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Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report

Description: The primary objectives of this work can be summed into two major categories. Firstly, the fundamentals of the combustion of glycerol (in both a refined and unrefined form) were to be investigated, with emphasis of the development of a system capable of reliably and repeatedly combusting glycerol as well as an analysis of the emissions produced during glycerol combustion. Focus was placed on quantifying common emissions in comparison to more traditional fuels and this work showed that the burner developed was able to completely combust glycerol within a relatively wide range of operating conditions. Additionally, focus was placed on examining specific emissions in more detail, namely interesting NOx emissions observed in initial trials, acrolein and other volatile organic emissions, and particulate and ash emissions. This work showed that the combustion of crude glycerol could result in significantly reduced NOx emissions as a function of the high fuel bound oxygen content within the glycerol fuel. It also showed that when burned properly, the combustion of crude glycerol did not result in excessive emissions of acrolein or any other VOC compared to the combustion from more traditional fuels. Lastly however, this work has shown that in any practical application in which glycerol is being burned, it will be necessary to explore ash mitigation techniques due to the very high particulate matter concentrations produced during glycerol combustion. These emissions are comparable to unfiltered coal combustion and are directly tied to the biodiesel production method. The second focus of this work was directed to developing a commercialization strategy for the use of glycerol as a fuel replacement. This strategy has identified a 30 month plan for the scaling up of the laboratory scale burner into a pre-pilot scale system. Additionally, financing options were explored and an assessment was made of the economics of replacing ...
Date: October 31, 2012
Creator: ROberts, William L.
Partner: UNT Libraries Government Documents Department

Final Project Report Project 10749- 2007-2009

Description: This is the final report for the DOE Project 10749- for the FY2007 - FY2009 period. This report is non-proprietary, and will be submitted to DOE as a final project report. The report covers activities under the DOE Project inside CRADA 269 (Project 53231) as well as project activites outside of that CRADA (Project 56662). This is the final report that is summarized from the non-proprietary quarterlies submitted to DOE over the past 2.5 years, which in turn are summaries from the proprietary technical reporting to UOP.
Date: May 11, 2009
Creator: Zacher, Alan H.; Holladay, Johnathan E.; Frye, J. G.; Brown, Heather M.; Santosa, Daniel M. & Oberg, Aaron A.
Partner: UNT Libraries Government Documents Department

High Activity catalysts for Polyols Production From C-6 Sugars

Description: Over the course of this project, many significant discoveries have been made in the process for the conversion of sorbitol to value added products. The object was developing a process for the production of propylene glycol (PG), ethylene glycol (EG), and glycerol from sorbitol.
Date: May 6, 2003
Creator: Werpy, Todd; Zacher, Alan; Frye, John; Peterson, Keith; Neuenschwander, Gary; Alderson, Eric et al.
Partner: UNT Libraries Government Documents Department

Long-distance communication and signal amplication in systemic acquired resistance

Description: This review article summarizes the involvement and interaction between long-distance systemic acquired resistance (SAR) signals and details the recently discovered role of lysine catabolite pipecolic acid (Pip) in defense amplification and priming that allows plants to acquire immunity at the systemic level.
Date: February 22, 2013
Creator: Shah, Jyoti & Zeier, J├╝rgen
Partner: UNT College of Arts and Sciences

Structural and compositional modifications in lignin of transgenic alfalfa down-regulated in caffeic acid 3-O-methyltransferase and caffeoyl coenzyme A 3-O-methyltransferase

Description: Article on the structural and compositional modifications in lignin of transgenic alfalfa down-regulated in caffeic acid 3-O-methyltransferase and caffeoyl coenzyme A 3-O-methyltransferase.
Date: July 8, 2002
Creator: Marita, Jane M.; Ralph, John; Hatfield, Ronald D.; Guo, Dianjing; Chen, Fang & Dixon, R. A.
Partner: UNT College of Arts and Sciences

