, waste utilization and di… more
Date: August 1, 1985
Creator: Kukacka, L. E.
Partner: UNT Libraries Government Documents Department
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Spectrophotometric studies of solutions at elevated temperatures and pressures: status and program for FY1961 and part of FY 1962

Description: A program was initiated on the spectrophotometric study of aqueous solution chemistry. The goal is operation at temperatures up to at least 330 deg C and at pressures up to 200 atm, and to near the critical point if this appears to be feasible. A spectrometer capable of operation under these extreme conditions is being designed. (W.L.H.)
Date: July 19, 1960
Creator: Biggers, R. E. & Chilton, J. M.
Partner: UNT Libraries Government Documents Department
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Screening study on high temperature energy transport systems

Description: The purpose of the study described in this document is to identify the options for transporting thermal energy over long distances. The study deals specifically and exclusively with high temperature (> 400/sup 0/C(752/sup 0/F)) energy for industrial use. Energy transport is seen as a potential solution to: high unit cost of small coal and nuclear steam generators, and opposition to siting of coal or nuclear plants near populated areas. The study is of a preliminary nature but covers many option… more
Date: October 1, 1980
Creator: Graves, R.L.
Partner: UNT Libraries Government Documents Department
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Drilling fluid/formation interaction at simulated in situ geothermal conditions. Final report

Description: Interaction of drilling fluids with a geothermal reservoir formation can result in significant permeability impairment and therefore reduced well productivity. This interaction is studied under simulated in situ geothermal conditions of overburden stress, pore fluid pressure, temperature, and pore fluid chemistry. Permeability impairment of an East Mesa KGRA reservoir material is evaluated as a function of stagnation time, drilling fluid, and temperature. Results indicate that all of these para… more
Date: July 1, 1980
Creator: Enniss, D. O.; Bergosh, J. L.; Butters, S. W. & Jones, A. H.
Partner: UNT Libraries Government Documents Department
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Surface damage of molybdenum and TZM alloy under D/sup +/ impact

Description: The surface damage of polycrystalline molybdenum and TZM alloy under 40-, 60-, and 120-keV D/sup +/ impact has been investigated for irradiation in both pulsed and continuous mode for total doses varying from 1.7 x 10/sup 17/ to 2.2 x 10/sup 19/ ions/cm/sup 2/ and for target temperatures verying from ambient temperature to 400/sup 0/C. Analysis by scanning electron microscopy of the MO samples held at ambient temperatures during D/sup +/ irradiations in both pulsed and continuous modes revealed… more
Date: January 1, 1977
Creator: Das, S.K.; Kaminsky, M. & Dusza, P.
Partner: UNT Libraries Government Documents Department
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Development of BEACON technology. Quarterly report, October-December 1982

Description: The BEACON process involves the catalytic deposition of a highly reactive form of carbon from a gas stream which contains carbon monoxide. The carbon-depleted gas is combusted with air to produce power, and the carbon is reacted with steam to produce methane or hydrogen. During the quarter both SOHIO and TRW worked on catalysts which would suppress methane formation during steaming thus increasing the amount of hydrogen formed. At SOHIO a C77-K2 catalyst promoted with a Class II compound showed… more
Date: April 1, 1983
Partner: UNT Libraries Government Documents Department
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Volatilities of ruthenium, iodine, and technetium on calcining fission product nitrate wastes

Description: Various high-level nitrate wastes were subjected to formic acid denitration. Formic acid reacts with the nitrate anion to yield noncondensable, inert gases according to the following equation: 4 HCOOH + 2 HNO/sub 3/ ..-->.. N/sub 2/O + 4 CO/sub 2/ + 5 H/sub 2/O. These gases can be scrubbed free of /sup 106/Ru, /sup 131/I, and /sup 99/Tc radioactivities prior to elimination from the plant by passage through HEPA filters. The formation of deleterious NO/sub x/ is avoided. Moreover, formic acid re… more
Date: January 1, 1980
Creator: Rimshaw, S. J. & Case, F. N.
Partner: UNT Libraries Government Documents Department
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High temperature fuel cell research and development. Final technical status report, 1 March 1979-31 March 1980. [Molten carbonate fuel cells]