Investigation of the effect of coal particle sizes on the interfacial and rheological properties of coal-water slurry fuels. Quarterly report No. 3, January 1, 1996--March 31, 1996

Description: A new sonic airblast atomization system has been designed and constructed to use in atomizing CWS fuels with two to three orders of magnitude higher viscosity values than water. Preliminary studies show that the new system successfully atomizes a glycerol/water solution that is one hundred times more viscous than pure water. This system, together with a constant displacement feed pump, will allow the study of CWS atomization under various surface tension properties, different coal loadings and particle sizes, and different surfactants. 4 figs., 1 tab.
Date: August 1, 1996
Creator: Kihm, K.D.
Partner: UNT Libraries Government Documents Department

Measurement of extensional viscosity using the falling drop technique. Final report, October 27, 1992--September 27, 1996

Description: In the falling drop technique, a drop is formed by slowly extruding a liquid downward through a small tube. The drop eventually falls, and fluid adheres to both the tube and the drop, creating a distinct extending fiber. Extensional viscosity may be determined by measuring the dimensions of the fiber as it extends. The flow of fluid in a falling drop has been modeled in order to determine extensional viscosity by measuring the extending fiber. A falling drop rheometer was built, and fiber dimensions were measured using two digital cameras and an image processing system. Extensional viscosity was measured for various solutions of glycerol, xanthan gum, and water. The falling drop technique proved to be an effective extensional rheometer for a range of solution concentrations. 6 refs., 3 figs., 1 tab.
Date: February 1, 1998
Creator: Jones, D.K. & Wildman, D.J.
Partner: UNT Libraries Government Documents Department

Low Temperature Polymeric Precursor Derived Zinc Oxide Thin Films

Description: Zinc oxide (ZnO) is a versatile environmentally benign II-VI direct wide band gap semiconductor with several technologically plausible applications such as transparent conducting oxide in flat panel and flexible displays. Hence, ZnO thin films have to be processed below the glass transition temperatures of polymeric substrates used in flexible displays. ZnO thin films were synthesized via aqueous polymeric precursor process by different metallic salt routes using ethylene glycol, glycerol, citric acid, and ethylene diamine tetraacetic acid (EDTA) as chelating agents. ZnO thin films, derived from ethylene glycol based polymeric precursor, exhibit flower-like morphology whereas thin films derived of other precursors illustrate crack free nanocrystalline films. ZnO thin films on sapphire substrates show an increase in preferential orientation along the (002) plane with increase in annealing temperature. The polymeric precursors have also been used in fabricating maskless patterned ZnO thin films in a single step using the commercial Maskless Mesoscale Materials Deposition system.
Date: December 2006
Creator: Choppali, Uma
Partner: UNT Libraries

Pestoides F, and Atypical Yersinia pestis Strain from the Former Soviet Union

Description: Unlike the classical Yersinia pestis strains, members of an atypical group of Y. pestis from Central Asia, denominated Y. pestis subspecies caucasica (also known as one of several pestoides types), are distinguished by a number of characteristics including their ability to ferment rhamnose and melibiose, their lacking the small plasmid encoding the plasminogen activator (pla) and pesticin, and their exceptionally large variants of the virulence plasmid pMT (encoding murine toxin and capsular antigen). We have obtained the entire genome sequence of Y. pestis Pestoides F, an isolate from the former Soviet Union that has enabled us to carryout a comprehensive genome-wide comparison of this organism's genomic content against the six published sequences of Y. pestis and their Y. pseudotuberculosis ancestor. Based on classical glycerol fermentation (+ve) and nitrate reduction (+ve) Y. pestis Pestoides F is an isolate that belongs to the biovar antiqua. This strain is unusual in other characteristics such as the fact that it carries a non-consensus V antigen (lcrV) sequence, and that unlike other Pla{sup -} strains, Pestoides F retains virulence by the parenteral and aerosol routes. The chromosome of Pestoides F is 4,517,345 bp in size comprising some 3,936 predicted coding sequences, while its pCD and pMT plasmids are 71,507 bp and 137,010 bp in size respectively. Comparison of chromosome-associated genes in Pestoides F with those in the other sequenced Y. pestis strains, reveals a series of differences ranging from strain-specific rearrangements, insertions, deletions, single nucleotide polymorphisms, and a unique distribution of insertion sequences. There is a single {approx}7 kb unique region in the chromosome not found in any of the completed Y. pestis strains sequenced to date, but which is present in the Y. pseudotuberculosis ancestor. Taken together, these findings are consistent with Pestoides F being derived from the most ancient lineage of Y. pestis ...
Date: January 5, 2007
Creator: Garcia, E.; Worsham, P.; Bearden, S.; Malfatti, S.; Lang, D.; Larimer, F. et al.
Partner: UNT Libraries Government Documents Department

Measurement and Analysis of Gas Bubbles Near a Reference Electrode in Aqueous Solutions

Description: Bubble size distributions (BSDs) near a reference electrode (RE) in aqueous glycerol solutions of an electrolyte NaCl have been investigated under various gas superficial velocities (U{sub S}). BSD and voltage reading of the solution were measured by using a high-speed digital camera and a pH/voltage meter, respectively. The results show that bubble size (b) increases with liquid viscosity ({mu}{sub c}) and U{sub S}. Self-similarity is seen and can be described by the log-normal form of the continuous number frequency distribution. The result shows that b controls the voltage reading in each solution. As b increases, the voltage increases because of gas bubbles interrupting their electrolyte paths in the solutions. An analysis of bubble rising velocity reveals that Stokes Law should be used cautiously to describe the system. The fundamental equation for bubble formation was developed via Newton's second law of motion and shown to be the function of three dimensionless groups--Weber number, Bond number, and Capillary number. After linking an electrochemical principle in the practical application, the result indicates that the critical bubble size is {approx}177 {micro}m. Further analysis suggests that there may be 3000 to 70,000 bubbles generated on the anode surface depending on the size of initial bubbles and provides the potential cause of the efficiency drop observed in the practical application.
Date: October 1, 2005
Creator: Phongikaroon, Supathorn; Herrmann, Steve; Li, Shelly & Simpson, Michael
Partner: UNT Libraries Government Documents Department

Genomic Prospecting for Microbial Biodiesel Production

Description: Biodiesel is defined as fatty acid mono-alkylesters and is produced from triacylglycerols. In the current article we provide an overview of the structure, diversity and regulation of the metabolic pathways leading to intracellular fatty acid and triacylglycerol accumulation in three types of organisms (bacteria, algae and fungi) of potential biotechnological interest and discuss possible intervention points to increase the cellular lipid content. The key steps that regulate carbon allocation and distribution in lipids include the formation of malonyl-CoA, the synthesis of fatty acids and their attachment onto the glycerol backbone, and the formation of triacylglycerols. The lipid biosynthetic genes and pathways are largely known for select model organisms. Comparative genomics allows the examination of these pathways in organisms of biotechnological interest and reveals the evolution of divergent and yet uncharacterized regulatory mechanisms. Utilization of microbial systems for triacylglycerol and fatty acid production is in its infancy; however, genomic information and technologies combined with synthetic biology concepts provide the opportunity to further exploit microbes for the competitive production of biodiesel.
Date: March 20, 2008
Creator: Lykidis, Athanasios; Lykidis, Athanasios & Ivanova, Natalia
Partner: UNT Libraries Government Documents Department