Description: The objective of the program has been to evaluate potential materials for their chemical and physical stability in molten carbonate fuel cell electrolyte. Eleven powdered candidate materials were selected based on previous physical and chemical stability tests at elevated temperatures on solid materials and/or their thermodynamic stability with respect to proposed degradation reactions. The eleven candidate materials, plus gamma lithium aluminate, were characterized prior to corrosion testing u… more
Date: May 1, 1980
Creator: Lessing, P.A.
Partner: UNT Libraries Government Documents Department
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Phase Transformations in Alumina. Technical Report, May to December 1961

Description: e transformation studies showed that synthetic aluminas produced in the laboratory were not transformed to alpha alumina at 400 to 700' deg n the presence of nitric acid and water vapor. Amorphous aluminn produced in the pilot plant was transformed to alpha alumina. This indicated that the amorphous alumina produced in the pilot plant is structurally predisposed to form alpha alumina. Most additives did not appear to have any special effects. Lithium formed zeta alumina, LiAl/sub 5/O/sub 8/. Ph… more
Date: December 1, 1961
Creator: Eding, H J; Huggins, M L & Brown, A G
Partner: UNT Libraries Government Documents Department
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Superacid Catalyzed Coal Conversion Chemistry. 1st and 2nd Quarterly Technical Progress Reports, September 1, 1983-March 30, 1984. [Model Compound Consisting of 2 Benzene Rings Connected With Various Bridging Units Such as Alkylidene, Ether, Sulfide, Etc]

Description: In our laboratories we have previously developed a mild coal conversion process. This involves the use of a superacid system consisting of HF and BF/sub 3/ in presence of hydrogen and/or a hydrogen donor solvent. In order to understand the chemistry involved in the process of depolymerization of coal by the HF:BF/sub 3/:H/sub 2/ system we are carrying out a systematic study of a number of coal model compounds. The model compounds selected for present study have two benzene rings connected with … more
Date: January 1, 1984
Creator: Olah, G.A.
Partner: UNT Libraries Government Documents Department
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Enthalpy measurement of coal-derived liquids. Quarterly technical progress report, July-September 1980

Description: Equipment modifications to a Freon 11 boil-off type calorimeter are described. The calorimetric system was used to measure the enthalpies of thiophene experimentally. Data were taken over a temperature range of 100/sup 0/F to 750/sup 0/F at pressures of 50, 100, 200, 400, 600, 825.9 (the critical), 1000, and 1500 psia. Thermodynamic properties derived from the data are compared to values in the literature, and the agreement is exceptionally good. The data are then compared directly to results c… more
Date: September 15, 1980
Creator: Kidnay, A. J. & Yesavage, V. F.
Partner: UNT Libraries Government Documents Department
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Organic iodine removal from simulated dissolver off-gas streams using partially exchanged silver mordenite

Description: The removal of methyl iodide by adsorption onto silver mordenite was studied using a simulated off-gas from the fuel dissolution step of a nuclear fuel reprocessing plant. The methyl iodide adsorption of partially exchanged silver mordenite was examined for the effects of NO/sub x/, humidity, filter temperature, and degree of silver exchange. Partially exchanged silver mordenite, in general, achieved significantly higher silver utilizations than the fully exchanged material. Silver utilizations… more
Date: January 1, 1982
Creator: Jubin, R. T.
Partner: UNT Libraries Government Documents Department
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Voloxidation studies with UO/sub 2/ reactor fuels

Description: Voloxidation was studied experimentally in small-scale laboratory tests with irradiated UO/sub 2/ reactor fuels. The present study developed new data on the effects on the voloxidation reaction of hull length, oxygen concentration, temperature, agitation, fuel density, and fuel type and burnup. The reaction was studied by measuring weight gains, yields of U/sub 3/O/sub 8/, product densities and particle-size distributions, reaction rates, tritium release, and behavior of other off-gases (/sup 1… more
Date: January 1, 1980
Creator: Stone, J A
Partner: UNT Libraries Government Documents Department
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Multi-temperature gas chromatography using isothermal columns in series. Technical report

Description: A computer-controlled three-oven gas chromatograph having a multi-position stream-switching valve has been used first to divide a wide-boiling mixture of n-alkanes into three cuts and then to fractionate each cut using a packed column at a different temperature. After initial injection of the sample into the highest temperature column, the low boilers were switched to a low temperature oven. Then, the mid-boilers were switched to a column at an intermediate temperature. For routine repetitive a… more
Date: August 11, 1980
Creator: Spencer, W. A. & Rogers, L. B.
Partner: UNT Libraries Government Documents Department
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