Reactive Membrane Barriers for Containment of Subsurface Contamination

Description: The overall goal of this project was to develop reactive membrane barriers--a new and flexible technique to contain and stabilize subsurface contaminants. Polymer membranes will leak once a contaminant is able to diffuse through the membrane. By incorporating a reactive material in the polymer, however, the contaminant is degraded or immobilized within the membrane. These processes increase the time for contaminants to breakthrough the barrier (i.e. the lag time) and can dramatically extend barrier lifetimes. In this work, reactive barrier membranes containing zero-valent iron (Fe{sup 0}) or crystalline silicotitanate (CST) were developed to prevent the migration of chlorinated solvents and cesium-137, respectively. These studies were complemented by the development of models quantifying the leakage/kill time of reactive membranes and describing the behavior of products produced via the reactions within the membranes. First, poly(vinyl alcohol) (PVA) membranes containing Fe{sup 0} and CST were prepared and tested. Although PVA is not useful in practical applications, it allows experiments to be performed rapidly and the results to be compared to theory. For copper ions (Cu{sup 2+}) and carbon tetrachloride, the barrier was effective, increasing the time to breakthrough over 300 times. Even better performance was expected, and the percentage of the iron used in the reaction with the contaminants was determined. For cesium, the CST laden membranes increased lag times more than 30 times, and performed better than theoretical predictions. A modified theory was developed for ion exchangers in reactive membranes to explain this result. With the PVA membranes, the effect of a groundwater matrix on barrier performance was tested. Using Hanford groundwater, the performance of Fe{sup 0} barriers decreased compared to solutions containing a pH buffer and high levels of chloride (both of which promote iron reactivity). For the CST bearing membrane, performance improved by a factor of three when groundwater was ...
Date: February 26, 2007
Creator: Arnold, William A. & Cussler, Edward L.
Partner: UNT Libraries Government Documents Department

Top Value Added Chemicals From Biomass: I. Results of Screening for Potential Candidates from Sugars and Synthesis Gas

Description: This report identifies twelve building block chemicals that can be produced from sugars via biological or chemical conversions. The twelve building blocks can be subsequently converted to a number of high-value bio-based chemicals or materials. Building block chemicals, as considered for this analysis, are molecules with multiple functional groups that possess the potential to be transformed into new families of useful molecules. The twelve sugar-based building blocks are 1,4-diacids (succinic, fumaric and malic), 2,5-furan dicarboxylic acid, 3-hydroxy propionic acid, aspartic acid, glucaric acid, glutamic acid, itaconic acid, levulinic acid, 3-hydroxybutyrolactone, glycerol, sorbitol, and xylitol/arabinitol. In addition to building blocks, the report outlines the central technical barriers that are preventing the widespread use of biomass for products and chemicals.
Date: November 1, 2004
Creator: Werpy, Todd A.; Holladay, John E. & White, James F.
Partner: UNT Libraries Government Documents Department


Description: In support of Hanford's feed delivery of high level waste (HLW) to the Waste Treatment and Immobilization Plant (WTP), pilot-scale testing and demonstrations with simulants containing cohesive particles were performed as a joint collaboration between Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL) staff. The objective of the demonstrations was to determine the impact that cohesive particle interactions in the simulants, and the resulting non-Newtonian rheology, have on tank mixing and batch transfer of large and dense seed particles. The work addressed the impacts cohesive simulants have on mixing and batch transfer performance in a pilot-scale system. Kaolin slurries with a range of wt% concentrations to vary the Bingham yield stress were used in all the non-Newtonian simulants. To study the effects of just increasing the liquid viscosity (no yield stress) on mixing and batch transfers, a glycerol/water mixture was used. Stainless steel 100 micron particles were used as seed particles due to their density and their contrasting color to the kaolin and glycerol. In support of Hanford's waste certification and delivery of tank waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring tank waste in a Double Shell Tank (DST) to the WTP Receipt Tank. The work addresses the impacts cohesive simulants have on mixing and batch transfer performance. This work is follow-on to the previous tasks 'Demonstration of Mixer Jet Pump Rotational Sensitivity on Mixing and Transfers of the AY-102 Tank' and 'Demonstration of Simulated Waste Transfers from Tank AY-102 to the Hanford Waste Treatment Facility'. The cohesive simulants were investigated and selected jointly by SRNL and PNNL and a white paper was written on this evaluation. The testing and demonstrations of cohesive ...
Date: January 3, 2012
Creator: Adamson, D. & Gauglitz, P.
Partner: UNT Libraries Government Documents Department

Integrated Investigation on the Production and Fate of Organo-Cr(III) Complexes from Microbial Reduction of Chromate

Description: The screening of different genera of bacteria for production of soluble Cr(III) complexes has been completed. A total of eight organisms were screened for production of soluble Cr(III); three were Gram positive and five were Gram negative. The Gram positive bacteria were Cellulomonas sp. ES 6, Rhodococcus sp., and Leafsonia sp., while Shewanella. oneidensis MR 1, Desulfovibrio desulfuricans G20, D. vulgaris Hildenborough, Pseudomonas putida MK 1 and Ps. aeruginosa PAO 1 were Gram negative. S. oneidensis MR 1 and Cellulomonas sp ES 6 were grown in minimal media, GWM (Ground Water Medium with lactate/fumarate) and SGM (Simulated Groundwater Medium with sucrose), respectively. Other bacteria were screened under non-growth conditions with sucrose, lactate, or glycerol as electron donor. All experiments were carried out for a period of 15-30 days, with different organisms reaching a maximum soluble Cr(III) concentrations at different times: S. oneidensis, 2d; Cellulomonas sp., 8d; Leafsonia, 6d; Rhodococcus, 9d; Ps. putida MK 1, 6d, Ps. aeruginosa PAO 1, 3d; D. vulgaris Hildenborough, 3d; and D. desulfuricans G20, 21d. Initial characterization indicates that the soluble Cr(III) fraction produced by both S. oneidensis MR 1 and Cellulomonas sp. ES 6 passes through a 1-Kd cut off filter.
Date: June 1, 2004
Creator: Xun, Luying
Partner: UNT Libraries Government Documents Department

Rheological properties essential for the atomization of Coal Water Slurries (CWS). Final report, September 1, 1991--July 31, 1995

Description: The objective of this study was to understand the effect of low shear, high shear rheology, viscoelastic, and extensional properties on the atomization of CWS. In the atomization studies, the mean drop size of the CWS sprays were determined at various air-to-CWS ratios using a Malvern 2600 particle size analyzer and a Delavan Solid Cone Atomizing Nozzle. Solids-loading, coal particle size distributions, and chemical additives were varied in order to determine the significant properties that influence CWS atomization. A correlation of the mass mean droplet size with high shear, viscoelastic and extensional behaviors were made in order to determine the influence of these parameters on CWS atomization.
Date: December 31, 1995
Creator: Ohene, F.
Partner: UNT Libraries Government Documents Department

Investigation of the effect of coal particle sizes on the interfacial and rheological properties of coal-water slurry fuels. Quarterly report No. 2, October 1, 1995--December 31, 1995

Description: Experiments have been performed to simulate the effects of high viscosity and surface tension of CWS fuel on its atomization. Aqueous solutions of glycerol simulated the high viscosity condition of CWS fuels and ethanol solutions allowed to separately investigate the effect of surface tension. A Fraunhofer diffraction particle sizing technique measured the spatial distribution of Sauter mean diameters (SMDs) for the cross injecting sprays which were previously described in the Quarterly Report No. 1. Experimentally determined parametric correlations reveals the dependence of the spray SMDs on the liquid viscosity, surface tension, the air flow rate, the liquid flow rate, the orifice nozzle diameter, and the measurement locations. This simulated correlation will provide important guidelines for the actual CWS spray experiment to be performed in the successive quarter.
Date: December 31, 1995
Creator: Kihm, K.D.
Partner: UNT Libraries Government Documents Department

Effect of coal beneficiation process on rheology/atomization of coal water slurries. Quarterly progress report, October 1, 1995--December 31, 1995

Description: The overall objective of this project is to perform experiments to understand the effect of coal beneficiation processes and high shear rheological properties on the atomization of coal-water slurries (CWS). In the atomization studies, the mean drop size of the CWS sprays will be determined at various air-to CWS. A correlation between the high shear rheological properties, particle size distributions and the atomization will be made in order to determine the influence of these parameters on the atomization of CWS. During the past quarter, the experimental data obtained from the previous quarter on pressure dependent atomization of coal-water slurries and simulated fluids glycerol-water and glycerol-xanthum gum, were analyzed. The spray data for the glycerol-water and glycerol-xantham gum solution are as shown in Figures 3 and 4. The plots indicate that the Sauter mean diameter (SMD) increase with decrease in Air/Fuel (AFR). Comparison of Figures 3 and 4 indicate that the addition of the xantham gum to the glycerol solution increases the SMD values especially in the low AFR regime. Figure 5 compares SMD data as a function of AFR for the CWS samples under study. The data indicate that the beneficiated CWS samples atomized well, and that the SMD values obtained at all AFR were smaller than the run-off mine CWS sample.
Date: December 31, 1995
Creator: Ohene, F.
Partner: UNT Libraries Government Documents Department

Solution structure of detergent micelles at conditions relevant to membrane protein crystallization.

Description: In this study small angle neutron scattering was used to characterize the formation of micelles in aqueous solutions of the detergents DMG and SPC as a function of detergent concentration and ionic strength of the solvent. The effects on the micelle structure of the additives glycerol and PEG, alone as well as in combination typical for actual membrane protein crystallization, were also explored. This research suggests that the micelles are cigar-like in form at the concentrations studied. The size of the micelles was observed to increase with increasing ionic strength but decrease with the addition of glycerol or PEG.
Date: July 2, 1999
Creator: Littrell, K.; Thiyagarajan, P.; Tiede, D. & Urban, V.
Partner: UNT Libraries Government Documents Department

Analysis of glycerin waste in A-Area sanitary treatment facility material

Description: TNX has a large supply of 55 gallon drums containing pure glycerin and glycerin with additives. The glycerin drums were procured to simulate the glass stream in a pilot-scale melter process at TNX. Since the glycerin was not used for this process, TNX is looking at disposing the material in a sanitary waste treatment facility onsite. The effect of adding the contents of the drums to sewage bacteria was tested. A drum of pure glycerin and a drum of glycerin mixed with lithium chloride were tested. The test consisted of mixing sanitary sludge material with the glycerin material. The purpose of the test was to determine if the glycerin impacted the aerobic bacterial population. The bacterial densities were determined by taking samples from the sludge/glycerin mixtures and using aerobic plate count methods. The total organic carbon (TOC) levels were measured before and after testing. The results indicate that the cell density of the aerobic bacteria increased with the addition of glycerin and the glycerin mixture and the TOC removal rate was different for all tests. Disposal of glycerin in the wastewater treatment facilities should pose no problems. Additional testing and analysis of the mixed samples should be done before its disposal in a waste water treatment facility.
Date: January 1, 1995
Partner: UNT Libraries Government Documents Department

Mississippi State Biodiesel Production Project

Description: Biodiesel is a renewable fuel conventionally generated from vegetable oils and animal fats that conforms to ASTM D6751. Depending on the free fatty acid content of the feedstock, biodiesel is produced via transesterification, esterification, or a combination of these processes. Currently the cost of the feedstock accounts for more than 80% of biodiesel production cost. The main goal of this project was to evaluate and develop non-conventional feedstocks and novel processes for producing biodiesel. One of the most novel and promising feedstocks evaluated involves the use of readily available microorganisms as a lipid source. Municipal wastewater treatment facilities (MWWTF) in the USA produce (dry basis) of microbial sludge annually. This sludge is composed of a variety of organisms, which consume organic matter in wastewater. The content of phospholipids in these cells have been estimated at 24% to 25% of dry mass. Since phospholipids can be transesterified they could serve as a ready source of biodiesel. Examination of the various transesterification methods shows that in situ conversion of lipids to FAMEs provides the highest overall yield of biodiesel. If one assumes a 7.0% overall yield of FAMEs from dry sewage sludge on a weight basis, the cost per gallon of extracted lipid would be $3.11. Since the lipid is converted to FAMEs, also known as biodiesel, in the in Situ extraction process, the product can be used as is for renewable fuel. As transesterification efficiency increases the cost per gallon drops quickly, hitting $2.01 at 15.0% overall yield. An overall yield of 10.0% is required to obtain biodiesel at $2.50 per gallon, allowing it to compete with soybean oil in the marketplace. Twelve plant species with potential for oil production were tested at Mississippi State, MS. Of the species tested, canola, rapeseed and birdseed rape appear to have potential in Mississippi ...
Date: March 20, 2008
Creator: Hernandez, Rafael; French, Todd; Fernando, Sandun; Li, Tingyu; Braasch, Dwane; Silva, Juan et al.
Partner: UNT Libraries Government Documents Department

RELAP5-3D Code Includes Athena Features and Models

Description: Version 2.3 of the RELAP5-3D computer program includes all features and models previously available only in the ATHENA version of the code. These include the addition of new working fluids (i.e., ammonia, blood, carbon dioxide, glycerol, helium, hydrogen, lead-bismuth, lithium, lithium-lead, nitrogen, potassium, sodium, and sodium-potassium) and a magnetohydrodynamic model that expands the capability of the code to model many more thermal-hydraulic systems. In addition to the new working fluids along with the standard working fluid water, one or more noncondensable gases (e.g., air, argon, carbon dioxide, carbon monoxide, helium, hydrogen, krypton, nitrogen, oxygen, sf6, xenon) can be specified as part of the vapor/gas phase of the working fluid. These noncondensable gases were in previous versions of RELAP5- 3D. Recently four molten salts have been added as working fluids to RELAP5-3D Version 2.4, which has had limited release. These molten salts will be in RELAP5-3D Version 2.5, which will have a general release like RELAP5-3D Version 2.3. Applications that use these new features and models are discussed in this paper.
Date: July 1, 2006
Creator: Riemke, Richard A.; Davis, Cliff B. & Schultz, Richard R.
Partner: UNT Libraries Government Documents Department


Description: In support of Hanford's waste certification and delivery of tank waste to the Waste Treatment and Immobilization Plant (WTP), Savannah River National Laboratory (SRNL) was tasked by the Washington River Protection Solutions (WRPS) to evaluate the effectiveness of mixing and transferring tank waste in a Double Shell Tank (DST) to the WTP Receipt Tank. The work discussed in this report (Phase III) address the impacts cohesive simulants have on mixing and batch transfer performance. The objective of the demonstrations performed in Phase III was to determine the impact that cohesive particle interactions in the simulants have on tank mixing using 1/22{sup nd} scale mixing system and batch transfer of seed particles. This testing is intended to provide supporting evidence to the assumption that Hanford Small Scale Mixing Demonstration (SSMD) testing in water is conservative. The batch transfers were made by pumping the simulants from the Mixing Demonstration Tank (MDT) to six Receipt Tanks (RTs), and the consistency in the amount of seed particles in each batch was compared. Tests were conducted with non-Newtonian cohesive simulants with Bingham yield stress ranging from 0.3 Pa to 7 Pa. Kaolin clay and 100 {mu}m stainless steel seed particles were used for all the non-Newtonian simulants. To specifically determine the role of the yield stress on mixing and batch transfer, tests were conducted with a Newtonian mixture of glycerol and water with at viscosity of 6.2 cP that was selected to match the Bingham consistency (high shear rate viscosity) of the higher yield stress kaolin slurries. The water/glycerol mixtures used the same 100 {mu}m stainless steel seed particles. For the transfer demonstrations in Phase III, the mixer jet pumps were operated either at 10.0 gpm (28 ft/s nozzle velocity, U{sub o}D=0.63 ft{sup 2}/s) or 8.0 gpm (22.4 ft/s nozzle velocity, U{sub o}D=0.504 ft{sup 2}/s). ...
Date: August 4, 2011
Creator: Adamson, D.
Partner: UNT Libraries Government Documents Department